Journal of Solid State Chemistry最新文献

筛选
英文 中文
Optimizing adding sequence of carbon black in solid-state synthesis of hierarchical TS-1 zeolite for efficient 1-hexene epoxidation
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-24 DOI: 10.1016/j.jssc.2025.125339
Yuan Li , Shengkai Sun , Hanfang Liu , Wenna Wang , Dehong Chen , Yu Yang , Feng Liu , Bin Yu , Jia Liu , Binjie Li , Lei Wang , Bin Li
{"title":"Optimizing adding sequence of carbon black in solid-state synthesis of hierarchical TS-1 zeolite for efficient 1-hexene epoxidation","authors":"Yuan Li ,&nbsp;Shengkai Sun ,&nbsp;Hanfang Liu ,&nbsp;Wenna Wang ,&nbsp;Dehong Chen ,&nbsp;Yu Yang ,&nbsp;Feng Liu ,&nbsp;Bin Yu ,&nbsp;Jia Liu ,&nbsp;Binjie Li ,&nbsp;Lei Wang ,&nbsp;Bin Li","doi":"10.1016/j.jssc.2025.125339","DOIUrl":"10.1016/j.jssc.2025.125339","url":null,"abstract":"<div><div>Epoxidation of olefin catalyzed by titanium silicalite-1 (TS-1) can obtain important intermediate epoxides of industrial production in a green and pollution-free manner. However, due the problem of macromolecules transport path restraint, which cause the catalyst to fail in lifetime and activity. Strategically, to increase the transport channel of macromolecules and shorten the transport path, it is necessary to introduce mesoporous structures into zeolite. Here, we report a solid-state synthesis of hierarchical TS-1 zeolite by optimizing carbon black sequence. The texture property of hierarchical TS-1 can be optimized by carbon black. Most importantly, the addition sequence of carbon black can impact the porosity of hierarchical TS-1. The hierarchical zeolite is synthesized by incorporating 0.2 g carbon black into the seeds. When carbon black is firstly combined with seeds, the enhanced interaction facilitates the subsequent growth process, leading to large surface area from mesopores (121 m<sup>2</sup>/g) and abundant pores size (8–40 nm) and enhanced exposure of Ti active sites. The optimized hierarchical TS-1 possesses excellent catalytic performance with high conversion rate (24.4 %) and similar selectivity (93.8 %), which are 1.6 times higher than that of traditional TS-1 zeolites.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125339"},"PeriodicalIF":3.2,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143706348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Band Gap Tuning in Inorganic Chlorine-Based Halide Perovskites Via Solid-State Synthesis at Room Temperature
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-24 DOI: 10.1016/j.jssc.2025.125341
Mahsa Shekarnoush , Francisco S. Aguirre-Tostado , Leunam Fernandez-Izquierdo , Manuel Quevedo Lopez
{"title":"Band Gap Tuning in Inorganic Chlorine-Based Halide Perovskites Via Solid-State Synthesis at Room Temperature","authors":"Mahsa Shekarnoush ,&nbsp;Francisco S. Aguirre-Tostado ,&nbsp;Leunam Fernandez-Izquierdo ,&nbsp;Manuel Quevedo Lopez","doi":"10.1016/j.jssc.2025.125341","DOIUrl":"10.1016/j.jssc.2025.125341","url":null,"abstract":"<div><div>Inorganic chlorine-based halide perovskites have emerged as promising materials in optoelectronics and photovoltaics due to their high electron mobility and tunable optical properties. However, traditional solution-based synthesis methods for these perovskites face significant challenges, such as poor solubility, environmental sensitivity, and scalability issues. This paper introduces an energy-efficient, environmentally friendly approach using ball-milling for room-temperature solid-state synthesis of inorganic chlorine-based halide perovskites with variable band gaps, including CsCdCl<sub>3</sub> (4.72 eV) and mixed chlorine systems CsPbBr<sub>2</sub>Cl (2.58 eV) and CsPbCl<sub>2</sub>Br (2.40 eV). This solid-state method not only effectively overcomes the limitations of solution-based synthesis, including the need for toxic solvents and significant environmental impact, but also enables precise band gap tuning and yields materials with excellent phase control, high purity, and stability. The stability of the resulting materials was evaluated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis, and photoluminescence (PL). The results show remarkable stability for up to 90 days when stored in air at room temperature. Utilizing the room-temperature solid-state approach to synthesize chlorine-based halide perovskites not only overcomes the limitations of traditional methods but also paves the way for the development of advanced optoelectronic devices.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"348 ","pages":"Article 125341"},"PeriodicalIF":3.2,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143786219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of sintering temperature on cation distribution in CoFe2O4 nanoparticles
