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Isolating multiplet structure in 5f inverse photoemission 5f逆光电发射中分离多晶结构
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107779
J.G. Tobin , H. Ramanantoanina , C. Daul , P. Roussel , S.-W. Yu , D. Sokaras , A. Kutepov
{"title":"Isolating multiplet structure in 5f inverse photoemission","authors":"J.G. Tobin ,&nbsp;H. Ramanantoanina ,&nbsp;C. Daul ,&nbsp;P. Roussel ,&nbsp;S.-W. Yu ,&nbsp;D. Sokaras ,&nbsp;A. Kutepov","doi":"10.1016/j.solidstatesciences.2024.107779","DOIUrl":"10.1016/j.solidstatesciences.2024.107779","url":null,"abstract":"<div><div>It is shown herein that the multiplet structure of the 5f<sub>5/2</sub> manifold, caused by angular momentum coupling in the final state, can be extracted from the Inverse Photoelectron Spectroscopy (IPES) and Bremsstrahlung Isochromat Spectroscopy (BIS) of uranium dioxide and plutonium dioxide. Comparisons between the extracted components and x-ray absorption calculations performed using Ligand Field Density Functional Theory (LFDFT) are presented and discussed.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107779"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143149349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of annealing and hydrogenation on the superconducting transition temperature of (TiNbMoTaW)Nx high entropy alloy nitride films 退火和加氢对(TiNbMoTaW)Nx高熵合金氮化膜超导转变温度的影响
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2025.107851
Gabriel Pristáš , Georg C. Gruber , Július Bačkai , Filip Košuth , Lukas Kölbl , Radovan Bureš , Mária Fáberová , Slavomír Gabáni , Oleksandr Onufriienko , Serhii Vorobiov , Christian Mitterer , Karol Flachbart
{"title":"Impact of annealing and hydrogenation on the superconducting transition temperature of (TiNbMoTaW)Nx high entropy alloy nitride films","authors":"Gabriel Pristáš ,&nbsp;Georg C. Gruber ,&nbsp;Július Bačkai ,&nbsp;Filip Košuth ,&nbsp;Lukas Kölbl ,&nbsp;Radovan Bureš ,&nbsp;Mária Fáberová ,&nbsp;Slavomír Gabáni ,&nbsp;Oleksandr Onufriienko ,&nbsp;Serhii Vorobiov ,&nbsp;Christian Mitterer ,&nbsp;Karol Flachbart","doi":"10.1016/j.solidstatesciences.2025.107851","DOIUrl":"10.1016/j.solidstatesciences.2025.107851","url":null,"abstract":"<div><div>Very recently it was shown that incorporation of nitrogen into Ti<sub>0.2</sub>Nb<sub>0.2</sub>Mo<sub>0.2</sub>Ta<sub>0.2</sub>W<sub>0.2</sub> high-entropy alloy films leads to a considerable superconducting transition temperature <em>T</em><sub><em>C</em></sub> enhancement in corresponding (TiNbMoTaW)<sub>1.0</sub>N<sub>x</sub> nitrides. Here we report, independently, about the impact of subsequent annealing and the influence of additional hydrogen incorporation on these films, which should lead to a further enhancement of <em>T</em><sub><em>C</em></sub>. However, the expected <em>T</em><sub><em>C</em></sub> increase was not observed, on the contrary, both annealing of films at 800 °C in vacuum and incorporation of hydrogen into these films led to a reduction of <em>T</em><sub><em>C</em></sub>. Analysis of the results shows that in case of annealing this is related to nitrogen release from the films, in case of hydrogenation to reductions of the density of states at the Fermi level and of the electron-phonon interaction.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"161 ","pages":"Article 107851"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143161869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, dielectric and magnetic properties of multi-walled carbon nanotubes decorated BiFeO3 nanocomposites for technological applications 多壁碳纳米管修饰BiFeO3纳米复合材料的结构、介电和磁性能及其技术应用
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107800
M.G.B. Ashiq
{"title":"Structural, dielectric and magnetic properties of multi-walled carbon nanotubes decorated BiFeO3 nanocomposites for technological applications","authors":"M.G.B. Ashiq","doi":"10.1016/j.solidstatesciences.2024.107800","DOIUrl":"10.1016/j.solidstatesciences.2024.107800","url":null,"abstract":"<div><div>In this study, an inexpensive technique known as the sol-gel auto-combustion method was employed for the synthesis of BiFeO<sub>3</sub> (BFO) nanoparticles. The BFO/MWCNTs nanocomposites with varying weight percentages of multi-walled carbon nanotubes (MWCNTs), specifically with x = 0, 5, 10, 15, and 20 wt%, were prepared using the ultra-sonication method. Toluene was employed as a functionalization agent to enhance the dispersion. Various characterization techniques, including X-ray diffraction (XRD), Transmission electron microscopy (TEM) and Raman