Journal of Solid State Chemistry最新文献

{"title":"High-rate performance and long-cycle stability of Sn-doped Na0.44MnO2 cathode material","authors":"Bo Li,&nbsp;Yueming Lin,&nbsp;Zhou Fang,&nbsp;RuiZe Yang,&nbsp;Xiaohong Zhu","doi":"10.1016/j.jssc.2025.125218","DOIUrl":"10.1016/j.jssc.2025.125218","url":null,"abstract":"<div><div>Sodium-ion batteries, as one of the best alternatives to lithium-ion batteries, have a broad application prospect. Manganese-based oxide anode Na_0.44MnO₂ has attracted much attention due to its simple, environmentally friendly, and cost-effective synthesis method. However, continuous phase transition and kinetic retardation hinder its practical application. In this study, we synthesized trace Sn-doped Na_0.44MnO₂ using a solid-state method and obtained a cathode material Na_0.44Mn_0.99Sn_0.01O₂ (NMSO-1) with a more stable crystal lattice structure and faster sodium ion transport rate. The capacity retention of NMSO-1 cathode was 94.6 % after 200 cycles at 1C rate, and 91.6 % after 1000 cycles at 5C rate. The material analysis shows that the introduction of a small amount of Sn can increase the lattice spacing of the material and reduce its morphological particle size, which is conducive to the enhancement of the stability of the material structure and the shortening of the ion transport path, and the positive effect of Sn is quantitatively analyzed with the help of experiments and fitting calculations. This study provides a new scheme for the doping design of cathode materials with tunneling structure, which effectively improves the multiplication capacity and cycling performance of cathode material NMO.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"344 ","pages":"Article 125218"},"PeriodicalIF":3.2,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143142318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ionic conductivity improvement of Li0.5La0.5TiO3 solid electrolyte by addition of borosilicate glasses","authors":"Jiawei Zhao ,&nbsp;Lei Liu ,&nbsp;Yuanhao Ma,&nbsp;Beibei Pan,&nbsp;Jiayu Liu,&nbsp;Zhenyuan Zhang,&nbsp;Yuebo Hu,&nbsp;Shujiang Liu","doi":"10.1016/j.jssc.2025.125219","DOIUrl":"10.1016/j.jssc.2025.125219","url":null,"abstract":"<div><div>Borosilicate glass has certain toughness, and doping it into the brittle Li_0.5La_0.5TiO₃ (LLTO) solid electrolyte can not only improve the mechanical strength, but also enhance the ionic conductivity. However, as the different components in the glass change, the degree of improvement in the ion conductivity of the composite solid electrolyte also varies. Herein, Li₂O–B₂O₃–SiO₂ (LBS) glasses with different Si/B ratio, Li₂O–B₂O₃–SiO₂–Al₂O₃ (LBSA) glasses with different B/Al ratio and LLTO solid electrolyte were prepared, respectively. The effects of adding these two types of glasses separately on the microstructure and ionic conductivity of the LLTO solid electrolyte were studied. At room temperature, the highest ionic conductivity observed in the solid electrolytes doped with LBS was 1.0 × 10⁻³ S cm⁻¹, while the maximum value for LBSA glass-doped solid electrolyte reached 1.31 × 10⁻³ S cm⁻¹. This research provides a new idea for the development of solid-state electrolytes.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"344 ","pages":"Article 125219"},"PeriodicalIF":3.2,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143142400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Economically and eco-friendly synthesis of SSZ-13 zeolite using choline chloride as template with the investigation effects of sodium ion and aging","authors":"Ze Chen,&nbsp;Yuping Li,&nbsp;Fuchao Ji,&nbsp;Xiaohong Liang,&nbsp;Haicheng Xuan,&nbsp;Lina Han,&nbsp;Peide Han","doi":"10.1016/j.jssc.2025.125216","DOIUrl":"10.1016/j.jssc.2025.125216","url":null,"abstract":"<div><div>Economical and efficient synthesis of small-size SSZ-13 zeolite catalysts with CHA topology is attractive for reducing the nitrogen oxide (NO_x) emissions from diesel vehicles. Herein, SSZ-13 zeolites were prepared using low-cost and environmental-friendly choline chloride (CC) as a template. The effects of additional sodium ions and dynamic stirring aging on the crystallization quality, solid yield and physicochemical properties of the obtained SSZ-13 were investigated by XRD, FT-IR, SEM, N₂ sorption and TG-DTG techniques. The results show that three sodium salts (NaCl, NaF, and Na₂SO₄) and aging steps can improve the relative crystallinity and solid yield of the SSZ-13 zeolites to a certain extent. Meanwhile, it was found that sodium salt and aging process significantly changed the crystal morphology of SSZ-13 zeolite from irregular particle aggregates to regular and uniform cubic