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-24 DOI: 10.1016/j.jssc.2025.125338
V. Bilovol , P. Jeleń , K. Mech , K. Sokołowski , P. Botella , E. Bandiello , F.J. Manjón , D. Errandonea
{"title":"Effect of sintering temperature on cation distribution in CoFe2O4 nanoparticles","authors":"V. Bilovol ,&nbsp;P. Jeleń ,&nbsp;K. Mech ,&nbsp;K. Sokołowski ,&nbsp;P. Botella ,&nbsp;E. Bandiello ,&nbsp;F.J. Manjón ,&nbsp;D. Errandonea","doi":"10.1016/j.jssc.2025.125338","DOIUrl":"10.1016/j.jssc.2025.125338","url":null,"abstract":"<div><div>We report a study of the cation arrangement in CoFe<sub>2</sub>O<sub>4</sub> nanoparticles synthesized using a co-precipitation method followed by high-temperature sintering in the range of 500–1000 °C. Analysis of the samples by Raman, infrared, and X-ray photoelectron spectroscopy (Fe 2p<sub>3/2</sub> and Co 2p<sub>3/2</sub>) revealed that the sintering temperature influences the distribution of cations in the spinel lattice. Specifically, increasing the sintering temperature leads to an increase in the inversion degree parameter (γ), which represents the fraction of Co ions residing in octahedral sites, driving the structure toward a fully inverted spinel. These results are in good agreement with those previously obtained by <sup>57</sup>Fe Mössbauer spectroscopy, X-ray diffraction, and X-ray absorption experiments on the same set of samples. Additionally, as shown by the UV–visible spectra, the cationic distribution in the samples clearly affects the band gap value (2.5–2.8 eV).</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125338"},"PeriodicalIF":3.2,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143697919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructural, hydrogenation and electrochemical properties of La2Mg1-xYxNi10Mn0.5 (x= 0.1, 0.38) alloys for Ni-MH battery anode
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-24 DOI: 10.1016/j.jssc.2025.125340
Zohre Salighe , Hadi Arabi , ShabanReza Ghorbani , Mojtaba Komeili
{"title":"Microstructural, hydrogenation and electrochemical properties of La2Mg1-xYxNi10Mn0.5 (x= 0.1, 0.38) alloys for Ni-MH battery anode","authors":"Zohre Salighe ,&nbsp;Hadi Arabi ,&nbsp;ShabanReza Ghorbani ,&nbsp;Mojtaba Komeili","doi":"10.1016/j.jssc.2025.125340","DOIUrl":"10.1016/j.jssc.2025.125340","url":null,"abstract":"<div><div>Metal hydride alloys are promising materials for hydrogen storage and Ni-MH battery applications, yet challenges remain in optimizing their composition and performance. In this study, hydrogen absorbent alloys La<sub>2</sub>Mg<sub>1-x</sub>Y<sub>x</sub>Ni<sub>10</sub>Mn<sub>0.5</sub> (x = 0.1, 0.38) were produced by vacuum electric arc remelting. Crystal structure investigations revealed the presence of the LaNi<sub>5</sub> phase in both alloys and the formation of the (La, Mg)<sub>2</sub> Ni<sub>7</sub> phase in La<sub>2</sub>Mg<sub>0·62</sub>Y<sub>0·38</sub>Ni<sub>10</sub>Mn<sub>0.5</sub> alloy. The alloy with x = 0.38 demonstrated superior properties, including increased hydrogen absorption capacity (1.925 wt% vs 1.667 wt%) and improved hydrogenation kinetics which were related to the A<sub>2</sub>B<sub>7</sub> superstructure phase. Electrochemical tests conducted at temperatures of 273, 283, 298, 313, and 338 K showed that an increasing temperature improved electrode surface activation. At room temperature, the retention rates of the discharge capacity after 50 charge and discharge cycles for the alloy electrodes (x = 0.1, 0.38) were 93.32 % and 96.56 % respectively, with maximum discharge capacities of 378.01 and 400.77 mAh/g. The high rate dischargeability (HRD) was evaluated, at different temperatures, demonstrating that the presence of a multiphase structure in the alloy with x = 0.38 created interphase boundaries, which reduced distortion, and network strain. These interphase boundaries also provided tunnels for hydrogen diffusion, improving activation and electrochemical stability. These findings suggest that partial substitution of Y for Mg in La–Mg–Ni based alloys offers a promising approach for developing high-performance hydrogen storage materials.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"348 ","pages":"Article 125340"},"PeriodicalIF":3.2,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143786222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of cesium ion sieve composite material and its adsorption properties of Cs+
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-22 DOI: 10.1016/j.jssc.2025.125327
Jiumei Chu, Debin Wang, Xue Yang, Mengyu Lin, Dianquan Dong
