RecyclingPub Date : 2024-02-04DOI: 10.3390/recycling9010013
Mattia Gianvincenzi, E. Mosconi, Marco Marconi, Francesco Tola
{"title":"Battery Waste Management in Europe: Black Mass Hazardousness and Recycling Strategies in the Light of an Evolving Competitive Regulation","authors":"Mattia Gianvincenzi, E. Mosconi, Marco Marconi, Francesco Tola","doi":"10.3390/recycling9010013","DOIUrl":"https://doi.org/10.3390/recycling9010013","url":null,"abstract":"The increasing significance of batteries in the 21st century and the challenges posed by the anticipated surge in end-of-life batteries, particularly within the European context, are examined in this study. Forecasts predict a notable escalation in battery waste, necessitating a focus on the recycling of black mass (BM)—a complex and hazardous byproduct of the battery recycling process. Employing systematic analysis, this research investigates the hazardous nature of BM derived from various battery types. The study underscores the urgent need for definitive legislative classification of BM’s hazardous properties (HPs), in accordance with European regulations. This comprehensive examination of BM’s HPs contributes significantly to the understanding of BM recycling complexities, proving essential for industry stakeholders and guiding future developments in this field. Additionally, the study explores innovative technologies and strategies that could improve recycling efficiency and reduce associated risks. A pivotal finding of this investigation is the inherently hazardous nature of BM, leading to the recommendation that BM should be classified at a minimum under the “HP3—Flammable” category. This discovery underscores the critical need for stringent management protocols and robust regulatory frameworks to address the burgeoning challenge of battery waste in Europe.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139807536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-02-02DOI: 10.3390/recycling9010011
Tekin Ozdemir, J. Deitzel, Roger Crane, Shridhar Yarlagadda, Chris Blackwell, Mark Davis, Rebecca Emmerich, Dirk Heider
{"title":"Carbon Fiber Composites Recycling Technology Enabled by the TuFF Technology","authors":"Tekin Ozdemir, J. Deitzel, Roger Crane, Shridhar Yarlagadda, Chris Blackwell, Mark Davis, Rebecca Emmerich, Dirk Heider","doi":"10.3390/recycling9010011","DOIUrl":"https://doi.org/10.3390/recycling9010011","url":null,"abstract":"Carbon Fiber Composites (CFCs) recycling has received increasing interest by the composites industry, but it is still in its early stages as an industry. There are two primary challenges that need to be addressed in order to achieve full property retention during CFC recycling: (1) the ability to recover the fiber content without property loss; and (2) conversion of the recycled, short fiber material back into high-performance CFC structures. The ability to manufacture high fiber volume fraction CFCs with end-of-life products would provide an opportunity to reduce material cost and lifetime-embodied energy. In this paper, recycled, short carbon fibers are processed via solvolysis and converted into high-performance CFCs with fiber volume fraction of ~50% and excellent composite property retention. This is enabled through alignment of the discontinuous, recycled fiber feedstock using the Tailorable universal Feedstock for Forming (TuFF) process. The paper introduces the necessary steps to process the fibers in the wet-laid process and explores the resulting mechanical and microstructural properties. The importance of incoming fiber surface quality and the effect of surface contamination from residue left by the recycling process on both the TuFF process and final composite properties is discussed in detail. A pyrolytic process has been adopted to remove the residue that is a by-product of the recycling process from the incoming recycled fiber surface. The approach presents a promising pathway for the recycling of high-performance CFCs.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139809403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-02-02DOI: 10.3390/recycling9010011
Tekin Ozdemir, J. Deitzel, Roger Crane, Shridhar Yarlagadda, Chris Blackwell, Mark Davis, Rebecca Emmerich, Dirk Heider
