Solid State Sciences最新文献_第7页

Dual S-scheme Bi2MoO6/g-C3N4/Ag2MoO4 ternary heterojunction: Interfacial charge transfer, broadband spectrum, enhanced redox ability 双 S 型 Bi2MoO6/g-C3N4/Ag2MoO4 三元异质结：界面电荷转移、宽带光谱、增强的氧化还原能力

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-09-12 DOI: 10.1016/j.solidstatesciences.2024.107693

Vasudha Hasija , Aftab Aslam Parwaz Khan , Sonu , Konstantin P. Katin , Savaş Kaya , Pardeep Singh , Pankaj Raizada , Mohammad Asad , Malik Abdul Rub , Khalid A. Alzahrani

{"title":"Dual S-scheme Bi2MoO6/g-C3N4/Ag2MoO4 ternary heterojunction: Interfacial charge transfer, broadband spectrum, enhanced redox ability","authors":"Vasudha Hasija , Aftab Aslam Parwaz Khan , Sonu , Konstantin P. Katin , Savaş Kaya , Pardeep Singh , Pankaj Raizada , Mohammad Asad , Malik Abdul Rub , Khalid A. Alzahrani","doi":"10.1016/j.solidstatesciences.2024.107693","DOIUrl":"10.1016/j.solidstatesciences.2024.107693","url":null,"abstract":"<div><div>A ternary heterojunction bearing Bi2MoO6 and g-C3N4 is deposited on Ag2MoO4 for the photocatalytic degradation of sulfamethoxazole (SMX) antibiotic. Though the hydrothermal synthesis is non-directional, the dual S- scheme heterojunction formation is governed by the g-C3N4 serving as an electron bridge between Bi2MoO6 and Ag2MoO4. The potent strong interaction with both Bi2MoO6 and Ag2MoO4 facilitates high oxidation and reduction potential. The optimized Bi2MoO6/g-C3N4/Ag2MoO4 heterojunction with extended visible light absorption exhibits 96 % SMX degradation efficiency within 240 min of irradiations. The dual S-scheme configuration endows in-built electric field with vigorous driving force for charge carrier separation. The charge transfer mechanisms were validated by the photoluminescence results. Bi2MoO6/g-C3N4/Ag2MoO4 heterojunction demonstrates pseudo-first order kinetics with 0.143 kmin−1 for SMX degradation and ternary photocatalyst 83 % degraded SMX after successive five cycles. In the formed dual S-scheme Bi2MoO6/g-C3N4/Ag2MoO4heterojunction, ●OH and ●O2− radicals were the main reactive species for SMX degradation. This research contributes to the formation of stable multicomponent photocatalytic systems.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"157 ","pages":"Article 107693"},"PeriodicalIF":3.4,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142315312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A 3D open-framework amino acid templated cerium phosphite-oxalate showing proton conductive property 具有质子传导特性的三维开放框架氨基酸模板化亚磷酸铈-草酸盐

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-09-12 DOI: 10.1016/j.solidstatesciences.2024.107692

Honglu Li, Liangliang Huang, Yang Lu, Shanshan Zhao, Xin Shao, Yanfeng Bi

引用次数: 0

One-pot construction of α-Fe2O3/ZnNiFe2O4 heterojunction by incomplete sol/gel-self-propagating method with choline chloride-ethylene glycol media and its photo-degradation performance 以氯化胆碱-乙二醇为介质的不完全溶胶/凝胶自促进法一锅构建α-Fe2O3/ZnNiFe2O4异质结及其光降解性能

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-09-10 DOI: 10.1016/j.solidstatesciences.2024.107694

