Sensors and Actuators B: Chemical最新文献_第4页

Wide range luminescence lifetime-based pH sensing with covalently immobilized multi-protonatable Ru(II) complexes 利用共价固定的多质子 Ru(II) 复合物进行基于寿命的宽范围 pH 值发光传感

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-19 DOI: 10.1016/j.snb.2024.136960

Ya Jie Knöbl, Maximino Bedoya, Alexander Farquharson, Patrick Courtney, Guillermo Orellana

{"title":"Wide range luminescence lifetime-based pH sensing with covalently immobilized multi-protonatable Ru(II) complexes","authors":"Ya Jie Knöbl, Maximino Bedoya, Alexander Farquharson, Patrick Courtney, Guillermo Orellana","doi":"10.1016/j.snb.2024.136960","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136960","url":null,"abstract":"To overcome the limitations of optical pH sensors, the response of which is just ca. one pH unit around the pKa value of the indicator dye and capitalize on the advantages of red-luminescent Ru(II) complexes for optical sensing, multi-pKa members of this family are proposed. Bipyridine ligands bearing protonatable groups (amines and carboxylates) are the basis to design and prepare the indicator dyes. Their photophysical properties and response to pH changes were investigated in the pH 3.5−9.0 range. The complex [Ru(DCB)2DEAMB], where DCB and DEAMB stand for 2,2’-bipyridine-4,4’-dicarboxylate and 4,4’-(N,N-diethylaminomethyl)-2,2’-bipyridine, respectively, shows a reversible monotonic change of its emission wavelength maximum (648 – 634 nm), luminescence intensity (1.40x) and lifetime (335 – 429 ns) in solution with increasing pH. This complex and two similar ones were covalently tethered to commercial TentaGel® M Br polymer microbeads for luminescence phase shift fiberoptic pH measurements. The immobilized [Ru(DCB)2DEAMB] displays the widest pH sensitivity over pH 3.5 to pH 8.5. The stability of this sensor was satisfactory when cycling between pH 3.5 and 8.5 for five days as well as under a three-day cycle between each pH unit. Changes of the buffer type, buffer concentration and osmolarity did not significantly influence the sensor response; however, large variations of dissolved oxygen and, naturally, temperature would require correction by the corresponding sensors. The novel, robust luminescent pH sensor has been tested in phase-sensitive mode for cell cultures monitoring in commercial bioreactors, but its response would also be suitable for in situ monitoring of natural waters.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"13 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142671054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An ultra-low fouling electrochemical mocularly imprinted sensor based on size exclusion effect for highly selective pentachlorophenol detection 基于尺寸排除效应的超低堵塞电化学摩卡印迹传感器，用于高选择性检测五氯苯酚

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-19 DOI: 10.1016/j.snb.2024.136974

Chen Cheng, Xiaoyu Zhu, Xingao Qin, Jinzhu Zhang, Meng Liu, Ying Wang

{"title":"An ultra-low fouling electrochemical mocularly imprinted sensor based on size exclusion effect for highly selective pentachlorophenol detection","authors":"Chen Cheng, Xiaoyu Zhu, Xingao Qin, Jinzhu Zhang, Meng Liu, Ying Wang","doi":"10.1016/j.snb.2024.136974","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136974","url":null,"abstract":"Pentachlorophenol (PCP) is considered as a highly toxic pollutant in water environment. However, detecting low concentrations of PCP precisely hindered by various interferences is still a tough challenge. In this study, an antifouling electrochemical molecularly imprinted (E-MIP) sensor harnessing the size exclusion effect was specifically designed for highly selective detection of PCP in water. The distinctive interaction between the size-selective poly-hydroxyproline helical peptide (PHHP) and poly(o-phenylenediamine) (p(o-PD)) molecularly imprinted films, strongly reduced non-specific adsorption. In the face of high concentrations of organic matters and ions, the reported sensor exhibited robust antifouling capabilities that it preserved 90 % of the initial signal. In addition, the limit of detection (LOD) reached an exceptionally low level of 1.13 nM (S/N = 3), spanning a wide linear range from 1 nM to 10 μM, and the sensor showed high selectivity with an impressive imprinted factor of 12.01 for PCP. Meanwhile, it owned great repeatability and reproducibility, long-term stability for PCP detection within 25 days, and decent reusability (retaining 92.33 % of its senor performance after 5 cycles), which ensured its excellent feasibility for determination of PCP in complex water samples with co-existing interferences due to acceptable recoveries. The development of this strategy provides an innovative platform for PCP quantification in real water samples, underscoring its potential as a key tool in managing PCP at relevant sites.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"99 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142673232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Direct synthesis of composite conductive carbon nanofiber aerogels with continuous internal networks for collaborative physiological signal monitoring under complex environments 直接合成具有连续内部网络的复合导电碳纳米纤维气凝胶，用于复杂环境下的协同生理信号监测

