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Buried interface regulation for efficient and stable perovskite minimodules 实现高效稳定的包晶最小模块的埋入式界面调节
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-28 DOI: 10.1016/j.nanoen.2024.110406
Ruoyao Xu , Yulu Sun , Jinfei Dai , Xinyi Zhu , Peizhou Li , Xiangrong Cao , Jun Xi , Fang Yuan , Chuantian Zuo , Liming Ding , Yingguo Yang , Jingrui Li , Jie Xu , Alex K.-Y. Jen , Zhaoxin Wu , Hua Dong
{"title":"Buried interface regulation for efficient and stable perovskite minimodules","authors":"Ruoyao Xu ,&nbsp;Yulu Sun ,&nbsp;Jinfei Dai ,&nbsp;Xinyi Zhu ,&nbsp;Peizhou Li ,&nbsp;Xiangrong Cao ,&nbsp;Jun Xi ,&nbsp;Fang Yuan ,&nbsp;Chuantian Zuo ,&nbsp;Liming Ding ,&nbsp;Yingguo Yang ,&nbsp;Jingrui Li ,&nbsp;Jie Xu ,&nbsp;Alex K.-Y. Jen ,&nbsp;Zhaoxin Wu ,&nbsp;Hua Dong","doi":"10.1016/j.nanoen.2024.110406","DOIUrl":"10.1016/j.nanoen.2024.110406","url":null,"abstract":"<div><div>Buried interface in perovskite solar cells (PSCs) is currently a highly focused study area due to their impact on device performance and stability. However, it remains a major challenge to rationally design buried interfaces. The properties of the buried interface not only affect carrier recombination and transport of perovskite layers, but also their crystallinity, orientation, and defects. In this work, ligand-modified ZrO<sub>2</sub> nanoparticles (NPs) were introduced as a functional bridging layer at the buried interface of the PSCs. The dense, ultra-thin insulating layer can effectively block holes but allow electrons to pass through the \"tunneling\" effect, thereby reducing charge recombination between the ETL and the perovskite bulk. In addition, ZrO<sub>2</sub> NPs functionalized with NH<sub>2</sub> groups can reconfigure the substrate to realize oriented growth of perovskite film and minimize bottom defects. This dual modulation of carrier behavior and film physical properties at the buried interface is very effective for improving both device performance and scaling. The efficiency of the champion small-area PSCs (with an active area of 0.0655 cm<sup>2</sup>) could reach 26.51 %. Moreover, the efficiencies of the PSC minimodules could reach 23.42 % at 23.23 cm<sup>2</sup> (certified as 22.32 %) and 22.26 % at 87.45 cm<sup>2</sup>, respectively. These devices also showed excellent shelf-life/light soaking stability based on the advanced level of ISOS stability protocols.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"133 ","pages":"Article 110406"},"PeriodicalIF":16.8,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142520242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Large increase of the thermoelectric power factor in multi-barrier nanodevices 大幅提高多势垒纳米器件的热电功率因数
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-28 DOI: 10.1016/j.nanoen.2024.110391
Antonella Masci , Elisabetta Dimaggio , Neophytos Neophytou , Dario Narducci , Giovanni Pennelli
{"title":"Large increase of the thermoelectric power factor in multi-barrier nanodevices","authors":"Antonella Masci ,&nbsp;Elisabetta Dimaggio ,&nbsp;Neophytos Neophytou ,&nbsp;Dario Narducci ,&nbsp;Giovanni Pennelli","doi":"10.1016/j.nanoen.2024.110391","DOIUrl":"10.1016/j.nanoen.2024.110391","url":null,"abstract":"<div><div>Improving the power factor (PF) of thermoelectric materials, crucial for enhancing the power output of thermoelectric generators, is challenging due to the adverse interdependence of the Seebeck coefficient and the electrical conductivity on carrier density. We introduce a novel strategy employing energy filtering via built-in potential barriers to alleviate this dependency, significantly enhancing the PF. Utilizing electron-beam lithography, we developed a Si-based nanodevice featuring a multiple well/barrier design. Measurements yielded a PF of 11 mW m<sup>−1</sup> K<sup>−2</sup>, more than doubling the optimal PF achievable in bulk silicon. Experimental findings align well with theoretical models, affirming the efficacy of the approach. Leveraging established silicon technologies in device fabrication unveils pathways for on-chip micro-energy harvesters and localized Peltier coolers. Moreover, the results validate a material-agnostic energy filtering model, guiding the creation of PF-enhanced devices across various thermoelectric materials.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110391"},"PeriodicalIF":16.8,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142520246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ transcribed local coordinations from CoP nanorods pre-catalyst for efficient electrocatalytic oxygen evolution 用于高效电催化氧进化的 CoP 纳米棒前催化剂的原位转录局部配位
