Journal of Power Sources最新文献

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Reaction time-driven structural and electrochemical analysis of MnFe2O4 for solid-state supercapacitor application 固态超级电容器用MnFe2O4反应时间驱动结构及电化学分析
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238459
Priyanka P. Chavan , Rahul S. Redekar , Umesh D. Babar , Ashok D. Chougale , N.L. Tarwal , Pradip D. Kamble
{"title":"Reaction time-driven structural and electrochemical analysis of MnFe2O4 for solid-state supercapacitor application","authors":"Priyanka P. Chavan ,&nbsp;Rahul S. Redekar ,&nbsp;Umesh D. Babar ,&nbsp;Ashok D. Chougale ,&nbsp;N.L. Tarwal ,&nbsp;Pradip D. Kamble","doi":"10.1016/j.jpowsour.2025.238459","DOIUrl":"10.1016/j.jpowsour.2025.238459","url":null,"abstract":"<div><div>This study synthesizes manganese ferrite (MF) using a low-cost hydrothermal method. During synthesis, hydrothermal reaction time is varied to monitor the morphological changes and their effects on electrochemical performance. Morphological study demonstrates that ions are effectively transported via strongly interconnected nanostructures. The MF electrodes undergo electrochemical characterizations using different techniques. The MF24 electrode shows a specific capacitance of 603.68 F/g at 2 mA/cm<sup>2</sup> under optimized conditions. To comprehend the dynamics of charge storage for the MF24 electrode, the electrochemical kinetics are evaluated, which show the dominance of diffusion contribution. The MF24 electrode shows an 89.91 % capacitance retention after 5000 cycles. Furthermore, a solid-state symmetric supercapacitor device (SSD) with a potential window of 1 V is tested. At 20 mA/cm<sup>2</sup>, the MF24//MF24 SSD device demonstrates an energy density and power density of 10.16 Wh/kg and 2439.02 W/kg. The results indicate that including this synergy of metal ferrite can enhance the performance of supercapacitors.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238459"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145119700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamic regulation of ionomer/catalyst interface via alcohol coordination engineering: Toward high–efficiency proton and oxygen transport in proton exchange membrane fuel cells 醇配位工程对离子/催化剂界面的动态调控:迈向质子交换膜燃料电池中高效的质子和氧传输
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238453
Junlang Huo , Hao Lin , Yangyang Chen , Tongmei Ma , Jinhui Liang , Yaohong Zhao , Li Du
{"title":"Dynamic regulation of ionomer/catalyst interface via alcohol coordination engineering: Toward high–efficiency proton and oxygen transport in proton exchange membrane fuel cells","authors":"Junlang Huo ,&nbsp;Hao Lin ,&nbsp;Yangyang Chen ,&nbsp;Tongmei Ma ,&nbsp;Jinhui Liang ,&nbsp;Yaohong Zhao ,&nbsp;Li Du","doi":"10.1016/j.jpowsour.2025.238453","DOIUrl":"10.1016/j.jpowsour.2025.238453","url":null,"abstract":"<div><div>To bolster the proliferation of proton exchange membrane fuel cells (PEMFCs), the development of high–performance, low–platinum PEMFCs is imperative. Based on interface alcohol coordination engineering, this study systematically investigates the structure–activity relationships of alcohol additives and their impact on the ionomer/catalyst interface from microscopic interactions to macroscopic catalyst layer (CL) changes. The findings reveal that the alcohol engineering modulates the ionomer/catalyst interface distribution through the coordination with −SO<sub>3</sub>H groups, thus improving the O<sub>2</sub> and proton transport capacity of the CL. Tert–heptanol, with its most alkaline structure, forms the strongest coordination with ionomers, resulting in the most notable improvements in a 25.23 % increase in peak power density under H<sub>2</sub>–Air conditions. In the optimized tert–heptanol system, peak power densities reach 0.93 W cm<sup>−2</sup> under H<sub>2</sub>–Air and 2.49 W cm<sup>−2</sup> under H<sub>2</sub>–O<sub>2</sub>, with an impressively low O<sub>2</sub> transport resistance of 10.9 s m<sup>−1</sup>. These insights will inform future ionomer/catalyst interface designs for PEMFCs and related technologies.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238453"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145119704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling single-layer Hittorf's violet phosphorus as a novel sodium host anode to advance Na-ion battery technology 揭示单层希托夫紫磷作为一种新型钠主阳极,推动钠离子电池技术的发展
