Rubin Han , Hongxiu Leng , Hui Luo , Wenbo Wu , Yunrui Zhao , Bukai Song , Meng Liu , Bao-Jie He
{"title":"Turning waste into treasure: Preparation, physical properties and microstructure of alkali-activated phosphorus tailings-based fully solid waste non-sintered lightweight aggregates","authors":"Rubin Han , Hongxiu Leng , Hui Luo , Wenbo Wu , Yunrui Zhao , Bukai Song , Meng Liu , Bao-Jie He","doi":"10.1016/j.jclepro.2025.146693","DOIUrl":"10.1016/j.jclepro.2025.146693","url":null,"abstract":"<div><div>Based on the potential safety risks associated with the buildup of solid waste in Lianyungang City, Jiangsu Province, and the dual challenges of high energy consumption and resource scarcity in conventional building material production. Herein, adhering to the concept of \"total solid waste utilization\", phosphorus tailings based artificial lightweight aggregates (PT-LWA) were fabricated through multi-component collaborative design, using phosphorus tailings (PT), fly ash (FA), soda residue (SR), and granulated blast furnace slag (GGBS) as the 100 % raw material system. A comprehensive analysis was conducted to assess how varying proportions of raw materials and diverse curing conditions influence physical performance, microstructural features, durability, release characteristics of heavy metals. Additionally, economic costs and economic emissions from PT-LWA were analyzed. The findings showed that the artificial lightweight aggregates exhibited optimal efficiency when fabricated with a raw material ratio of PT: FA: SR: GGBS = 40 %:20 %:30 %:10 % under 80 °C steam curing conditions. Specifically, the bulk density, softening coefficient, and 1-h water absorption of the resultant PT-LWA were 1038 kg/m<sup>3</sup>, 0.942, and 14.1 %, respectively. Additionally, the cylinder crush strength attained a value of 9.7 MPa, surpassing the performance observed in conventionally cured samples. Microstructural analysis revealed that the dominant hydration phases primarily consisted of C-(A)-S-H gel formations. They are evenly distributed on particle surfaces and form a robust colloidal structure, which further enhances its strength. The concentration values of released heavy metals are well below the thresholds defined by China's hazardous waste identification standards (GB 5085.3-2007), suggesting that PT-LWA will not cause secondary environmental pollution.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146693"},"PeriodicalIF":10.0,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145227730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Christian Clemm , Mitsutaka Matsumoto , Kenichiro Chinen , Yoon-Young Chun , Media Romadona
{"title":"Circular economy in practice: The influence of second-hand stores on used electronics consumption in Japan and Germany","authors":"Christian Clemm , Mitsutaka Matsumoto , Kenichiro Chinen , Yoon-Young Chun , Media Romadona","doi":"10.1016/j.jclepro.2025.146717","DOIUrl":"10.1016/j.jclepro.2025.146717","url":null,"abstract":"<div><div>This study examines consumer purchase intention for second-hand electrical and electronic equipment in Japan and Germany, focusing on attitudinal drivers in addition to the accessibility of physical stores. Two web-based surveys (n = 600 and n = 866) collected data on consumer perceptions and the proximity of second-hand retailers. Regression analyses show that perceived benefits and risks significantly correlate with purchase intention, with notable differences between the two countries. The availability of physical second-hand stores plays a key role, while expected benefits of physical shopping environments had limited impact. German consumers were found to purchase second-hand electronic equipment at a significantly higher rate compared to their Japanese counterparts. The study contributes to circular economy research by combining subjective perceptions with reported infrastructural data, offering a more integrated model of reuse behavior. Findings have practical implications for policy and retail, highlighting the importance of local accessibility and consumer trust. While grounded in high-income contexts, the methodological approach can inform future research in emerging economies and other product domains.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146717"},"PeriodicalIF":10.0,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145183123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shu Fu , Jianjun Zhang , Yufei Li , Wei Chen , Yaping Zhang , Kexin Yi , Yixin Dai
{"title":"Environmental variables affect the effectiveness of ecosystem services of ecological restoration project: Evidence from Xiangjiang River Basin-Dongting Lake","authors":"Shu Fu , Jianjun Zhang , Yufei Li , Wei Chen , Yaping Zhang , Kexin Yi , Yixin Dai","doi":"10.1016/j.jclepro.2025.146739","DOIUrl":"10.1016/j.jclepro.2025.146739","url":null,"abstract":"<div><div>Understanding the ecosystem services effectiveness of ecological restoration project (ERP) and their environmental impact factors is crucial for optimizing restoration strategies. However, current studies still have limitations in terms of the evaluation benchmarks for the ecological effects of ERP and the interaction pathways among the factors influencing those ecological effects. Therefore, this study explored a pilot restoration project of full-array