Journal of Cleaner Production最新文献

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Multi-objective interpretation machine learning framework for Synergistically optimizing energy consumption and surface quality in electrolytic copper foil production 电解铜箔生产中协同优化能耗和表面质量的多目标解释机器学习框架
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-13 DOI: 10.1016/j.jclepro.2025.146617
Zhengwu Yang , Xinwan Zhang , Huawei Hu , Yaqi Shi , Wenxuan Xu , Huiting Huang , Wenzhuo Zhang , Dan Fu , Zhihao Lu , Daqing Jia , Dingming Chang , Lehua Zhang
{"title":"Multi-objective interpretation machine learning framework for Synergistically optimizing energy consumption and surface quality in electrolytic copper foil production","authors":"Zhengwu Yang ,&nbsp;Xinwan Zhang ,&nbsp;Huawei Hu ,&nbsp;Yaqi Shi ,&nbsp;Wenxuan Xu ,&nbsp;Huiting Huang ,&nbsp;Wenzhuo Zhang ,&nbsp;Dan Fu ,&nbsp;Zhihao Lu ,&nbsp;Daqing Jia ,&nbsp;Dingming Chang ,&nbsp;Lehua Zhang","doi":"10.1016/j.jclepro.2025.146617","DOIUrl":"10.1016/j.jclepro.2025.146617","url":null,"abstract":"<div><div>The rapid growth of the electronic chip industry, fueled by the rise of artificial intelligence, is driving increasing demand for high-quality electrolytic copper foil (ECF). A major challenge for ECF production is achieving high-quality output in a cost-effective and low-carbon manner. In this study, a Composite-Feature-Multi-Objective-Interpretation (CFMI) framework based on machine learning (ML) was developed to simultaneously optimize energy consumption and CF surface roughness during ECF production. The results show that the eXtreme Gradient Boosting (XGBoost) model outperforms the other seven ML algorithms in predicting both energy consumption (RMSE = 50.39 kWh·t<sup>−1</sup>, R<sup>2</sup> = 0.93) and CF surface roughness (RMSE = 0.30 μm, R<sup>2</sup> = 0.73). SHapley Additive exPlanations (SHAP) analysis identifies current density, temperature, and sulfuric acid concentration as primary factors influencing energy consumption, while deposition time, current density, and copper ion predominantly affect CF surface roughness. Moreover, SHAP-based feature clustering effectively reduces dimensionality while maintaining model accuracy, with XGBoost showing less than 1 ‰ R<sup>2</sup> degradation. Furthermore, the proposed multi-objective Non-dominated Sorting Genetic Algorithm-II (NSGA-II) outperforms the traditional Response Surface Methodology (RSM), achieving 59.63 kWh·t<sup>−1</sup> energy savings (equivalent to a 33.63 kg CO<sub>2</sub>·t<sup>−1</sup> reduction) at a target CF roughness of 0.60 μm. The Pareto front further confirms the excellent dual-optimization capability of NSGA-II, which achieved a 10.15 % energy reduction while maintaining product quality. This study provides new insights for intelligent copper foil production and enables greener manufacturing paradigms.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146617"},"PeriodicalIF":10.0,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating the impact of wood-based materials on indoor air quality and carbon storage capacity 评估木质材料对室内空气质量和碳储存能力的影响
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146597
Su-Hwan Yeo , Haedeun Park , Hyeonwoo Jeong , Sumin Kim , Seong Jin Chang
{"title":"Evaluating the impact of wood-based materials on indoor air quality and carbon storage capacity","authors":"Su-Hwan Yeo ,&nbsp;Haedeun Park ,&nbsp;Hyeonwoo Jeong ,&nbsp;Sumin Kim ,&nbsp;Seong Jin Chang","doi":"10.1016/j.jclepro.2025.146597","DOIUrl":"10.1016/j.jclepro.2025.146597","url":null,"abstract":"<div><div>Indoor air quality (IAQ) has gained significant attention as a critical determinant of human health, given the modern lifestyle where individuals spend substantial time indoors. Numerous studies have been undertaken to improve IAQ, with the application of wood-based finishes emerging as a promising strategy. However, most of the existing research has concentrated on the emission of biogenic volatile organic compounds (BVOC) from natural forests, while the emission characteristics of BVOC and their physiological effects within indoor environments remain underexplored. This study aimed to address this gap by conducting a wood preference survey and analyzing the concentration characteristics of pollutants, including BVOC, particulate matter (PM), carbon dioxide (CO<sub>2</sub>), formaldehyde (HCHO), and anthropogenic volatile organic compounds (AVOC), through scale model experiments and elementary school wood remodeling. Additionally, the carbon storage potential of the wood employed was quantitatively assessed. The results revealed that α-pinene, which accounted for over 90 % of monoterpene concentrations, was present at high levels. Notably, BVOC concentrations from knotted wood were observed to be up to 2.7 times higher. Furthermore, the concentration of particulate matter decreased in the remodeled environments, indicating that the use of wood could enhance indoor air quality. Finally, with respect to carbon storage, sites primarily utilizing hardwood exhibited a 144 % greater carbon storage capacity compared to others, underscoring the considerable influence of wood type and density on carbon storage potential.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146597"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking industrial-scale lithium extraction from salt lake brines: A comprehensive sustainability, life cycle, and techno-economic comparative analysis 解锁工业规模的盐湖盐水锂提取:全面的可持续性、生命周期和技术经济比较分析