crystals. And the crystal size of obtained SSZ-13 zeolites also decreased from ∼3 μm to 250–400 nm (adding sodium salts) or ∼700 nm (adding aging steps), respectively. The decrease in the size of SSZ-13 crystals is mainly attributed to that the addition of additional sodium salts or aging steps promoted the formation of more CHA zeolite nuclei. Additionally, the influence of the Na⁺(NaF) content and aging time on the synthesis of SSZ-13 were explored, and the effect mechanism of additional sodium ions and aging steps in the current synthetic system were also discussed. Finally, the obtained Cu-SSZ-13 samples after Cu²⁺ exchange exhibits good catalytic performance for NH₃-SCR of NO_x reaction, and the NO_x conversion remained over 90 % across a temperature window from ∼200 to ∼500 °C, demonstrating its application potentials in diesel vehicle exhausts purification.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"345 ","pages":"Article 125216"},"PeriodicalIF":3.2,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143136718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Crosslinking ionic oligomers sol-gel synthesis of porous amorphous magnesium hydroxide and its application in Pb2+ adsorption","authors":"Guilan Chen ,&nbsp;Zhihui Kang ,&nbsp;Yuxiang Ma ,&nbsp;Xiaoli Huang ,&nbsp;Xiao Sun ,&nbsp;Qianwen Wang","doi":"10.1016/j.jssc.2025.125214","DOIUrl":"10.1016/j.jssc.2025.125214","url":null,"abstract":"<div><div>Porous magnesium hydroxide with high specific surface area is widely used in environmental applications. In traditional sol-gel methods, the preparation of high-surface-area porous magnesium hydroxide (HSA-PMH) necessitate the use of highly reactive alkoxide as a precursor, thereby limiting its development. Herein, HSA-PMH was prepared by a simple crosslinking ionic oligomer sol-gel method using MgCl₂·6H₂O as precursor, short-chain alkohol as solvent and triethylamine (TEA) as alkaline reagent and capping agent. The choice of alkohol solvent plays a significant role in influencing the degree of crystallinity, morphology and porosity of HSA-PMH. Alkohol solvent with high dielectric constant favors the formation of HSA-PMH. When the molar ratio of TEA to Mg²⁺ is 30:1 and methanol is used as the solvent, the specific surface area of HSA-PMH reaches 538 m²∙g⁻¹. The Pb²⁺ adsorption properties of the HSA-PMH were further investigated. It was found that 98 % of the Pb²⁺ could be removed within 15 min, and the maximum adsorption capacity calculated by Langmuir isotherm model reached 4245 mg∙g⁻¹. The results indicate that the synthesized HSA-PMH is an excellent adsorbent for Pb²⁺, boasting a high adsorption capacity and rapid rate of adsorption.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"345 ","pages":"Article 125214"},"PeriodicalIF":3.2,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143136722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dielectric constant prediction of polymers for organic solar cells and generation of library of new organic compounds","authors":"Mudassir Hussain Tahir ,&nbsp;Mahmoud A.A. Ibrahim ,&nbsp;Shaban R.M. Sayed ,&nbsp;Denis Magero ,&nbsp;Anthony Pembere","doi":"10.1016/j.jssc.2025.125213","DOIUrl":"10.1016/j.jssc.2025.125213","url":null,"abstract":"<div><div>This work is based on a rapid framework that has ability to design novel polymers for organic solar cells. Dielectric constant is predicted using machine learning (ML) models. In organic solar cells, the dielectric constant is critical because it influences the efficiency of charge separation and reduces recombination losses by stabilizing charge carriers. A higher dielectric constant can enhance exciton dissociation and improve the overall power conversion efficiency of the solar cell. 10,000 new polymers were generated, and their dielectric constant values were predicted using ML. Generated database of polymers is visualized using various measures. Polymers with higher dielectric constant values were selected and their synthetic accessibility was assessed to aid future empirical measurements. Additionally, chemical similarity analysis revealed structural resemblance among the selected polymers. This framework provides a quick and easy method for finding the efficient materials.