ecosystems in the Xiangjiang River Basin-Dongting Lake area as an example. By using Patch-generating Land Use Simulation and benefit transfer methods, an assessment baseline for the scenario without ERP was established, and the effectiveness of ecosystem service value (ESV) for different restoration types was evaluated. Redundancy analysis and Partial Least Squares Structural Equation Modeling were then employed to decouple the direct and indirect effects of environmental variables on the ESV effectiveness. The main findings indicate that climate, terrain, and human activity intensity were the primary environmental factors influencing the ESV effectiveness. In damaged areas with rich hydrothermal conditions, complex terrain, and strong human activity interference, the direct improvements in ESV after restoration were more obvious. However, the environmental constraints on the recovery of vegetation and water body were also greater, which indirectly weakens the ESV effectiveness. This study provided a comprehensive perspective for understanding the effectiveness of ERP and enriched decision-support methods for ERP.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146739"},"PeriodicalIF":10.0,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145183161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jian Li , Wen Fu , Xiaowei Bai , Ning Mao , Xiangrui Lin , Heping Yang , Mengfei Wang , Guangxuan Liu , Zhenghua Dai
{"title":"Oxidative pyrolysis of biomass waste: Efficient production of humic substances with enhanced agricultural potential and environmental benefits","authors":"Jian Li , Wen Fu , Xiaowei Bai , Ning Mao , Xiangrui Lin , Heping Yang , Mengfei Wang , Guangxuan Liu , Zhenghua Dai","doi":"10.1016/j.jclepro.2025.146691","DOIUrl":"10.1016/j.jclepro.2025.146691","url":null,"abstract":"<div><div>This study reports an innovative oxidative pyrolysis-based technology for the high-value conversion of biomass waste, achieving efficient co-production of humic acid (24.2 wt%), fulvic acid (7.9 wt%), and humin (15.0 wt%) under optimized reaction conditions (400 °C, <5 min). This breakthrough addresses long-standing challenges in humic acid production, particularly in terms of efficiency and energy consumption. Multi-scale characterization techniques, including FTIR and TG, revealed unique structural features of the products: compared to standard humic acid, the humic acid and humin derived from oxidative pyrolysis exhibit a higher proportion of lightweight components (e.g., carboxylic acids, polysaccharides, and phenols), lower aromaticity, and reduced molecular weight. These characteristics, characterized by low polymerization and high bioactivity, significantly enhance their potential for agricultural applications. A life cycle assessment (LCA) further quantified the environmental benefits of this technology, demonstrating a reduction of 12,700 tons of CO<sub>2</sub>-equivalent emissions per 10,000 tons of humic acid produced, alongside a waste resource utilization rate of approximately 75 %. The work establishes a rapid waste-to-product conversion route, elucidates transformation mechanisms, and provides a sustainable biomass utilization model, advancing green agriculture.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146691"},"PeriodicalIF":10.0,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145153847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Exploring the evolutionary driving factors of collaborative innovation networks based on complex network evolutionary game: a case study of China's smart grid industry","authors":"Yuan Tao","doi":"10.1016/j.jclepro.2025.146713","DOIUrl":"10.1016/j.jclepro.2025.146713","url":null,"abstract":"<div><div>The collaborative innovation network of China's smart grid industry plays a pivotal role in low-carbon economic transformation, energy security and smart city development. Clarifying its evolutionary driving factors is significant for optimizing the network. Based on collaborative patents of China's smart grid industry from 1987 to 2021, this study combines social network analysis and complex network evolutionary game model to construct collaborative innovation networks at different stages, exploring the impact of macro and micro driving factors on the network evolution. The results show that (1) the evolution depth and speed of the network are greater when the network heterogeneity is large. (2) The increase of allocated benefits, cooperation benefits, penalty for breach of contract, losses from competition and implicit benefits will improve the depth and speed of the network evolution. (3) The initial network state also affects the network evolution. The evolution depth and speed of the network are greater when the network scale is larger, the average number of connections is higher, and the average degree is higher. This study provides a theoretical support for improving the collaborative innovation network of China's smart grid industry and an analytical framework for studying the evolutionary driving factors of collaborative innovation networks through the complex network evolutionary game.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146713"},"PeriodicalIF":10.0,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145183160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Derrick K. Allotey , Ebenezer M. Kwofie , Praiya Asavajaru , Anusha G.P. Samaranayaka