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-28 DOI: 10.1016/j.nanoen.2024.110414
Yuhao Zhang , Xiuxiu Zhang , Jing Zhang , Chenyu Yang , Baojie Li , Jianglong Guo , Jingjing Jiang , Wanlin Zhou , Donghai Wu , Dongwei Ma , Shiqiang Wei , Qinghua Liu
{"title":"In-situ transcribed local coordinations from CoP nanorods pre-catalyst for efficient electrocatalytic oxygen evolution","authors":"Yuhao Zhang ,&nbsp;Xiuxiu Zhang ,&nbsp;Jing Zhang ,&nbsp;Chenyu Yang ,&nbsp;Baojie Li ,&nbsp;Jianglong Guo ,&nbsp;Jingjing Jiang ,&nbsp;Wanlin Zhou ,&nbsp;Donghai Wu ,&nbsp;Dongwei Ma ,&nbsp;Shiqiang Wei ,&nbsp;Qinghua Liu","doi":"10.1016/j.nanoen.2024.110414","DOIUrl":"10.1016/j.nanoen.2024.110414","url":null,"abstract":"<div><div>Transition metal-based compounds generally undergo dynamic surface changes to form active metal (oxy)hydroxides during the oxygen evolution reaction (OER). However, due to the core-shell structure formed by insufficient surface reconstruction and the complexity of the dynamic evolution process, understanding the origin of the catalytic performance derived from the pre-catalyst itself is a great challenge. Herein, we first reveal that a transcriptional relationship of local coordination between the pre-catalyst and the <em>in-situ</em> generated active species by regulating the lattice strain during phosphating with the aid of the nonequilibrium diffusion Kirkendall effect. The combination of electrochemical, <em>ex-situ</em> X-ray absorption fine structure spectroscopy (XAFS) and <em>in-situ</em> synchrotron radiation Fourier transform infrared spectroscopy (SR-FTIR) characterizations uncover that the variation trend of the first shell Co–O bond length in the active species is inherited from the Co–P bond length in the pre-catalyst and the shortened optimal distance of the second shell dual-Co sites is strongly correlated with the inherent OER activity. Thereby, a relation mapping to modify the coordination structure of the active species via the lattice strain of the pre-catalysts is established. This work not only provides a strategy to regulate OER performance via the lattice strain, but also sheds light on the role of the structural and compositional evolution of catalysts in activity during electrocatalytic reactions.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110414"},"PeriodicalIF":16.8,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimized architectural engineering and interface modulation in metallic-phase selenide for exceptional sodium-storage performance 优化金属相硒化物的结构工程和界面调制,实现卓越的钠存储性能
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-28 DOI: 10.1016/j.nanoen.2024.110408
Lei Wang , Yanchen Fan , Yan Zhao , Qiang Yuan , Haoxi Ben , Hui (Claire) Xiong , Ying Shao , Chunfu Lin , Chunrong Ma
{"title":"Optimized architectural engineering and interface modulation in metallic-phase selenide for exceptional sodium-storage performance","authors":"Lei Wang ,&nbsp;Yanchen Fan ,&nbsp;Yan Zhao ,&nbsp;Qiang Yuan ,&nbsp;Haoxi Ben ,&nbsp;Hui (Claire) Xiong ,&nbsp;Ying Shao ,&nbsp;Chunfu Lin ,&nbsp;Chunrong Ma","doi":"10.1016/j.nanoen.2024.110408","DOIUrl":"10.1016/j.nanoen.2024.110408","url":null,"abstract":"<div><div>Transition metal selenides (TMSs) exhibit promise as anode materials for sodium-ion batteries (SIBs) due to their high specific capacity and diverse electronic properties. However, practical implementation faces challenges such as structural deterioration, solid-electrolyte interphase (SEI) instability, and diminished coulombic