Science of the Total Environment最新文献

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Identification of spatiotemporal behavior of organic micropollutants in an agricultural and urban lowland river catchment 农业和城市低地河流流域有机微污染物的时空特征
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-16 DOI: 10.1016/j.scitotenv.2025.179665
Johanna Buss, Christine Achten
{"title":"Identification of spatiotemporal behavior of organic micropollutants in an agricultural and urban lowland river catchment","authors":"Johanna Buss,&nbsp;Christine Achten","doi":"10.1016/j.scitotenv.2025.179665","DOIUrl":"10.1016/j.scitotenv.2025.179665","url":null,"abstract":"<div><div>Mixed land-use, medium-sized lowland rivers are subject to contamination by various input pathways for organic micropollutants. This study provides a unique long-term (2016–2020) and high-resolution investigation of the Münstersche Aa River (Northwestern Germany) focusing on the thorough characterization of input pathways for pesticides, biocides and pharmaceuticals in the catchment with heterogeneous land-use (62 % agricultural and 26 % urbanized). 468 samples were collected using two automated high-frequency samplers and five catchment-wide sampling campaigns providing a comprehensive data set. While the input of pesticides is the major stressor in the agriculturally dominated upper catchment, input of treated wastewater is dominating the water chemistry of the lower catchment, especially during summer low flows (up to 100 % wastewater fraction). Detected pharmaceuticals in the catchment include carbamazepine, diclofenac, metoprolol, phenazone and sulfamethoxazole. Moreover, caffeine as an indicator substance suggests input through non-conventionally treated wastewater. The pesticides chlortoluron (winter) as well as terbuthylazine and 2-methyl-4-chlorophenoxyacetic acid (MCPA) (summer), occur related to their respective application time. Moreover, a belated, accumulated input of terbuthylazine was observed in winter 2019/2020 after an extremely dry period from 2018 to 2019. Urban runoff adds further pesticides such as mecoprop-P while tebuconazole input from both agricultural and urban land-use was identified. Even though detected concentrations are below thresholds for acute toxicity, mixture toxicity could pose risks in the Münstersche Aa. Ongoing climate change is expected to intensify these seasonal patterns in the catchment. Lake Aasee may however function as a sink for OMPs through degradation processes especially during low-flow conditions. This study enhances the understanding of river pollution dynamics in small, mixed land-use catchments and aids targeting the goals of the Water Framework Directive for the Münstersche Aa and other lowland streams with comparable land use.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179665"},"PeriodicalIF":8.2,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144070546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Production of high value-added carbon material precursors via direct hydrothermal conversion of municipal sewage sludge coupled with air flotation separation: A review 城市污水污泥直接水热转化-气浮分离生产高附加值碳材料前驱体的研究进展
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-16 DOI: 10.1016/j.scitotenv.2025.179655
Yulu Yang, Zihan Du, Changqing Cao, Peigao Duan
{"title":"Production of high value-added carbon material precursors via direct hydrothermal conversion of municipal sewage sludge coupled with air flotation separation: A review","authors":"Yulu Yang,&nbsp;Zihan Du,&nbsp;Changqing Cao,&nbsp;Peigao Duan","doi":"10.1016/j.scitotenv.2025.179655","DOIUrl":"10.1016/j.scitotenv.2025.179655","url":null,"abstract":"<div><div>Municipal sewage sludge, as a byproduct of the sewage treatment process, has a large yield and needs to be properly disposed of and utilized as resources. Hydrothermal carbonization (HTC) is a green, efficient and clean production technology that converts sewage sludge into solid-phase products (including hydrochar and ash) and liquid-phase products. Hydrochar has potential as a precursor of high-value-added carbon materials, but ash residues limit its