Journal of Cleaner Production最新文献

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Facilitating lignocellulose fractionation of Moringa oleifera Lam. husk by pretreatment with a novel 1-tetradecyl-3-carboxymethylimidazolium bromide-based deep eutectic solvent 使用新型 1-十四烷基-3-羧甲基溴化咪唑鎓深共晶溶剂进行预处理,促进油辣木籽壳的木质纤维素分馏
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-18 DOI: 10.1016/j.jclepro.2024.144249
Jiabo Cheng, Yuan Gao, Jie Liu, Yuting Zhang, Mengfei Tian, Mengying Zhang, Yaru Zhang, Chunjian Zhao, Chunying Li
{"title":"Facilitating lignocellulose fractionation of Moringa oleifera Lam. husk by pretreatment with a novel 1-tetradecyl-3-carboxymethylimidazolium bromide-based deep eutectic solvent","authors":"Jiabo Cheng, Yuan Gao, Jie Liu, Yuting Zhang, Mengfei Tian, Mengying Zhang, Yaru Zhang, Chunjian Zhao, Chunying Li","doi":"10.1016/j.jclepro.2024.144249","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144249","url":null,"abstract":"Refining lignocellulose into fermentable monosaccharides remains a challenging endeavor. In this study, we employed a novel deep eutectic solvent (DES) composed of 1-tetradecyl-3-carboxymethylimidazolium bromide (C<sub>14</sub>CIMBr) and lactic acid (LA) for the pretreatment of <em>Moringa oleifera</em> Lam. husk <em>(M. oleifera</em> husk), aiming to enhance lignocellulose fractionation. The optimal conditions identified were 165°C, 43.9 minutes, and a molar ratio of C<sub>14</sub>CIMBr to LA at 1:4.8, resulting in the removal of 93.8% of lignin and 96.8% of hemicellulose. Following enzymatic hydrolysis of the pretreated <em>M. oleifera</em> husk, yields of glucose and xylose reached 94.3% and 86.1%, respectively, representing significant increases by factors of 7.0-fold and 10.3-fold compared to untreated <em>M. oleifera</em> husk. Molecular simulations indicated that the novel DES effectively disrupts the original internal hydrogen bonding network while reconstructing new DES-lignocellulosic hydrogen bonds, it also demonstrates excellent solubilization capabilities for lignin cleavage products. Finally, the yield of regenerated lignin reached 81.3%, exhibiting notable bactericidal activity under blue light irradiation.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"168 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
What affects consumer’s participation in vehicle scrappage programmes? An empirical study on scrapping intentions 是什么影响了消费者参与汽车报废计划?关于报废意向的实证研究
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-18 DOI: 10.1016/j.jclepro.2024.144254
, Sarada Prasad Sarmah, Nikesh Nayak
{"title":"What affects consumer’s participation in vehicle scrappage programmes? An empirical study on scrapping intentions","authors":", Sarada Prasad Sarmah, Nikesh Nayak","doi":"10.1016/j.jclepro.2024.144254","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144254","url":null,"abstract":"This study examines consumer intentions toward scrapping End-of-Life vehicles (ELVs) to understand how vehicle scrappage policies might alleviate environmental deterioration caused by emissions from outdated vehicles. The research objective is to assess the factors influencing consumer decisions regarding vehicle scrappage, using a model grounded in the Theory of Planned Behavior (TPB). Data was collected from 403 valid responses and analyzed using exploratory factor analysis, confirmatory factor analysis, and structural equation modeling.The findings reveal that the original TPB model accounts for 58.3% of the variance in consumer intentions to scrap vehicles. However, incorporating sociodemographic variables into the model increases the explained variance to 80.6%, with perceived behavioral control as the most influential factor, followed by consumer attitudes. We found that subjective norms do not influence consumers' intentions to participate in scrappage programs. Younger consumers were more likely to support vehicle scrappage, while environmental concerns alone did not foster a positive attitude toward scrappage.In conclusion, while consumer intentions to scrap vehicles are primarily influenced by control and attitude, targeted interventions are needed to enhance policy adoption. Key managerial implications include: promoting acceptance through tailored advertisements, offering differentiated subsidies, engaging younger audiences through awareness campaigns, and redefining promotional strategies to encourage ELV scrappage effectively.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"10 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Data-driven ship typical operational conditions: a benchmark tool for assessing ship emissions 数据驱动的船舶典型运行条件:评估船舶排放的基准工具
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144252
Ailong Fan, Xuelong Fan, Mingyang Zhang, Liu Yang, Yuqi Xiong, Xiao Lang, Chenxing Sheng, Yapeng He