efficiency, especially at the nanoscale. Here, we introduce a novel approach that combines surface engineering of Fe<sub>3</sub>Se<sub>4</sub> with an interface engineering strategy (Fe<sub>3</sub>Se<sub>4</sub>@NC) to effectively address these issues. By incorporating engineered void spaces and an electrolyte-blocking layer within micrometer-sized secondary clusters, Fe<sub>3</sub>Se<sub>4</sub> nanoparticles gain the ability to expand and contract freely during cycling, thereby preserving interparticle connections and enhancing the structural integrity. The synergy of surface engineering with a nitrogen-doped carbon layer and interface engineering through electrolyte modulation leads to an outstanding 95.1 % initial Coulombic efficiency in the Fe<sub>3</sub>Se<sub>4</sub>@NC electrode. Even after 2000 cycles at 5 A g<sup>−1</sup>, the electrode retains over 89.2 % of its initial capacity with an average specific capacity of 450 mAh g<sup>−1</sup>. In situ transmission electron microscopy (TEM) and in situ X-ray diffraction (XRD) analysis shed light on the structural evolution and sodiation dynamics during charge/discharge process. Experimental investigations and DFT calculations provide a comprehensive understanding of the SEI composition and the structural stability of the composite.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110408"},"PeriodicalIF":16.8,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142520241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient electrical energy conversion strategies from triboelectric nanogenerators to practical applications: A review 从三电纳米发电机到实际应用的高效电能转换策略:综述
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-26 DOI: 10.1016/j.nanoen.2024.110383
Hu Zhang , Yurun Chen , Long Deng , Xifeng Zhu , Caihua Xu , Liqiang Xie , Qiliang Yang , Haitao Zhang
{"title":"Efficient electrical energy conversion strategies from triboelectric nanogenerators to practical applications: A review","authors":"Hu Zhang ,&nbsp;Yurun Chen ,&nbsp;Long Deng ,&nbsp;Xifeng Zhu ,&nbsp;Caihua Xu ,&nbsp;Liqiang Xie ,&nbsp;Qiliang Yang ,&nbsp;Haitao Zhang","doi":"10.1016/j.nanoen.2024.110383","DOIUrl":"10.1016/j.nanoen.2024.110383","url":null,"abstract":"<div><div>Triboelectric nanogenerators (TENGs) have emerged as a promising energy-harvesting technology that can efficiently convert ambient mechanical energy into electricity. Compared to traditional electromagnetic generators, TENGs offer advantages such as high power density, low cost, material flexibility, and simple fabrication, demonstrating broad application prospects in self-powered sensors, wearable devices, and biomedical systems. However, the mismatch between the output electrical energy of TENGs (alternating current, high voltage, low current) and the requirements of most electronic devices (direct current, constant voltage) often limits their practical application. To enhance the energy conversion efficiency of TENGs in real-world applications, researchers have developed various efficient energy conversion circuits and implementation strategies. This paper provides a comprehensive overview of advanced strategies for achieving pulse triggering, AC–DC conversion, voltage regulation, and energy storage, covering the entire process of TENG electrical energy conversion. In addition, several efficient TENG energy conversion circuits are presented for different application scenarios. Finally, the challenges and future directions of TENG energy conversion circuit design are discussed, aiming to provide a reference for designing more efficient TENG energy conversion systems.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110383"},"PeriodicalIF":16.8,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent progress towards the diverse practical applications of Lithium-sulfur batteries 实现锂硫电池多样化实际应用的最新进展
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-26 DOI: 10.1016/j.nanoen.2024.110387
Mahrima Majid, Zhiping Deng, Xiaolei Wang