application. Air flotation technology uses the differences in the physical and chemical properties of mineral particles to separate them. Owing to the differences between hydrochar and ash, they are expected to be separated by flotation technology. Therefore, this systematic review examines the migration and transformation pathways of sewage sludge components during HTC and discusses the parameters affecting HTC. The optimization of operating parameters (including bubble size, flotation reagent type, and dosage) in the air flotation process is briefly introduced. The key is to propose a coupling technology of HTC and air flotation, which is used to separate hydrochar and ash. Coupling technology provides a new perspective and reference for future research on the high value-added use of sludge, provides innovative references for sustainable organic solid waste disposal and supports the transition to a carbon-neutral future.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179655"},"PeriodicalIF":8.2,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144070527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Circularity potential identification for new bio-materials using material flow analysis 利用物料流分析识别新型生物材料的循环势
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-15 DOI: 10.1016/j.scitotenv.2025.179649
Mariusz Kruczek, Karolina Jąderko-Skubis, Małgorzata Markowska, Aleksandra Zgórska, Małgorzata Białowąs
{"title":"Circularity potential identification for new bio-materials using material flow analysis","authors":"Mariusz Kruczek,&nbsp;Karolina Jąderko-Skubis,&nbsp;Małgorzata Markowska,&nbsp;Aleksandra Zgórska,&nbsp;Małgorzata Białowąs","doi":"10.1016/j.scitotenv.2025.179649","DOIUrl":"10.1016/j.scitotenv.2025.179649","url":null,"abstract":"<div><div>Transitioning to a Circular Economy (CE) in the bio-based materials sector is essential for achieving sustainability and reducing environmental impacts. This study presents a comprehensive circularity assessment across three novel bio-based value chains: multifunctional rubber panels, bioplastic bottle closures, and wood composite bearings. Utilizing an integrated methodological approach that combines Material Flow Analysis (MFA) with advanced circularity indicators and Bill of Materials (BoM), the research quantifies resource efficiency, waste reduction potential, and closed-loop material flows within these systems.</div><div>The analysis reveals substantial differences in circularity outcomes among these three value chains. Multifunctional rubber panels demonstrate a high circularity potential, with recycled content constituting up to 68.1 % of the total material input. However, opportunities for improvement remain in addressing the variability in secondary rubber quality and optimizing lignin recovery processes to enhance circularity. Bioplastic bottle closures exhibit the highest renewable input utilization, reaching up to 85 %, yet still present opportunities for improvement, particularly in the scalability of waste recovery systems and addressing regulatory constraints on food-grade recycled materials. Wood composite bearings effectively utilize forest residues and natural fibers, thereby reducing their dependency on non-renewable inputs, but are currently facing technical development needs in component disassembly and recycling strategies, presenting pathways for future optimization of material recirculation.</div><div>To address these challenges, the study proposes strategic interventions tailored to each value chain, including the development of advanced recycling technologies, enhancement of eco-design for disassembly and recyclability, and fostering stakeholder collaboration to close material loops. By advancing the application of MFA combined with BoM in evaluating circularity metrics, this research provides a robust analytical framework that transcends conventional qualitative assessments. The value chain-specific evaluation contributes to operationalizing CE principles within bio-based production systems and offers actionable insights for policymakers, industry leaders, and researchers. These findings support strategic decision-making aimed at aligning industrial practices with the European Green Deal and global sustainability targets.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179649"},"PeriodicalIF":8.2,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144067997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainability assessment of home textiles made of recycled PET fibre using life cycle assessment and life cycle costing analyses 利用生命周期评价和生命周期成本分析对再生PET纤维家纺的可持续性评价