Benjing Ren, Xiaoyi Wang, Qingxin Xu, Yuqi Sun, Qiaoji Yu, Jie Sun, Jinhong Meng

{"title":"One-pot construction of α-Fe2O3/ZnNiFe2O4 heterojunction by incomplete sol/gel-self-propagating method with choline chloride-ethylene glycol media and its photo-degradation performance","authors":"Benjing Ren, Xiaoyi Wang, Qingxin Xu, Yuqi Sun, Qiaoji Yu, Jie Sun, Jinhong Meng","doi":"10.1016/j.solidstatesciences.2024.107694","DOIUrl":"10.1016/j.solidstatesciences.2024.107694","url":null,"abstract":"<div>A magnetic α-Fe2O3/ZnNiFe2O4 composite photocatalyst was synthesized through a one-pot reaction employing choline chloride-ethylene glycol deep eutectic solvents and an incomplete sol-gel self-propagating method. The photocatalytic performance was assessed by removing methylene blue (MB) under 40 W visible light. With a 1.0 g/L catalyst dosage, 10 mg/L MB concentration, and pH levels of 6 and 12, removal rates of 97 % and 99 % were achieved within 90 min, respectively. The composite also demonstrated effective degradation of methyl orange (MO) and malachite green (MG). Stability tests revealed minimal reduction in photocatalytic activity after four cycles. Active species analysis identified ·O2⁻ and ·OH as the primary agents in the photocatalytic process. XRD, XPS, UV–VIS DRS, HRTEM, PL, and EIS analyses confirmed the formation of a Z-scheme heterojunction between ZnNiFe2O4 and α-Fe2O3, which enhanced the specific surface area, electron transport capacity, and narrowed the band gap. This heterojunction improved the separation efficiency of photogenerated electron-hole pairs, resulting in enhanced photocatalytic activity and stability. This study presents a novel approach for preparing Z-scheme heterojunction photocatalysts through a one-pot reaction.</div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"157 ","pages":"Article 107694"},"PeriodicalIF":3.4,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142167458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thinly-walled NiFe2O4 nanotubes derived from Ni, Fe, N-codoped carbon nanofibers toward oxygen evolution reaction 掺杂 Ni、Fe、N 的纳米碳纤维衍生出的薄壁 NiFe2O4 纳米管，用于氧进化反应

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-09-08 DOI: 10.1016/j.solidstatesciences.2024.107691

Zhan Tian , He Wang , Guoqiang Li , Hongrui Jia , Guoxin Zhang

{"title":"Thinly-walled NiFe2O4 nanotubes derived from Ni, Fe, N-codoped carbon nanofibers toward oxygen evolution reaction","authors":"Zhan Tian , He Wang , Guoqiang Li , Hongrui Jia , Guoxin Zhang","doi":"10.1016/j.solidstatesciences.2024.107691","DOIUrl":"10.1016/j.solidstatesciences.2024.107691","url":null,"abstract":"<div>NiFe2O4 has emerged as an efficient oxygen evolution reaction (OER) electrocatalyst, with outstanding stability in alkaline media and excellent redox properties. In order to further improve the catalytic performance, thinly-walled NiFe2O4 nanotubes (NiFe2O4-NTs), efficiently derivable from Ni, Fe, N-codoped carbon nanofibers, were innovatively synthesized through a sequential route combing hydrothermal, electrospinning, and high-temperature sintering in this work. The NiFe2O4-NTs possess large diameter of around 120 nm and their thickness of the tube wall is only about 10 nm. The surface properties of NiFe2O4 can be adjusted by forming the Ni-N/Fe-N bonds. Excitingly, largely exposed active surface area and boosted catalytic reaction kinetics toward oxygen evolution reaction are realized. The required overpotential to deliver 10 mA cm−2 is only 331 mV, accompanied with favorable Tafel slope of only 51.8 mV dec−1, small charge transfer resistance, and superior reaction stability.</div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"157 ","pages":"Article 107691"},"PeriodicalIF":3.4,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142164797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and study of structural, electric, and dielectric behavior of La0.5Sm0.2Sr0.3Mn1-xFexO3 perovskite La0.5Sm0.2Sr0.3Mn1-xFexO3 包晶的合成及其结构、电学和介电行为研究

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-09-02 DOI: 10.1016/j.solidstatesciences.2024.107682

Khouloud Abdouli , Wajdi cherif , Fatma khammassi , M.P. F. Graça , Olfa Messaoudi , Latifah Alfhaid , Rabaa Bousbih

{"title":"Synthesis and study of structural, electric, and dielectric behavior of La0.5Sm0.2Sr0.3Mn1-xFexO3 perovskite","authors":"Khouloud Abdouli , Wajdi cherif , Fatma khammassi , M.P. F. Graça , Olfa Messaoudi , Latifah Alfhaid , Rabaa Bousbih","doi":"10.1016/j.solidstatesciences.2024.107682","DOIUrl":"10.1016/j.solidstatesciences.2024.107682","url":null,"abstract":"<div>In this study, the synthesized samples La0.5Sm0.2Sr0.3Mn1-xFexO3 (x = 0.05, 0.15 and 0.20) were thoroughly investigated for their crystalline structure, electrical conductivity, and dielectric properties, the samples were prepared using autocombustion method. According to the X-ray diffraction study, the samples crystallized in an orthorhombic symmetry with the Pnma space group. To measure the dielectric characteristics, impedance spectroscopy was conducted over the temperature range of 100–260 K and a frequency range of 100 Hz to 1 MHz. Measurements of AC conductivity are indeed utilized to investigate the transport properties of materials being studied. The results indicated that both temperature and frequency significantly influence the conduction process. Three theoretical hypotheses were proposed to explain the hopping conduction: overlapping large polaron tunneling (OLPT), the non-overlapping small polaron tunneling (NSPT) mechanism, and correlated barrier hopping (CBH). It is also shown that the conductivity diminishes with an increase in Fe content. La0.5Sm0.2Sr0.3Mn1-xFexO3 (x = 0.05, 0.15 and 0.20) can be used in electronic applications because of the high permittivity values confirmed by the dielectric measurements. With the aim of evaluating the distinct impacts of electrodes, grain boundaries, and grains on the complex impedance results, an appropriate alternative electrical circuit was utilized. Analysis of the sample's modulus indicated non-Debye characteristics and electrical relaxation phenomena. The materials exhibit good electrical properties, as well as strong chemical and thermal stability.</div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"157 ","pages":"Article 107682"},"PeriodicalIF":3.4,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142164796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Corrigendum to “Influence of cobalt on magnetic, dielectric and electrochemical properties of copper ferrite nanoparticles via hydrothermal method” [Solid State Sci., 137 [March 2023] [107123] 钴对水热法纳米铜铁氧体磁性、介电和电化学特性的影响》更正 [Solid State Sci.