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"345 ","pages":"Article 125213"},"PeriodicalIF":3.2,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143136721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An efficient porous carbon catalyst derived by Cobalt-MOF precursor for degrading antibiotics in aqueous system","authors":"Zhan-Qing Yu ,&nbsp;Yu-Mei Wang ,&nbsp;Xin Zhang ,&nbsp;Ya-Ru Gong ,&nbsp;Xiao-Li Hu ,&nbsp;Zhong-Min Su","doi":"10.1016/j.jssc.2025.125199","DOIUrl":"10.1016/j.jssc.2025.125199","url":null,"abstract":"<div><div>The environment of human life especially in aqueous system becomes an attractive topic of the wastewater treatment investigation. With the development of chemical research, more and more wastewater treatment methods had become main trend in controlling water pollution. In this work, a new porous carbon material (Co/CoO-NC/Br) derived by one-step pyrolysis of cobalt metal-organic-framework (CUST-594) was synthesized. The obtained catalyst had excellent catalytic property and recycling features with peroxymonosulfate (PMS) activation process. The results indicated that 6 mg catalyst with 1.0 mL PMS (50 mg/L) had the degradation efficiency of 93.6 % of tetracycline (TC) in 20 min. The other experiment parameters like PMS and catalyst dosage, pH, temperature and interfering anions were also studied to verify the catalytic activity. In addition, this catalyst can deal with most part of aqueous system (pH = 5–9) and perform great cycling ability (after 5 cycles). The possible reaction mechanism was discussed and the main reaction substances were determined by scavenger experiments. This work provides a new way of synthesizing low cost, less side-effect catalyst to deal with most part of wastewater conditions.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"344 ","pages":"Article 125199"},"PeriodicalIF":3.2,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143142399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The multicomponent heterostructure flower spherical Ce-MOF/CdIn2S4/CdS for ciprofloxacin photodegradation via effective electron transfer","authors":"Hong Zheng ,&nbsp;Fengyan Ma ,&nbsp;Meihua Ling ,&nbsp;Ziqi Yang ,&nbsp;Ran Ji ,&nbsp;Yan Jiang ,&nbsp;Li Li ,&nbsp;Wenzhi Zhang","doi":"10.1016/j.jssc.2025.125210","DOIUrl":"10.1016/j.jssc.2025.125210","url":null,"abstract":"<div><div>The charge separation efficiency and photocatalytic performance can be effectively improved by constructing heterojunction between an inorganic semiconductor and a metal-organic framework. Consequently, in this paper, Ce-MOF synthesized in a water bath was used as the precursor, and Ce-MOF/CdIn₂S₄/CdS multicomponent heterojunction composites were successfully prepared by microwave-assisted hydrothermal method. The rod-like Ce-MOF interspersed with CdIn₂S₄/CdS composite material with spherical morphology formed by CdIn₂S₄ nanosheets loaded around the center spherical CdS. Meanwhile, in ciprofloxacin (CIP) degradation experiments, the photocatalytic efficiency of 10 % Ce-MOF/CdIn₂S₄/CdS for CIP reached 76.7 % within 120 min of full-spectrum light irradiation; the corresponding kinetic rate constant was 0.0089 min⁻¹. Its value was 12.7, 2.6, 2.6, 1.5, 1.4, 1.7, and 1.2 times higher than those of Ce-MOF, CdIn₂S₄, CdS, CdIn₂S₄/CdS, 5 % Ce-MOF/CdIn₂S₄/CdS, 20 % Ce-MOF/CdIn₂S₄/CdS, and 40 % Ce-MOF/CdIn₂S₄/CdS, respectively. The improved photocatalytic activity of 10 % Ce-MOF/CdIn₂S₄/CdS composite toward CIP is attributed to the synergistic effect between the unique Ce-MOF structure and multicomponent heterojunction. It not only promotes the tunable bandgap characteristics of the composite but also greatly prolongs the lifetime of photogenerated electrons (e⁻) and holes (h⁺), thereby improving the utilization efficiency of photogenerated carriers and enhancing the electron transfer efficiency at the interface. This speculation can be directly confirmed by photoelectric chemical experiments. The multicomponent heterojunction existed in photocatalyst system can be speculated by combined with active species capture experiment and energy band structure, which has a prominent application prospect in the treatment of antibiotic wastewater.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"344 ","pages":"Article 125210"},"PeriodicalIF":3.2,"publicationDate":"2025-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143142398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"In-situ construction of CeO2–Co3O4 heterostructure on nickel foam for efficient oxygen evolution reaction","authors":"Yushi Guo,&nbsp;Yaxuan Chen,&nbsp;Chen Wang,&nbsp;Guolin Zhang,&nbsp;Qiuhua Wu","doi":"10.1016/j.jssc.2025.125209","DOIUrl":"10.1016/j.jssc.2025.125209","url":null,"abstract":"<div><div>The creation and fabrication of inexpensive and efficacious catalysts for the oxygen evolution reaction (OER) hold great significance for advancing water electrolysis technology. In this study, CeO₂ and Co₃O₄ heterostructure was synthesized in situ on nickel foam using a two-step electrodeposition process followed by calcination, and it was used as the electrode material for OER. The material exhibits a low overpotential of 284 mV at a current density of 10 mA cm⁻² and a small Tafel slope of 35.5 mV dec⁻¹. The enhanced activity of the composite is attributed to rapid charge transfer and the synergistic effect between Co and Ce metal oxides. Meanwhile, the composite exhibits great stability in alkaline electrolyte.