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-15 DOI: 10.1016/j.scitotenv.2025.179652
Amal Fatima , Farman Ullah Khan , Majid Hussain , Riffat Naseem Malik
{"title":"Sustainability assessment of home textiles made of recycled PET fibre using life cycle assessment and life cycle costing analyses","authors":"Amal Fatima ,&nbsp;Farman Ullah Khan ,&nbsp;Majid Hussain ,&nbsp;Riffat Naseem Malik","doi":"10.1016/j.scitotenv.2025.179652","DOIUrl":"10.1016/j.scitotenv.2025.179652","url":null,"abstract":"<div><div>Textile and plastic waste are major environmental challenges. Recycling post-consumer polyethylene terephthalate (PET) bottles into recycled PET (r-PET) fibres for home textiles provides sustainable solutions by extending materials life cycles. This study evaluates environmental and economic sustainability dimensions of producing home textiles using r-PET fibre. Life Cycle Assessment (LCA) and Life Cycle Costing (LCC) were used to explore the impacts of various energy sources and fibre blends on sustainability outcomes. The system boundary of this study covers collection of post-consumer PET bottles by scavengers, sale to the local crushing plants and their conversion to PET flakes. Pet flakes are then sent to an extrusion facility for conversion into r-PET fibre which is used in the home textiles production. Using a cradle-to-gate approach, SimaPro v9.6 software and the ReCiPe 2016 midpoint methodology was employed to quantify environmental and economic impacts of one tone home textiles. LCA identified human carcinogenic toxicity (105.36 kg 1,4-DCB) as the highest impact, driven by chemical use and transportation, and low global warming (3.43 kg CO <sub>2</sub> eq) values. LCC estimated total production cost of $28,000/ton, with 39.5 % attributed to dyeing and finishing processes. Substituting heavy fuel oil-generated electricity with solar energy reduced global warming potential by 5–6 %, and a 50:50 blend of r-PET and virgin cotton fibres significantly decreased all impact categories, including a 14 % reduction in water use. The findings underscore the need for increased r-PET use and adoption of solar energy to improve sustainability in Pakistan's textile sector.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179652"},"PeriodicalIF":8.2,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143948523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding particulate matter emissions from cooking meals, health impacts and policy path in Ecuador 了解厄瓜多尔烹饪过程中的颗粒物排放、健康影响和政策路径
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-15 DOI: 10.1016/j.scitotenv.2025.179628
Gladys Rincon , Giobertti Morantes , Andrea Garcia-Angulo , Sofia Mota , Maria del Pilar Cornejo-Rodriguez , Benjamin Jones
{"title":"Understanding particulate matter emissions from cooking meals, health impacts and policy path in Ecuador","authors":"Gladys Rincon ,&nbsp;Giobertti Morantes ,&nbsp;Andrea Garcia-Angulo ,&nbsp;Sofia Mota ,&nbsp;Maria del Pilar Cornejo-Rodriguez ,&nbsp;Benjamin Jones","doi":"10.1016/j.scitotenv.2025.179628","DOIUrl":"10.1016/j.scitotenv.2025.179628","url":null,"abstract":"<div><div>Cooking is a major source of indoor air pollution, but little is known about its emissions or health impacts in Ecuadorian households. This study quantified PM₂.₅ and PM₁₀ emissions from six common menus (three fried, three stewed) cooked in a real-life kitchen in Guayaquil lacking natural or mechanical ventilation. Each menu was replicated 30 times, yielding 180 PM concentration profiles. After quality control, 120 profiles were retained for analysis. Median PM₂.