Separation and Purification Technology最新文献

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Fabrication of cellulose acetate membrane using deep eutectic solvent for water/isopropyl alcohol pervaporation
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132406
Sun Ho Bae, Geumbee Lee, Jae Bem You, Youngmin Yoo
{"title":"Fabrication of cellulose acetate membrane using deep eutectic solvent for water/isopropyl alcohol pervaporation","authors":"Sun Ho Bae, Geumbee Lee, Jae Bem You, Youngmin Yoo","doi":"10.1016/j.seppur.2025.132406","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132406","url":null,"abstract":"Deep eutectic solvents (DES) are eco-friendly alternatives to conventional organic solvents and have receive significant attention due to their low cost and biodegradable properties. These characteristics provide DES highly suitable for membrane applications. In this study, cellulose acetate (CA) membrane is fabricated using DES. The DES is prepared by mixing thymol (Thy) and decanoic acid (DA). CA is dissolved in the DES and the solution is casted into a film to fabricate non-porous membranes by phase inversion method. To find the optimum solvent for CA, various types of DES are tested with different compositions of which Thy and DA, both naturally occurring chemicals, are selected. Variations in membrane structure and performance are also analyzed by altering the ratio of Thy to DA. Additionally, it is confirmed that DES is completely removed during the phase inversion process after casting the CA dope solution, demonstrating that DES functions solely as a solvent and not as an additive. The fabricated non-porous CA membranes are applied for dehydration of a water and isopropyl alcohol mixture via pervaporation. The membranes exhibit a high flux of 5.381 kg/m<sup>2</sup>·h and a selectivity of 16. Both DES and CA are biodegradable and biocompatible, yielding viable substitutes for the toxic and harsh organic solvents traditionally used in membrane fabrication.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"1 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design of dual-layer Janus polyelectrolyte hydrogel via dynamic covalent bonds for highly efficient solar desalination
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132404
Xuechun Wang, Zhiye Ma, Dan Zheng, Bo Bai, Shichao Zong, Weijia Jin
{"title":"Design of dual-layer Janus polyelectrolyte hydrogel via dynamic covalent bonds for highly efficient solar desalination","authors":"Xuechun Wang, Zhiye Ma, Dan Zheng, Bo Bai, Shichao Zong, Weijia Jin","doi":"10.1016/j.seppur.2025.132404","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132404","url":null,"abstract":"Solar-driven evaporation offers a promising solution for water scarcity and efficient desalination with low energy requirements. Recently, polyelectrolyte hydrogels have attracted considerable attention in the field of salt resistance owing to their electrostatic effect between the charged groups within the skeleton of hydrogel. The conventional polyelectrolyte hydrogels mostly use single-charged groups, limiting their ability to resist salt accumulation during prolonged operation. For solving this problem, we herein demonstrated self-healing as an effective method for binding anionic–cationic polyelectrolyte dual-layer hydrogels using dynamic covalent bonds of borax. Such design have minimized the amount of Na<sup>+</sup> and Cl<sup>−</sup> ions diffusion into the hydrogel matrix and achieved exceptional salt-resistance, benefiting from electrostatic interaction between functional groups of the evaporator and salt ions. Additionally, the dual layers provided excellent thermal insulation, reducing the heat loss to surrounding water. Hereby the hydrogel evaporator achieved stable long-term performance with an evaporation rate of 2.43 kg m<sup>−2</sup>h<sup>−1</sup> under 1sun irradiation. More importantly, no salt precipitation occurred on the solar absorber surface, even with varying salinities over more than seven days. All in all, the integration of anionic and cationic hydrogel layers achieved through the self-healing feature, significantly enhances the performance of interfacial steam generators used in seawater desalination applications.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"59 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modelling selective lithium recovery from brines via membrane flow electrode capacitive de-ionization
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132400
Giorgio Purpura, Hafiz Muhamad Saif, Andrea Culcasi, Sylwin Pawlowski, Joao Goulão Crespo, Andrea Cipollina
{"title":"Modelling selective lithium recovery from brines via membrane flow electrode capacitive de-ionization","authors":"Giorgio Purpura, Hafiz Muhamad Saif, Andrea Culcasi, Sylwin Pawlowski, Joao Goulão Crespo, Andrea Cipollina","doi":"10.1016/j.seppur.2025.132400","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132400","url":null,"abstract":"The recent growing demand for lithium worldwide, led by the Li-ion battery market, has sparked research into alternative sources of this material. In this context, selective lithium recovery from concentrated brines represents a sustainable and economical alternative to lithium mining activities. In this work, we developed a mathematical model of the recently implemented Lithium Membrane Flow Electrode Capacitive De-Ionization (Li-MFCDI) process, used to selectively extract lithium from a synthetic geothermal brine. The model was validated against the available experimental data and was used to perform a comprehensive parametric analysis. The model predicts the effects of the applied voltage, flow rates, and the adopted membranes on the process performance. These findings highlight the importance of the membrane conductivity-selectivity trade-off for process productivity. Furthermore, this simulation tool will substantially contribute to the development of this novel technology.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"8 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Surfactant modified PTFE-based forward osmosis membrane with high performance and superior stability
