RecyclingPub Date : 2023-06-09DOI: 10.3390/recycling8030051
Beatriz Arioli de Sá Teles, I. L. C. Cunha, Manoel L. da Silva Neto, H. Wiebeck, T. S. Valera, Simara Silveira de Souza, Alfredo Felipe de Oliveira Schmitt, V. Oliveira, L. Kulay
{"title":"Effect of Virgin PP Substitution with Recycled Plastic Caps in the Manufacture of a Product for the Telephony Sector","authors":"Beatriz Arioli de Sá Teles, I. L. C. Cunha, Manoel L. da Silva Neto, H. Wiebeck, T. S. Valera, Simara Silveira de Souza, Alfredo Felipe de Oliveira Schmitt, V. Oliveira, L. Kulay","doi":"10.3390/recycling8030051","DOIUrl":"https://doi.org/10.3390/recycling8030051","url":null,"abstract":"This study investigated the effects of partial and total substitutions of fossil polypropylene (PP) for recycled plastic cap equivalents in the manufacture of signage labels used by the telephone industry. Four alternative scenarios to using virgin PP were evaluated considering recycled material in flake and pellet forms based on environmental performance, degree of circularity, and technical behavior. The environmental analysis was performed by the life cycle assessment (LCA) technique, and for all impact categories evaluated, using recycled material to replace the virgin reduced adverse effects on the environment. The most significant results in this dimension, with gains of 81% in the Global Environmental Indicator, occurred when recycled PP flakes entirely replaced the fossil polymer. Once again, the highest values of the Materials Circularity Indicator (MCI) were achieved by scenarios with full recycled resin in processing the tags; however, this product must also be reused. The mechanical behavior of the tags measured technical performance, and in this case, the product made with virgin PP outperformed the recycled options except for elongation. An analysis that integrated the three dimensions into a single performance index pointed to the complete substitution of virgin material for recycled as the most balanced option.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49165775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-05-24DOI: 10.3390/recycling8030050
Larissa Macelle De Paulo Barbosa, Jorge Oliveira Santos, Rayssa Carolinne Mouzinho de Sousa, Jomar Livramento Barros Furtado, P. Vidinha, Marco Aurélio Suller Garcia, Hector Aguilar Vitorino, Daiane Fossatti Dall’Oglio
{"title":"Bioherbicide from Azadirachta indica Seed Waste: Exploitation, Efficient Extraction of Neem Oil and Allelopathic Effect on Senna occidentalis","authors":"Larissa Macelle De Paulo Barbosa, Jorge Oliveira Santos, Rayssa Carolinne Mouzinho de Sousa, Jomar Livramento Barros Furtado, P. Vidinha, Marco Aurélio Suller Garcia, Hector Aguilar Vitorino, Daiane Fossatti Dall’Oglio","doi":"10.3390/recycling8030050","DOIUrl":"https://doi.org/10.3390/recycling8030050","url":null,"abstract":"Bioherbicides are an alternative to minimize the damage caused to the environment using agrochemicals. This study had the objective of extracting neem oil from ripe waste fruits that Azadirachta indica A. Juss and optimizing the process using solvents (or a mixture of solvents) with different polarities. Then, through a solid-liquid extraction system (Soxhlet), the solvents hexane, methanol/hexane (1:1), ethanol, and hexane/ethanol (1:1) were used to determine the process with the highest yield and most efficiency. The physicochemical parameters of the extracted oil (density, acidity value, iodine value, saponification value, esters value, and molecular weight) and the % of free fatty acids were determined. In addition, the allelopathic properties of the oil (0%, 2%, 3%, and 4% m/v) on septic weed Senna occidentalis seeds were evaluated, analyzing their growth and development parameters (germination, germination speed, hypocotyl, and radicle length). Hexane was the most efficient (4 h) in neem oil extraction, with the highest yield (43%). It also provided a better oleic and linoleic acid content (41.3% and 18.6%), similar to ethanol extraction (41.1% and 20.22%). Moreover, the allelopathic properties were more prominent for the oils extracted with hexane and hexane/ethanol. This optimized process provides an efficient alternative to obtain a natural herbicidal potential for strategically controlling harmful plants.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46272391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-05-19DOI: 10.3390/recycling8030049
G. Lourinho, O. Alves, B. Garcia, Bruna Rijo, P. Brito, C. Nobre