{"title":"Recent progress towards the diverse practical applications of Lithium-sulfur batteries","authors":"Mahrima Majid,&nbsp;Zhiping Deng,&nbsp;Xiaolei Wang","doi":"10.1016/j.nanoen.2024.110387","DOIUrl":"10.1016/j.nanoen.2024.110387","url":null,"abstract":"<div><div>Rechargeable Lithium-sulfur batteries (LSBs) have garnered significant attention as promising alternatives to traditional Lithium-ion batteries (LIBs) due to their high theoretical energy density, lower cost of raw materials, enhanced safety features, and reduced environmental footprint. However, the practical application of LSBs faces significant challenges due to several issues such as poor electrical conductivity and substantial volumetric variations of the sulfur cathode, polysulfide shuttle effect, and limited practical energy density. This review explores the recent advancements aimed at mitigating these issues, with a particular focus on addressing some diverse practical factors such as temperature resilience, extended shelf-life, enhanced safety, and flexibility in addition to considerations like rapid charging, long life span, and scalability for widespread commercialization of LSBs. The review also outlines the challenges and future perspectives of the development of practical LSBs. The aim of the review is to highlight the versatility that LSBs can bring to the energy transition sector and the recent progress that can take LSBs closer to their practical implementations. Ultimately, this review seeks to contribute to the broader discourse on the potential of LSBs and encourage further research and development efforts to facilitate their integration into the evolving landscape of global energy storage systems.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110387"},"PeriodicalIF":16.8,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sb-anchoring single-crystal engineering enables ultra-high-Ni layered oxides with high-voltage tolerance and long-cycle stability 掺锑单晶工程实现了具有高压耐受性和长周期稳定性的超高镍层状氧化物
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-26 DOI: 10.1016/j.nanoen.2024.110413
Zhuolin Yang , Zhikun Zhao , Xinyu Zhang , Shijie Lu , Yuxiang Zhang , Qi Liu , Feng Wu , Guoqiang Tan , Daobin Mu
{"title":"Sb-anchoring single-crystal engineering enables ultra-high-Ni layered oxides with high-voltage tolerance and long-cycle stability","authors":"Zhuolin Yang ,&nbsp;Zhikun Zhao ,&nbsp;Xinyu Zhang ,&nbsp;Shijie Lu ,&nbsp;Yuxiang Zhang ,&nbsp;Qi Liu ,&nbsp;Feng Wu ,&nbsp;Guoqiang Tan ,&nbsp;Daobin Mu","doi":"10.1016/j.nanoen.2024.110413","DOIUrl":"10.1016/j.nanoen.2024.110413","url":null,"abstract":"<div><div>Ni-rich layered oxides are promising cathodes for Li-ion batteries, but the inherent structural defects result in severe surface/bulk degradation during long cycling, especially at high cutoff voltage. Herein we propose a Sb-anchoring single-crystalline engineering to enhance the microstructural and electrochemical stability of ultra-high-Ni layered oxides, where the surface-enriched Sb doping inhibits Li-Ni mixing, suppressing the undesired layered to mixed/rock-salt phase transformation; the bulk-doped Sb rivets into Ni sites, reinforcing the bulk phase stability; the single-crystal endows enhanced crack resistance and reduced surface area, preventing surface parasitic reactions and the subsequent proliferation of cathode electrolyte interfaces. In-situ XRD reveals an essential correlation between cycle stability and phase reversibility, whereas Sb doping into both surface and bulk structures showcases a continuous anchoring effect, largely enhancing the phase transformation reversibility. DFT calculations prove a high oxidation tolerance, as Ni<sup>2+</sup> diffusion barrier is higher than the pure cathode. A representative Li(Ni<sub>0.9</sub>Co<sub>0.05</sub>Mn<sub>0.05</sub>)<sub>0.99</sub>Sb<sub>0.01</sub>O<sub>2</sub> cathode exhibits a high-voltage up to 4.6 V, and a Li(Ni<sub>0.9</sub>Co<sub>0.05</sub>Mn<sub>0.05</sub>)<sub>0.99</sub>Sb<sub>0.01</sub>O<sub>2</sub>//graphite full-cell demonstrates an ultra-high capacity retention of 93.4 % after 1000 cycles at 1 C in 3.0−4.2 V. This simple and efficient cathode engineering will promote the promising application of Ni-rich layered oxides in high-energy Li-ion batteries.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110413"},"PeriodicalIF":16.8,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biodegradable, stretchable, and high-performance triboelectric nanogenerators through interfacial polarization in bilayer structure 通过双层结构中的界面极化实现可生物降解、可拉伸和高性能的三电纳米发电机