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132419
Wenpei Ye, Lijun Meng, Ruizhe Wang, Mengying Yan, Fan Yu, Yinzhou Bao, Haoyu Xing, Jun Li, Niğmet UZAL, Manhong Huang
{"title":"Surfactant modified PTFE-based forward osmosis membrane with high performance and superior stability","authors":"Wenpei Ye, Lijun Meng, Ruizhe Wang, Mengying Yan, Fan Yu, Yinzhou Bao, Haoyu Xing, Jun Li, Niğmet UZAL, Manhong Huang","doi":"10.1016/j.seppur.2025.132419","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132419","url":null,"abstract":"The absence of membranes with high stability and excellent permeation performance hinders the progress of forward osmosis (FO) technology. In this work, a high-strength polytetrafluoroethylene (PTFE) substrate was used for interfacial polymerization (IP) to fabricate FO membranes. The innovative approach enhances membrane performance by improving hydrophilicity with surfactant modification to facilitate better water transport in FO. Dodecyl trimethylammonium bromide (DTAB) was added into the<!-- --> <!-- -->aqueous phase to control the IP process, and the optimized DTAB concentration was determined to be 70 mg L<sup>−1</sup>, which was<!-- --> <!-- -->labeled as PTFE-DTAB<sub>70</sub> membrane. Characterization analysis showed that DTAB stabilized carboxyl groups in the PA layer through electrostatic interactions, inhibiting amide bond hydrolysis. After immersed for 60 days under extreme pH conditions (1–13), the membrane maintained high water flux (&gt;16 LMH) and low reverse salt flux (&lt;0.56 g L<sup>−1</sup>). Its chemical stability significantly surpassed that of commercial CTA membrane, with a 295 % increase in water flux at pH 13. When treating simulated wastewater, a 99.9 % chromium (Cr) rejection and a 96 % chemical oxygen demand (COD) rejection were obtained. The membrane showed great potential for treating high-salinity, strong acid and alkaline industrial wastewater. This study provides an innovative strategy for developing highly stable FO membranes and reveals the universal mechanism of surfactant molecular design in membrane separation.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"53 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green and efficient lithium recovery from spent lithium-ion batteries via waste graphite-assisted sulfidation roasting
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132414
He Li, Yadong Ning, Guangye Wei, Jingkui Qu, Caixia Lv, Zhihui Yu
{"title":"Green and efficient lithium recovery from spent lithium-ion batteries via waste graphite-assisted sulfidation roasting","authors":"He Li, Yadong Ning, Guangye Wei, Jingkui Qu, Caixia Lv, Zhihui Yu","doi":"10.1016/j.seppur.2025.132414","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132414","url":null,"abstract":"The rapid growth of electric vehicles has limited the sustainable development capacity of the lithium-ion battery (LIBs) industry, and the buildup of spent LIBs has caused safety and environmental problems. This study proposed a new method for selective lithium extraction from waste LIBs using graphite-assisted sulfidation roasting. Waste graphite and sodium sulfide served as roasting reagents. At a roasting temperature of 650 ℃, mass ratio of Na<sub>2</sub>S·9H<sub>2</sub>O to black mass of 1.6:1 and roasting time of 2 h, lithium was converted into a soluble compound. After water leaching, lithium was leached at a rate of up to 96.68 % and a maximum leaching selectivity of 99.55 % while preserving other transition metals. The lithium carbonate product with 99.5 % purity was prepared using the lithium-rich leach solution. The thermodynamic mechanism based on controlled reducing driving force for targeted lithium extraction and the phase transformation process were investigated, and environmental and economic impacts of new approach were studied. This study provides a new selective sulfidation process with a high lithium leaching rate and selectivity, with good economic and environmental benefits, and provides a new strategy for green lithium recovery and resource recycling of spent LIBs.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"36 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review on mitigation of pressure-driven membrane fouling by coagulation/flocculation as a pretreatment in membrane separation processes
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132370
Yuyang Wang, Munan Li, Hu Yang