{"title":"Preparation of cesium ion sieve composite material and its adsorption properties of Cs+","authors":"Jiumei Chu,&nbsp;Debin Wang,&nbsp;Xue Yang,&nbsp;Mengyu Lin,&nbsp;Dianquan Dong","doi":"10.1016/j.jssc.2025.125327","DOIUrl":"10.1016/j.jssc.2025.125327","url":null,"abstract":"<div><div>In the previous work, our research group adopted sol-gel technology to incorporate trace Zn<sup>2+</sup> into the Ti–O lattice of Cs<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub> to improve the cell structure and prepared zinc-doped titanate precursor material (CZnTO). This precursor is acid-treated to form a zinc-doped protonated titanate (HZnTO). Based on previous studies in our research group, this paper proposed a membrane support and creating technology for preparing powdered zinc-doped titanium-based cesium ion sieves. It made a batch adsorption test to explore the adsorption performance of Cs<sup>+</sup>. The main research contents are as follows: A phase transition synthesis method is used to composite PVDF material with powdered ion sieve HZnTO to form a microporous hydrophobic polymer membrane HZnTO@PVDF. The higher the pH in the solution, the greater its saturated adsorption capacity. The composite membrane maintains good stability in both acidic and alkaline solutions. Compared with the powdered ion sieves, HZnTO@PVDF the adsorption rate is significantly faster, reaching saturated adsorption capacity in about 2 h in 3000 mg/L Cs<sup>+</sup> solution. HZnTO @ PVDF has good cyclic adsorption stability, maintaining 90.33 % of the initial adsorption capacity after five adsorption-desorption cycles. Moreover, after 5 cycles, the composite membrane still maintained the integrity of its original structure.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125327"},"PeriodicalIF":3.2,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143738194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistically enhanced selective adsorption of cationic dyes from aqueous solutions using porphyrin-confined zeolitic imidazolate framework
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-22 DOI: 10.1016/j.jssc.2025.125329
Zahra Karami, Alireza Abbasi, Peyman Ghorbani, Samira Zamani
{"title":"Synergistically enhanced selective adsorption of cationic dyes from aqueous solutions using porphyrin-confined zeolitic imidazolate framework","authors":"Zahra Karami,&nbsp;Alireza Abbasi,&nbsp;Peyman Ghorbani,&nbsp;Samira Zamani","doi":"10.1016/j.jssc.2025.125329","DOIUrl":"10.1016/j.jssc.2025.125329","url":null,"abstract":"<div><div>Encapsulation of a free base meso-Tetra(4-carboxyphenyl)porphine ligand (TCPP) into the cavities of zeolitic imidazolate framework (ZIF-8) via the bottle-around-ship (BAS) approach generated an extremely selective reusable biomimetic adsorbent (TCPP@ZIF-8) for the elimination of hazardous cationic organic dyes. Entrapment in the MOF host prevents TCPP aggregation and provides a high surface area and protective environment for better TCPP dispersion, enhancing dye adsorption via electrostatic interaction. The appropriate synthesis of the adsorbent and the stability of the MOF throughout the modification were confirmed by multiple analyses. After being modified with TCPP, the adsorption efficacy of porous ZIF-8 is substantially increased, as seen by the significantly improved methyl violet (MV) cationic dye removal efficiency of TCPP@ZIF-8 (83.46 % and 41.67 mg/g at 10 mg dosage within 15 min) compared to ZIF-8 alone (23.83 % and 11.91 mg/g at 10 mg dosage within 15 min). The kinetic and isotherm studies revealed that adsorption adhered to pseudo-second-order (PSO) kinetics and the Langmuir isotherm, implies that the process is primarily governed by chemisorption and occurs as a monolayer on homogeneous adsorption sites. According to the reusing study, the stability of the adsorbent did not alter during the adsorption process, and the adsorbent could be easily recycled for use in consecutive cycles.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125329"},"PeriodicalIF":3.2,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143748464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of iron-based metal-organic frameworks for the efficient removal of industrial dye: Effect of ligands on morphological and adsorption parameters
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-21 DOI: 10.1016/j.jssc.2025.125337
Nitin Kumar , Vanish Kumar , Vinod Kumar Garg