₅ and PM₁₀ 24 h concentrations were 16 μg/m<sup>3</sup> and 21 μg/m<sup>3</sup>, respectively—exceeding WHO 24-hour guidelines 16 % for PM₂.₅. Using Disability-Adjusted Life Years (DALYs), the harm from exposure was estimated at 990 DALYs per 100,000 person-years for the analyzed cooking scenarios. These levels indicate quantifiable chronic health risks despite emissions being lower than in other Low Middle Income Countries studies. Findings support the need for indoor air quality guidelines, ventilation strategies, and public health policies tailored to urban Latin American households.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179628"},"PeriodicalIF":8.2,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144067998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Linking phosphorus dynamics with hypereutrophic conditions on the millennial scale: The paleolimnology of shallow and subtropical Lake Wauberg, Florida, USA 千禧年尺度上磷动态与富营养化条件的联系:美国佛罗里达州浅海和亚热带沃伯格湖的古湖泊学
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-15 DOI: 10.1016/j.scitotenv.2025.179625
Savvas Paradeisis-Stathis, Matthew N. Waters
{"title":"Linking phosphorus dynamics with hypereutrophic conditions on the millennial scale: The paleolimnology of shallow and subtropical Lake Wauberg, Florida, USA","authors":"Savvas Paradeisis-Stathis,&nbsp;Matthew N. Waters","doi":"10.1016/j.scitotenv.2025.179625","DOIUrl":"10.1016/j.scitotenv.2025.179625","url":null,"abstract":"<div><div>Eutrophication and harmful algal blooms pose a global challenge to water quality and ecosystem services. Whereas eutrophication has been linked to nutrient additions in conjunction with human activities, much less is known about water quality trends when nutrient additions persist for centuries or millennia. Here, we used paleolimnological techniques to reconstruct eutrophication and cyanobacteria dynamics in Lake Wauberg, FL, USA, a lake that has experienced millennial-scale nutrient additions from natural phosphate geology. We measured photosynthetic pigments, cyanotoxins, and nutrient concentrations on a sediment core spanning the last ~6900 years. Our primary hypothesis is that the long-term total phosphorus (TP) additions caused constant cyanobacteria dominance throughout the entire history of the lake. Focusing on the last 5 ka BP with constant lake conditions, photosynthetic pigments and cyanotoxins demonstrated a strong positive relationship with TP over other nutrients. By dividing TP inputs into three levels, primary producers positively increased with low TP inputs but showed no change under moderate levels. Under high (2.2–3 mg g<sup>−1</sup>) and extreme (&gt;3 mg g<sup>−1</sup>) TP sedimentary concentrations over the last 0.3 ka BP, substantial increases in cyanobacteria abundance, rapid production of microcystins (MCs), and a possible shift to N-fixation occurred. These data show that chronic and additive TP inputs can produce asynchronous responses in the primary producer community and MC concentrations with substantial increases occurring at higher TP thresholds. Linking the historic ecological response to TP periods with current limnological conditions could provide new directions in forecasting and managing aquatic ecosystems that experience chronic TP inputs.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179625"},"PeriodicalIF":8.2,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143948020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Upstream SARS-CoV-2 variant surveillance at Breede Valley municipality using wastewater-based epidemiology 利用基于废水的流行病学对布里德谷市上游SARS-CoV-2变种进行监测
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-15 DOI: 10.1016/j.scitotenv.2025.179648
Kholofelo Malemela , Noluxabiso Mangwana , Stephanie Dias , Jyoti Rajan Sharma , Pritika Ramharack , Anri Kotze , Rianita van Onselen , Sizwe Nkambule , Johan Louw , Mongezi Mdhluli , Glenda Gray , Christo Muller , Angela Mathee , Renée Street , Rabia Johnson