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"344 ","pages":"Article 125209"},"PeriodicalIF":3.2,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143142395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced photoelectrochemical water splitting performance of CuBi2O4 nanosphere photocathode by CuO decoration","authors":"Thitirat Kansaard ,&nbsp;Thareerat Singha ,&nbsp;Surangkana Wannapop ,&nbsp;Taweesak Sudyoadsuk ,&nbsp;Nuchanaporn Pijarn ,&nbsp;Asanee Somdee","doi":"10.1016/j.jssc.2025.125208","DOIUrl":"10.1016/j.jssc.2025.125208","url":null,"abstract":"<div><div>A photoelectrochemical cell (PEC) was invented a few decades ago to split water molecules into hydrogen (H₂) and oxygen (O₂) gases. Historically, the efficiency of PEC has been relatively small, which limits its application in the field of H₂ fuel generation. In this work, CuBi₂O₄ and enchanted CuO/CuBi₂O₄ heterostructures were investigated. The pure and enchanted nanostructures were synthesized by a one-pot hydrothermal method. The film coated on the transparent conducting electrode employed the doctor blade method. The crystal structures of the products were analyzed by X-ray diffraction. The crystal structure of CuBi₂O₄ and CuO were identified as kusachiite and ternorite, respectively. Scanning electron microscopy, Transmission electron microscopy, and X-ray photoelectron spectroscopy investigated those materials' surface morphology and chemical species. The photocurrent density of the material was investigated under visible light illumination. The photocurrent signal of all CuO/CuBi₂O₄ heterostructure photocathodes exhibited higher values than the pristine CuBi₂O₄ and CuO. The photocurrent of the best CuO/CuBi₂O₄ heterostructure photocathode was 1.2 mA/cm⁻² at applied 0.5 V (vs. RHE) greater than 5 times the pure CuBi₂O₄ and CuO materials. Electrochemical impedance spectroscopy was used to reveal the internal impedance of the PEC. Regarding the CuO forming to CuBi₂O₄, the internal resistance of all CuO/CuBi₂O₄ photocathodes showed lower impedance, and the Mott-Schottky analysis showed that the charge carrier density of CuBi₂O₄ enhanced by CuO was increased, resulting in a greater photocurrent density of the PEC.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"344 ","pages":"Article 125208"},"PeriodicalIF":3.2,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143142322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design, synthesis, and structural elucidation of tin(IV)-based metal-organic hybrids: Hirshfeld surface analysis of bis(4-cyanopyridinium) hexahalostannate(IV)","authors":"P. Suppuraj ,&nbsp;R. Aadhithan ,&nbsp;M. Santhamoorthy ,&nbsp;A.S. Normamatov ,&nbsp;A.B. Ibragimov ,&nbsp;Kareem Yusuf ,&nbsp;L. Guganathan ,&nbsp;Ahmed M. Aljuwayid ,&nbsp;N. Vijayan ,&nbsp;I.B. Tulaganovich ,&nbsp;C. Balakrishnan","doi":"10.1016/j.jssc.2025.125204","DOIUrl":"10.1016/j.jssc.2025.125204","url":null,"abstract":"<div><div>The research focuses on the synthesis and characterization of two hybrid materials: bis(4-cyanopyridinium) hexachlorostannate(IV) and hexabromostannate(IV). The compounds were synthesized by reacting 4-cyanopyridinium halides with tin halides, yielding crystalline materials. Infrared spectroscopy revealed key functional groups, including cyano, aromatic, and C–H stretches, while UV-DRS analysis showed distinct band gaps (4.10 eV for the chlorostannate and 2.94 eV for the bromostannate). Photoluminescence studies indicated promising emission properties for optoelectronic applications. SEM/EDS analyses provided insights into surface morphology and elemental composition, and X-ray diffraction confirmed the high crystallinity of both compounds. Single-crystal X-ray analysis revealed isostructural monoclinic arrangements with octahedral geometries for the anions, with π-π stacking and hydrogen bonding contributing to structural stability. Bond valence sum calculations for SnCl₆²⁻ and SnBr₆²⁻ anions gave values of 3.95 and 3.97, respectively. Hirshfeld surface analysis highlighted significant intermolecular interactions crucial for molecular packing and crystal cohesion.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"344 ","pages":"Article 125204"},"PeriodicalIF":3.2,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143142327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}