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238466
Zouhir Mansouri , Fatima Ezzahra Khatta , Youness Kaddar , Nohayla Regragui , Hamid Ez-Zahraouy , Omar Mounkachi
{"title":"Unveiling single-layer Hittorf's violet phosphorus as a novel sodium host anode to advance Na-ion battery technology","authors":"Zouhir Mansouri ,&nbsp;Fatima Ezzahra Khatta ,&nbsp;Youness Kaddar ,&nbsp;Nohayla Regragui ,&nbsp;Hamid Ez-Zahraouy ,&nbsp;Omar Mounkachi","doi":"10.1016/j.jpowsour.2025.238466","DOIUrl":"10.1016/j.jpowsour.2025.238466","url":null,"abstract":"<div><div>While sodium-ion batteries (SIBs) are widely regarded as the most viable successor to lithium-ion batteries, thanks to sodium's abundant supply and low cost, their progress is still hampered by the lack of efficient anode materials. Here, we explore a newly exfoliated two-dimensional phase of Hittorf's violet phosphorus (2D VP) as a potential sodium host anode using density functional theory and ab initio molecular dynamics simulations. The results confirm that 2D VP is energetically, kinetically, and thermally stable. The material behaves as a direct semiconductor with a band gap of 1.72 eV, which disappears upon multiple Na adsorption. Moreover, 2D VP exhibits strong Na adsorption (−2.17 eV) and rapid diffusion (0.13 eV), effectively suppressing Na dendrite formation and demonstrating compatibility with common electrolytes. Notably, 2D VP offers an average potential of 0.62 V and a high theoretical capacity of 618.06 mAh/g, outperforming several known phosphorus allotropes. We anticipate that these computationally screened results will not only broaden the landscape of phosphorus-based anodes but also stimulate experimental efforts toward synthesizing and evaluating 2D VP for practical sodium-ion energy storage solutions.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238466"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Predicting Si-anode calendar life using machine learning: Correlating electrolyte properties and electrochemical signals 使用机器学习预测硅阳极日历寿命:关联电解质特性和电化学信号
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238338
Maxwell C. Schulze , Nina Prakash , Kevin Gering , Andrew M. Colclasure , Peter J. Weddle
{"title":"Predicting Si-anode calendar life using machine learning: Correlating electrolyte properties and electrochemical signals","authors":"Maxwell C. Schulze ,&nbsp;Nina Prakash ,&nbsp;Kevin Gering ,&nbsp;Andrew M. Colclasure ,&nbsp;Peter J. Weddle","doi":"10.1016/j.jpowsour.2025.238338","DOIUrl":"10.1016/j.jpowsour.2025.238338","url":null,"abstract":"<div><div>This study evaluates novel electrolytes tailored for Si-containing anodes to promote calendar-life. Drawing inspiration from advancements in electrolytes for Li-metal cells, the work investigates correlations between predicted electrolyte properties and measured electrochemical performance using several machine-learning models. By leveraging machine learning and advanced modeling techniques, this study aims to establish predictive frameworks that accelerate calendar-aging experiments and inform rational electrolyte design for Si-containing cells. In the present study, fifteen different electrolytes are evaluated in a Si-containing cell using an accelerated calendar-life protocol. For each electrolyte considered, 87 properties (features) from the Advanced Electrolyte Model were produced to identify key property/performance relationships. In this study, the best performing electrolytes were generally those formulations that included non-coordinating fluoroether solvents, and the most predictive features for long-term calendar-life were features related to salt concentration and electrolyte viscosity as well as early capacity, ionic conductivity, and Coulombic efficiency measurements. The framework developed in this study correlating electrolyte properties to measured electrochemical performance is expected to accelerate electrolyte design for Si-containing anodes and ultimately enable high-energy-density, long-life Li-ion batteries.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238338"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145119701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding the influence of particle size on the reaction mechanism in porous La0.6Sr0.4CoO3-δ air electrodes 了解粒径对La0.6Sr0.4CoO3-δ多孔空气电极反应机理的影响