{"title":"Costs of Gasification Technologies for Energy and Fuel Production: Overview, Analysis, and Numerical Estimation","authors":"G. Lourinho, O. Alves, B. Garcia, Bruna Rijo, P. Brito, C. Nobre","doi":"10.3390/recycling8030049","DOIUrl":"https://doi.org/10.3390/recycling8030049","url":null,"abstract":"During recent years, gasification technology has gained a high potential and attractiveness to convert biomass and other solid wastes into a valuable syngas for energy production or synthesis of new biofuels. The implementation of real gasification facilities implies a good insight of all expenses that are involved, namely investments required in equipment during the project and construction phases (capital expenditures, CapEx) and costs linked to the operation of the plant, or periodic maintenance interventions (operational expenditures, OpEx) or costs related to operations required for an efficient and sustainable performance of a gasification plant (e.g., feedstock pre-treatment and management of by-products). Knowledge of these economic parameters and their corresponding trends over time may help decision-makers to make adequate choices regarding the eligible technologies and to perform comparisons with other conventional scenarios. The present work aims to provide an overview on CapEx associated with gasification technologies devoted to convert biomass or solid waste sources, with a view of reducing the carbon footprint during energy generation or production of new energy carriers. In addition, an analysis of technology cost trends over time using regression methods is also presented, as well as an evaluation of specific capital investments according to the amount of output products generated for different gasification facilities. The novelty of this work is focused on an analysis of CapEx of existing gasification technologies to obtain distinct products (energy and fuels), and to determine mathematical correlations relating technology costs with time and product output. For these purposes, a survey of data and categorization of gasification plants based on the final products was made, and mathematical regression methods were used to obtain the correlations, with a statistical analysis (coefficient of determination) for validation. Specific investments on liquid biofuel production plants exhibited the highest decreasing trend over time, while electricity production became the least attractive solution. Linear correlations of specific investment versus time fitted better for electricity production plants (R2 = 0.67), while those relating the product output were better for liquid biofuel plants through exponential regressions (R2 = 0.65).","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44504974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-05-08DOI: 10.3390/recycling8030048
S. Afroze, M. S. Reza, K. Kuterbekov, A. Kabyshev, M. Kubenova, K. Bekmyrza, A. Azad
{"title":"Emerging and Recycling of Li-Ion Batteries to Aid in Energy Storage, A Review","authors":"S. Afroze, M. S. Reza, K. Kuterbekov, A. Kabyshev, M. Kubenova, K. Bekmyrza, A. Azad","doi":"10.3390/recycling8030048","DOIUrl":"https://doi.org/10.3390/recycling8030048","url":null,"abstract":"The global population has increased over time, therefore the need for sufficient energy has risen. However, many countries depend on nonrenewable resources for daily usage. Nonrenewable resources take years to produce and sources are limited for generations to come. Apart from that, storing and energy distribution from nonrenewable energy production has caused environmental degradation over the years. Hence, many researchers have been actively participating in the development of energy storage devices for renewable resources using batteries. For this purpose, the lithium-ion battery is one of the best known storage devices due to its properties such as high power and high energy density in comparison with other conventional batteries. In addition, for the fabrication of Li-ion batteries, there are different types of cell designs including cylindrical, prismatic, and pouch cells. The development of Li-ion battery technology, the different widely used cathode and anode materials, and the benefits and drawbacks of each in relation to the most appropriate application were all thoroughly studied in this work. The electrochemical processes that underlie battery technologies were presented in detail and substantiated by current safety concerns regarding batteries. Furthermore, this review collected the most recent and current LIB recycling technologies and covered the three main LIB recycling technologies. The three recycling techniques—pyrometallurgical, hydrometallurgical, and direct recycling—have been the subject of intense research and development. The recovery of valuable metals is the primary goal of most recycling processes. The growth in the number of used LIBs creates a business opportunity to recover and recycle different battery parts as daily LIB consumption rises dramatically.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46492107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-05-04DOI: 10.3390/recycling8030047
Z. Al-Saffar, A. Eltwati, E. Aziz, H. Yaacob, Halah Abdulsattar Dawood, R. Jaya, Mohammed S. Al Jawahery, E. Shaffie
