Journal of Power Sources最新文献

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Real-vehicle experimental validation of a predictive energy management strategy for fuel cell vehicles
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-12-01 DOI: 10.1016/j.jpowsour.2024.235901
Sandro Kofler , Georg Rammer , Alexander Schnabel , David Weingrill , Peter Bardosch , Stefan Jakubek , Christoph Hametner
{"title":"Real-vehicle experimental validation of a predictive energy management strategy for fuel cell vehicles","authors":"Sandro Kofler ,&nbsp;Georg Rammer ,&nbsp;Alexander Schnabel ,&nbsp;David Weingrill ,&nbsp;Peter Bardosch ,&nbsp;Stefan Jakubek ,&nbsp;Christoph Hametner","doi":"10.1016/j.jpowsour.2024.235901","DOIUrl":"10.1016/j.jpowsour.2024.235901","url":null,"abstract":"<div><div>Predictive information is highly valuable for energy management strategies (EMSs) of fuel cell vehicles. In particular, long-term predictions can significantly improve the fuel efficiency because they allow for an optimization of the energy management before departure. This potential has been demonstrated in numerous simulation studies. This work extends the literature with an extensive experimental validation of a predictive EMS that exploits route-based long-term predictions in the form of optimized reference trajectories for the battery state of charge. The experimental validation is performed with a real passenger fuel cell vehicle and strongly focuses on the real-world application where random influences such as traffic cause considerable disturbances with respect to the long-term prediction. The validation comprises two stages: First, real driving tests are repeatedly conducted on public roads, analyzing the robustness of the predictive EMS and assessing fuel efficiency gains over a nonpredictive EMS. Second, chassis dynamometer tests are performed where a selected real driving cycle is reproduced to compare the two EMSs directly. The chassis dynamometer tests confirm a significant reduction in the fuel consumption by <span><math><mrow><mtext>6.4</mtext><mspace></mspace><mtext>%</mtext></mrow></math></span> compared to the nonpredictive EMS. The experimental results are analyzed quantitatively and qualitatively in detail.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235901"},"PeriodicalIF":8.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142756607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced chemical stability and H+/V4+ selectivity of microporous sulfonated polyimide via a triptycene-based crosslinker
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-12-01 DOI: 10.1016/j.jpowsour.2024.235964
Jiachen Chu , Luxin Sun , Han Zhang , Jianxin Li , Xiaohua Ma
{"title":"Enhanced chemical stability and H+/V4+ selectivity of microporous sulfonated polyimide via a triptycene-based crosslinker","authors":"Jiachen Chu ,&nbsp;Luxin Sun ,&nbsp;Han Zhang ,&nbsp;Jianxin Li ,&nbsp;Xiaohua Ma","doi":"10.1016/j.jpowsour.2024.235964","DOIUrl":"10.1016/j.jpowsour.2024.235964","url":null,"abstract":"<div><div>Long durability of sulfonated polyimide in vanadium redox flow battery (VRFB) is urgently required to be solved. Herein, we synthesize a triptycene-based crosslinker and use it as chemical crosslinking point to modify a linear sulfonated polyimide for promoting its antioxidative stability. The novel triptycene-based cross-linked sulfonated polyimide (TCSPI-X) membranes featuring covalently crosslinked network display lower water uptake and swelling ratio than the commercial perfluorinated ionomer membrane (Nafion 117) membrane. More importantly, unnoticeable proton conductivity loss is appeared. We speculate this is because of the covalently crosslinking structure provides stable proton transportation channels, and the formation of micropores induced by rigid triptycene unit decrease proton migration resistance. In which, the TCSPI-5 (with 5 % molar triptycene unit) exhibit higher voltage efficiency as compared with the pristine membrane TCSPI-0. Combined with the excellent vanadium ions resistance, the TCSPI-5 reaches energy efficiency of 78 % at the current density of 140 mA cm<sup>−2</sup>. In addition, TCSPI-5 also shows high oxidation resistance even under strong acid and pentavalent vanadium ions (V<sup>5+</sup>) conditions. The above results suggest the potential of TCSPI-X membranes in VRFB application.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235964"},"PeriodicalIF":8.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142756606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Jackfruit waste derived oxygen-self-doped porous carbon for aqueous Zn-ion supercapacitors