{"title":"Upstream SARS-CoV-2 variant surveillance at Breede Valley municipality using wastewater-based epidemiology","authors":"Kholofelo Malemela ,&nbsp;Noluxabiso Mangwana ,&nbsp;Stephanie Dias ,&nbsp;Jyoti Rajan Sharma ,&nbsp;Pritika Ramharack ,&nbsp;Anri Kotze ,&nbsp;Rianita van Onselen ,&nbsp;Sizwe Nkambule ,&nbsp;Johan Louw ,&nbsp;Mongezi Mdhluli ,&nbsp;Glenda Gray ,&nbsp;Christo Muller ,&nbsp;Angela Mathee ,&nbsp;Renée Street ,&nbsp;Rabia Johnson","doi":"10.1016/j.scitotenv.2025.179648","DOIUrl":"10.1016/j.scitotenv.2025.179648","url":null,"abstract":"<div><div>The COVID-19 pandemic has strained economies and health systems worldwide, particularly in low- and middle-income countries, where limited resources were further stretched by the crisis. In response, innovative strategies like wastewater-based epidemiology (WBE) have emerged as cost-effective and efficient alternatives to traditional surveillance. In Breede Valley Municipality, Western Cape, South Africa, weekly monitoring of wastewater treatment plants (WWTPs) showed consistently high SARS-CoV-2 viral loads in Rawsonville, especially of the Delta variant (AY.32 and B.1.617.2), despite Omicron's dominance in other regions. Total RNAs of all samples were extracted using the Qiagen RNeasy PowerSoil Kit, from which both RT-qPCR and whole genome sequencing were performed to determine the amount of SARS-CoV-2 RNA and their variants, respectively. Rawsonville had the highest median viral load, measured in genome copies per millilitre (gc/mL) at 2211 gc/mL, compared to Worcester (1790 gc/mL), De Doorns (1438 gc/mL), and Touws River (1253 gc/mL). Neighbourhoods in Rawsonville (RV) upstream of the main WWTP, where manholes were sampled, indicated that the suburban manhole on Grey Street (RV_G, 2347 gc/mL) and the peri-urban manhole on Rugby Street (RV_R, 714 gc/mL) were the primary contributors to the SARS-CoV-2 viral load. In contrast, the manhole near public toilets (RV_P, 470 gc/mL) had the lowest viral load. Notably, sequencing data indicated that only Omicron (BA.5) was detected in upstream sites RV_G and RV_R when Deltacron was present in Rawsonville, suggesting complex transmission dynamics requiring further study. These findings underscore the importance of targeted upstream surveillance to trace variant emergence and inform public health interventions.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179648"},"PeriodicalIF":8.2,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144067999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing advances in mechanisms, detection, and strategies to combat antimicrobial resistance
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-14 DOI: 10.1016/j.scitotenv.2025.179641
Ritik Kumar Thakur , Kaushal Aggarwal , Nayan Sood , Aman Kumar , Sachin Joshi , Priya Jindal , Rashmi Maurya , Preeti Patel , Balak Das Kurmi
{"title":"Harnessing advances in mechanisms, detection, and strategies to combat antimicrobial resistance","authors":"Ritik Kumar Thakur ,&nbsp;Kaushal Aggarwal ,&nbsp;Nayan Sood ,&nbsp;Aman Kumar ,&nbsp;Sachin Joshi ,&nbsp;Priya Jindal ,&nbsp;Rashmi Maurya ,&nbsp;Preeti Patel ,&nbsp;Balak Das Kurmi","doi":"10.1016/j.scitotenv.2025.179641","DOIUrl":"10.1016/j.scitotenv.2025.179641","url":null,"abstract":"<div><div>Antimicrobial resistance (AMR) is a growing global health crisis, threatening the effectiveness of antibiotics and other antimicrobial agents, leading to increased morbidity, mortality, and economic burdens. This review article provides a comprehensive analysis of AMR, beginning with a timeline of antibiotics discovery and the year of first observed resistance. Main mechanisms of AMR in bacteria, fungi, viruses, and parasites are summarized, and the main mechanisms of bacteria are given in detail. Additionally, we discussed in detail methods for detecting AMR, including phenotypic, genotypic, and advanced methods, which are crucial for identifying and monitoring AMR. In addressing AMR mitigation, we explore innovative interventions such as CRISPR-Cas systems, nanotechnology, antibody therapy, artificial intelligence (AI), and the One Health approach. Moreover, we discussed both finished and ongoing clinical trials for AMR. This review emphasizes the urgent need for global action and highlights promising technologies that could shape the future of AMR surveillance and treatment. By integrating interdisciplinary research and emerging clinical insights, this study aims to guide individuals toward impactful solutions in the battle against AMR.