Journal of Organometallic Chemistry最新文献

{"title":"Advances in Wacker oxidation: From palladium to first-row transition metal catalysts","authors":"Jisna Jose ,&nbsp;Diana Elizabeth Jose ,&nbsp;Thomas V. Mathew","doi":"10.1016/j.jorganchem.2025.123625","DOIUrl":"10.1016/j.jorganchem.2025.123625","url":null,"abstract":"<div><div>The widespread presence of carbonyl scaffolds in agrochemical and pharmaceutical compound libraries has led to an increased focus on creating sustainable and effective processes for transforming olefins into their carbonyl derivatives. The first breakthrough was made possible by the Wacker method, which transformed alkenes into aldehydes or ketones by utilizing the mutually exclusive interactions of palladium and copper. Replacing palladium with a readily available and affordable metal has the potential to revolutionize the Wacker-type oxidation (WTOx), making it a more environmentally friendly and economically feasible method for olefin oxidation. This review explores the recent advances in WTOx, emphasizing the mechanistic insights and innovations in catalytic systems that enable the selective oxidation of olefins. It emphasizes the shift from noble metals to first-row transition metal catalysts for more sustainable synthetic applications. Advancements in palladium-catalyzed Wacker systems have led to significant improvements in yields, regioselectivity, and functional group tolerance. These improvements have been achieved through the use of novel ligands, oxidants, and reaction conditions.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123625"},"PeriodicalIF":2.1,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143697601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, characterization, X-ray structures, and catalytic activity of new Mn(I) and Re(I) metal complexes of chelating phosphinopyridylamine and its sulfide ligands","authors":"Harbi Tomah Al-Masri ,&nbsp;Akram Ali Almejled ,&nbsp;Ziad Moussa","doi":"10.1016/j.jorganchem.2025.123620","DOIUrl":"10.1016/j.jorganchem.2025.123620","url":null,"abstract":"<div><div>The reaction of 4-Me-C₅H₃N-2-NH(PPh₂) (<strong>1</strong>) with Mn(CO)₅Br in refluxing chloroform produced the <em>fac</em>-[Mn(CO)₃Br{<strong>1</strong>-κ²<em>P,N</em>}] (<strong>2</strong>) and [Mn(CO)₂{<strong>1</strong>-κ²<em>P,N</em>}₂]Br (<strong>3</strong>) complexes. Furthermore, the refluxing of the monooxidized thioyl (4-CH₃)C₆H₃N-2-NH(P(S)Ph₂) (<strong>4</strong>) ligand with M(CO)₅Br (<em>M</em> = Mn, <em>Re</em>) in chloroform yielded the <em>fac</em>-[M(CO)₃Br{<strong>4</strong>-κ²<em>S,N^py</em>}] (<em>M</em> = Mn (<strong>5</strong>), <em>Re</em>(<strong>6</strong>)) complexes. The investigation of complexes <strong>2, 3, 5</strong>, and <strong>6</strong> was carried out with the use of multinuclear NMR (¹H, ¹³C and ³¹P NMR), infrared spectroscopy, and the determination of crystal structures. Complexes <strong>5</strong> and <strong>6</strong> represent the inaugural structurally characterized instances of this category of chalcogenide ligands associated with Mn and <em>Re</em> metals documented thus far. Complexes <strong>5</strong> and <strong>6</strong> demonstrate significant catalytic efficacy in the hydrogenation of acetophenone derivatives to yield 1-phenylethanol derivatives, utilizing 2-propanol as a hydrogen source.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123620"},"PeriodicalIF":2.1,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The first organometallic complex bearing a diacylthiourea ligand","authors":"Matthew C. Risi ,&nbsp;Graham C. Saunders","doi":"10.1016/j.jorganchem.2025.123636","DOIUrl":"10.1016/j.jorganchem.2025.123636","url":null,"abstract":"<div><div>Here we report the first example of an organometallic complex bearing a diacylthiourea ligand. The title complex, [(η⁶-p-cymene)Ru{(CH₃CH₂CONH)₂CS}Cl₂], was prepared form the diacylthiourea ligand (CH₃CH₂CONH)₂CS and the ruthenium cymene dimer [(η⁶-<em>p</em>-cymene)RuCl₂]₂. The X-ray crystallographic structure of the complex revealed the diacylthiourea molecule to coordinate as a neutral monodentate ligand through the core thiourea sulfur atom. The spatial arrangement of the piano stool complex is governed by a series of hydrogen bonding and chalcogen non-covalent interactions which were subsequently confirmed using the non-covalent interactions index.