{"title":"Data-driven ship typical operational conditions: a benchmark tool for assessing ship emissions","authors":"Ailong Fan, Xuelong Fan, Mingyang Zhang, Liu Yang, Yuqi Xiong, Xiao Lang, Chenxing Sheng, Yapeng He","doi":"10.1016/j.jclepro.2024.144252","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144252","url":null,"abstract":"Analysing operational conditions of ships presents a novel approach to assessing emission levels, motivated by the inadequacy of traditional static weighting factors, such as ISO 8178-E3 cycle, to capture the dynamic and complex operating characteristics of ships at sea. This study introduces a data-driven method to construct and validate ship typical operational conditions. The method encompasses identifying ship motion states, extracting features, compressing time series data based on these features, and performing cluster analysis. It has been applied to process over 12.6 million data points, demonstrating its applicability to a large dataset. The results indicate that by using actual measurement data and the proposed methodology, three typical operational conditions for ships were successfully established. There are significant differences in the feature parameters among these conditions, highlighting the distinct characteristics of each operational state. The validity of the constructed typical operational conditions was confirmed through a validation process, which involved analysing the differences in feature parameters and comparing the probability distributions of speed and acceleration to the overall dataset. Additionally, energy consumption and emission levels calculated using the typical conditions were validated through comparison with real-world data from upstream and downstream voyages. This study providing a novel tool for assessing emissions in the maritime industry.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"76 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The cost of sustainability in the construction sector – the case of family houses in Belgium 建筑行业可持续性的成本--以比利时家庭住宅为例
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144240
J. Douhard, B. Van Pottelsberghe de la Potterie
{"title":"The cost of sustainability in the construction sector – the case of family houses in Belgium","authors":"J. Douhard, B. Van Pottelsberghe de la Potterie","doi":"10.1016/j.jclepro.2024.144240","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144240","url":null,"abstract":"The housing sector is a major contributor to greenhouse gas emissions and a large body of literature has focused on measuring the environmental impact of houses, using the Life Cycle Assessment (LCA) methodology. This literature reaches the conclusion that alternative construction materials should be used to reduce the environmental impact of buildings. While such research provides essential knowledge on the carbon footprint of the housing sector, few studies take into account the economic side of the issue. This paper addresses this gap by calculating the Life Cycle Cost (LCC) of houses and matching the results with the LCA stages. The methodology is developed for two reference houses in Belgium. Considering all elements and materials used in the construction process, this approach allows a comparison of each house’s elements based on the required investment to abate their carbon footprint. The most striking results are that <span><span>(1)</span></span> the operational stage (i.e., the use of houses) accounts for about 65% of the total carbon impact of a house; (2) a 1€ investment in sustainable materials induces a drop of 1 to 1.3 kgCO<sub>2</sub>eq; (3) this effect is heterogeneous across materials, with the highest returns obtained for external walls (-6 KgCO<sub>2</sub>eq) and windows (-3 to -6 kgCO<sub>2</sub>eq) and the lowest returns obtained for ground floor (-0.3 kgCO<sub>2</sub>eq).","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"13 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Education for Sustainable Development (ESD) through Participatory Research (PR): A systematic review 通过参与式研究(PR)开展可持续发展教育(ESD):系统回顾
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144237
Alexa Ray R. Fernando, Gizelle P. Tajan
{"title":"Education for Sustainable Development (ESD) through Participatory Research (PR): A systematic review","authors":"Alexa Ray R. Fernando, Gizelle P. Tajan","doi":"10.1016/j.jclepro.2024.144237","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144237","url":null,"abstract":"With less than a decade left to achieve the SDGs, developing human capacity and promoting transformative learning is crucial to encourage as many people as possible to become agents of change toward achieving these goals. The literature suggests that Participatory Research (PR)—a host of methods, designs, and collaborative frameworks—has the potential to facilitate inclusive, participatory, and bottom-up approaches to knowledge co-generation and transformative learning in various communities. Using a systematic review approach, this study explored the use of PR in ESD in the recent global literature on education. PR’s efficacy as a participatory tool for ESD among collegiate and adult learners was analyzed. PR’s use and effectiveness in ESD to various stakeholders were also examined. The reviewed studies emphasized the potential of PR in promoting inclusive and participatory approaches to transformative learning and knowledge co-generation among many stakeholders. It highlights the need for academic institutions to adopt participatory and collaborative research methods to enhance their contributions towards achieving the SDGs through ESD. Furthermore, the study investigated how ESD through PR enables individuals to become active social agents and decision-makers in the quest for transformative change and sustainable development. Implications to curriculum and pedagogy enhancement and future directions for using PR in ESD were also presented.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"76 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Circular economy in action: Transforming textile waste into sustainable soil additives - Physicochemical properties and biodegradability” [J. Clean. Prod. 480 (2024) 144093] 循环经济在行动:将纺织废物转化为可持续的土壤添加剂--物理化学特性和生物降解性"[J. Clean. Prod.