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238442
Mina Yamaguchi , Yuki Amano , Marika Sakai , Riyan Achmad Budiman , Keiji Yashiro , Tatsuya Kawada
{"title":"Understanding the influence of particle size on the reaction mechanism in porous La0.6Sr0.4CoO3-δ air electrodes","authors":"Mina Yamaguchi ,&nbsp;Yuki Amano ,&nbsp;Marika Sakai ,&nbsp;Riyan Achmad Budiman ,&nbsp;Keiji Yashiro ,&nbsp;Tatsuya Kawada","doi":"10.1016/j.jpowsour.2025.238442","DOIUrl":"10.1016/j.jpowsour.2025.238442","url":null,"abstract":"<div><div>Enhancing the electrode performance of high-temperature devices such as solid oxide fuel cells and solid oxide electrolysis cells is essential for reducing their operating temperatures. One approach is to reduce the particle size in the porous electrodes, which has been shown to decrease their area specific resistance. In this study, we investigated the effect of particle size on the reaction mechanism of mixed-conducting La<sub>0.6</sub>Sr<sub>0.4</sub>CoO<sub>3-δ</sub> electrodes by fabricating half-cells with 650 nm-thick films composed of 55 ± 15 nm particles (nanoporous) and 15 μm-thick films composed of ∼800 nm particles (microporous). Electrochemical impedance spectroscopy and analysis using the Gerischer model were performed. For both micro- and nanoporous electrodes, a consistent relationship was found between the reaction field and the particle size, with the reaction field being about three times the particle size under our conditions. The surface reaction resistance and the effective oxygen transport resistance of microporous and nanoporous electrodes show overall similar values, with differences on the order of 0.5–1 orders of magnitude, indicating that they are largely comparable. In the DC polarization measurements, the current density of the microporous sample, when multiplied by a constant factor, closely matched that of the nanoporous sample. This suggests that the reaction mechanisms at both these electrodes were similar. This study demonstrates that the improvement in electrode performance with reduced particle size does not arise from intrinsic changes in the material properties, but rather from the increase in specific surface area. These findings provide useful guidelines for designing high-performance mixed-conducting porous electrodes.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238442"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145119813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen production via ammonia using trimetallic-doped aerogels based on Fe, Ni, Co 基于Fe, Ni, Co的三金属掺杂气凝胶的氨制氢研究
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238448
J. González-Lavín , Y. Salazar-Lara , N. Rey-Raap , G. Luna-Barcenas , A. Arenillas , L.G. Arriaga , J. Ledesma-García
{"title":"Hydrogen production via ammonia using trimetallic-doped aerogels based on Fe, Ni, Co","authors":"J. González-Lavín ,&nbsp;Y. Salazar-Lara ,&nbsp;N. Rey-Raap ,&nbsp;G. Luna-Barcenas ,&nbsp;A. Arenillas ,&nbsp;L.G. Arriaga ,&nbsp;J. Ledesma-García","doi":"10.1016/j.jpowsour.2025.238448","DOIUrl":"10.1016/j.jpowsour.2025.238448","url":null,"abstract":"<div><div>This article explores the electrocatalytic response of novel iron-nickel-cobalt unsupported doped aerogels (FeNiCoA) in a microfluidic electrochemical ammonia device for hydrogen production and electrolyser cell operation. These aerogels were synthesised by the ultrafast sol-gel method assisted by microwave heating, resulting in homogeneous morphological structures. Different stoichiometries of the aerogel: raw FeNiCoA, reduced rFeNiCoA, and heteroatom-doped FeNiCoA were used as electrocatalysts for the ammonia oxidation reaction (AOR) and to produce clean hydrogen. The incorporation of carbon (C-FeNiCoA) and nitrogen (N-FeNiCoA) into the aerogel matrix played a crucial and innovative role in improving the electrocatalytic activity and promoting electron transfer. The microfluidic device using these novel aerogels exhibits high power and current densities, demonstrating its potential for high hydrogen generation (3 <span><math><mrow><mo>·</mo></mrow></math></span> 10<sup>−8</sup> mol of hydrogen in 20 s). This study shows that transition metal aerogels are a cost-effective alternative to noble metals as electrocatalysts for hydrogen production.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238448"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancements in battery state prediction methods: A comprehensive review of data-driven approaches and degradation mechanisms 电池状态预测方法的进展:数据驱动方法和退化机制的综合综述