{"title":"The Use of Vacuum Residue as a Potential Rejuvenator in Reclaimed Asphalt Pavement: Physical, Rheological, and Mechanical Traits Analysis","authors":"Z. Al-Saffar, A. Eltwati, E. Aziz, H. Yaacob, Halah Abdulsattar Dawood, R. Jaya, Mohammed S. Al Jawahery, E. Shaffie","doi":"10.3390/recycling8030047","DOIUrl":"https://doi.org/10.3390/recycling8030047","url":null,"abstract":"Asphalt recycling technology with a high content of reclaimed asphalt pavement (RAP) is becoming more important as the price of paving materials rises and sustainable development and environmental conservation rules become more rigorous. Nevertheless, road authorities in numerous countries still prohibit the utilisation of RAP in asphalt mixes due to the negative impacts of RAP on the performance of asphalt mixtures. Consequently, different rejuvenators have been introduced to reinstate the original attributes of aged asphalt to resolve this issue. This study incorporated vacuum residue (VR) into mixtures with 40% RAP. The physical, rheological, and mechanical traits of the resultant samples were assessed. The results show that the 7.5% VR rejuvenator minimised the RAP asphalt ageing impact. Furthermore, the rejuvenating agent demonstrated physical and rheological rehabilitative benefits for the aged asphalt. The mechanical attributes of the rejuvenated samples were also enhanced compared to the virgin asphalt (VA) specimens.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49075759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-05-01DOI: 10.3390/recycling8030046
Alejandro Moure Abelenda, F. Aiouache
{"title":"Microfactory Design for Valorization of E-Waste Plastics (Acrylonitrile-Butadiene-Styrene, Polycarbonate, and Polypropylene) on Additive Manufacturing Sector","authors":"Alejandro Moure Abelenda, F. Aiouache","doi":"10.3390/recycling8030046","DOIUrl":"https://doi.org/10.3390/recycling8030046","url":null,"abstract":"Less than half of e-waste plastics are sorted worldwide, and this rate is likely to decline as major processing countries have banned importation of e-waste plastics. This forces the development of decentralized processing facilities, also known as microfactories. The present work investigates the recyclability of different grades of acrylonitrile-butadiene-styrene (ABS) copolymer, polycarbonate, and polypropylene, which were found to be very abundant in a recycling site in the UK. The determination of the matrix relied on the resin identification codes imprinted in the e-waste plastics and subsequent Fourier-transform infrared spectroscopy (FTIR). Melt-blend extrusion technology enabled the valorization of the wasted thermoplastics as 3D filament without significant degradation of the polymers. The recycled materials maintained the tensile strength at around 2.5 MPa in agreement with the specifications offered by virgin polymers. Further characterization was done by means of laser microscope, thermogravimetric analysis, and X-ray fluorescence to determine the commercial viability of the recycled filament. A modified solvent-based method was developed with acetone to remove the brominated flame retardants: 25 g/100 mL, 30 min of contact time, and 4 extraction steps. The FTIR results show that the degradation of the rubbery dispersed phase corresponding to the butadiene can be accumulated in the less soluble fraction of the extracted ABS.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45057341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-05-01DOI: 10.3390/recycling8030045
B. Aver, N. Alfirević, A. Fošner
{"title":"Municipal Waste Recycling Customer Education and Communication in Slovenia and Croatia","authors":"B. Aver, N. Alfirević, A. Fošner","doi":"10.3390/recycling8030045","DOIUrl":"https://doi.org/10.3390/recycling8030045","url":null,"abstract":"The aim of this paper is twofold: (a) to present the existing regional research related to customer education and communication in municipal waste recycling from the viewpoint of a comparative bibliometric analysis and (b) to illustrate how municipal waste recycling practices in the two countries mirror the theoretical trends identified in the literature and the EU institutional and policy requirements. We discuss the practical implementation of municipal waste recycling practices in the two European countries and provide practical recommendations for local governments, municipal companies, and other stakeholders of the municipal waste management process.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42747810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-04-21DOI: 10.3390/recycling8020044
Nara Cangussu, Maria Luiza C. Vieira, L. Maia