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144216
Daria Marczak, Krzysztof Lejcuś, Joanna Grzybowska-Pietras, Włodzimierz Biniaś, Ahmed Tamma
{"title":"Corrigendum to “Circular economy in action: Transforming textile waste into sustainable soil additives - Physicochemical properties and biodegradability” [J. Clean. Prod. 480 (2024) 144093]","authors":"Daria Marczak, Krzysztof Lejcuś, Joanna Grzybowska-Pietras, Włodzimierz Biniaś, Ahmed Tamma","doi":"10.1016/j.jclepro.2024.144216","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144216","url":null,"abstract":"No Abstract","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"1 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance of surfactant supplementation on alleviating membrane fouling in treatment of waste activated sludge: Experimental and modeling analyses 在处理废弃活性污泥时补充表面活性剂对减轻膜堵塞的作用:实验和模型分析
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144248
Mohsen Taghavijeloudar, Bahman Nazari, Mahdokht Safaei
{"title":"Performance of surfactant supplementation on alleviating membrane fouling in treatment of waste activated sludge: Experimental and modeling analyses","authors":"Mohsen Taghavijeloudar, Bahman Nazari, Mahdokht Safaei","doi":"10.1016/j.jclepro.2024.144248","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144248","url":null,"abstract":"In this research, surfactant supplementation was investigated as a novel strategy for alleviation of membrane fouling in waste activated sludge (WAS) membrane filtration process. The effect of WAS pre-treatment with different surfactants on membrane performance were investigated in terms of flux variation, membrane rejection and fouling mechanisms. A generalization form of blocking law was developed to determine membrane fouling mechanism. According to the results, cationic surfactant below critical micelle concentration (CMC) values improved membrane performance, while anionic and non-ionic surfactant showed a negative impact at all dosages. It was observed that WAS pretreatment with 300 mg/L Cetyltrimethylammonium bromide (CTAB) could increase the water flux from 195 to 611 L/m<sup>2</sup>/h (LMH) and decrease the rejection rate from 93% to 85%, respectively. Although CTAB addition increased the total extracellular polymeric substances (EPSs) amount from 56.16 to 119.6 mg/L which was due to the surfactant solubilization property, the total resistance decreased from 0.33×10<sup>10</sup> to 0.11×10<sup>10</sup> m<sup>-1</sup>. This was attributed to the flock formation induced by CTAB through charge neutralization and bridging mechanism. Modeling simulation of the results indicated that CTAB addition transformed fouling mechanism from cake to intermediate-blocking model. The environmental risk assessment revealed that only 0.3 mg/L surfactant penetrated in permeate which was low ecological risk (risk quotients (RQ) &lt; 0.5) to the aquatic environment. Our finding suggested CTAB treatment at low dosage (0.1 g/L) as a promising and efficient approach for fouling mitigation and improving membrane process for wastewater treatment.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"50 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Public Complaints of Water Pollution: A Long-term Spatiotemporal Analysis in Japan 公众对水污染的投诉:日本的长期时空分析
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144239
Qiyang Nie, Tong Liu
{"title":"Public Complaints of Water Pollution: A Long-term Spatiotemporal Analysis in Japan","authors":"Qiyang Nie, Tong Liu","doi":"10.1016/j.jclepro.2024.144239","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144239","url":null,"abstract":"Public complaints about water pollution are important indicators of public environmental risk perception and provide crucial feedback for evaluating the effectiveness of water resource management strategies. This study conducts a comprehensive analysis of water pollution complaint in Japan from 1989 to 2021, utilizing integrated datasets that include river networks, water quality monitoring stations, regional industrial demographics, and socioeconomic indicators. Our findings reveal a significant decline in complaints—over 45% from the peak in 2006—following the implementation of various environmental policies aimed at reducing industrial discharge and restoring natural ecosystem function. The shift in complaint targets from industries to individuals suggests that these policies have been effective in mitigating industrial pollution, while also highlighting the need to address individual behaviors that impact water quality. Despite long-term improvement in water quality indicators such as Suspended Solids (SS) and Dissolved Oxygen (DO), no significant correlation was observed between these indicators and the temporal or spatial patterns of water pollution complaints. Instead, a strong positive correlation was observed between complaints and reported water quality incidents, reflecting heightened public sensitivity to acute pollution events. Spatial analysis further identified a significant association between complaints and the manufacturing workforce, indicating that industrial activity continues to shape public perception of water pollution risks. Our findings underscore the complex interaction between public perception, environmental policies, and industrial activities, and suggest that effective water management requires a multifaceted approach. Policymakers should continue to enforce stringent industrial regulations, while also enhancing public education and communication strategies to improve awareness of individual responsibilities in water protection. This research provides a theoretical basis for developing more responsive and effective environmental policies and public education strategies.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"18 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Prediction of Dominant Roof Water Inrush Windows and Analysis of Control Target Area based on Set Pair Variable Weight - Forward Correlation Cloud Model 基于集对变量权重-前向相关云模型的屋顶主要涌水窗口预测和控制目标区域分析