{"title":"A review on mitigation of pressure-driven membrane fouling by coagulation/flocculation as a pretreatment in membrane separation processes","authors":"Yuyang Wang, Munan Li, Hu Yang","doi":"10.1016/j.seppur.2025.132370","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132370","url":null,"abstract":"Membrane fouling is an inevitable consequence of the membrane operation process. Coagulation/flocculation is simple, effective, and low-cost membrane pretreatment method. The performance of coagulation/flocculation, including its coupling processes with other pretreatment technologies, in controlling pressure-driven membrane fouling has been reviewed in detail according to fouling type (including inorganic, organic, and microbial fouling) in this paper. The development prospects of this technology are also explored to further improve its application performance. Coagulation/flocculation generally shows high efficiency in removal of insoluble inorganic, organic and microbial colloids in effluents by charge neutralization, bridging and sweeping effects to thus mitigate membrane fouling. For soluble matter, especially for low molecular-weight ones, the mitigation effect highly depends on the selected coagulant/flocculant, in addition to the coupling pretreatment technologies. A desired coagulant/flocculant can effectively bind to and transform the solute from hydrophilic to hydrophobic by some valid interactions, and cause an easy destabilization, aggregation and final formation of large and loose flocs. The resultant flocs can be trapped on the membrane and further form loose and porous cake layer, thus increasing membrane flux, decreasing membrane resistance, and alleviating membrane fouling. Based on an improved understanding of the membrane fouling and also coagulation/flocculation mechanisms at the molecular levels, designing and selecting an advanced coagulant/flocculant, with the advantages of high performance, environmental friendliness and low cost, is crucial to achieve the desired pretreatment effect","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"131 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrocatalytic reductive removal of arsenite from nonferrous smelting waste acid on copper electrode
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132393
Minhan Pi, Tingting You, Ning Liu, Xiangfeng Zeng, Yongfeng Jia, Shaofeng Wang
{"title":"Electrocatalytic reductive removal of arsenite from nonferrous smelting waste acid on copper electrode","authors":"Minhan Pi, Tingting You, Ning Liu, Xiangfeng Zeng, Yongfeng Jia, Shaofeng Wang","doi":"10.1016/j.seppur.2025.132393","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132393","url":null,"abstract":"Nonferrous smelting waste acid containing a high concentration of arsenite (As(III)) may pose a serious contamination to local ecosystems and a threat to human health. The direct electrocatalytic reduction of highly toxic As(III) to elemental arsenic (As(0)) in waste acid represents a promising green strategy for As removal. However, several obstacles remain to be overcome. In this study, we investigated the electrocatalytic reduction of As(III) to As(0) in simulated and real waste acid using an H-type cell at room temperature. The effects of diverse parameters, including cathode materials, potential, pH, and coexisting ions, on the reduction efficiency of As(III) to As(0) were examined. The selection of copper foam as the electrocatalyst was based on the findings of linear sweep voltammetry (LSV), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). These measurements indicated that the Tafel slope and resistance of the copper foam were comparatively lower, thereby rendering it a suitable candidate for the desired application. The findings indicated that a lower pH was more conducive to the reduction of As(III), whereas the presence of co-existing cations impeded the reduction of As(III). The removal efficiency of As(III) was observed to reach 98 % within a 4 h period at an electrode potential of −1.25 V (vs. Hg/Hg<sub>2</sub>SO<sub>4</sub>) and pH 0.34. The XPS, SEM, and EDS results show that the solid precipitates are mainly composed of As(0) with a small amount of As(III). Electron paramagnetic resonance (EPR) analysis and radical scavenging experiments indicate that both direct electro-reduction and H• contribute significantly to the reduction of As(III). Our results provide a promising method for the direct removal and recovery of As(0) from nonferrous smelting waste acid.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"50 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
NiAl-LDH/MXenes intercalated anode for enhanced electrochemical oxidation to synergistically degrade norfloxacin and antibiotic resistance genes in wastewater
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132392
Yuyang Li, Wenchao Yu, Hairui Lv, Lumeng Jia, Haining Shi, Zhaoyong Bian, Hui Wang