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-12-01 DOI: 10.1016/j.jpowsour.2024.235931
Qian Chu , Zhizhou Chen , Changyu Cui , Can Xie , Zhen Wei , Xiao Li , Yanbin Xu , Yulin Li , Yuming Cui , Shihao Pei
{"title":"Jackfruit waste derived oxygen-self-doped porous carbon for aqueous Zn-ion supercapacitors","authors":"Qian Chu ,&nbsp;Zhizhou Chen ,&nbsp;Changyu Cui ,&nbsp;Can Xie ,&nbsp;Zhen Wei ,&nbsp;Xiao Li ,&nbsp;Yanbin Xu ,&nbsp;Yulin Li ,&nbsp;Yuming Cui ,&nbsp;Shihao Pei","doi":"10.1016/j.jpowsour.2024.235931","DOIUrl":"10.1016/j.jpowsour.2024.235931","url":null,"abstract":"<div><div>To fully harness the benefits of high energy density, strategic fabrication of hierarchical porous carbon (PC) materials is essential and highly impactful. In this study, oxygen-self-doped PC materials are synthesized from jackfruit waste (JK) through pyrolysis combined with chemical activation. The resulting material (JKPC-4) features abundant interfacial active sites and a short ions/electrons transfer distance, enhancing the ion adsorption capacity and kinetic behavior of the cathode. Additionally, the oxygen-rich functional groups contribute to increased pseudocapacitance and enhance the wettability and conductivity of the material. Consequently, the assembled JKPC-4//JKPC-4 symmetric supercapacitor in 2M Na<sub>2</sub>SO<sub>4</sub> electrolyte exhibits a high energy density of 36.06 Wh kg<sup>−1</sup> at 647.94 W kg<sup>−1</sup>. Furthermore, the JKPC-4//Zn device demonstrates a notable capacity of 225 mAh g<sup>−1</sup> at 0.1 A g<sup>−1</sup>, exceptional rate capability (93 mAh g<sup>−1</sup> at 10 A g<sup>−1</sup>), high energy density (154 Wh kg<sup>−1</sup>), and impressive cycle stability, retaining 97 % of its capacity after 10,000 cycles at 10 A g<sup>−1</sup>. The electrochemical process is studied using ex-situ characterization. Mechanistic studies have shown that the outstanding energy storage capability and charge-transfer processes of JKPC-4 stem from the synergistic interplay between oxygen heteroatoms and suitable pore structure.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235931"},"PeriodicalIF":8.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142756601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A free-standing sulfide polyacrylonitrile/reduced graphene oxide film cathode with nacre-like architecture for high-performance lithium-sulfur batteries
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-12-01 DOI: 10.1016/j.jpowsour.2024.235916
Junhong Lu, Yanlin Zhang, Jie Huang, Haoyang Jiang, Ben Liang, Benyuan Wang, Dafang He, Haiqun Chen
{"title":"A free-standing sulfide polyacrylonitrile/reduced graphene oxide film cathode with nacre-like architecture for high-performance lithium-sulfur batteries","authors":"Junhong Lu,&nbsp;Yanlin Zhang,&nbsp;Jie Huang,&nbsp;Haoyang Jiang,&nbsp;Ben Liang,&nbsp;Benyuan Wang,&nbsp;Dafang He,&nbsp;Haiqun Chen","doi":"10.1016/j.jpowsour.2024.235916","DOIUrl":"10.1016/j.jpowsour.2024.235916","url":null,"abstract":"<div><div>Sulfide polyacrylonitrile (SPAN) is regarded as a promising cathode material to replace traditional carbon/sulfur composites, due to its conversion solid-solid transformation mechanism that effectively eliminates the shuttle effect of lithium sulfur batteries (LSBs). Unfortunately, its low sulfur content and slow reaction kinetics greatly affect the electrochemical performance. In this paper, a scalable production method is developed to fabricate free-standing sulfide polyacrylonitrile/reduced graphene oxide (SPAN/RGO) film cathode with nacre-like architecture. In this novel free-standing film cathode, graphene nanosheets act as a stable conductive framework and SPAN nanoparticles evenly disperse between the graphene nanosheets. The dense layered structure effectively alleviates the volume expansion of sulfur during cycling. <em>Ex-situ</em> Raman analysis provides evidence for the reversible cleavage and reformation of C−S/S−S bonds throughout the charge-discharge cycle. With these advantages, free-standing SPAN/RGO film cathode exhibits a low-capacity decay rate of 0.052 % over 1000 cycles at 0.5 C. Additionally, it maintains stable cycling performance even when the SPAN loading reaches 10.0 mg cm<sup>−2</sup>. This offers a straightforward and effective approach for the development of practical cathode materials for lithium-sulfur batteries (LSBs).</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235916"},"PeriodicalIF":8.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142756603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Increased electrolyte flow resistance and blockage due to hydrogen evolution in a flow battery single cell under stack electrolyte feeding conditions