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123636"},"PeriodicalIF":2.1,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143682530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solvothermal Synthesis of Innovative and Efficient Ag/NA-MOF Nanoparticles for One-Pot Synthesis of Imidazoquinazolinones and In vitro Validation as Anti-Alzheimer Agents","authors":"Gehad E. Said ,&nbsp;Mahmoud Tarek ,&nbsp;Abdulrahman A. Almehizia ,&nbsp;Ahmed M. Naglah ,&nbsp;Hazem A. Ghabbour ,&nbsp;Tamer K. Khatab","doi":"10.1016/j.jorganchem.2025.123623","DOIUrl":"10.1016/j.jorganchem.2025.123623","url":null,"abstract":"<div><div>Nicotinic acid was presented as MOF-mediated in the hydrothermal synthesis of silver MOF nanoparticles followed by the crystallography study of its structure by IR, SEM, TEM, and XRD. The catalytic properties of the prepared Ag/NA-MOF were achieved in the synthesis of some new tetrahydrobenzo[4,5]imidazo[2,1-<em>b</em>]quinazolin-1(2<em>H</em>)-one derivatives through one pot mixing of dimedone, 2-aminobenzimidazole and aromatic aldehyde in the presence of catalytic amount of Ag/NA-MOF under solvent-free conditions. The synthesized tetracyclic imidazoquinazoline derivatives were binding ligands with acetylcholine esterase (AChE inhibitors). The <em>in vitro</em> validation approved the theoretical data through colorimetric determination of acetylcholinesterase activity. The data obtained explained that the compounds <strong>4c, 4f, 4i</strong> and <strong>4j</strong> give promising values and the most potent one is <strong>4i</strong> by IC₅₀ value of <strong>5.93 ± 0.02 μg/mL</strong> compared to the standard donepezil value of <strong>5.18 ± 0.02 μg/mL</strong> as a reference Alzheimer's drug.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123623"},"PeriodicalIF":2.1,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Manganese Phenoxyimine complexes: Structures, reactions, and water-assisted hydrosilylation of aldehydes","authors":"Kouki Matsubara,&nbsp;Kaichi Ikuta,&nbsp;Shoko Koga,&nbsp;Yuji Koga","doi":"10.1016/j.jorganchem.2025.123634","DOIUrl":"10.1016/j.jorganchem.2025.123634","url":null,"abstract":"<div><div>A series of Mn(I) and Mn(II) complexes was synthesized from a three-coordinate phenoxyimine ligand with hemilabile pendant groups and readily available manganese salts. Under pyrolytic conditions, Mn(I) carbonyl complexes decomposed in the presence of 2e-donor ligands into Mn(II) and other complexes via disproportionation reactions. Mn(II) complexes exhibited catalytic activity in hydrosilylation of aldehydes and acetophenone. Hydrosilylation proceeded with phenylsilane and water accelerated the catalytic reaction in a system similar to that previously reported for Co(II) analog.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123634"},"PeriodicalIF":2.1,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143705216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic effects and comprehensive analysis of photodegradability inhibition of PVC plastics film by novel Schiff base metal complex additives: Performance and Dechlorination mechanism","authors":"Eslam A. Mohamed ,&nbsp;Amal A. Altalhi ,&nbsp;Hend M. Ahmed ,&nbsp;Nabel A. Negm","doi":"10.1016/j.jorganchem.2025.123626","DOIUrl":"10.1016/j.jorganchem.2025.123626","url":null,"abstract":"<div><div>Three photo-stabilizers were prepared and designed from a complexation reaction of (2E)-2-(4-((E)-(2-hydroxyphenylimino)methyl)benzylideneamino)phenol Schiff base and three metal ions: Fe(III), Cu(II), and Ni(II). Their chemical structures were elucidated using elemental analysis, FTIR, ^1HNMR, and UV/Vis spectroscopy. The photo-stabilizers were formulated at 0.5 % in PVC sheets and tested under ultraviolet light for 0–250 h. The degradation indexes including unsaturation (I_C_<img>_C), carbonyl (I_C_<img>_O), and hydroxyl (I_OH) indexes of pure PVC were 0.12, 0.2, and 0.23. While, the index values were decreased moderately in the case of Cu-stabilizer to 0.025, 0.112, and 0.122, respectively. In the case of the Ni-stabilizer, the degradation indexes considerably reduced to 0.062, 0.078, and 0.110 respectively. The average molecular weight of PVC after 200 h of photo-irradiation was decreased by 80 % in the case of pure PVC, while in the case of stabilized PVC by the prepared photo-stabilizers were 69 %, 56 %, and 39 % for PVC-Fe, PVC<img>Cu, and PVC<img>Ni, respectively. The photo-stabilizing tendencies of the prepared photo-stabilizers were ascribed based on their ability for radical scavenging and were associated with their antioxidant efficiencies. The antioxidant efficiencies of the synthesized photo-stabilizers were measured and compared to 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS⁺) as standards. Copper and nickel complexes exhibited higher efficiency than ferric complexes during the photo-stabilization of PVC under the studied conditions. The role of the synthesized photo-stabilizers in the photo-stabilization mechanism was explained.