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-19 DOI: 10.1016/j.snb.2024.136975

Shouzhi Yan, Shixin Jin, Xinyan He, Jinhao Xu, Hao Feng, Wenyu Xing, Binjie Xin, Dahua Shou

{"title":"Direct synthesis of composite conductive carbon nanofiber aerogels with continuous internal networks for collaborative physiological signal monitoring under complex environments","authors":"Shouzhi Yan, Shixin Jin, Xinyan He, Jinhao Xu, Hao Feng, Wenyu Xing, Binjie Xin, Dahua Shou","doi":"10.1016/j.snb.2024.136975","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136975","url":null,"abstract":"The emergence of multifunctional wearable flexible sensors has propelled advancements in healthcare and outdoor sports. However, conventional aerogels used for multifunctional sensing often involve complex fabrication processes, lack durability, and struggle to achieve collaborative sensing in complex scenarios, sometimes even lacking conductivity. This paper presents a novel strategy for synthesizing aerogels with interconnected internal networks directly through electrospinning technology, forming a three-dimensional fluffy structure with interlinked nanofibers. Subsequently, ultra-lightweight, highly elastic, and conductive composite carbon nanofiber aerogels (CCNA) were synthesized through high-temperature calcination and in-situ polymerization, suitable for collaborative physiological signal monitoring in complex situations. By controlling the density and phase separation of the charge jet, the three-dimensional fluffy structure of CCNA can be directly formed without strict reliance on external environmental conditions. The combination of CCNA's three-dimensional fluffiness and hydrophobic-hydrophilic properties enables it to operate within an extremely wide range of relative humidity (10% RH - 95% RH), while its internally continuous fiber network structure ensures stable and reliable electrical signal response even after 5000 compression cycles, with a compression response time of only 55ms. The developed flexible wearable electronic device holds promising prospects in healthcare and intelligent sensing applications.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"15 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142673202","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Highly dispersed CeO2 nanocubics supported on hydrogen substituted graphyne sheets for highly NH3 gas sensing detection and humidity independent at room temperature 氢取代石墨烯片上支持的高度分散 CeO2 纳米立方体，用于室温下高度 NH3 气体传感检测且不受湿度影响

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-18 DOI: 10.1016/j.snb.2024.136972

Chuantao Zhang, Lingmin Yu, Senlin Li, Lei Cao, Ning Nan, Rushun Xue, Man Gong, Yaxuan Zhang, Hao Zhang, Xuefeng Xiao, Shanglin Yang, Xinhui Fan, Peichang Shi