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-11-30 DOI: 10.1016/j.jpowsour.2024.235940
Jincheng Dai , Qiang Ye , Tianshou Zhao
{"title":"Increased electrolyte flow resistance and blockage due to hydrogen evolution in a flow battery single cell under stack electrolyte feeding conditions","authors":"Jincheng Dai ,&nbsp;Qiang Ye ,&nbsp;Tianshou Zhao","doi":"10.1016/j.jpowsour.2024.235940","DOIUrl":"10.1016/j.jpowsour.2024.235940","url":null,"abstract":"<div><div>In a flow battery stack, individual cells are typically fed with electrolyte in a parallel configuration, resulting in identical pressure drops across each cell. In this parallel liquid supply system, the distribution of electrolyte flow is closely related to the flow resistance in each branch. During operation, gas bubbles generated by chemical and physical processes tend to accumulate in the electrode pores, obstructing electrolyte flow and leading to uneven electrolyte distribution. Previous studies have mainly focused on single-cell experiments using constant flow pumps, which differ significantly from the nearly constant pressure difference liquid supply within the stack electrodes. To investigate the effects of gas evolution on liquid flow under constant pressure difference conditions, we propose a gravity-driven electrolyte feeding system for testing in a single cell, which simulates the flow conditions encountered in real stack applications. Under the interaction between gas bubbles and liquid flow, hydrogen evolution reactions at the scale of “mA cm<sup>-2</sup>” significantly reduce the electrolyte flow through the porous electrode. When the pressure difference drops below a critical threshold, the electrolyte flow rate continues to decrease significantly and may even stop entirely. And a sufficient feeding pressure difference is essential for enhancing bubble removal efficiency.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"628 ","pages":"Article 235940"},"PeriodicalIF":8.1,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142744460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Li-ion batteries with poly[poly(ethylene glycol) methyl ether methacrylate]-grafted oxidized starch solid and gel polymer electrolytes
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-11-30 DOI: 10.1016/j.jpowsour.2024.235971
Zahra Hajian , Seyedeh-Arefeh Safavi-Mirmahalleh , Amir Rezvani Moghaddam , Hossein Roghani-Mamaqani , Mehdi Salami-Kalajahi
{"title":"Li-ion batteries with poly[poly(ethylene glycol) methyl ether methacrylate]-grafted oxidized starch solid and gel polymer electrolytes","authors":"Zahra Hajian ,&nbsp;Seyedeh-Arefeh Safavi-Mirmahalleh ,&nbsp;Amir Rezvani Moghaddam ,&nbsp;Hossein Roghani-Mamaqani ,&nbsp;Mehdi Salami-Kalajahi","doi":"10.1016/j.jpowsour.2024.235971","DOIUrl":"10.1016/j.jpowsour.2024.235971","url":null,"abstract":"<div><div>Polymer electrolytes are considered in lithium-ion batteries because of their high safety and properties such as flexibility, easy moldability, etc. Starch is one of these polymers from renewable resources. Considering the semi-crystal structure of starch and ion conduction in amorphous phase, herein starch is oxidized and then modified with poly[poly(ethylene glycol) methyl ether methacrylate]. Solid polymer electrolytes (SPEs) are prepared by dissolution of lithium salt within polymer while gel polymer electrolytes (GPEs) as crosslinked structures are swollen in lithium salt solution. After validation of successful syntheses, all SPEs and GPEs with different oxidation state and various PEGMA/oxidized starch are evaluated in Li-ion battery performance. The synthesized GPEs and SPEs show the highest ionic conductivity of 5.5 × 10<sup>−3</sup> and 2.19 × 10⁻⁴ S cm⁻<sup>1</sup>, respectively at room temperature. Lithium ion transfer number (t<sup>+</sup>) of 0.6–0.9 and electrochemical stability window of 4.4–4.9 V are obtained for SPEs and GPEs. The discharge capacity is ∼180 mAh g<sup>−1</sup> at 0.2 C with capacity retention of 75 % after 100 cycles.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235971"},"PeriodicalIF":8.1,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142756602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ethyl 2-butene phosphite as a film-forming additive for high voltage lithium-ion batteries