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238192
Wentao Zheng , Dinglan Wu , Chenbo Yuan , Huan Jiang , Shenghan Wang
{"title":"Advancements in battery state prediction methods: A comprehensive review of data-driven approaches and degradation mechanisms","authors":"Wentao Zheng ,&nbsp;Dinglan Wu ,&nbsp;Chenbo Yuan ,&nbsp;Huan Jiang ,&nbsp;Shenghan Wang","doi":"10.1016/j.jpowsour.2025.238192","DOIUrl":"10.1016/j.jpowsour.2025.238192","url":null,"abstract":"<div><div>Predicting the state of lithium-ion batteries (LIBs) plays a vital role in proactively identifying aging and damage, thereby enabling timely maintenance and repairs to extend their lifespan and ultimately reduce waste while advancing the development of clean energy. This comprehensive review aims to provide an extensive overview of state prediction methods and characterization techniques, emphasizing the need for specific data-driven approaches to characterize battery degradation and establish correlations between inputs and outputs. Furthermore, the evaluation of primary anode, cathode, and separator materials in batteries is discussed. The study delves into the significance of both cycle degradation and calendar degradation, providing insights into degradation phenomena and parameters perspectives. Moreover, the roles and characteristics of physical parameters for degradation characterization and state parameters for battery operation status are analyzed. The review extensively examines the strengths and weaknesses of classic and state-of-the-art physics-based models, as well as data-driven models, highlighting critical issues and challenges related to degradation mechanisms, datasets, performance trade-offs, and optimization methods. Additionally, innovative ideas are proposed, and future development directions are discussed.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238192"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145119699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A two-phase stable model for non-isothermal direct ethanol proton exchange membrane fuel cells 非等温直接乙醇质子交换膜燃料电池的两相稳定模型
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238394
A.L. De Bortoli
{"title":"A two-phase stable model for non-isothermal direct ethanol proton exchange membrane fuel cells","authors":"A.L. De Bortoli","doi":"10.1016/j.jpowsour.2025.238394","DOIUrl":"10.1016/j.jpowsour.2025.238394","url":null,"abstract":"<div><div>This article introduces a two-phase model developed for direct ethanol proton exchange membrane (PEM) fuel cells. The model calculates variables such as ethanol fuel and oxygen concentrations, evaporation–condensation dynamics, overpotential losses, catalytic reactions, membrane behavior, temperature, and pressure, as these variables influence fuel cell performance and longevity. The governing equations are discretized using the central finite difference method, while integration is achieved through the Rosenbrock method. By employing dimensionless equations, variables were normalized to the order of unity, enhancing iterative stability during computations. A review of existing literature revealed no equivalent model to the one proposed in this work.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238394"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ternary zinc-based deep eutectic solvents for durable zinc-ion capacitors capable of withstanding extreme high temperatures 用于耐极端高温的耐用锌离子电容器的三元锌基深共晶溶剂
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238397
Li Pan , Yongfeng Bu , Hongyu Zhang , Zhaomin Zhu , Hui Li , Hongyu Liang
