Journal of Solid State Chemistry最新文献

{"title":"N-doping of β-ketoenamine based covalent organic frameworks (COFs) for enhancing photocatalytic oxidation activity","authors":"Jun Fan ,&nbsp;Qibiao Wang ,&nbsp;Shuyan Wang ,&nbsp;Hongliang Guan ,&nbsp;Bing Han ,&nbsp;En Liang ,&nbsp;Xianglin Yu ,&nbsp;Junbo Li","doi":"10.1016/j.jssc.2024.125017","DOIUrl":"10.1016/j.jssc.2024.125017","url":null,"abstract":"<div><p>β-ketoenamine-based COFs are widely investigated due to their high stability, good crystallinity and tunable skeleton structures. Nitrogen doping is one of the effective ways to enhance the catalytic activity of COFs. Herein, N-doping of β-ketoenamine-based (0N-TP-COF, 1N-TP-COF, 2N-TP-COF) COFs were successfully constructed by the Schiff base condensation reaction between 1,3,5-tiformylphloroglucinol (TP) and <em>p</em>-phenylenediamine containing different numbers of nitrogen atoms. Studies showed that the as-prepared COFs exhibited more suitable electronic structure and more electron-rich active sites with the increasing of N atoms. Furthermore, the photocatalytic performance of 4-formylphenylboronic acid transformation was 0N-TP-COF (99 %, 48 h) &lt; 1N-TP-COF (99 %, 32 h) &lt; 2N-TP-COF (99 %, 16 h), and the photocatalytic performance of benzylamine coupling was 0N-TP-COF (99 %, 16 h) &lt; 1N-TP-COF (99 %, 3.5 h) &lt;2N-TP-COF (99 %, 1.5 h), respectively. Note that all N-doping COFs have excellent catalytic activity as well as stability, and 2N-TP-COF exhibits the highest catalytic activity. This work demonstrates that doping of nitrogen atoms is an effective way to enhance photocatalytic performance.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125017"},"PeriodicalIF":3.2,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142243348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and physical properties of Sm2PdGe3 in a context of RE2PdGe3 family","authors":"L.S. Litzbarski ,&nbsp;M. Łapiński ,&nbsp;T. Klimczuk ,&nbsp;M.J. Winiarski","doi":"10.1016/j.jssc.2024.125010","DOIUrl":"10.1016/j.jssc.2024.125010","url":null,"abstract":"<div><p>In this study, we present the crystallographic and magnetic characterization of a new intermetallic compound Sm₂PdGe_3, which was synthetized by a two stage method employing an eutectic alloy. The investigations carried out exhibited, that Sm₂PdGe₃ crystallize in AlB₂-type structure with lattice parameters <em>a</em> = 4.2189(1) Å and <em>c</em> = 4.1031(2) Å. This compound can be classified as a cluster-glass with a spin freezing temperature <em>T</em>_<em>f</em> = 10.5 K. Furthermore, there were carried out the analysis of the role of the rare earth (<em>RE</em>) elements on the structural parameters of <em>RE</em>₂PdGe₃ and draw a correlation between the <em>RE</em> radius and the unit cell parameters. We show that a deviation from the ideal 1:3 Pd:Ge ratio is necessary to synthesize <em>RE</em>₂PdGe₃ with smaller <em>RE</em> elements.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125010"},"PeriodicalIF":3.2,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142243345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Visible-light-driven Z-scheme ZnTe/WO3 heterojunction for simultaneous elimination of tetracycline and Cu(II)","authors":"Hongyan Zhang ,&nbsp;Jiehui Huang ,&nbsp;Yuxiang Shen ,&nbsp;Zuofang Yao ,&nbsp;Chenchen Xing ,&nbsp;Yanping Hou","doi":"10.1016/j.jssc.2024.125014","DOIUrl":"10.1016/j.jssc.2024.125014","url":null,"abstract":"<div><p>Z-Scheme heterojunction photocatalysts can effectively suppress the recombination of charge carriers while maintaining high redox capacity. In this study, ZnTe/WO₃ (ZW) Z-scheme heterojunction photocatalysts were synthesized