{"title":"An integrative framework for eco-efficiency assessment in plant-protein extraction processes: Hotspot analysis, protein loss tracking, and uncertainty analysis","authors":"Derrick K. Allotey , Ebenezer M. Kwofie , Praiya Asavajaru , Anusha G.P. Samaranayaka","doi":"10.1016/j.jclepro.2025.146684","DOIUrl":"10.1016/j.jclepro.2025.146684","url":null,"abstract":"<div><div>Over the past few years, the growing demand for plant-based proteins has intensified the need to scale up extraction technologies, for efficient and sustainable protein production. Towards the adoption of existing methods, modified extraction methods as well as emerging technologies, there is the need to assess and ascertain the overall sustainability performance of the methods, integrating economic, product quality and environmental perspectives. However, a comprehensive assessment framework that integrates these three (3) sustinability dimensions, for the plant-protein industry, remains lacking. This study proposes a novel eco-efficiency assessment framework tailored to evaluate sustainability of plant-protein extraction methods, with a focus on industrial commercialization potential. The framework integrates eco-efficiency analysis, hotspot identification of economic value, protein loss tracking, protein purity, environmental impacts, and uncertainty and global sensitivity analyses to highlight key production variables that influences sustainability outcomes. The framework was applied to a case study of pea protein extraction by the alkaline-isoelectric precipitation (ALK-IEP) method with multiple trials using different yellow pea varieties. Results highlighted the major contribution of the spray drying, pasteurization and extraction-decantation sections to eco-environmental outcomes and protein content loss. The findings offer insights for optimizing the extraction process and improving eco-efficiency, contributing to more sustainable, scalable commercial pea protein production.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146684"},"PeriodicalIF":10.0,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145183159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Machine learning-enhanced uncertainty quantification for renewable-powered hybrid green ammonia and refrigeration systems: Technoeconomic and environmental effects","authors":"Muzumil Anwar , Israfil Soyler , Nader Karimi","doi":"10.1016/j.jclepro.2025.146702","DOIUrl":"10.1016/j.jclepro.2025.146702","url":null,"abstract":"<div><div>Renewable-powered ammonia production is a promising route for sustainable energy and hydrogen storage but is highly sensitive to operational uncertainty from variable power supply and component performance. This study presents a novel machine learning–enhanced uncertainty quantification (ML-UQ) framework that, for the first time, integrates a high-fidelity surrogate model—an artificial neural network with autoregressive feedback—into Aspen Plus simulations of a hybrid ammonia production system coupled with a vapour absorption refrigeration unit for heat recovery. The framework captures nonlinear interactions among six critical uncertain parameters, including renewable power variability, heat exchanger effectiveness, and compressor efficiency. It reduces the computational cost by three orders of magnitude while maintaining high predictive accuracy (R<sup>2</sup> = 0.97, MAE = 8.57, RMSE = 11.3). The ANN surrogate enables scalable uncertainty propagation via polynomial chaos expansion. Results show that, across nominal power levels of 10–20 MW, uncertainties can cause up to 18 % variation in ammonia output, 30 % in refrigeration, and 40–50 % in CO<sub>2</sub> emissions reduction. Heat exchanger effectiveness alone accounts for nearly 50 % of total variability. Economic analysis indicates a 5 % increase in the levelized cost of ammonia and 30–40 % variation in annual refrigeration revenue. This work delivers the first computationally feasible, ML-assisted surrogate-based UQ framework for hybrid green ammonia systems. More broadly, it offers a practical and readily scalable tool for designing resilient, economically viable, and low-carbon energy and chemical manufacturing systems.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146702"},"PeriodicalIF":10.0,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145153955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guilin Wen , Fangxin Li , Min Xu , Xin Li , Yinglong Wang , Guohua Tang , Zhaoyou Zhu , Limei Zhong