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-24 DOI: 10.1016/j.nanoen.2024.110411
Yong-Jin Park , Min Sub Kwak , Yonggi Kim , Sangyun Na , Yoojin Chang , Young-Ryul Kim , Haryeong Cho , Seungjae Lee , Jae Joon Kim , Hyunhyub Ko
{"title":"Biodegradable, stretchable, and high-performance triboelectric nanogenerators through interfacial polarization in bilayer structure","authors":"Yong-Jin Park ,&nbsp;Min Sub Kwak ,&nbsp;Yonggi Kim ,&nbsp;Sangyun Na ,&nbsp;Yoojin Chang ,&nbsp;Young-Ryul Kim ,&nbsp;Haryeong Cho ,&nbsp;Seungjae Lee ,&nbsp;Jae Joon Kim ,&nbsp;Hyunhyub Ko","doi":"10.1016/j.nanoen.2024.110411","DOIUrl":"10.1016/j.nanoen.2024.110411","url":null,"abstract":"<div><div>The increasing demand for wearable electronics has led to the development of triboelectric nanogenerators (TENGs) as a promising energy harvesting and sensing technology. However, conventional TENGs often utilize non-biodegradable materials, contributing to environmental pollution. In this work, we present a stretchable and biodegradable TENG based on hydroxyethyl cellulose (HEC) and gelatin (HG-TENG). The HG-TENG features a bilayered structure, where the large difference in their relative permittivity between HEC and gelatin induces interfacial polarization, effectively mitigating charge recombination and enhancing triboelectric performance. The optimized HG-TENG achieves an open-circuit voltage (V<sub>oc</sub>) of 93 V, a maximum power density of 57.8 µW/cm<sup>2</sup>, and can power 38 blue light-emitting diodes. The device exhibits a stretchability of 150 % and biodegrades within 3 hours in phosphate-buffered saline. Furthermore, we demonstrate the application of the HG-TENG as a wearable sensor by modifying it with trichloro(1H, 1H, 2H, 2H-perfluorooctyl)silane (FOTS) (FHG-TENG). The FHG-TENG-based smart glove, integrated with machine learning algorithms, enables real-time monitoring of blood pressure waveforms and finger motions, showcasing its potential for human-machine interfaces. The smart glove, equipped with five FHG-TENGs on the proximal interphalangeal joints of each finger, detects diverse finger gestures and generates voltage signals that control a robotic hand in real-time, demonstrating effective human-machine interaction through synchronized motion. Moreover, the smart glove achieves a high recognition accuracy of 96.15 % for 10 different hand sign languages.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110411"},"PeriodicalIF":16.8,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142489287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Moisture-triggered hybrid soft actuator and electric generator for self-sensing wearables and adaptive human-environment interaction 用于自感应可穿戴设备和自适应人与环境交互的湿气触发式混合软致动器和发电机
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-24 DOI: 10.1016/j.nanoen.2024.110410
Liuxiang Zhan , Jian Lv , Shaohua Chen , Adit Gupta , Yangyang Xin , Feng Jiang , Jin Pyo Lee , Jiaqing Xiong , Ni Wang , Pooi See Lee
{"title":"Moisture-triggered hybrid soft actuator and electric generator for self-sensing wearables and adaptive human-environment interaction","authors":"Liuxiang Zhan ,&nbsp;Jian Lv ,&nbsp;Shaohua Chen ,&nbsp;Adit Gupta ,&nbsp;Yangyang Xin ,&nbsp;Feng Jiang ,&nbsp;Jin Pyo Lee ,&nbsp;Jiaqing Xiong ,&nbsp;Ni Wang ,&nbsp;Pooi See Lee","doi":"10.1016/j.nanoen.2024.110410","DOIUrl":"10.1016/j.nanoen.2024.110410","url":null,"abstract":"<div><div>As ubiquitous energy available from the human body and surrounding environment, moisture converted into both mechanical and electrical energy simultaneously offers appealing strategies for adaptive self-sensing wearables. However, most energy conversion devices typically achieve only single-form energy conversion. Here, we