spectroscopy, as well as dielectric and magnetic property measurements were conducted to comprehensively analyze the prepared nanocomposites. XRD analysis confirmed the crystalline structure of the nanocomposites. Scherrer's formula calculated the crystallite size based on the major plane peak in XRD patterns, which revealed a range of 45 nm–50 nm. TEM micrographs showed the morphology, dispersion and interaction of nanoparticles with MWCNTs. The Raman spectroscopy was utilized to reveal the phonon modes of the nanocomposites. The dielectric response was investigated in a wide range of frequencies ranging from 1 MHz to 3 GHz and observed a significant change with the addition of MWCNTs. Vibrating sample magnetometery (VSM) analysis was conducted under magnetic fields ranging from −20 to 20 KOe. The magnetic constraints such as saturation magnetization (M<sub>s</sub>), coercivity (H<sub>c</sub>), remanent magnetization (M<sub>r</sub>), squareness (M<sub>r</sub>/M<sub>s</sub>) and anisotropic constant (K) have decreased with the increasing content of the MWCNTs. The high dielectric and low magnetic properties make these nanocomposites suitable for energy and data storage applications.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107800"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143093219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Investigation of structural, magnetic, optical and dielectric characteristics of Al-doped MgFe2O4 nanoparticles” [Solid State Sci. 159 (2025) 107761] “al掺杂MgFe2O4纳米颗粒的结构、磁性、光学和介电特性的研究”的勘误表[固体科学]. 159 (2025)107761]
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107811
R. Srimathi , N.V.S.S. Seshagiri Rao , A. Merlin , R. Kiruthika , A. Selvaraj , Omar H. Abd-Elkader , Chandra Sekhar Dash , S. Revathi , Anis Ahamed , Jothi Ramalingam Rajabathar , M. Sundararajan , S. Yuvaraj , L. Rajadurai
{"title":"Corrigendum to “Investigation of structural, magnetic, optical and dielectric characteristics of Al-doped MgFe2O4 nanoparticles” [Solid State Sci. 159 (2025) 107761]","authors":"R. Srimathi ,&nbsp;N.V.S.S. Seshagiri Rao ,&nbsp;A. Merlin ,&nbsp;R. Kiruthika ,&nbsp;A. Selvaraj ,&nbsp;Omar H. Abd-Elkader ,&nbsp;Chandra Sekhar Dash ,&nbsp;S. Revathi ,&nbsp;Anis Ahamed ,&nbsp;Jothi Ramalingam Rajabathar ,&nbsp;M. Sundararajan ,&nbsp;S. Yuvaraj ,&nbsp;L. Rajadurai","doi":"10.1016/j.solidstatesciences.2024.107811","DOIUrl":"10.1016/j.solidstatesciences.2024.107811","url":null,"abstract":"","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107811"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143098776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Scintillation properties of Eu-doped Al2O3-SiO2 glasses prepared by melt-quenching method 熔淬法制备掺铕Al2O3-SiO2玻璃的闪烁特性
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107812
Akihiro Nishikawa , Daiki Shiratori , Shiyu Rim , Takumi Kato , Daisuke Nakauchi , Noriaki Kawaguchi , Takayuki Yanagida
{"title":"Scintillation properties of Eu-doped Al2O3-SiO2 glasses prepared by melt-quenching method","authors":"Akihiro Nishikawa ,&nbsp;Daiki Shiratori ,&nbsp;Shiyu Rim ,&nbsp;Takumi Kato ,&nbsp;Daisuke Nakauchi ,&nbsp;Noriaki Kawaguchi ,&nbsp;Takayuki Yanagida","doi":"10.1016/j.solidstatesciences.2024.107812","DOIUrl":"10.1016/j.solidstatesciences.2024.107812","url":null,"abstract":"<div><div>In this study, we prepared the Eu-doped 10Al<sub>2</sub>O<sub>3</sub>-90SiO<sub>2</sub> glasses with different Eu concentrations (0.1, 0.3, 1.0, and 3.0 %) and investigated the photoluminescence (PL) and scintillation properties. All samples showed the Eu<sup>2+</sup> and Eu<sup>3+</sup> luminescence peaks at around 450 and 600 nm, respectively. The quantum yield monitored Eu<sup>2+</sup> luminescence decreased from 82.7 to 2.3 % with increasing Eu concentration. Scintillation peaks of Eu<sup>2+</sup> and Eu<sup>3+</sup> were observed at around 450 and 600 nm, the same as PL. We measured pulse height spectra to estimate light yields (<em>LY</em>). All samples indicated the full-energy absorption peaks, and especially the 0.3 % Eu-doped sample had the highest <em>LY</em> (1400 photons/5.5 MeV) among all samples. The energy resolution and α/γ ratio of the 0.3 % Eu-doped sample were 13 % and 0.3, respectively.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107812"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143098237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of surfactants on the morphology of ZnCo2O4 nanoflowers prepared by hydrothermal method 表面活性剂对水热法制备ZnCo2O4纳米花形貌的影响
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107808