{"title":"Development of iron-based metal-organic frameworks for the efficient removal of industrial dye: Effect of ligands on morphological and adsorption parameters","authors":"Nitin Kumar ,&nbsp;Vanish Kumar ,&nbsp;Vinod Kumar Garg","doi":"10.1016/j.jssc.2025.125337","DOIUrl":"10.1016/j.jssc.2025.125337","url":null,"abstract":"<div><div>Recently, the utilization of metal-organic frameworks (MOFs) enhanced the significance of the adsorptive removal of pollutants by several folds. To explore the unmatched potentials of MOFs, MIL-100 &amp; MIL-101 (iron-based MOFs) have been fabricated via a solvothermal process for Orange G dye removal (adsorption-based) from the aqueous system. The adsorption results show that MIL-100 has superior adsorption capacity (357.3 mg/g) in comparison to MIL-101 (206.9 mg/g) via pseudo-second-order kinetics. Moreover, both the adsorbents displayed their effectiveness for the removal of Orange G dye under extreme testing conditions (e.g., varying pH and high salt strength). The interactions between the target dye with the adsorbents have been inferred using three different adsorption isotherm models. Fascinatingly, as per isotherm models, significantly higher q<sub>max</sub> values of 540.5 and 321.5 mg/g were achieved using MIL-100 and MIL-101, respectively. The current study revealed that the ligand type is crucial in deciding the MOF properties and their adsorption capacities.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125337"},"PeriodicalIF":3.2,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143684310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The construction of metal-organic frameworks based on 2-(1-hydroxy-ethyl)-3H-benzoimidazole-5-carboxylic acid
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-20 DOI: 10.1016/j.jssc.2025.125336
Zhi-Xiong Lin , Zi-Yi Zhu , Yu-Huan Tang , Hui-Zi Li , Fei Wang , Jian Zhang
{"title":"The construction of metal-organic frameworks based on 2-(1-hydroxy-ethyl)-3H-benzoimidazole-5-carboxylic acid","authors":"Zhi-Xiong Lin ,&nbsp;Zi-Yi Zhu ,&nbsp;Yu-Huan Tang ,&nbsp;Hui-Zi Li ,&nbsp;Fei Wang ,&nbsp;Jian Zhang","doi":"10.1016/j.jssc.2025.125336","DOIUrl":"10.1016/j.jssc.2025.125336","url":null,"abstract":"<div><div>Presented here are two novel metal-organic frameworks (MOFs) synthesized by employing a trifunctional imidazolate derivative, 2-(1-hydroxy-ethyl)-3H-benzoimidazole-5-carboxylic acid (H<sub>2</sub>ebimc) as a ligand. In compound <strong>1</strong>, the Zn atoms and ebimc<sup>2−</sup> ligands were crosslinked to build a wavelike two-dimensional (2D) layer with 3-connected (4.8<sup>2</sup>) topology, with water molecules as terminal ligands coordinated on both sides of the layers. Then, the D-(+)-camphoric acid (H<sub>2</sub>cam) ligand was introduced into the synthesis system to obtain compound <strong>2</strong>. In compound <strong>2</strong>, similar topological layers were formed based on Zn<sub>2</sub>(CO<sub>2</sub>)<sub>3</sub> subunits (SBUs) and then were further pillared by cam<sup>2−</sup> ligands to construct the final three-dimensional (3D) pillar-layered framework. Moreover, compound <strong>2</strong> exhibited high selectivity of CO<sub>2</sub> over N<sub>2</sub> and CH<sub>4</sub>, along with a distinctive framework flexibility triggered by C<sub>2</sub>H<sub>6</sub>. Our results highlight the great potential of H<sub>2</sub>ebimc as a multifunctional ligand for synthesizing MOFs.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125336"},"PeriodicalIF":3.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143684305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A dual-emissive Ln-MOF as a visual dipicolinic acid sensor of high sensitivity and selectivity
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-20 DOI: 10.1016/j.jssc.2025.125334
Yu Yang , Xinyi Wang , Xiaoman Zhang, Yuting Yang, Jiangnan Dong, Lin Zhang, Yabing He, Dian Zhao
{"title":"A dual-emissive Ln-MOF as a visual dipicolinic acid sensor of high sensitivity and selectivity","authors":"Yu Yang ,&nbsp;Xinyi Wang ,&nbsp;Xiaoman Zhang,&nbsp;Yuting Yang,&nbsp;Jiangnan Dong,&nbsp;Lin Zhang,&nbsp;Yabing He,&nbsp;Dian Zhao","doi":"10.1016/j.jssc.2025.125334","DOIUrl":"10.1016/j.jssc.2025.125334","url":null,"abstract":"<div><div>Dipicolinic acid (DPA) is a valuable biomarker for the detection of Bacillus anthracis, but its detection still faces challenges such as enhancing sensitivity and selectivity. Herein, biphenyl-3,3′,5,5′-tetracarboxylic acid (H<sub>4</sub>BPTC), possessing several carboxyl groups, and large conjugated system, was selected as ligand to synthesize a mixed-lanthanide metal-organic framework (MOF), Tb<sub>x</sub>Eu<sub>1−<em>x</em></sub>-BPTC, for an effective DPA sensor. The optimal sample, Eu<sub>0.549</sub>Tb<sub>0.451</sub>-BPTC, demonstrated excellent water and thermal stability. Luminescence investigations revealed Tb<sup>3+</sup> emissions intensified while Eu<sup>3+</sup> emissions dimmed towards addition of DPA. The detection mechanism was due to inner filter effects, inhibition of energy transfer from Tb<sup>3+</sup> to Eu<sup>3+</sup> and chelation by DPA. Eu<sub>0.549</sub>Tb<sub>0.451</sub>-BPTC showed remarkable sensitivity (LOD = 1.68 μM) and excellent selectivity when detecting DPA. To expand the application prospect, Eu<sub>0.549</sub>Tb<sub>0.451</sub>-BPTC was mixed with agarose to form a MOF-based mixed matrix membrane. This flexible and portable membrane can achieve visual detection of DPA by analyzing RGB values using smartphone. This work offers an effective method to ascertain the presence of DPA in practical application scenario.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125334"},"PeriodicalIF":3.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143684309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