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144253
Wenju Cheng, Huiyong Yin, Daolei Xie, Fangying Dong, Yongjie Li, Teng Zhu, Ji Wang
{"title":"Prediction of Dominant Roof Water Inrush Windows and Analysis of Control Target Area based on Set Pair Variable Weight - Forward Correlation Cloud Model","authors":"Wenju Cheng, Huiyong Yin, Daolei Xie, Fangying Dong, Yongjie Li, Teng Zhu, Ji Wang","doi":"10.1016/j.jclepro.2024.144253","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144253","url":null,"abstract":"Coal mining disturbs the roof overlying rock, forming a channel for roof water inrush. This process destroys the primary seepage state of the deep aquifer, resulting in waste and pollution of deep water resources and posing a significant threat to coal mining. Therefore, through field measurement and numerical simulation, this paper comprehensively analyzes the development law of coal seam mining overlying rock fracture, and determines the influence range of coal seam roof water inrush. Then, a set pair variable weight - forward associated cloud prediction model is constructed to predict the dominant water inrush window and seepage channel of coal seam roof, and the key protection area of coal mining roof water inrush is delineated. The results show that with the continuous advance of the coal face, the stress shifts to both sides of the face, forming a stress concentration area, and the vertical fissure develops intensively, which becomes the main channel of water inrush. After the development is stable, it is comprehensively determined that the fissure production ratio of the coal seam is 11.7, and the fracture zone extends to the aquifer area are the water inrush source. Then, through the prediction model, the edge of the danger area near the high-risk area is defined as the advantage window of coal seam roof water inrush, and the result is consistent with the actual water inrush event. Therefore, the target of water inrush in roof is determined, and the effective measures of water reduction mining are put forward. This study is of great significance for protecting deep water resources, ensuring mine safety, and creating efficiency and increasing income.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"248 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Arsenic Removal using De-oiled Mentha Biomass Biochar: Adsorption Kinetics and the Role of Iron Modification 利用脱油薄荷生物质生物炭去除砷:吸附动力学和铁改性的作用
IF 11.1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2024-11-17 DOI: 10.1016/j.jclepro.2024.144247
Sampurna Nand, Saroj Kumar, Bhanu Pratap, Divya Dubey, Mariya Naseem, Anju Patel, Siddharth Shukla, Pankaj Kumar Srivastava
{"title":"Arsenic Removal using De-oiled Mentha Biomass Biochar: Adsorption Kinetics and the Role of Iron Modification","authors":"Sampurna Nand, Saroj Kumar, Bhanu Pratap, Divya Dubey, Mariya Naseem, Anju Patel, Siddharth Shukla, Pankaj Kumar Srivastava","doi":"10.1016/j.jclepro.2024.144247","DOIUrl":"https://doi.org/10.1016/j.jclepro.2024.144247","url":null,"abstract":"Arsenic contamination in water threatens millions of people globally, demanding the development of sustainable and effective remediation strategies. This work investigates the removal of As(V) using Fe-modified biochar derived from de-oiled Mentha waste (MMBC). The study aimed to synthesize MMBC and evaluate its adsorption capacity; secondly, to investigate adsorption kinetics; and lastly, to elucidate the governing mechanisms behind the process. Proximate analysis revealed MMBC's stability (low moisture: 6.48%, high fixed carbon: 54.7%) and high adsorption potential (low volatile matter: 9.77%). Characterization techniques (SEM-EDX, XRD, FTIR, TGA) confirmed a desirable porous structure, favourable chemical composition, and surface functionality critical for As(V) adsorption. Importantly, MMBC exhibited a significantly larger surface area providing more active sites (378.08 m<sup>2</sup> g⁻<sup>1</sup>) as compared to the unmodified biochar. Concerning operational conditions, the optimal As(V) removal was achieved at pH 7.5 with a 25 mg/50 mL MMBC dosage in a 24 h contact time. Further, kinetic modelling indicated a pseudo-second-order mechanism, suggesting chemisorption as the dominant process. However, isotherm studies revealed favourable multilayer adsorption, with the Freundlich model best describing the data. The combined effects of MMBC's porosity, functional groups, and Fe modification facilitated both physical and chemical adsorption mechanisms. These findings highlight MMBC's potential as a promising biochar-based adsorbent for efficient As(V) removal from contaminated water for sustainable remediation.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"32 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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