using a hydrothermal method, and a series of photocatalytic materials were prepared for the simultaneous removal of tetracycline (TC) and Cu(II) from water. The physicochemical and photoelectrochemical properties of the catalytic materials were characterized through various methods, including SEM, XRD, XPS, and others. The experimental results indicate that the ZW-10 % composite material exhibits the most significant removal efficiency for pollutants. Within 150 min of visible light irradiation, the removal rates for TC and Cu(II) reach 73.8 % and 73.3 %, respectively, representing a substantial improvement compared to individual ZnTe and WO₃. Free radical capture experiments and electron spin resonance analysis reveal that ·O₂⁻ and ·OH are the key reactive species responsible for TC oxidation, while electrons (e⁻) dominate the reduction of Cu(II).</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125014"},"PeriodicalIF":3.2,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ionic substitutions in the Cu3TeO6 structure type and magnetic properties of “medium entropy” Cu3/2Mn1/2Co1/2Fe1/2SbO6","authors":"V.B. Nalbandyan ,&nbsp;M.A. Evstigneeva ,&nbsp;R.V. Bazhan ,&nbsp;A.N. Vasiliev ,&nbsp;A.N. Bulgakov ,&nbsp;T.M. Vasilchikova","doi":"10.1016/j.jssc.2024.125013","DOIUrl":"10.1016/j.jssc.2024.125013","url":null,"abstract":"<div><p>Cubic antiferromagnet Cu₃TeO₆ demonstrates interesting magnetic properties. Aimed at modification of them, we tried multiple ionic substitutions in its structure. However, single-phase materials could only be prepared with large fraction of the Jahn-Teller ions (Cu²⁺ and Mn³⁺), although formally isostructural bixbyites R₂O₃ (R₄O₆) with R = Sc, In, Tl, Sm…Lu exist with no Jahn-Teller ions. Moreover, ions having highest octahedral crystal field stabilization energy (Ni²⁺ and Cr³⁺) were found least tolerable. This points to Cu₃TeO₆ as a separate structure type, distinct from classical bixbyites. We report crystal structure, magnetic and thermodynamic properties of a rare single-phase multicomponent preparation, Cu_3/2Mn_1/2Co_1/2Fe_1/2SbO₆. The <em>dc</em> magnetic studies show that the formation of the ground spin-cluster state at <em>T</em> = 18 K is preceded by a broad anomaly at ∼122 K. Both specific heat and <em>ac</em> susceptibility data rule out the long-range magnetic ordering, in contrast to closely related Cu₂MSbO₆ (M = Mn or Fe).</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125013"},"PeriodicalIF":3.2,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142243347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Modification of Co3O4 by Al2O3: Influence on the reducibility","authors":"Svetlana V. Cherepanova ,&nbsp;Egor G. Koemets ,&nbsp;Evgeny Yu. Gerasimov ,&nbsp;Irina I. Simentsova ,&nbsp;Olga A. Bulavchenko","doi":"10.1016/j.jssc.2024.125012","DOIUrl":"10.1016/j.jssc.2024.125012","url":null,"abstract":"<div><p>In this study, we used a coprecipitation method followed by calcination at 500 °C to synthesize undoped and Al³⁺-doped Co₃O₄ nanoparticles with different aluminum fractions (x = Al/(Co + Al) = 1/60, 1/30, 1/15, 1/75, 1/6 and 1/5). An addition of Al³⁺ ions led to a decrease in the average crystallite size from 29 to 11 nm, and growth of the specific surface area from 28 to 91 m²/g. TEM images indicated round and platelet shapes of the nanoparticles. According to HAADF-STEM combined with EDS elemental mapping, the platelet shape particles are Al³⁺-enriched, while the round shape particles are Al³⁺-depleted. The origin of Al³⁺ distribution over the oxide volume is conditioned by the state of the hydroxide precursor. It was shown by XRD that the coprecipitation yielded homogeneous