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146535
Yong Niu , Yibo Yuan , Yani Wang , Changyuan Wang , Xinhao Zhang , Yanyan Fang , Yuze Zhang , Shaolei Xie , Xiaowu Peng , Hailong Lu , Xin Zhou , Lianying Wu , Dong Shi , Lijuan Li
{"title":"Unlocking industrial-scale lithium extraction from salt lake brines: A comprehensive sustainability, life cycle, and techno-economic comparative analysis","authors":"Yong Niu ,&nbsp;Yibo Yuan ,&nbsp;Yani Wang ,&nbsp;Changyuan Wang ,&nbsp;Xinhao Zhang ,&nbsp;Yanyan Fang ,&nbsp;Yuze Zhang ,&nbsp;Shaolei Xie ,&nbsp;Xiaowu Peng ,&nbsp;Hailong Lu ,&nbsp;Xin Zhou ,&nbsp;Lianying Wu ,&nbsp;Dong Shi ,&nbsp;Lijuan Li","doi":"10.1016/j.jclepro.2025.146535","DOIUrl":"10.1016/j.jclepro.2025.146535","url":null,"abstract":"<div><div>Lithium extraction plays a critical role in the development of sustainable energy systems, particularly in electric vehicles and renewable energy storage. This study represents a pioneering effort in providing industrial-scale, data-driven insights into lithium extraction technologies, offering a comprehensive and quantifiable sustainability and techno-economic assessment. We conducted an in-depth evaluation of four salt-lake lithium extraction processes—solvent extraction, adsorption, membrane separation, and the adsorption-membrane hybrid process—providing detailed life cycle and economic data. Our investigation reveals that, with respect to global warming potential, these processes emit 52.7 kg CO<sub>2</sub>-eq/kg of lithium carbonate (LCE) for solvent extraction, 47.9 kg CO<sub>2</sub>-eq/kg for adsorption, 17.7 kg CO<sub>2</sub>-eq/kg for membrane separation, and 36.1 kg CO<sub>2</sub>-eq/kg for the hybrid process. Economically, the solvent extraction process proves to be the most cost-effective, with a production cost of 9135 yuan/ton of LCE. All cost values are reported in 2023 Chinese yuan and are normalized to per ton LCE production for cross-comparison. Our work lays the foundation for further optimization and provides valuable guidance for selecting the most sustainable and economically feasible extraction technologies in the future.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146535"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Back to rags: Producing packaging paper from post-consumer textile waste 回到破布:从消费后的纺织废料中生产包装纸
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146524
Thomas Harter, Alexander Wagner, Alexander Weissensteiner, Ulrich Hirn
{"title":"Back to rags: Producing packaging paper from post-consumer textile waste","authors":"Thomas Harter,&nbsp;Alexander Wagner,&nbsp;Alexander Weissensteiner,&nbsp;Ulrich Hirn","doi":"10.1016/j.jclepro.2025.146524","DOIUrl":"10.1016/j.jclepro.2025.146524","url":null,"abstract":"<div><div>Textile recycling remains a critical challenge in efforts to establish circular material flows, particularly for low-grade post-consumer textile waste that falls outside the scope of high-quality fibre-to-fibre recycling. In this study, we revisit the historical practice of processing textiles into papermaking fibres and adapt it to present-day waste streams. Using mechanical disintegration, we investigate the impact of scrap size and defibration time on fibre and suspension properties. Our results show that a broad processing window exists, with effective fibre separation achievable through relatively coarse cutting and moderate defibration times. The resulting suspensions were blended with industrial recycled paper stock and used to produce handsheets, which were evaluated for key packaging-relevant mechanical properties: tensile strength, bending stiffness, and short-span compression strength (SCT). A blend with 30 % textile-derived fibres yielded papers with equal or improved mechanical performance compared to reference sheets made from industrial paper stock alone. These findings support the feasibility of incorporating post-consumer cotton textiles into packaging paper production. Due to the large demand of fibres for packaging paper the proposed processing pathway has the potential for diverting significant volumes of textile waste from disposal. Rather than competing with fibre-to-fibre recycling, this approach targets lower-grade waste and proposes a complementary route toward more comprehensive circularity in the textile and packaging sectors.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146524"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intellectual property protection and energy efficiency: Evidence from a quasi-natural experiment in China 知识产权保护与能源效率:来自中国准自然实验的证据
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146625
Shanyong Wang, Jun Wang