report an integrated device concept that breaks this limit—a moisture-triggered hybrid soft actuator and electric generator (MTAEG) capable of generating reliable actuation and superior electrical output concurrently. By utilizing printable asymmetric electrodes and hygroscopic polyelectrolyte composite film, we achieve the all-in-one device with hybrid functionalities for effective moisture-energy conversion. The MTAEG demonstrates reversible stable actuation (125° bending angle at 80 % RH) and offers a current density of up to 76.41 μA cm<sup>−2</sup>, accompanied by a power density of 11.24 μW cm<sup>−2</sup>. This outstanding electrical performance exceeds that of most reported conventional moist-electric generators, thanks to the optimization of asymmetric electroactive electrodes and the excellent ion-transport ability of the polyelectrolyte composites. Moreover, MTAEGs can be compatibly integrated into arrays for various applications, including bioenergy modules, self-powered tracking/sensing, adaptive personal comfort management, and physical activity monitoring. Such printable MTAEGs with ingenious materials combinations, high-throughput fabrication, and attractive performance offer a promising hybrid platform for self-sensing wearables and adaptive human-environment interaction.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110410"},"PeriodicalIF":16.8,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142489021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wet-adaptive strain sensor based on hierarchical core-sheath yarns for underwater motion monitoring and energy harvesting 基于分层芯鞘纱线的湿自适应应变传感器,用于水下运动监测和能量收集
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2024-10-24 DOI: 10.1016/j.nanoen.2024.110407
Haiyang Jiang , Ruicheng Zhang , Keshuai Liu , Yuting Luo , Zhiyong Peng , Senyuan Ye , Yuan Qin , Xianzhang Wu , Chong Gao , Yingcun Liu , Duo Xu , Weilin Xu
{"title":"Wet-adaptive strain sensor based on hierarchical core-sheath yarns for underwater motion monitoring and energy harvesting","authors":"Haiyang Jiang ,&nbsp;Ruicheng Zhang ,&nbsp;Keshuai Liu ,&nbsp;Yuting Luo ,&nbsp;Zhiyong Peng ,&nbsp;Senyuan Ye ,&nbsp;Yuan Qin ,&nbsp;Xianzhang Wu ,&nbsp;Chong Gao ,&nbsp;Yingcun Liu ,&nbsp;Duo Xu ,&nbsp;Weilin Xu","doi":"10.1016/j.nanoen.2024.110407","DOIUrl":"10.1016/j.nanoen.2024.110407","url":null,"abstract":"<div><div>Bifunctional flexible electronics with motion monitoring and energy harvesting have broad application prospects in day-to-day activities of human society. Nevertheless, conventional electronics are difficult to adapt to the wear comfortability and anti-sensing interference properties in wet environments. Herein, a wet-adaptive spandex/graphene@cotton/polyurethane yarn (SGCPY) sensor is fabricated with excellent sensing and triboelectric performance, which comprises core layer of spandex fibers, middle layer of graphene@cotton sensing fibers and outer layer of spindle-knotted polyurethane nanofibers. Benefiting from its unique structure, as-prepared SGCPY sensor exhibits high mechanical properties (∼80 %), superhydrophobic performance (&gt;130°), good strain sensitivity (1.82) and fatigue resistance (12,000 cycles) even under water condition. The usage of the SGCPY sensor is demonstrated for the stable monitoring of human body motions and human-machine interaction in both air and water environments. When SGCPY sensor weave as plain fabric, the textile also can convert various mechanical energy into electric power for driving electronic device, showing a maximum voltage of ∼3.9 V and ∼0.7 V with solid-solid and liquid-solid contact. This work fosters the in-depth study of textile-based electronics for underwater applications and highlights the promising prospects of multi-functional flexible electronics based on textiles.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"132 ","pages":"Article 110407"},"PeriodicalIF":16.8,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142488708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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