Sixteenth Annual Battery Conference on Applications and Advances. Proceedings of the Conference (Cat. No.01TH8533)最新文献_第7页

Dendrite-preventive additive (DPA) for lead-acid batteries 铅酸电池防枝晶添加剂(DPA)

Sixteenth Annual Battery Conference on Applications and Advances. Proceedings of the Conference (Cat. No.01TH8533) Pub Date : 1900-01-01 DOI: 10.1109/BCAA.2001.905104

G. Mayer

引用次数: 0

Layered cobalt and nickel oxide cathodes: a comparison of their structural and chemical stabilities 层状钴和镍氧化物阴极:结构和化学稳定性的比较

Sixteenth Annual Battery Conference on Applications and Advances. Proceedings of the Conference (Cat. No.01TH8533) Pub Date : 1900-01-01 DOI: 10.1109/BCAA.2001.905137

A. Manthiram, R. Chebiam, F. Prado

{"title":"Layered cobalt and nickel oxide cathodes: a comparison of their structural and chemical stabilities","authors":"A. Manthiram, R. Chebiam, F. Prado","doi":"10.1109/BCAA.2001.905137","DOIUrl":"https://doi.org/10.1109/BCAA.2001.905137","url":null,"abstract":"Layered LiNi/sub 0.85/Co/sub 0.15/O/sub 2/ cathodes have drawn much attention recently due to its higher capacity compared to the currently used layered LiCoO/sub 2/ cathode. However, the structural and chemical stabilities of the LiNi/sub 0.85/Co/sub 0.15/O/sub 2/ cathodes during long-term cycling in lithium-ion cells have not been fully assessed. From a systematic investigation, the structural and chemical stabilities of the two systems are compared. Wet-chemical analysis of chemically delithiated Li/sub 1-x/CoO/sub 2/ and Li/sub 1-x/Ni/sub 0.85/Co/sub 0.15/O/sub 2/ establish that the former system tends to lose oxygen from the lattice for (1-x)<0.5, which limits its capacity to 140 mAh/g, while the latter system does not suffer from oxygen loss at least for 0.3/spl les/(1-x)/spl les/1. However, the nickel oxide system suffers from structural instability under mild heat (T>50/spl deg/C) due to a migration of Ni/sup 3+/ ions from the nickel layer to the lithium layer. The differences in the structural and chemical stabilities between the two systems are explained based on crystal field stabilization energies and the relative positions of metal:3d and O:2p bands.","PeriodicalId":360008,"journal":{"name":"Sixteenth Annual Battery Conference on Applications and Advances. Proceedings of the Conference (Cat. No.01TH8533)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128192941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Absorbency of separators under compression 压缩条件下分离器的吸收性

Sixteenth Annual Battery Conference on Applications and Advances. Proceedings of the Conference (Cat. No.01TH8533) Pub Date : 1900-01-01 DOI: 10.1109/BCAA.2001.905103

A. Kallmes, P. Kallmes

引用次数: 0

Equalization requirements for series VRLA batteries 串联VRLA蓄电池的均衡要求

Sixteenth Annual Battery Conference on Applications and Advances. Proceedings of the Conference (Cat. No.01TH8533) Pub Date : 1900-01-01 DOI: 10.1109/BCAA.2001.905111

P. Krein, S. West, C. Papenfuss

引用次数: 24