hydroxides only for Al fractions x = 0 and x = 1/5. For the intermediate compositions, the precursors represent a mixture of Co₆(CO₃)₂(OH)₈*H₂O and Co_0.8Al_0.2(OH)₂(CO₃)_0.1*nH₂O. On the TPR-H₂ profiles, reduction peaks for three (Co,Al)₃O₄ oxides differing in the Al³⁺ concentration (y) can be found. Two of these oxides with y = 0 and y = 0.2 are formed from different hydroxides, and third one with y ∼0.05 is the result of their mutual interaction. In situ XRD allowed us to interpret the TPR peaks correctly and showed that the reduction of all the oxides occurs in two steps. In the first step, Co³⁺ → Co²⁺, and (Co_1-yAl_y)₃O₄ oxides transform to (Co,Al)O. In the second step, Co²⁺ → Co⁰, and (Co,Al)O is reduced into metallic cobalt. In undoped Co₃O₄, Co³⁺ → Co²⁺ and Co²⁺ → Co⁰ reduction steps occur at T₁ = 280 and T₂ = 325 °C, respectively. For Al-depleted (Co_1-yAl_y)₃O₄ (y ∼ 0.05 in the interior of particles), both reduction steps shift toward higher temperatures T₁ = 305 and T₂ = 405 °C, respectively. The reduction of Al-enriched (Co_0.8Al_0.2)₃O₄ is more difficult; first and second reduction steps occur at T₁ = 345 and T₂ = 610−690 °C. Therefore, Al³⁺ ions have a little effect on the first step and very significantly influence the second one. Additionally, it was shown by TEM that after the reduction at 700 °C metallic cobalt particles were surrounded by the Al-enriched oxide shell. Apparently, that is why the addition of even a small amount of Al³⁺ ions prevents a quick sintering of metallic cobalt observed for pure Co₃O₄.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125012"},"PeriodicalIF":3.2,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Computational exploration of alternative mixed-valence double perovskites via cation-anion dual-doping strategy","authors":"Diwen Liu ,&nbsp;Hongyan Zeng ,&nbsp;Rongjian Sa","doi":"10.1016/j.jssc.2024.125011","DOIUrl":"10.1016/j.jssc.2024.125011","url":null,"abstract":"<div><p>Mixed-valence Cs₂Au^IAu^IIIX₆ (X = I, Br, Cl) double perovskites (DPs) exhibit high chemical stability and tunable optical band gaps, which renders their potential for photovoltaics. As an alternative, the suitability of novel mixed-valence mixed-halide perovskites for solar cell devices is studied herein. The cation-anion dual-doping strategy is utilized for Cs₂Au^IAu^IIIX₆, where the Au^I cations are substituted by the Ag^I cations and the anions are doped by different proportions of halide anions. The class of mixed-valence mixed-halide perovskites Cs₂Ag^IAu^IIIX₄Y₂ and Cs₂Ag^IAu^IIIX₂Y₄ (X = I or Br; X = Br or Cl) is comprehensively investigated with regard to their optoelectronic properties and structural stability. Apart from good thermodynamic and mechanical stability, Cs₂Ag^IAu^IIII₄X₂ (X = Br, Cl) and Cs₂Ag^IAu^IIIBr₄Cl₂ exhibit optimum band gaps within 1.2–1.4 eV and have low reduced effective masses (&lt;0.25 <em>m</em>₀) and small exciton binding energies (&lt;110 meV). Additionally, three alternative mixed-halide DPs show high visible-light absorption. Ultimately, the simulated maximum efficiency is within 29–31 % for three novel mixed-halide DPs. Considering structural stability and optoelectronic properties, Cs₂Ag^IAu^IIII₄Br₂ is expected to be an appropriate candidate for high-efficiency thin-film solar cells. The theoretical prediction of mixed-valence mixed-halide DPs can provide an attractive route to discover high-performance photovoltaic materials.