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123626"},"PeriodicalIF":2.1,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143682478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mesoporous Carbon@ZnCuFeS nanoparticles for photocatalytic degradation of organic pollutants via peroxymonosulfate activation","authors":"Ghulam Abbas Ashraf ,&nbsp;Sulaiman Al-Sulaimi ,&nbsp;Noor Hassan ,&nbsp;Zeeshan Ajmal ,&nbsp;Sajid Mahmood ,&nbsp;Raqiqa Tur Rasool ,&nbsp;Muhammad Tuoqeer Anwar ,&nbsp;Naveed Husnain ,&nbsp;Nouf H. Alotaibi ,&nbsp;Hanadi Yaqob Alsoqair","doi":"10.1016/j.jorganchem.2025.123624","DOIUrl":"10.1016/j.jorganchem.2025.123624","url":null,"abstract":"<div><div>Various activation mechanisms have been developed for peroxymonosulfate (PMS), an oxidant that is extensively employed in sulfate radical-based advanced oxidation processes for the elimination of organic contaminants from water. Visible-light-assisted PMS activation presents significant potential for pollution remediation. This study generated Carbon@ZnCuFeS nanoparticles (NPs) via hydrothermal processing and employed them to activate PMS under visible light, resulting in effective pollutant degradation. NPs enabled a synergistic interaction between photocatalysis and PMS activation, with the NPs/Light/PMS combination exhibiting efficacy across a broad pH spectrum, especially in neutral and slightly acidic environments. The reaction rate follows a pseudo-first-order (PFO) kinetic model, with rate constants (0.1056 min⁻¹) varying across systems, highlighting the superior efficiency of the light/NPs/PMS system in accelerating RhB degradation (95.8 %). The radical quenching tests identified SO₄^•^‒ and ^•OH as reactive species, with h^⁺, ¹O₂, and ^•O₂⁻ as the primary contributors to pollutant degradation. The ^•O₂⁻ produced further activated PMS, generating more ^•OH via interactions involving SO₄^•^‒ and H₂O/OH⁻. RhB degradation is most efficient at neutral pH, with modest decreases in acidic settings due to H^⁺ interference and considerable drops in alkaline surroundings due to charge repulsion and PMS deactivation. The system demonstrated remarkable reusability; nevertheless, degradation efficiency and reaction speeds diminished at elevated RhB concentrations. The efficacy of the NPs/Light/PMS system was assessed across several water types and contaminants, yielding significant insights into the mechanics of visible-light-assisted PMS activation and endorsing an environmentally sustainable approach for the degradation of organic pollutants.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123624"},"PeriodicalIF":2.1,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143682477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Encapsulation of chiral CoII(R,R)(salen) in mesocellular foam as an efficient heterogeneous catalyst for asymmetric electrocarboxylation of 1-phenylethyl chloride with CO2","authors":"Meng-han Li ,&nbsp;Feng Zhang ,&nbsp;Bao-Han Shan ,&nbsp;Yue Zhao ,&nbsp;Jia-Xing Lu ,&nbsp;Huan Wang","doi":"10.1016/j.jorganchem.2025.123621","DOIUrl":"10.1016/j.jorganchem.2025.123621","url":null,"abstract":"<div><div>The electrocarboxylation of organic molecules with CO₂ allows the synthesis of important carboxylic acids under mild conditions. The introduction of chiral sources enables the catalytic asymmetric synthesis of chiral carboxylic acids using CO₂ as a C1 source, which has important application prospects. In this work, we have successfully prepared chiral immobilized electrode materials by encapsulating chiral Co^II(R,R)(salen) (Co^IIL) complexes in the pores of mesocellular foam (MCF) materials using the strategy of silanization to reduce the pore size. The prepared Co^IIL@MCF composites exhibited good electrocatalytic performance in the asymmetric electrocarboxylation of 1-phenylethyl chloride with CO₂, leading to the synthesis of chiral 2-phenylpropionic acid with an enantiomeric excess value of 71% and a yield of 49%. The encapsulated Co^IIL@MCF composites can significantly reduce the amount of chiral Co^IIL complexes used. Moreover, they are stable, easy to separate, and have excellent reusability.