{"title":"Carbon Fiber Composites Recycling Technology Enabled by the TuFF Technology","authors":"Tekin Ozdemir, J. Deitzel, Roger Crane, Shridhar Yarlagadda, Chris Blackwell, Mark Davis, Rebecca Emmerich, Dirk Heider","doi":"10.3390/recycling9010011","DOIUrl":"https://doi.org/10.3390/recycling9010011","url":null,"abstract":"Carbon Fiber Composites (CFCs) recycling has received increasing interest by the composites industry, but it is still in its early stages as an industry. There are two primary challenges that need to be addressed in order to achieve full property retention during CFC recycling: (1) the ability to recover the fiber content without property loss; and (2) conversion of the recycled, short fiber material back into high-performance CFC structures. The ability to manufacture high fiber volume fraction CFCs with end-of-life products would provide an opportunity to reduce material cost and lifetime-embodied energy. In this paper, recycled, short carbon fibers are processed via solvolysis and converted into high-performance CFCs with fiber volume fraction of ~50% and excellent composite property retention. This is enabled through alignment of the discontinuous, recycled fiber feedstock using the Tailorable universal Feedstock for Forming (TuFF) process. The paper introduces the necessary steps to process the fibers in the wet-laid process and explores the resulting mechanical and microstructural properties. The importance of incoming fiber surface quality and the effect of surface contamination from residue left by the recycling process on both the TuFF process and final composite properties is discussed in detail. A pyrolytic process has been adopted to remove the residue that is a by-product of the recycling process from the incoming recycled fiber surface. The approach presents a promising pathway for the recycling of high-performance CFCs.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139869222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-02-02DOI: 10.3390/recycling9010012
T. Phan, San-Lang Wang, T. Nguyen, T. Nguyen, Thi Huyen Thoa Pham, M. Doan, Thi Ha Trang Tran, V. Ngo, A. Nguyen, V. Nguyen
{"title":"Using Cassava Starch Processing By-Product for Bioproduction of 1-Hydroxyphenazine: A Novel Fungicide against Fusarium oxysporum","authors":"T. Phan, San-Lang Wang, T. Nguyen, T. Nguyen, Thi Huyen Thoa Pham, M. Doan, Thi Ha Trang Tran, V. Ngo, A. Nguyen, V. Nguyen","doi":"10.3390/recycling9010012","DOIUrl":"https://doi.org/10.3390/recycling9010012","url":null,"abstract":"This study aimed to develop the eco-friendly production of bioactive 1-hydroxyphenazine (HP) through fermentation using an industrial processing by-product of cassava as the main carbon/nitrogen source. Cassava starch processing by-product (CSPB) was screened as a suitable substrate for fermentation to produce HP with a high yield. Mixing CSPB with a minor amount of tryptic soy broth (TSB) at a ratio of 8/2 and with 0.05% K2HPO4 and 0.05% FeSO4 was effective in HP production by Pseudomonas aeruginosa TUN03. HP was also further scaled up through production on a bioreactor system, which achieved a higher level yield (36.5 µg/mL) in a shorter fermentation time (10 h) compared to its production in the flask (20.23 µg/mL after 3 days). In anti-fungal activity tests against various Fusarium phytopathogens, HP exhibited the most significant effect on Fusarium oxysporum F10. It could inhibit the mycelial growth of this fungus, with an inhibition rate of 68.7% and anti-spore germination activity of up to 98.4%. The results of the docking study indicate that HP effectively interacted with the protein 1TRY targeting anti-F. oxysporum, with all obtained docking parameters in the accepted range. This study supports the novel use of CSPB as the carbon/nitrogen source for P. aeruginosa fermentation to produce HP, a F. oxysporum anti-fungal agent reported here for the first time.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139811110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-02-02DOI: 10.3390/recycling9010012
T. Phan, San-Lang Wang, T. Nguyen, T. Nguyen, Thi Huyen Thoa Pham, M. Doan, Thi Ha Trang Tran, V. Ngo, A. Nguyen, V. Nguyen
{"title":"Using Cassava Starch Processing By-Product for Bioproduction of 1-Hydroxyphenazine: A Novel Fungicide against Fusarium oxysporum","authors":"T. Phan, San-Lang Wang, T. Nguyen, T. Nguyen, Thi Huyen Thoa Pham, M. Doan, Thi Ha Trang Tran, V. Ngo, A. Nguyen, V. Nguyen","doi":"10.3390/recycling9010012","DOIUrl":"https://doi.org/10.3390/recycling9010012","url":null,"abstract":"This study aimed to develop the eco-friendly production of bioactive 1-hydroxyphenazine (HP) through fermentation using an industrial processing by-product of cassava as the main carbon/nitrogen source. Cassava starch processing by-product (CSPB) was screened as a suitable substrate for fermentation to produce HP with a high yield. Mixing CSPB with a minor amount of tryptic soy