{"title":"Highly dispersed CeO2 nanocubics supported on hydrogen substituted graphyne sheets for highly NH3 gas sensing detection and humidity independent at room temperature","authors":"Chuantao Zhang, Lingmin Yu, Senlin Li, Lei Cao, Ning Nan, Rushun Xue, Man Gong, Yaxuan Zhang, Hao Zhang, Xuefeng Xiao, Shanglin Yang, Xinhui Fan, Peichang Shi","doi":"10.1016/j.snb.2024.136972","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136972","url":null,"abstract":"NH3 is a fairly important raw material in a number of fields but harmful to the human. Currently, hydrogen substituted graphyne (HsGY) shows fast response to NH3 gas based on our previous report. However, it still suffers from low response values and humidity interference. CeO2 has the advantage of moisture resistance as NH3 gas sensor but prone to agglomeration, whereas the alkyne bond of HsGY can anchor CeO2 to form a discretely distributed CeO2. Therefore, highly dispersed CeO2 nanocubics anchoring on HsGY sheets are synthesized through hydrothermal method. The gas sensing characteristics show that the gas sensing response value to 80 ppm NH3 is increased by 3 times compared to pure HsGY. Furthermore, they present relatively stable NH3 gas response under relative humidity variation (20–80 %). In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) is used to reveal the gas sensing mechanism. Energy bands are analyzed using ultraviolet photoemission spectroscopy (UPS), revealing the improvement mechanism of NH3 gas-sensitive performance. Density functional theory (DFT) calculations are employed to explain selectivity mechanism to NH3 against other interference gases. Our research provides novel gas sensing materials for the development of high-performance, moisture-resistant room temperature NH3 sensors.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"46 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142671055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Split-type photoelectrochemical immunosensor integrating ZIF-8@Ag NPs-assisted cation-exchange and Fe2O3/ZnIn2S4 nanoarrays for detection of carbohydrate antigen 72–4 集成 ZIF-8@Ag NPs 阳离子交换和 Fe2O3/ZnIn2S4 纳米阵列的分体式光电化学免疫传感器用于检测碳水化合物抗原 72-4

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-18 DOI: 10.1016/j.snb.2024.136967

Shanghua Liu, Feng Jiang, Yueyuan Li, Huijuan Lin, Qing Liu, Shujun Wang, Qin Wei, Yueyun Li

{"title":"Split-type photoelectrochemical immunosensor integrating ZIF-8@Ag NPs-assisted cation-exchange and Fe2O3/ZnIn2S4 nanoarrays for detection of carbohydrate antigen 72–4","authors":"Shanghua Liu, Feng Jiang, Yueyuan Li, Huijuan Lin, Qing Liu, Shujun Wang, Qin Wei, Yueyun Li","doi":"10.1016/j.snb.2024.136967","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136967","url":null,"abstract":"The sensitivity, accuracy, and stability of a photoelectrochemical (PEC) immunosensor directly depends on the type of sensing substrate and the efficiency of the recognition model in immobilizing biological elements within multilayer assemblies. In this work, a split-type PEC immunosensor integrating Ag nanoparticles-modified ZIF-8 (ZIF-8@Ag NPs)-assisted cation-exchange and Fe2O3/ZnIn2S4 nanoarrays (NAs) as well-ordered sensing substrate and photoactive material was developed for the detection of carbohydrate antigen 72–4 (CA72–4), a novel gastric cancer target. With effectively harvesting visible light, the stability signal output and the rapid carrier separation, the Z-Scheme Fe2O3/ZnIn2S4 NAs heterojunction was successfully grown on an indium tin oxide (ITO) electrode as the signal converter and sensing substrate via two-step solvothermal method. The ZIF-8@Ag NPs were employed as the signal label to release silver ions (Ag+), relying on the acidolysis in the 96-well plate. The released Ag+ initiated a cation-exchange (CE) reaction with the Fe2O3/ZnIn2S4 NAs, forming Fe2O3/ZnIn2S4/Ag2S ternary complexes with higher photocurrent density. This resulted in a positive correlation trend between CA72–4 concentration (0.01 U/mL to 100 U/mL), and improved the recognition sensitivity of the sensor to trace target, with the limit of detection is 0.0032 U/mL. This work represents an important advancement in overcoming the limitations of multilayer assembly in constructing immunosensors, providing a valuable reference for trace detection of low-abundance disease-related biomarkers.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"250 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142671052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A polydopamine coated magnetic spiral switchable composite material for photothermal sterilization and dual-color fluorescence detection of food-borne pathogens 用于光热灭菌和食源性病原体双色荧光检测的聚多巴胺涂层磁性螺旋可切换复合材料

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-17 DOI: 10.1016/j.snb.2024.136935