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-11-30 DOI: 10.1016/j.jpowsour.2024.235966
Jianguo Liu , Jinghang Cao , Baohui Li , Xiao Xing , Gan Cui
{"title":"Ethyl 2-butene phosphite as a film-forming additive for high voltage lithium-ion batteries","authors":"Jianguo Liu ,&nbsp;Jinghang Cao ,&nbsp;Baohui Li ,&nbsp;Xiao Xing ,&nbsp;Gan Cui","doi":"10.1016/j.jpowsour.2024.235966","DOIUrl":"10.1016/j.jpowsour.2024.235966","url":null,"abstract":"<div><div>Increasing the charge cutoff voltage can significantly improve the capacity of lithium-ion batteries. However, the structural degradation of Ni-rich cathodes and high reactivity of electrolytes at the high-potential cathodes greatly affect the cycling stability. In this paper, a new type of cathode film-forming additive, ethyl 2-butene phosphite (EBP), is synthesized based on the molecular design of phosphite by increasing the functional group of carbon-carbon double bond and ring structure. Theoretical calculation shows that EBP has a higher HOMO level and can form a cathode electrolyte interphase (CEI) on the cathode electrode surface before the electrolyte in theory. The electrochemical performance of NCM622/Li half-cells is significantly enhanced by incorporating EBP into the electrolyte, achieving 72.52 % capacity retention over 100 cycles at 0.5C. Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS) and Energy Dispersive Spectroscopy (EDS) are used to characterize the morphology of the anode and cathode, revealing that EBP forms a dense and complete CEI film on the surface of the LiNi<sub>0.6</sub>Co<sub>0.2</sub>Mn<sub>0.2</sub>O<sub>2</sub> electrode. This film effectively blocks direct contact between the electrolyte and the cathode active material, prevents the dissolution of transition metals, improves interfacial stability, and consequently enhances the high-voltage cycling performance of the battery.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235966"},"PeriodicalIF":8.1,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142756604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boron doped Ti2Nb10O29 nanosheets core/shell arrays as advanced high-energy anode for fast lithium ions storage
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-11-30 DOI: 10.1016/j.jpowsour.2024.235944
Xingchen Zhao , Ruiwang Zhang , Shengjue Deng , Qin Zhou , Yan Zhang , Chunqing Huo , Shiwei Lin
{"title":"Boron doped Ti2Nb10O29 nanosheets core/shell arrays as advanced high-energy anode for fast lithium ions storage","authors":"Xingchen Zhao ,&nbsp;Ruiwang Zhang ,&nbsp;Shengjue Deng ,&nbsp;Qin Zhou ,&nbsp;Yan Zhang ,&nbsp;Chunqing Huo ,&nbsp;Shiwei Lin","doi":"10.1016/j.jpowsour.2024.235944","DOIUrl":"10.1016/j.jpowsour.2024.235944","url":null,"abstract":"<div><div>Titanium niobium oxide (Ti<sub>2</sub>Nb<sub>10</sub>O<sub>29</sub>, TNO) as anode for high-energy lithium ion batteries (LIBs) typically suffers from sluggish kinetics and reaction activity because of its inferior electronic/ionic conductivity and easy aggregation feature. Herein, we present a novel synergistic strategy to tackle such problems of TNO by combining boron (B) doping and porous carbon nanosheet (PCN) arrays support. Experiment results and theoretical calculations demonstrate that the doped B substantially ameliorates the intrinsic electronic/ionic conductivity of TNO, increases the oxygen vacancy content in TNO, and accelerates lithium ion diffusion. Meanwhile, high-conductive PCN arrays as growth skeleton can avoid the agglomeration of B-TNO particles. As a result, the as-prepared PCN/B-TNO anode delivers an impressive specific capacity of 303 mAh g<sup>−1</sup> at 1 C and 104 mAh g<sup>−1</sup> at 20 C, superior to the PCN/TNO anode. Additionally, PCN/B-TNO anode also possesses a prominent long-time durability (85 % capacity retention after 2000 cycles). Our work paves a new way of rationally constructing high-energy anodes for fast energy storage and release.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235944"},"PeriodicalIF":8.1,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142744262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ decoration of NiCo-thiophene based metal-organic framework on nickel foam as an efficient electrocatalyst for oxygen evolution reaction