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179641"},"PeriodicalIF":8.2,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143941102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydroxypropyl-β-cyclodextrin (HPCD) extraction of urban soils: mass balance, bioaccessibility, and cancer risk assessment of 71 polycyclic aromatic hydrocarbons (PAH) from petrogenic and pyrogenic sources 城市土壤中羟丙基-β-环糊精(HPCD)提取:71种多环芳烃(PAH)的质量平衡、生物可及性和致癌风险评价
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-14 DOI: 10.1016/j.scitotenv.2025.179639
Viviane J. Bayer, Alicja Behrensmeier, Christine Achten
{"title":"Hydroxypropyl-β-cyclodextrin (HPCD) extraction of urban soils: mass balance, bioaccessibility, and cancer risk assessment of 71 polycyclic aromatic hydrocarbons (PAH) from petrogenic and pyrogenic sources","authors":"Viviane J. Bayer,&nbsp;Alicja Behrensmeier,&nbsp;Christine Achten","doi":"10.1016/j.scitotenv.2025.179639","DOIUrl":"10.1016/j.scitotenv.2025.179639","url":null,"abstract":"<div><div>Bioaccessibility of polycyclic aromatic hydrocarbons (PAH) in soils is often determined by extraction with hydroxypropyl-β-cyclodextrin (HPCD), yet there is no standardized approach for determining bioaccessible concentrations (<em>c</em><sub>bio</sub>), which are either calculated or directly measured. Additionally, most studies analyze solely the 16 EPA PAH, neglecting more carcinogenic PAH with higher relative potency factors (RPFs) and often disregarding PAH sources. This study examines optimal <em>c</em><sub>bio</sub> determination by providing mass balances of HPCD extraction. Moreover, this study investigates the bioaccessibility of 71 PAH in five urban soils, considering their petrogenic to pyrogenic sources and their carcinogenic potential.</div><div>Checking HPCD mass balances revealed that mechanical stress and residual HPCD can artificially increase the residual PAH content (<em>c</em><sub>non-bio</sub>), making <em>c</em><sub>bio</sub> calculation using <em>c</em><sub>non-bio</sub> unfeasible. We therefore recommend re-extraction of HPCD extracts to measure <em>c</em><sub>bio</sub>. The measured <em>c</em><sub>bio</sub> of PAH depended on PAH sources, with lower <em>c</em><sub>bio</sub> observed in petrogenic coal-containing soils. Within <em>c</em><sub>bio</sub>, 7<em>H</em>-benzo[<em>c</em>]fluorene contributes most to toxicity equivalents (TEQs), while the most carcinogenic EPA PAH, benzo[<em>a</em>]pyrene, contributes little. Dibenzopyrenes, considered highly carcinogenic, were not bioaccessible. TEQs could only be calculated for 24 PAH with available RPFs. However, additional PAH with evidence for carcinogenicity were also bioaccessible, with 2-methylfluoranthene and benzo[<em>c</em>]phenanthrene reaching <em>c</em><sub>bio</sub> of &gt;1 mg/kg. Notably, benzo[<em>c</em>]phenanthrene is classified by the IARC as a group 2B carcinogen.</div><div>These findings suggest that particularly 7<em>H</em>-benzo[<em>c</em>]fluorene and benzo[<em>c</em>]phenanthrene should be included in routine risk assessments due to their carcinogenic categorization and bioaccessibility. Future studies should focus on expanding carcinogenicity data and RPF values for additional PAH.</div></div>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":"982 ","pages":"Article 179639"},"PeriodicalIF":8.2,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143942492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
From winery by-product to soil improver? – A comprehensive review of grape pomace in agriculture and its effects on soil properties and functions 从酿酒厂副产品到土壤改良剂?综述了葡萄渣在农业中的应用及其对土壤性质和功能的影响
IF 8.2 1区 环境科学与生态学
Science of the Total Environment Pub Date : 2025-05-14 DOI: 10.1016/j.scitotenv.2025.179611
Christian Buchmann , Sven Korz , Anja Moraru , Elke Richling , Sullivan Sadzik , Maren Scharfenberger-Schmeer , Katherine Muñoz
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