{"title":"Environmental Analysis of the Incorporation of Sugarcane Bagasse in Medium Density Particleboard Panels through Life Cycle Assessment","authors":"Nara Cangussu, Maria Luiza C. Vieira, L. Maia","doi":"10.3390/recycling8020044","DOIUrl":"https://doi.org/10.3390/recycling8020044","url":null,"abstract":"The growth of civil construction and agroindustry, resulting from population growth, caused an increase in the demand for non-renewable resources and for the exploitation of natural resources. Consequently, it caused a greater generation of waste, causing the current scenario to require alternatives for the reuse of these materials. Particleboard panels, for example, used in civil construction, can add value to waste or materials of low acceptance, such as thinning wood, mechanical wood processing waste or agro-industrial waste. Thus, this study proposed to analyse the life cycle of the sugarcane bagasse, considering the stages of extraction of materials and energy resources until their final disposal. This study aimed to compare impacts generated by the production of particleboards panels produced with wood from plantations (pine) and with the sugarcane bagasse. As a result, a better environmental performance was obtained from the panel composed of sugarcane bagasse, as it generated lower environmental impacts in all impact categories studied. The benefits range from the reduction in waste disposed of in landfills, which increase its useful life, the lower demand for reforestation, with steps that generate atmospheric emissions and degrade the soil.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47612280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-04-13DOI: 10.3390/recycling8020043
A. Saud, J. Havukainen, Petteri Peltola, M. Horttanainen
{"title":"Environmental Performance of Nitrogen Recovery from Reject Water of Sewage Sludge Treatment Based on Life Cycle Assessment","authors":"A. Saud, J. Havukainen, Petteri Peltola, M. Horttanainen","doi":"10.3390/recycling8020043","DOIUrl":"https://doi.org/10.3390/recycling8020043","url":null,"abstract":"Recovering and recycling nitrogen available in waste streams would reduce the demand for conventional fossil-based fertilizers and contribute toward food security. Based on life cycle assessment (LCA), this study aimed to evaluate the environmental performance of nitrogen recovery for fertilizer purposes from sewage sludge treatment in a municipal wastewater treatment plant (WWTP). Utilizing either air stripping or pyrolysis-derived biochar adsorbent, nitrogen was recovered from ammonium-rich reject streams generated during mechanical dewatering and thermal drying of anaerobically digested sewage sludge. A wide range of results was obtained between different scenarios and different impact categories. Biochar-based nitrogen recovery showed the lowest global warming potential with net negative GHG (greenhouse gas) emissions of −22.5 kt CO2,eq/FU (functional unit). Ammonia capture through air stripping caused a total GHG emission of 2 kt CO2,eq/FU; while in the base case scenario without nitrogen recovery, a slightly lower GHG emission of 0.2 kt CO2,eq/FU was obtained. This study contributes an analysis promoting the multifunctional nature of wastewater systems with integrated resource recovery for potential environmental and health benefits.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46316977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RecyclingPub Date : 2023-04-08DOI: 10.3390/recycling8020042
A. Karaeva, E. Magaril
{"title":"Considering Waste Generation in the Energy Sector during the Transition to a Circular Economy","authors":"A. Karaeva, E. Magaril","doi":"10.3390/recycling8020042","DOIUrl":"https://doi.org/10.3390/recycling8020042","url":null,"abstract":"The need to reduce the negative environmental impact of energetics with the growing energy demand in the world is the core objective of the industry for the upcoming decades. The global agenda in the field of environmental protection increases the requirements for evaluation of the energy investment projects, in particular for their environmental efficiency. Currently, much attention is paid to assessing the impact of the project on atmospheric air, water bodies and land resources, including the formation of industrial waste during the operational stage. The formation of production and consumption waste at other stages of the project life cycle is not considered either when generating cash flows or when conducting the assessment pf environmental efficiency. It might significantly reduce the reliability of assessment results. The purpose of this study is to develop a system of integrated accounting for all types of waste generated and the environmental costs incurred for handling them during the environmental and economic assessment of energy projects. The paper discusses modern waste management practices at energy enterprises, waste generation at various stages of investment projects implementation, and provides recommendations on waste accounting when assessing their environmental and economic efficiency.","PeriodicalId":36729,"journal":{"name":"Recycling","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47708886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}