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-11-30 DOI: 10.1016/j.jpowsour.2024.235942
Muhammad Salman , Hanli Qin , Yuming Zou , Zhenyuan Ji , Hu Zhou , Xiaoping Shen , Hongbo Zhou , Guoxing Zhu , Premlatha Subramanian , Aihua Yuan
{"title":"In-situ decoration of NiCo-thiophene based metal-organic framework on nickel foam as an efficient electrocatalyst for oxygen evolution reaction","authors":"Muhammad Salman ,&nbsp;Hanli Qin ,&nbsp;Yuming Zou ,&nbsp;Zhenyuan Ji ,&nbsp;Hu Zhou ,&nbsp;Xiaoping Shen ,&nbsp;Hongbo Zhou ,&nbsp;Guoxing Zhu ,&nbsp;Premlatha Subramanian ,&nbsp;Aihua Yuan","doi":"10.1016/j.jpowsour.2024.235942","DOIUrl":"10.1016/j.jpowsour.2024.235942","url":null,"abstract":"<div><div>Developing efficient electrocatalysts for oxygen evolution reaction (OER) is highly demanded but still challenging due to sluggish reaction kinetics. Metal-organic frameworks (MOFs) are considered potential electrocatalysts for efficient OER. Herein, NiCo-thiophene based metal-organic frameworks (NiCo-TDC-MOF) are <em>in situ</em> grown on nickel foam (NF) <em>via</em> a convenient hydrothermal approach. The as-prepared binder-free NiCo-TDC-MOF electrode exhibits exceptional OER performance with ultralow overpotentials of 194, 248, and 296 mV at current densities of 10, 100 and 200 mA cm<sup>−2</sup>, respectively. Notably, the electrode displays outstanding OER stability, operating steadily for 110 h and 73 h at current densities of 100 and 500 mA cm<sup>−2</sup>, respectively. This work develops a facile strategy for designing lattice defect MOF-based electrocatalysts, paving the way for efficient OER systems. Moreover, the as-prepared electrocatalyst meets industrial applicability criteria with its stability at high current density.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235942"},"PeriodicalIF":8.1,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142744963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Heuristic method for electric vehicle charging in a Spanish microgrid: Leveraging renewable energy surplus
IF 8.1 2区 工程技术
Journal of Power Sources Pub Date : 2024-11-30 DOI: 10.1016/j.jpowsour.2024.235945
Oscar Izquierdo-Monge, Amy Zulema Velasco Bonilla, Marta Lafuente-Cacho, Paula Peña-Carro, Ángel Hernández-Jiménez
{"title":"Heuristic method for electric vehicle charging in a Spanish microgrid: Leveraging renewable energy surplus","authors":"Oscar Izquierdo-Monge,&nbsp;Amy Zulema Velasco Bonilla,&nbsp;Marta Lafuente-Cacho,&nbsp;Paula Peña-Carro,&nbsp;Ángel Hernández-Jiménez","doi":"10.1016/j.jpowsour.2024.235945","DOIUrl":"10.1016/j.jpowsour.2024.235945","url":null,"abstract":"<div><div>The transition towards renewable energies has intensified due to the global energy crisis, climate neutrality goals, and the increase in electrical demand. Technologies such as wind and solar have driven this change, although they present challenges such as intermittency and volatility. To maintain grid stability, solutions such as microgrids and energy storage system are required, improving supply quality and energy efficiency. Electric vehicles have gained importance as energy storage system through Vehicle-to-Grid technology. This article describes the implementation of a heuristic method in the microgrid of CEDER-CIEMAT (Center for Renewable Energy Development – Center for Energy, Environmental and Technological Research) in Spain. This microgrid, with a diversity of components and consumption profiles, allows for the acquisition of accurate data in a real-world setting. The heuristic method optimizes the charging of electric vehicles by leveraging the surplus renewable energy from the center, achieving 78 % of charging with surplus power and 96 % with renewable energy. This results in annual savings exceeding 900 €, ensuring sustainable energy use in the microgrid.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"629 ","pages":"Article 235945"},"PeriodicalIF":8.1,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142744261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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