Jiaqi Feng, Jin Li, Xianfeng Lin, Lixin Kang, Nuo Duan, Zhouping Wang, Shijia Wu

{"title":"A polydopamine coated magnetic spiral switchable composite material for photothermal sterilization and dual-color fluorescence detection of food-borne pathogens","authors":"Jiaqi Feng, Jin Li, Xianfeng Lin, Lixin Kang, Nuo Duan, Zhouping Wang, Shijia Wu","doi":"10.1016/j.snb.2024.136935","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136935","url":null,"abstract":"A multifunctional magnetic composite material (MSp@PDA) featuring with helical structure, superparamagnetism, photothermal properties, and fluorescence quenching capability was synthesized through sequential magnetization and in-situ polydopamine coating on the Spirulina surface, then applied for multi-scenario application of pathogens capture, sterilization, and sensitive detection. The pathogens capture and sterilization was investigated by loading bacterial broad-spectrum recognition molecule (MPBA) on MSp@PDA, the capture efficiencies of 91.6% and 94.2% were obtained for Escherichia coli and Staphylococcus aureus in 15 minutes, respectively, with complete photothermal sterilization achieved within 4 minutes. The fluorescence real-time detection of E. coli and S. aureus was realized by connecting dual-color fluorescent carbon dots to MSp@PDA through specific aptamers (dCD-apt-MSp@PDA), the corresponding detection limits were 2 and 3 cfu·mL-1, respectively, with linear ranges of 101~107 cfu·mL-1. The spiked recovery rates of target bacteria in actual samples were 97.4%~101.1% and 98.2%~101.4% for E. coli and S. aureus, respectively. The constructed capture, sterilization, and fluorescence detection methods demonstrated promising application value for on-site monitoring of food-borne pathogens in complex matrices.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"21 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development of a chemiluminescent detection method for absolute activity measurement of Taq DNA polymerase through dATP consumption 开发一种化学发光检测方法，通过消耗 dATP 来测量 Taq DNA 聚合酶的绝对活性

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-17 DOI: 10.1016/j.snb.2024.136918

Wei Jing, Xuefeng Wang, Jingjie Jiang, Ping Gui, Xiao Li, Feng Lu, Yanna Lin, Haichao Li, Huancai Yin, Fuqiang Ma

{"title":"Development of a chemiluminescent detection method for absolute activity measurement of Taq DNA polymerase through dATP consumption","authors":"Wei Jing, Xuefeng Wang, Jingjie Jiang, Ping Gui, Xiao Li, Feng Lu, Yanna Lin, Haichao Li, Huancai Yin, Fuqiang Ma","doi":"10.1016/j.snb.2024.136918","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136918","url":null,"abstract":"Being one of the most extensively researched and widely used thermostable DNA polymerases, Taq DNA polymerase derived from Thermus aquaticus has played pivotal roles in numerous molecular biology applications. The accurate and convenient determination of enzymatic activity is a fundamental prerequisite for both academic research and the industrial application of Taq DNA polymerase. To address the limitations of traditional methods for polymerase activity determination, such as low accuracy, complicated operation, and radioactive hazards, we have devised an absolute-quantitation method for Taq DNA polymerase based on chemiluminescence detection of the consumption of dATP (CDC-dATP). The CDC-dATP method offers several advantages, including simplicity suitable for routine laboratory use, high sensitivity (detecting as low as 0.0025 U/μL), excellent reproducibility, a broad linear range for Taq DNA polymerase (0.0025-0.1 U/μL) with a strong linear relationship (R2 > 0.99), and, significantly, absolute activity quantitation without the associated radioactive hazards. We delved into the molecular behavior of Taq DNA polymerase in the CDC-dATP method. Furthermore, we explored the extensive application potential of the CDC-dATP methodology for measuring the activity of various other enzymes involved in dATP/ATP generation or consumption, encompassing other DNA polymerases, reverse transcriptases, RNA polymerases, hydrolases, and protein kinases, covering all seven major categories of enzymes.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"22 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Gap-free Hybridized Plasmonics with Tunable Decay Channels for Surface-Enhanced Raman Spectroscopy 用于表面增强拉曼光谱的具有可调谐衰减通道的无间隙杂化等离子体

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-17 DOI: 10.1016/j.snb.2024.136968