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125011"},"PeriodicalIF":3.2,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Stable metal-organic frameworks with Zr6 clusters for alkaline battery-supercapacitor devices","authors":"Zhuoyin Deng ,&nbsp;Lianchao Wang ,&nbsp;Tianqi Chen ,&nbsp;Ruiying Fu ,&nbsp;Cheng Zhang ,&nbsp;Kuaibing Wang","doi":"10.1016/j.jssc.2024.125009","DOIUrl":"10.1016/j.jssc.2024.125009","url":null,"abstract":"<div><p>An alkaline-stable Zr-based material, PCN-777, has been elected and solvothermally prepared by reacting ZrOCl₂ with the tripodal linker 4,4′,4″-<em>s</em>-triazine-2,4,6-triyl-tribenzoate (H₃TATB). This powder material exhibits an irregular octahedron motif, providing good stability and high-power density when it is employed as electrode material for supercapacitors (SCs). The results indicate that the specific capacity, under a three-electrode configuration, is 291.9 C g⁻¹ at a current density of 1.5 A g⁻¹ obtained from the chronopotentiometry charge-discharge test. Assembled into a two-electrode system with activated carbon (AC) negative, the corresponding battery-supercapacitor device denoted as PCN-777//AC delivers a specific capacitance of 48.72 F g⁻¹ at the constant current-density value of 0.5 A g⁻¹. Besides, this device delivered a maximum energy density of 17.3 Wh kg⁻¹ within the power-density value of 399 W kg⁻¹, an excellent alkaline-endurance life during 2000 unceasing cycles and practical applications in powering LEDs, suggesting the potential practicality under strong alkaline surroundings. Furthermore, the structural alteration before and after long-term cycling has also been investigated.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125009"},"PeriodicalIF":3.2,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"α-Bi2O3 tubular rods coated on Bi2O2CO3 nanosheets for high-performance asymmetric supercapacitor applications","authors":"Sethumathavan Vadivel ,&nbsp;P. Sujita ,&nbsp;Bappi Paul ,&nbsp;Harshavardhan Mohan","doi":"10.1016/j.jssc.2024.125008","DOIUrl":"10.1016/j.jssc.2024.125008","url":null,"abstract":"<div><p>Mixed phases of bismuth oxide nanostructures as an active electrode material in supercapacitor applications have recently gained huge research interest. In this study, the layered Bi₂O₂CO₃ nanosheets and the secondary phase of α-Bi₂O₃ tubular rods named Bi₂O₂CO₃/α-Bi₂O₃ heterostructure have been synthesized and utilized for supercapacitor applications. The crystal nature and microstructure of the Bi₂O₂CO₃/α-Bi₂O₃ heterostructure were initially confirmed by powder X-ray diffraction (<em>p</em>-XRD), Raman, UV-Vis diffuse reflectance spectroscopy (UV-DRS, absorbance), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) studies. X-ray photoelectron spectroscopy (XPS) measurements have investigated the oxidation states and chemical binding energies. Regarding the electrochemical performances, the Bi₂O₂CO₃/α-Bi₂O₃ heterostructure as electro-active material delivered a maximum specific capacitance (C_s) value of 635 F g⁻¹ at the given current density value of 1 A g⁻¹ in a conventional three-electrode mode. A coin cell type electrode has been fabricated using Bi₂O₂CO₃/α-Bi₂O₃ heterostructure, resulting in an asymmetric supercapacitor device cell (ASC), which has a C_s of 112 F g^{− 1} (at 1 A g^{− 1}) and a power density and energy density values of 515 W kg⁻¹ and 22.5 Wh kg⁻¹ respectively. The two supercapacitor electrodes in sequence effectively ignite the red-light-emitting diode (LED). Moreover, in the ASC type Bi₂O₂CO₃ /α-Bi₂O₃ heterostructure, the specific capacitance value was slightly reduced to 12.3 % by 2000 cycles, showing favourable cyclic performance and stability during the electrochemical process. Based on the above-mentioned characterization, the appropriate electrochemical performances of Bi₂O₂CO₃/α-Bi₂O₃ tubular rod heterostructures make them a promising candidate for future energy storage devices.