{"title":"Ternary zinc-based deep eutectic solvents for durable zinc-ion capacitors capable of withstanding extreme high temperatures","authors":"Li Pan ,&nbsp;Yongfeng Bu ,&nbsp;Hongyu Zhang ,&nbsp;Zhaomin Zhu ,&nbsp;Hui Li ,&nbsp;Hongyu Liang","doi":"10.1016/j.jpowsour.2025.238397","DOIUrl":"10.1016/j.jpowsour.2025.238397","url":null,"abstract":"<div><div>The employment of aqueous zinc salt solutions as electrolytes confers cost and safety advantages to aqueous zinc-ion capacitors (ZICs). However, the high chemical H<sub>2</sub>O with low boiling point in typical aqueous zinc sulfate (ZS) electrolyte greatly restricts the performance of ZICs in high-temperature conditions. Herein, a ternary deep eutectic solvent (DES) electrolyte capable of withstanding extreme high temperatures of up to 80 °C is synthesized for the first time by utilizing inter-component hydrogen bonding. The DES with optimized component ratios allows long-term stable cycling of Zn||Zn cells for &gt;1200 h with nearly 100 % Coulombic efficiency. When used as the high-temperature electrolyte, ZICs at 80 °C yield a much higher specific capacitance of up to 247 F g<sup>−1</sup> than at room temperature, while those with ZS as the electrolyte hardly work properly under this condition. The hydrogen bonding system reconfigured by ligand competition in DESs effectively inhibits Zn dendrite formation and the activity of H<sub>2</sub>O, thus endowing ZICs up to 10000 cycles at 80 °C. This ternary DES not only opens the way for the design of high-temperature electrolytes for ZICs, but also offers new possibilities for the development of other energy storage devices that need to be adapted to extreme operating environments.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238397"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hierarchical graphitic carbon nitride-polypyrrole on metal-organic framework-derived carbon nanorod: Metal-Free electrocatalyst for solid-state flexible zinc-air batteries 金属有机框架衍生碳纳米棒上的分层石墨氮化碳聚吡咯:固态柔性锌空气电池的无金属电催化剂
IF 7.9 2区 工程技术
Journal of Power Sources Pub Date : 2025-09-24 DOI: 10.1016/j.jpowsour.2025.238425
Anup Kumar Pradhan , Sayan Halder , Sankar Ganesh Palani , Chanchal Chakraborty
{"title":"Hierarchical graphitic carbon nitride-polypyrrole on metal-organic framework-derived carbon nanorod: Metal-Free electrocatalyst for solid-state flexible zinc-air batteries","authors":"Anup Kumar Pradhan ,&nbsp;Sayan Halder ,&nbsp;Sankar Ganesh Palani ,&nbsp;Chanchal Chakraborty","doi":"10.1016/j.jpowsour.2025.238425","DOIUrl":"10.1016/j.jpowsour.2025.238425","url":null,"abstract":"<div><div>Rechargeable Zn-air batteries (ZABs) offer high energy density and environmental friendliness but require durable, nonprecious bifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) to enhance oxygen electrocatalysis, improving reaction kinetics and performance in practical applications. Herein, a unique metal-free throne-like hierarchical ternary electrocatalyst containing graphitic carbon nitrides-polypyrrole on carbon nanorod (g-C<sub>3</sub>N<sub>4</sub>-PPy@CNR) is synthesized by depositing g-C<sub>3</sub>N<sub>4</sub>-PPy on the surface of a metal-organic framework-derived carbon nanorod (CNR). g-C<sub>3</sub>N<sub>4</sub>-PPy@CNR catalyst exhibits outstanding ORR and OER in alkaline media with a low potential gap of 0.63 V, more efficient than commercial catalysts like the mixture of Platinum on Carbon (Pt-C) and ruthenium dioxide (RuO<sub>2</sub>). Moreover, the g-C<sub>3</sub>N<sub>4</sub>-PPy@CNR catalyst is utilized to assemble the ZABs with solution and solid-state electrolytes. The ZAB comprised of g-C<sub>3</sub>N<sub>4</sub>-PPy@CNR cathode reveals a high energy density of 620 Wh/kg, a specific capacity of 541.2 mAh/g with an open circuit potential of 1.39 V. Assembled solid-state ZAB outperforms the commercial Pt-C and RuO<sub>2</sub>-based ZAB with impressive energy density, capacity, and high charge-discharge stability and is used efficiently as the energy sources for green hydrogen generation through overall water splitting, light emitting diode (LED) panel and wearable electronics.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"659 ","pages":"Article 238425"},"PeriodicalIF":7.9,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145119696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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