Jia Du , Qi Liu , Wenquan Jiang , Hengrui Qiu , Yongqiang Zhang , Wenxiu He
{"title":"Effect of surfactants on the morphology of ZnCo2O4 nanoflowers prepared by hydrothermal method","authors":"Jia Du ,&nbsp;Qi Liu ,&nbsp;Wenquan Jiang ,&nbsp;Hengrui Qiu ,&nbsp;Yongqiang Zhang ,&nbsp;Wenxiu He","doi":"10.1016/j.solidstatesciences.2024.107808","DOIUrl":"10.1016/j.solidstatesciences.2024.107808","url":null,"abstract":"<div><div>In this paper, flower-like ZnCo<sub><strong>2</strong></sub>O<sub><strong>4</strong></sub> with different morphologies was prepared by using nickel foam as a collector and three different surfactants under hydrothermal and calcination conditions. One of the samples using polymer surfactant PVP has a large specific surface area, the petals of nanosheets, which can promote the migration and diffusion of lithium ions and electrons in the electrode materials and improve the electrical conductivity, thus significantly enhancing the electrochemical performance of the materials. As a lithium anode showing excellent cycling and multiplication performance, the discharge capacity can still reach 1072 mAh/g after 100 cycles at a current density of 0.1A/g, and when the current reaches 1.4A/g, it can still maintain a reversible capacity of 652mAh/g. The material has a high reversible capacity, good cycling stability, and good multiplication properties.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107808"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143098238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formamide as novel catalyst for the gelation of water glass to synthesize silica aerogel monolith 甲酰胺作为水玻璃凝胶合成二氧化硅气凝胶整体体的新型催化剂
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107820
Meng-Jie Chang, Xin Li, Jun Liu, Ge Bai, Qiu-Yu Hu
{"title":"Formamide as novel catalyst for the gelation of water glass to synthesize silica aerogel monolith","authors":"Meng-Jie Chang,&nbsp;Xin Li,&nbsp;Jun Liu,&nbsp;Ge Bai,&nbsp;Qiu-Yu Hu","doi":"10.1016/j.solidstatesciences.2024.107820","DOIUrl":"10.1016/j.solidstatesciences.2024.107820","url":null,"abstract":"<div><div>Water glass (WG)-based aerogels (WAGs) are challenged with requirement of acid catalyst and poor mechanical property. In this work, we have developed a novel formamide (FA) as catalyst for gelation of WG at alkaline condition to prepare WAG monolith under atmospheric pressure drying (APD). The FA serves both as the catalyst by hydrolyzing product formic acid and drying control agent. The effect of the gelation temperature, FA dosage, and WG concentration on the gelation time, density, shrinkage and microstructure of the aerogels were analyzed. The optimum WAG monolith shows a low shrinkage of 20 % and density of 0.165 g cm<sup>−3</sup>, as well as large specific surface area of 229.4 m<sup>2</sup> g<sup>−1</sup> and superhydrophobic surface. The connected nanoparticle into three-dimensional network endows the WAG monolith with good mechanical property. Due to the low-cost, easy fabrication process and free usage of acids, the method expands the synthesis of aerogel monolith.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107820"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143097798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Augmenting the broadband feature in CdS CQDs thin film photodetectors by Ag assimilation 银同化增强CdS CQDs薄膜光电探测器的宽带特性
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107805
Tania Kalsi , Nupur Saxena , Pragati Kumar
{"title":"Augmenting the broadband feature in CdS CQDs thin film photodetectors by Ag assimilation","authors":"Tania Kalsi ,&nbsp;Nupur Saxena ,&nbsp;Pragati Kumar","doi":"10.1016/j.solidstatesciences.2024.107805","DOIUrl":"10.1016/j.solidstatesciences.2024.107805","url":null,"abstract":"<div><div>High-performance photodetectors (PDs) with broadband (BB) responses are crucial for many optoelectronic and imaging technologies. In the present work, BBPDs were fabricated employing simple spin coated thin films (TFs) of Cd<sub>(1-x)</sub>Ag<sub>x</sub>S colloidal quantum dots (CQDs), where x = 0.0 to 0.05. The x-ray diffraction (XRD) patterns of TFs confirm the formation of a cubic phase with a crystallite size very close to Bohr's atomic radius. The existence of microstructural defects like twinning/multiple twinning was confirmed by HRTEM images of the undoped and 3 wt% Ag-doped CdS QDs. The spectral tunability along with modifications in detector characteristic parameters were observed with varying concentrations of Ag. The maximum value of various performance parameters like sensitivity (S), responsivity (R), detectivity (D), and external quantum efficiency (EQE) were estimated as ∼ 1.95 × 10<sup>4</sup> %, 14.67 A/W, 4.84 × 10<sup>12</sup> cmHz<sup>1/2</sup>W<sup>−1</sup>, and 3.8 × 10<sup>3</sup> %, respectively. Besides, the response speed of PD was also improved by twofold due to the insertion of Ag. The fastest PD responds within 104 ms (rise time)/98 ms (fall time). The present work demonstrates BB spectral (405 nm–845 nm) detection by Cd<sub>(1-x)</sub>Ag<sub>x</sub>S CQDs-based PDs and tunability in the selectivity and detectable wavelength with variation of Ag dopant. The device <em>S</em><sub><em>3</em></sub> is the fastest and demonstrated the highest <em>S</em> and <em>D</em> among all devices under 782 nm illumination; however, <em>S</em><sub><em>1</em></sub> is optimised for PD in the present study as it delivered the best performance in the said BB spectral region with a reasonably good response speed of 200 ms.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107805"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143098235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Features of the formation of baro- and piezocaloric effects in ferroelastics and ferroelectrics 铁弹性材料和铁电材料中气压和压电效应形成的特点
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107799
I.N. Flerov , M.V. Gorev , E.V. Bogdanov , V.S. Bondarev , E.A. Mikhaleva
{"title":"Features of the formation of baro- and piezocaloric effects in ferroelastics and ferroelectrics","authors":"I.N. Flerov ,&nbsp;M.V. Gorev ,&nbsp;E.V. Bogdanov ,&nbsp;V.S. Bondarev ,&nbsp;E.A. Mikhaleva","doi":"10.1016/j.solidstatesciences.2024.107799","DOIUrl":"10.1016/j.solidstatesciences.2024.107799","url":null,"abstract":"<div><div>The analysis of baro- and piezo-caloric effects in ferroelectrics and ferroelastics containing tetrahedral and octahedral ion groups in the structure is carried out. The role of the degree of structural disorder in the formation of both effects is discussed. The features of the caloric response at phase transitions of different proximity to the tricritical point are revealed. The strong piezocaloric anisotropy of the studied materials is a convenient tool for extending the operating temperature range of the cooling cycle. An important advantage of ferroelastics and ferroelectrics undergoing transformations of the first order is the combination in one material of low thermal hysteresis and high sensitivity to hydrostatic and/or uniaxial pressure.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107799"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143098360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Scintillation light yields of Ce-doped BaO-SiO2-P2O5 glasses synthesized by the melt-quenching method 熔融猝灭法合成掺铈BaO-SiO2-P2O5玻璃的闪烁光产率
IF 3.4 3区 化学
Solid State Sciences Pub Date : 2025-02-01 DOI: 10.1016/j.solidstatesciences.2024.107807
Akihiro Nishikawa , Daiki Shiratori , Takumi Kato , Daisuke Nakauchi , Noriaki Kawaguchi , Takayuki Yanagida
{"title":"Scintillation light yields of Ce-doped BaO-SiO2-P2O5 glasses synthesized by the melt-quenching method","authors":"Akihiro Nishikawa ,&nbsp;Daiki Shiratori ,&nbsp;Takumi Kato ,&nbsp;Daisuke Nakauchi ,&nbsp;Noriaki Kawaguchi ,&nbsp;Takayuki Yanagida","doi":"10.1016/j.solidstatesciences.2024.107807","DOIUrl":"10.1016/j.solidstatesciences.2024.107807","url":null,"abstract":"<div><div>In this study, we synthesized BaO-SiO<sub>2</sub>-P<sub>2</sub>O<sub>5</sub> glasses doped with 5.0, 10, 15, and 20 % Ce by a melt-quenching method and investigated XRD patterns, transmittance spectra, photoluminescence properties, and scintillation properties. The 5.0–15 % samples were transparent and colorless, while the 20 % sample was colored yellow. All samples indicated only a halo peak, which is characteristic of an amorphous. The absorption originated from the 4f-5d transitions of Ce<sup>3+</sup>, and the charge transfer of O<sup>2-</sup>-Ce<sup>4+</sup> was observed at 280–310 and 250–370 nm, respectively. Photoluminescence of the 5d-4f transitions of Ce<sup>3+</sup> was detected in all samples, and the 5.0–15 % samples showed high quantum yields of 86–90 %. As a result of measurements of scintillation properties, the 15 % sample indicated the highest light yield of 685 photons/MeV and an energy resolution of 21 %.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"160 ","pages":"Article 107807"},"PeriodicalIF":3.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143098784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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