{"title":"Enhanced acid gas capture in Rectisol process with methanol-DES mixed absorbents","authors":"Guilin Wen , Fangxin Li , Min Xu , Xin Li , Yinglong Wang , Guohua Tang , Zhaoyou Zhu , Limei Zhong","doi":"10.1016/j.jclepro.2025.146729","DOIUrl":"10.1016/j.jclepro.2025.146729","url":null,"abstract":"<div><div>Rectisol process is a widely used technology to absorb the acid gases such as CO<sub>2</sub> and H<sub>2</sub>S produced from the coal gasification. The low operating temperature and the high operating pressure cause the high energy consumption of the absorption process. To achieve energy efficiency, the deep eutectic solvent (DES) choline chloride-monoethanolamine (1:5), which features high capacity for absorbing acid gases, was selected as the key component of the mixed absorbent blended with methanol. The key physicochemical properties of methanol-DES mixed absorbents with different mass ratios, which significantly affect practical application, were investigated experimentally. The mixed absorbents with different mass ratios were used to absorb CO<sub>2</sub> and H<sub>2</sub>S in the shifted gas absorption column and mixing effects were analyzed. The results show that the mixed absorbent with the mass ratio of 6:4 exhibits the lowest refrigeration cost. The dynamic control structure of the process was also developed to maintain the absorption performance under ±10 % CO<sub>2</sub> composition disturbances. A multi-proportion control structure was explored to control the shifted gas absorption column well. This comprehensive approach not only boosts economic viability but also supports environmental sustainability, making it a viable solution for industrial applications.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146729"},"PeriodicalIF":10.0,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145153879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The impact of protected area establishment on biodiversity via tourism pressure: a case study in Three-river-source National Park, China","authors":"Yuxi Zeng , Lingen Wang , Linsheng Zhong","doi":"10.1016/j.jclepro.2025.146654","DOIUrl":"10.1016/j.jclepro.2025.146654","url":null,"abstract":"<div><div>Establishing protected areas (PAs) and sustainably developing PA tourism are critical for balancing biodiversity conservation (SDG 15) and poverty alleviation (SDG 1). However, the mechanisms by which the establishment of PAs influences tourism and, consequently, biodiversity remain unclear, particularly regarding the differing impacts within PAs and their surrounding areas. This study examines Three-River-Source National Park in China and its surrounding areas to analyze the effects of PA establishment on biodiversity via tourism pressure from 2005 to 2020. The results show that PA establishment notably improves biodiversity within the PA by alleviating tourism pressure. PA establishment increased biodiversity by approximately 5.8 %. However, in certain surrounding areas, the reduction in tourism pressure negatively affected biodiversity, likely due to the weakening of tourism as an alternative livelihood and the reinforcement of traditional livelihoods that harm biodiversity. This study enhances the understanding of the mechanisms through which PA establishment influences tourism pressure and biodiversity, offering insights for optimizing tourism development and biodiversity conservation strategies in PAs to support the achievement of SDG goals.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146654"},"PeriodicalIF":10.0,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yixin Liao , Jiajun Huang , Chenrui Luo , Minzi Fang , Xinliang Xu , Zhi Qiao , Luo Liu
{"title":"Deciphering supply-demand mismatch and influencing mechanisms of cropland multifunction in China: Toward targeted spatial governance","authors":"Yixin Liao , Jiajun Huang , Chenrui Luo , Minzi Fang , Xinliang Xu , Zhi Qiao , Luo Liu","doi":"10.1016/j.jclepro.2025.146719","DOIUrl":"10.1016/j.jclepro.2025.146719","url":null,"abstract":"<div><div>The imbalance between the supply and demand of cropland multifunction has emerged as a key challenge for the sustainable use of cropland in high-density population areas globally. However, current research mainly focuses on supply-side mechanisms and lacks a systematic analysis of the spatial relationships and factors influencing the supply-demand matching of cropland multifunction, thereby constraining decision-making for managing multifunctional mismatches. To solve these problems, this study constructs an integrated framework of \"supply-demand matching - process response - zoning management,\" combining the eXtreme gradient boosting, Shapley additive exPlanations for interpretability, to analyze the spatial heterogeneity and influencing factors of cropland multifunction supply-demand relationships in China. Based on the clustering of self-organizing maps, spatially adaptive governance strategies are proposed. Results show that: (1) Cropland multifunctional supply-demand presents significant spatial mismatches, with most regions showing supply surpluses; 47.9 %, 54.9 %, and 75.9 % of areas exceed demand in production, ecological, and landscape-cultural functions, respectively, while 52.4 % of areas exhibit deficits in social security functions. (2) Factors influencing supply-demand matching vary markedly among different cropland functions, with population size and economic development accounting for 21 %–39 % and showing pronounced nonlinear effects. (3) Eight cropland functional clusters are identified, supporting targeted governance strategies such as cross-regional resource coordination, ecological compensation, and urban-rural cultural integration. This study highlights the importance of considering spatial relationships and influencing factors in spatial policy formulation, offering recommendations for optimizing cropland resource allocation and promoting sustainable management.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"527 ","pages":"Article 146719"},"PeriodicalIF":10.0,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}