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125008"},"PeriodicalIF":3.2,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design and preparation of carbon-coated NaZnFe(MoO4)3 composite as novel anode materials for lithium/sodium-ion batteries","authors":"Xin Zhao,&nbsp;Xiuxia Lu,&nbsp;Limin Zhang,&nbsp;Jianyin Zhang","doi":"10.1016/j.jssc.2024.125007","DOIUrl":"10.1016/j.jssc.2024.125007","url":null,"abstract":"<div><p>The investigation of new anode materials with novel crystal structure and high ionic conductivity is of great significance for potential applications in lithium/sodium-ion batteries. Herein, carbon-coated NaZnFe(MoO₄)₃ composite was produced by solid state method coupled with the mechanical ball milling technique. The crystal and morphology were accurately confirmed by XRD, XPS and SEM techniques. When tested with lithium-ion batteries, the charging capacity reached an impressive 1005 mA h g⁻¹ during the initial cycle and 840 mA h g⁻¹ after 50 cycles, resulting in a capacity retention of 84.2 %. This performance is 40 % higher than that of the sample without a carbon layer coating. When utilized as an anode for sodium-ion batteries, the carbon-coated NaZnFe(MoO₄)₃ composite electrode exhibited a remarkable specific capacity of 152 mA h g⁻¹ and a high capacity retention of 74.9 % after 100 cycles at a rate of 100 mA g⁻¹. Furthermore, the charge capacity was measured at 105 mA h g⁻¹ after 500 cycles test conducted at 500 mA g⁻¹, with a capacity retention of 86.0 %. The advantages of polyanionic molybdate NaZnFe(MoO₄)₃ combined with the simple carbon coating strategy make it possible to application in the next generation of Li/Na secondary batteries.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125007"},"PeriodicalIF":3.2,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient palladium ion adsorption and catalyst preparation from pharmaceutical wastewater using amino-functionalized Ti3C2","authors":"Dancheng Zhu,&nbsp;Yonghui Lin,&nbsp;Changhui Chen,&nbsp;Hao Xu,&nbsp;Jiabin Shen,&nbsp;Jun Qiao,&nbsp;Chao Shen","doi":"10.1016/j.jssc.2024.125006","DOIUrl":"10.1016/j.jssc.2024.125006","url":null,"abstract":"<div><p>This paper reports the recovery and reuse of Pd ions from pharmaceutical wastewater using amino-modified Ti₃C₂. Ti₃C₂–NH₂ was synthesized by modifying (3-aminopropyl)triethoxysilane and the successful substitution of some surface functional groups of Ti₃C₂; the decrease in material thickness was verified by characterization. This study revealed that the presence of amino groups significantly enhanced the Pd(II) adsorption capacity of Ti₃C₂. The effects of the adsorbent material, adsorbent dosage, pH, initial concentration of Pd ions, presence of competing cations, and contact time on the adsorption performance were investigated. The maximum adsorption capacity of 20 mg of Ti₃C₂–NH₂ was 986.65 mg/g in 100 ml of a Pd-ion solution with an initial concentration of 200 mg/l at pH 3. A pseudo-second-order kinetic model fitted well with the experimentally obtained rate data, indicating that the main mode of Pd-ion removal by Ti₃C₂–NH₂ was via chemical reduction. Finally, the catalyst exhibited excellent performances during the photocatalytic and Suzuki coupling reactions with yields of 81 % and 95 %, respectively. The results demonstrated that Ti₃C₂–NH₂ is an excellent material for adsorbing Pd ions and can effectively recycle these ions from pharmaceutical wastewater.</p></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"340 ","pages":"Article 125006"},"PeriodicalIF":3.2,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142162716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}