Xu Yao, Sen Yan, Kang Yang, Yifan Bao, Bin Ren, Xiang Wang

{"title":"Gap-free Hybridized Plasmonics with Tunable Decay Channels for Surface-Enhanced Raman Spectroscopy","authors":"Xu Yao, Sen Yan, Kang Yang, Yifan Bao, Bin Ren, Xiang Wang","doi":"10.1016/j.snb.2024.136968","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136968","url":null,"abstract":"Surface-enhanced Raman spectroscopy (SERS) has been applied in many analytical fields owing to its features like single molecule sensitivity and fingerprint identification. To face the challenges in detecting large molecules, developing gap-free SERS substrates with excellent performance as well as desired electromagnetic (EM) field distribution is receiving increasing attentions. Herein, we propose a highly uniform gap-free SERS substrate consisting of Au nanodisk array / Si nanopillar spacer / Au nanohole array. The mode-hybridization between optical cavity mode and SPR mode can be simply and effectively controlled by tuning the cavity height, then the enhanced EM field can be optimized to the top surface, which is more available for analytes. Simultaneously, the decay channels were also manipulated to reduce the heat effect (with a decrease of around 10℃) of non-radiative decay during SERS measurement. Such a SERS substrate shows a great performance with the average enhancement factor of 6×106 as well as a high uniformity (with a relative standard deviation of 8.5%). This work provides new opportunities for the design and applications of gap-free SERS substrates.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"76 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Formaldehyde Gas Response and Selectivity of ZnO-SnO2 Gas Sensors ZnO-SnO2 气体传感器的甲醛气体响应和选择性

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-16 DOI: 10.1016/j.snb.2024.136958

Jaebum Park, Deepak Chaulagain, Same Noel Ngando, Abdulfatai Olatunji Yakub, Jeong Ok Lim, Jong Wook Roh, Jeung Soo Huh

引用次数: 0

Tin oxide nanoparticles anchored on ordered mesoporous carbon for efficient acetone sensing 锚定在有序介孔碳上的氧化锡纳米粒子用于高效丙酮传感

IF 8.4 1区化学

Sensors and Actuators B: Chemical Pub Date : 2024-11-16 DOI: 10.1016/j.snb.2024.136957

Jian Fang, Wei Wang, Yizhuo Fan, Heng Guan, Qilin Wang, Dali Liu, Ruiliang Xu, Shengping Ruan

{"title":"Tin oxide nanoparticles anchored on ordered mesoporous carbon for efficient acetone sensing","authors":"Jian Fang, Wei Wang, Yizhuo Fan, Heng Guan, Qilin Wang, Dali Liu, Ruiliang Xu, Shengping Ruan","doi":"10.1016/j.snb.2024.136957","DOIUrl":"https://doi.org/10.1016/j.snb.2024.136957","url":null,"abstract":"Rationally designed combinations of semiconductor metal oxides (SMO) and carbon materials can lead to the development of sensing materials with excellent gas performance. Herein, SnO2 nanoparticles (NPs) decorated on ordered mesoporous carbon (CMK-3) nanorods were synthetized by solvothermal and high-temperature calcination methods. Various characterization and gas sensing tests indicated that the resulting one-dimensional (1D) self-assembled SnO2@CMK-3 composite had a large specific surface area (88.02 m2/g) and excellent gas sensing performance. Specifically, at optimal working temperature, the as-prepared SnO2@CMK-3 sensor had a high response (122.1), low limit of detection, good linear fitting (R2=0.9892), rapid response/recovery time (5/27 s) towards 50 ppm acetone. Meanwhile, by detecting six gases, including acetone, ammonia, formaldehyde, xylene, triethylamine, and ethanol, it was found that the SnO2@CMK-3 sensor showed good selectivity to acetone. The unique nanostructure, large specific surface area, high oxygen vacancy content, and the formation of heterojunctions accounted for the good performance to acetone. These results highlighted the potential application of the SnO2@CMK-3 composite for the detection of acetone gas and presented a promising approach to prepare SMO@carbon composites for VOCs detection.","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":"98 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0