{"title":"NiAl-LDH/MXenes intercalated anode for enhanced electrochemical oxidation to synergistically degrade norfloxacin and antibiotic resistance genes in wastewater","authors":"Yuyang Li, Wenchao Yu, Hairui Lv, Lumeng Jia, Haining Shi, Zhaoyong Bian, Hui Wang","doi":"10.1016/j.seppur.2025.132392","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132392","url":null,"abstract":"Electrocatalytic oxidation is a promising treatment for remediating organic contaminants in wastewater. However, improving the mass transfer efficiency and catalytic activity of anode materials is essential for effective treatment. In this study, a NiAl-layered double hydroxide (LDH) intercalated MXenes composite anode (NiAl-LDH/MXenes) was developed via electrostatic self-assembly for the degradation of norfloxacin (NOR) and antimicrobial resistance genes (ARGs) in hospital wastewater. The insertion of NiAl-LDH sheets expanded the MXenes interlayer spacing, alleviated stacking, and reduced mass transfer distance. This intercalation strategy promoted electron transfer and •OH generation, enhancing catalytic activity and enabling efficient degradation of NOR and ARGs. Compared to NiAl-LDH and MXenes, the NiAl-LDH/MXenes composite exhibited a higher oxygen evolution overpotential (2.21 V vs. SCE) and lower energy consumption (0.003 kWh/m<sup>3</sup>), achieving 97.31 % NOR degradation in 120 min and 95.73 % DNA degradation in 90 s. The composite electrode also exhibited excellent performance in treating practical hospital wastewater, achieving 91.19 % NOR removal, significant ARGs removal (e.g., <em>qnrA</em> by 96.72 %), and effectively reducing pathogenic bacteria such as <em>Duganella</em> by 4.21 logs. Linear sweep voltammetry confirmed direct electron transfer in NOR degradation, while quenching experiments, EPR, and molecular probe assays elucidated the role of •OH in degrading NOR and DNA. DFT calculations revealed that •OH preferentially targets the piperazine ring and carboxyl groups of NOR, as well as the –OH and C=O/C-N sites of DNA. This study introduced a novel intercalation-based anode modulation strategy using NiAl-LDH/MXenes for the concurrent degradation of NOR and ARGs, offering a robust solution for wastewater treatment.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"3 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Layered sodium zirconium phosphate adsorbent for ammonia removal in cell culture media for cultivated meat application
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132415
Ming Yang, Ning Xiang, Yunan Tang, Yue Li, Ximing Zhang
{"title":"Layered sodium zirconium phosphate adsorbent for ammonia removal in cell culture media for cultivated meat application","authors":"Ming Yang, Ning Xiang, Yunan Tang, Yue Li, Ximing Zhang","doi":"10.1016/j.seppur.2025.132415","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132415","url":null,"abstract":"Ammonia accumulation poses a major challenge in high-density cell production, including cultivated meat. This study presents sodium zirconium phosphate (NaZrP) as an efficient ammonia adsorbent, synthesized via a minimal solvent thermal method. In discarded culture medium, NaZrP reduced ammonium concentration by 56 % and maintained efficiency over four reuse cycles. At 0.5–2.5 g/L, it sustained over 90 % cell survival after 24 h, confirming biocompatibility. The addition of disodium hydrogen phosphate improved NaZrP’s properties by increasing layer spacing, ion adsorption rate, and adsorption capacity. Adsorption followed pseudo-second-order kinetics and the Langmuir model, indicating monolayer adsorption. Chemisorption was the dominant mechanism, with ion exchange occurring under weakly alkaline conditions. NaZrP exhibited minimal glucose adsorption and negligible impact on solution pH. Its rapid and selective ammonia removal, combined with reusability and cell compatibility, makes it a promising solution for managing ammonia toxicity in large-scale cell cultures. Further optimization will enhance its potential for cost-effective applications in cultivated meat and other biotechnological industries.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"1 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermally rearranged polyimide membranes incorporating triptycenes for improved CO2 capture and hydrogen separation
IF 8.6 1区 工程技术
Separation and Purification Technology Pub Date : 2025-03-06 DOI: 10.1016/j.seppur.2025.132302
Siyao Wang, Jingfa Zhang, Yongchao Sun, Fangxu Fan, Qizheng Zhao, Gaohong He, Canghai Ma
{"title":"Thermally rearranged polyimide membranes incorporating triptycenes for improved CO2 capture and hydrogen separation","authors":"Siyao Wang, Jingfa Zhang, Yongchao Sun, Fangxu Fan, Qizheng Zhao, Gaohong He, Canghai Ma","doi":"10.1016/j.seppur.2025.132302","DOIUrl":"https://doi.org/10.1016/j.seppur.2025.132302","url":null,"abstract":"Thermally rearranged (TR) polymers are increasingly pivotal in gas separation membranes, with a pressing need for advancements in mechanical strength and separation performance. In this work, a novel variety of TR polymers were synthesized by polymerizing an amine-functionalized triptycene structure with thermally rearrangeable <em>ortho</em>-hydroxy groups. The TR membranes demonstrate enhanced gas permeability in H<sub>2</sub>/CH<sub>4</sub> and CO<sub>2</sub>/CH<sub>4</sub> tests and increased polymer chain spacing. Additionally, incorporating triptycene enhanced the mechanical properties of TR polymers, primarily attributed to the π-π stacking interactions of the triptycene units. Notably, the 6FDA-BAP:DAT (2:1) membrane thermally rearranged at 400 °C exhibited a H<sub>2</sub> permeability of 225.3 Barrer and a H<sub>2</sub>/CH<sub>4</sub> selectivity of 146.3, representing increases of 320 % and 154 %, respectively, compared to the precursor, and surpassing the H<sub>2</sub>/CH<sub>4</sub> upper bound. This work presents a robust design strategy for preparing mechanically durable TR membranes with enhanced gas separation performance.","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":"30 1","pages":""},"PeriodicalIF":8.6,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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