RbEu[AsS4], Rb4Eu[AsS4]2 and CsEu[AsS4]: Three europium(II) thioarsenates(V) with the heavy alkali metals
IF 3.2 3区 化学
Journal of Solid State Chemistry Pub Date : 2025-03-20 DOI: 10.1016/j.jssc.2025.125319
Katja Engel, Thomas Schleid
{"title":"RbEu[AsS4], Rb4Eu[AsS4]2 and CsEu[AsS4]: Three europium(II) thioarsenates(V) with the heavy alkali metals","authors":"Katja Engel,&nbsp;Thomas Schleid","doi":"10.1016/j.jssc.2025.125319","DOIUrl":"10.1016/j.jssc.2025.125319","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Three novel europium(II) thioarsenates(V) &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; (&lt;strong&gt;1&lt;/strong&gt;), &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; (&lt;strong&gt;2&lt;/strong&gt;), and &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; (&lt;strong&gt;3&lt;/strong&gt;) were synthesized by using the molten polysulfide-flux method. &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; and &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; crystallize isotypically in the orthorhombic space group &lt;em&gt;Pnma&lt;/em&gt; with &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;1729&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;53&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;9&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;b&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;679&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;18&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;c&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;670&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;46&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; for (&lt;strong&gt;1&lt;/strong&gt;) and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;1796&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;48&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;9&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;b&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;686&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;54&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;c&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;663&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;35&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; for (&lt;strong&gt;3&lt;/strong&gt;) with &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;Z&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;. An attempt to obtain single-phase &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; by changing the molar ratio of the reactants and optimizing the synthesis temperature led to &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; as main product and &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; as a second phase, which crystallizes orthorhombically in the space group &lt;em&gt;Ibam&lt;/em&gt; with &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;913&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;46&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;5&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;b&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;1873&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;08&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;11&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;c&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;1010&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;23&lt;/mn&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;6&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;pm&lt;/mi&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; for &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;Z&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mn&gt;4&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;. All crystal structures contain isolated &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; anions with sulfur corners and edges building &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; -centered &lt;figure&gt;&lt;img&gt;&lt;/figure&gt; polyhedra, whose condensation leads to &lt;span&gt;&lt;math&gt;&lt;mfrac&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125319"},"PeriodicalIF":3.2,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143687953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信