broth (TSB) at a ratio of 8/2 and with 0.05% K2HPO4 and 0.05% FeSO4 was effective in HP production by Pseudomonas aeruginosa TUN03. HP was also further scaled up through production on a bioreactor system, which achieved a higher level yield (36.5 µg/mL) in a shorter fermentation time (10 h) compared to its production in the flask (20.23 µg/mL after 3 days). In anti-fungal activity tests against various Fusarium phytopathogens, HP exhibited the most significant effect on Fusarium oxysporum F10. It could inhibit the mycelial growth of this fungus, with an inhibition rate of 68.7% and anti-spore germination activity of up to 98.4%. The results of the docking study indicate that HP effectively interacted with the protein 1TRY targeting anti-F. oxysporum, with all obtained docking parameters in the accepted range. This study supports the novel use of CSPB as the carbon/nitrogen source for P. aeruginosa fermentation to produce HP, a F. oxysporum anti-fungal agent reported here for the first time.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139870807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-01-27DOI: 10.3390/recycling9010010
Zuzana Šimková, M. Taušová, Katarína Čulková, P. Tauš, Danylo Shyp, David Krasniči, Simona Novotná
{"title":"Evaluation of the Landfill Storage Capacity in Slovakia, Compared to the EU Situation","authors":"Zuzana Šimková, M. Taušová, Katarína Čulková, P. Tauš, Danylo Shyp, David Krasniči, Simona Novotná","doi":"10.3390/recycling9010010","DOIUrl":"https://doi.org/10.3390/recycling9010010","url":null,"abstract":"The circular economy and efficient use of resources gained importance in the context of sustainable development. The paper aims to evaluate the development of landfilling in Slovakia. The next goal is to assess the trend in compared with the EU’s situation. The presented research presents a continuation of previous research in the area of waste recycling in Slovakia, pointing to the waste and landfilling, which is deserving of analysis from a long-term perspective. The research is carried out via data collection at the EU level by recording continuously published values. The paper’s results are processed in statistical software. Considering regional development, landfilling in Slovakia is followed up according to the geographical units of the entire country. The results shown here show that a higher recycling capacity is required and Slovakia should decrease its level of landfill. Such results can be used in the waste treatment area, protection of the living environment and sustainable development of regions.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140492155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-01-26DOI: 10.3390/recycling9010009
Bowen He, Han Zheng, Karl Tang, Ping Xi, Muqing Li, Laiwei Wei, Qun Guan
{"title":"A Comprehensive Review of Lithium-Ion Battery (LiB) Recycling Technologies and Industrial Market Trend Insights","authors":"Bowen He, Han Zheng, Karl Tang, Ping Xi, Muqing Li, Laiwei Wei, Qun Guan","doi":"10.3390/recycling9010009","DOIUrl":"https://doi.org/10.3390/recycling9010009","url":null,"abstract":"Adopting EVs has been widely recognized as an efficient way to alleviate future climate change. Nonetheless, the large number of spent LiBs associated with EVs is becoming a huge concern from both environmental and energy perspectives. This review summarizes the three most popular LiB recycling technologies, the current LiB recycling market trend, and global recycling magnates’ industrial dynamics regarding this subject. We mainly focus on reviewing hydrometallurgical and direct recycling technologies to discuss the advancement of those recycling technologies and their future commercialization pathway.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140494197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-01-22DOI: 10.3390/recycling9010008
A. Dhandapani, S. Krishnasamy, S. M. K. Thiagamani, Diwahar Periasamy, Chandrasekar Muthukumar, T. Sundaresan, Saood Ali, Rendi Kurniawan