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-08-31 DOI: 10.1016/j.solidstatesciences.2024.107657

R. Priyadharsini , P. Dhamodharan , M. Venkateshwarlu , C. Manoharan

引用次数: 0

Enhanced acetone gas sensor via TiO2 nanofiber-NiO nanoparticle heterojunction 通过 TiO2 纳米纤维-NiO 纳米粒子异质结强化丙酮气体传感器

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-08-31 DOI: 10.1016/j.solidstatesciences.2024.107683

Jiyeon Lee, Hyojung Kim, Muhammad Hilal, Zhicheng Cai

引用次数: 0

Crystal structure and hydrogen sorption properties of Nd0.5Y0.5MgNi4-xCox alloys (x = 0–3) Nd0.5Y0.5MgNi4-xCox 合金（x = 0-3 ）的晶体结构和吸氢特性

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-08-30 DOI: 10.1016/j.solidstatesciences.2024.107674

Yu Verbovytskyy , Kh Vlad , I. Zavaliy , B. Rożdżyńska-Kiełbik , V. Pavlyuk

{"title":"Crystal structure and hydrogen sorption properties of Nd0.5Y0.5MgNi4-xCox alloys (x = 0–3)","authors":"Yu Verbovytskyy , Kh Vlad , I. Zavaliy , B. Rożdżyńska-Kiełbik , V. Pavlyuk","doi":"10.1016/j.solidstatesciences.2024.107674","DOIUrl":"10.1016/j.solidstatesciences.2024.107674","url":null,"abstract":"<div>The gas-phase and electrochemical hydrogenation properties of Nd0.5Y0.5MgNi4-xCox (where x varies from 0 to 3) were studied. Samples were prepared using sintering and annealing procedures. X-ray diffraction analysis indicated that all the alloys were single-phase. The alloys readily absorbed hydrogen, and the crystal structures of the resulting saturated hydrides were refined. Nd0.5Y0.5MgNi4H4.2 and Nd0.5Y0.5MgNi3CoH4.4 belong to the NdMgNi4H3.6 structural type, while Nd0.5Y0.5MgNi2Co2H5.5 and Nd0.5Y0.5MgNiCo3H6.0 belong to the LaMgNi4H4.85 structural type. Electrochemical studies revealed that the maximum discharge capacity of Nd0.5Y0.5MgNi4-xCox electrodes increased from 236 mAh/g to 328 mAh/g as the cobalt content increased. The high-rate dischargeability (HRD1000) initially decreased from 48 % to 7 % with increasing cobalt content, but then increased to 32 % at the highest cobalt concentration. Additionally, the electrochemical kinetic properties were determined and compared for these electrodes, including the charge-transfer resistance (Rct), polarization resistance (Rp), exchange current density (I0), limiting current density (IL), and hydrogen diffusion coefficient (DH).</div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"156 ","pages":"Article 107674"},"PeriodicalIF":3.4,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142097143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Pt nanoclusters as co-catalysts for efficient photocatalytic hydrogen evolution 铂纳米团簇作为高效光催化氢气进化的辅助催化剂

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-08-29 DOI: 10.1016/j.solidstatesciences.2024.107680

Junhao Jia , Yingjun Wang , Xiang Miao , Chengjian Wu , Min Zhang , Yunyuan Dong , Jianming Liao , Xiaobin Chen , Jiacheng Yao , Hongfei Yin

引用次数: 0

An extension of atomic mean square displacement method for calculating melting temperatures in II-VI compounds 原子均方位移法在计算 II-VI 化合物熔化温度方面的扩展

IF 3.4 3区化学

Solid State Sciences Pub Date : 2024-08-29 DOI: 10.1016/j.solidstatesciences.2024.107681

Zhi-Yuan Qiu , Wen-Guang Li , Qi-Jun Liu , Zheng-Tang Liu

引用次数: 0