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123621"},"PeriodicalIF":2.1,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143642452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design and synthesis of [Fe3O4*SiO2*(CH2)3-methyl-Imidazolium N(NO2)2] as magnetic nano-catalyst for multi component reaction","authors":"Leila Pakjo,&nbsp;Shabnam Rahimpour,&nbsp;Benyamin Hosseindoust,&nbsp;Reza Teimuri-Mofrad","doi":"10.1016/j.jorganchem.2025.123619","DOIUrl":"10.1016/j.jorganchem.2025.123619","url":null,"abstract":"<div><div>In this research, the [Fe₃O₄*SiO₂*(CH₂)₃-methyl-Imidazolium N(NO₂)₂], which is a silica-coated Fe₃O₄ nanoparticle relying on ionic liquid as a recoverable catalyst for the one-pot synthesis of three-multicomponent reaction (t-MCR) designed and synthesized. The prepared [Fe₃O₄*SiO₂*(CH₂)₃-methyl-Imidazolium N(NO₂)₂] catalyst structure by XRD, EDX, TEM, FE-SEM, and FT-IR techniques was characterized. The catalytic activity of the nanoparticles was tested in the one-pot t-MCR synthesis of novel pyrano[3,2-b] pyran derivatives. The newly synthesized compounds derivatives of pyrano[3,2-b] pyran were identified by ¹³C, ¹H NMR and, FT-IR spectroscopies.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1034 ","pages":"Article 123619"},"PeriodicalIF":2.1,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Magnetic Fe3O4 nanoparticles modified with tannic acid as a support for silver nanoparticles: Catalytic efficiency in procuring 1-substituted-1H-tetrazoles and investigation its therapeutic effects on mycoplasma pneumonia infected pneumonia mice model","authors":"Jianhui Peng ,&nbsp;Siwei Luo ,&nbsp;Yisui Cen ,&nbsp;Hailiang Li ,&nbsp;DeQin Zeng ,&nbsp;Can Cai","doi":"10.1016/j.jorganchem.2025.123617","DOIUrl":"10.1016/j.jorganchem.2025.123617","url":null,"abstract":"<div><div>In this research, we present a green method for synthesizing silver nanoparticles supported on tannic acid (TA)-coated magnetic Fe₃O₄ nanoparticles (Fe₃O₄@TA). This nanocomposite functions as both reducing and stabilizing reagent. We specified the constructional and physicochemical features of the synthesized Fe₃O₄@TA/Ag NPs using several analytical tools, especially TEM, FE-SEM, EDX, elemental mapping, ICP, VSM, and XRD. For catalytic testing, we explored a 1-substituted-tetrazoles synthesis through a multicomponent reaction involving amines, triethyl orthoformate, and sodium azide in solvent-free circumstances, achieving good results. We also corroborated the catalyst stability by reusability tests across six cycles, along with hot filtration and leaching experiments. The in vivo investigation involves evaluating the <em>P. aeruginosa</em> lethal dose in Swiss albino mice, along with a disease manifestations analysis. This analysis includes monitoring reductions in bacteremia, body weight, hypothermia, and various other parameters throughout a 48-hour infection period. The untreated animals demonstrated a significant decline in body temperature, recorded at 25 °C after 48 h, in contrast to the initial measurement of 39 °C. Furthermore, a weight reduction of 30 % was observed by the study end. The evaluation of the efficacy of Fe₃O₄@TA/Ag NPs nanocomposite in treating lung infections was conducted through the use of calculated lethal doses, bacteremia assessments, and histopathological analyses. On day 8, the bacterial load in the Fe₃O₄@TA/Ag NPs nanocomposite group was recorded at 0.5 Log10CFU/mL, reflecting a significant reduction from the initial level of 1.5 Log10CFU/mL observed on day 1. The histopathological analysis demonstrated a pervasive and intermittent accumulation of inflammatory cells within the alveolar spaces, with infiltrates detected across all lung sections in the untreated animals. The group of animals that received treatment exhibited improved lung histology, characterized by a decrease in exudates at a dosage of 200 µg/kg. The research clearly establishes the effectiveness of Fe₃O₄@TA/Ag NPs nanocomposite in addressing lung infections caused by <em>P. aeruginosa</em> at a dosage of 200 µg/kg. This investigation seeks to examine the biomedical properties of these Fe₃O₄@TA/Ag NPs nanocomposite to formulate a robust treatment for this formidable pathogen.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1032 ","pages":"Article 123617"},"PeriodicalIF":2.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143644064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}