{"title":"Evolution, Prospects, and Predicaments of Polymers in Marine Applications: A Potential Successor to Traditional Materials","authors":"A. Dhandapani, S. Krishnasamy, S. M. K. Thiagamani, Diwahar Periasamy, Chandrasekar Muthukumar, T. Sundaresan, Saood Ali, Rendi Kurniawan","doi":"10.3390/recycling9010008","DOIUrl":"https://doi.org/10.3390/recycling9010008","url":null,"abstract":"Polymers are ideal solutions for architects and constructors in the marine field who require materials that can achieve light and stable structures owing to their unique advantages. For instance, they possess a high strength-to-weight ratio, high wear resistance and fatigue strength, resistance to corrosion, ease of fabrication, and superior vibration damping behavior. These properties make polymers well suited for marine-based applications. However, polymers have their disadvantages, such as contributing to plastic pollution, which has a detrimental impact on the environment. In recent times, various concurrent methods have been employed to advance the future of polymers. This review explores (i) an overall view of polymers used in marine industries, (ii) a focus on reducing plastic wastage, (iii) challenges involved in recycling polymers and ensuring their sustainability, and (iv) the development of renewable plastics.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139608800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-01-22DOI: 10.3390/recycling9010007
Yannick Igor Fogue Djombou, Melvyn Gorra, B. Malet-Damour
{"title":"Hygrothermal Optimization for Excavated Soil Reuse in Various Climate Buildings: A Global Literature Meta-Analysis","authors":"Yannick Igor Fogue Djombou, Melvyn Gorra, B. Malet-Damour","doi":"10.3390/recycling9010007","DOIUrl":"https://doi.org/10.3390/recycling9010007","url":null,"abstract":"This article investigates the hygrothermal properties of earth-based materials by analyzing experimental data from 88 articles spanning 32 countries worldwide. The focus is determining effective techniques for leveraging the use of excavated soil in construction, particularly emphasizing enhancement of hygrothermal comfort in specific climates. Based on statistical analysis, the study presents a comprehensive classification of earth production techniques, incorporating additives, and examines their impacts on hygrothermal properties of excavated soils. Additionally, it explores the intricate relationship between the climatic conditions of a region and the chosen earth-material production techniques. The analysis aims to propose standard parameters for earthen materials and identify gaps in both methods and experimental studies. Therefore, this study will provide valuable insights by proposing new design tools (ternary diagrams) to maximize the use of excavated soils in construction practices. The proposed diagrams illustrate the intricate relation linking either hygrothermal properties, the climate zone, and manufacturing techniques, or the relation between the most studied manufacturing techniques (compaction, fibered, and stabilization) and expected dry thermal conductivity. Thereby, results from this meta-analysis and critical review will contribute to advancing sustainable construction practices.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139607826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2024-01-18DOI: 10.3390/recycling9010006
Kundani Magoda, P. Nomngongo, L. Mekuto
{"title":"Two-Step Bio-Dissolution of Metals from Printed Circuit Boards Using Acidophilic Iron- and Sulfur-Oxidizing Mesophiles","authors":"Kundani Magoda, P. Nomngongo, L. Mekuto","doi":"10.3390/recycling9010006","DOIUrl":"https://doi.org/10.3390/recycling9010006","url":null,"abstract":"To date, electronic waste (e-waste) is the fastest-growing waste stream worldwide due to technological advancement and the advent of the Fourth Industrial Revolution. Although e-waste is an environmental hazard, these materials are considered good secondary sources of metals. This study examined the bioleaching of metals from printed circuit boards, where a two-step bioleaching approach was used with iron–sulfur-oxidizing microorganisms at different e-waste particle sizes. The metal analysis from the different particle sizes (PSs) showed that copper (Cu), tin (Sn), and lead (Pb) were predominantly deposited in the coarser fraction, ranging from 500 to 710 µm at 28.7, 20.5, and 11.1 wt.%, respectively. On the other hand, metals such as iron (Fe), zinc (Zn), manganese (Mn), nickel (Ni), and aluminum (Al) were mostly deposited in the finer fraction, which ranged from 38 to 150 µm at 37.3, 5.9, 8.8, 1.3, and 4.2 wt.%, respectively. After the bioleaching process, it was observed that higher metal extraction occurred at a PS ranging from 38 to 150 µm, which achieved recovery efficiency rates of 62.9%, 68.2%, 95.3%, 86.1%, 61.9%, 47.2%, 21.2%, and 63.6% for Al, Cu, Fe, Mn, Ni, Pb, Sn, and Zn, respectively, over 10 days.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":null,"pages":null},"PeriodicalIF":4.3,"publicationDate":"2024-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139614091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}