5f逆光电发射中分离多晶结构

IF 3.4 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Solid State Sciences Pub Date : 2025-02-01 DOI:10.1016/j.solidstatesciences.2024.107779

J.G. Tobin , H. Ramanantoanina , C. Daul , P. Roussel , S.-W. Yu , D. Sokaras , A. Kutepov

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引用次数: 0

摘要

结果表明，利用二氧化铀和二氧化钚的逆光电子能谱（IPES）和轫致等色谱（BIS）可以提取出终态角动量耦合引起的5f5/2流形的多重结构。比较提取的成分和x射线吸收计算执行配体场密度泛函理论（LFDFT）提出和讨论。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Isolating multiplet structure in 5f inverse photoemission

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Isolating multiplet structure in 5f inverse photoemission

It is shown herein that the multiplet structure of the 5f_5/2 manifold, caused by angular momentum coupling in the final state, can be extracted from the Inverse Photoelectron Spectroscopy (IPES) and Bremsstrahlung Isochromat Spectroscopy (BIS) of uranium dioxide and plutonium dioxide. Comparisons between the extracted components and x-ray absorption calculations performed using Ligand Field Density Functional Theory (LFDFT) are presented and discussed.

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来源期刊

Solid State Sciences 化学-无机化学与核化学

CiteScore

6.60

自引率

2.90%

发文量

214

审稿时长

27 days

期刊介绍： Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments. Key topics for stand-alone papers and special issues: -Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials -Physical properties, emphasizing but not limited to the electrical, magnetical and optical features -Materials related to information technology and energy and environmental sciences. The journal publishes feature articles from experts in the field upon invitation. Solid State Sciences - your gateway to energy-related materials.