{"title":"Intellectual property protection and energy efficiency: Evidence from a quasi-natural experiment in China","authors":"Shanyong Wang,&nbsp;Jun Wang","doi":"10.1016/j.jclepro.2025.146625","DOIUrl":"10.1016/j.jclepro.2025.146625","url":null,"abstract":"<div><div>Boosting regional energy efficiency is key to mitigating the adverse impacts of climate change, but the effect of intellectual property protection remains unclear. Using Chinese National Intellectual Property Rights Demonstration City (NIPRDC) policy as a quasi-natural experiment, this study employs a DID approach to assess its impact on energy efficiency. The results show that NIPRDC policy significantly enhances regional energy efficiency, which is delayed over time. Heterogeneity analysis further reveals that the positive effects are more pronounced in large cities, and regions with stronger resource endowments, richer human capital and stricter environmental regulation. Mechanism analysis indicates that NIPRDC policy improves energy efficiency by optimizing market resource allocation, promoting regional innovation and facilitating industrial upgrading. Additionally, further analysis uncovers a synergistic effect between NIPRDC policy and data openness pilot policy, with the optimal outcome achieved when “Data openness pilot policy first, NIPRDC policy later”. We offer valuable insights for the effective implementation of NIPRDC policy and provide important references for improving energy efficiency.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146625"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Italian farmers’ preferences for adopting agriculture 4.0 technologies: A choice experiment analysis 意大利农民采用农业4.0技术的偏好:选择实验分析
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146601
Roberto Fragomeli , Wojciech Zawadzki , Mikołaj Czajkowski , Azzurra Annunziata , Gennaro Punzo
{"title":"Italian farmers’ preferences for adopting agriculture 4.0 technologies: A choice experiment analysis","authors":"Roberto Fragomeli ,&nbsp;Wojciech Zawadzki ,&nbsp;Mikołaj Czajkowski ,&nbsp;Azzurra Annunziata ,&nbsp;Gennaro Punzo","doi":"10.1016/j.jclepro.2025.146601","DOIUrl":"10.1016/j.jclepro.2025.146601","url":null,"abstract":"<div><div>Digital (“Agriculture 4.0”) technologies can improve both sustainability and productivity; however, their uptake in Italy remains uneven, partly due to fragmented farm structures and limited digital readiness. Grounded in the Theory of Reasoned Goal Pursuit (TRGP) and underpinned by Random Utility Theory, the study employs a nationwide discrete choice experiment (n = 452, May–June 2024) and a mixed logit model in willingness to pay (WTP) space to quantify Italian farmers’ preferences and WTP for five key attributes: work hours saved, energy saved, water saved, sales increase, and adoption cost. The results show that farmers place the highest WTP on labour and water savings, followed by the prospect of higher sales, whereas energy-saving attributes exert the weakest influence. High adoption costs are a major deterrent, especially for small and medium-sized farms. Interaction effects reveal that farm size, working hours, income, resource use and attitudes towards innovation significantly moderate preferences. The findings highlight the need for differentiated policy packages – combining financial incentives, tailored training, and effective communication – to foster wider and more equitable adoption of Agriculture 4.0 technologies in Italy.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146601"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145043074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Consumers’ affinity to the circular economy: Empirical evidence utilizing the circular economy cube 消费者对循环经济的亲和力:利用循环经济立方体的经验证据
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146539
Alexandra Anderluh , Roland Hackl , Zahra Mesbahi , Tassilo Pellegrini , Clemens Raffler
{"title":"Consumers’ affinity to the circular economy: Empirical evidence utilizing the circular economy cube","authors":"Alexandra Anderluh ,&nbsp;Roland Hackl ,&nbsp;Zahra Mesbahi ,&nbsp;Tassilo Pellegrini ,&nbsp;Clemens Raffler","doi":"10.1016/j.jclepro.2025.146539","DOIUrl":"10.1016/j.jclepro.2025.146539","url":null,"abstract":"<div><div>The European Circular Economy Action Plan s establishes sustainability requirements and standards aimed at making products more durable, reusable, and recyclable. It specifically targets sectors that consume substantial resources and offer significant recycling potential, while also emphasizing waste prevention and consumer empowerment. However, understanding how consumers from all socioeconomic backgrounds engage in circular practices - such as reducing, reusing, and repairing - is essential for two key reasons. First, without a shift in consumer behaviour aligned with circular economy principles, effective implementation is not possible. Second, insights into consumer engagement across diverse socioeconomic groups are crucial for guiding businesses and policymakers in designing effective strategies and interventions to foster circular behaviours. To address this knowledge gap, the paper examines high-impact R-strategies and product group combinations, taking into account varying socioeconomic backgrounds. The Circular Economy Cube - a three-dimensional framework mapping R-strategies to relevant product groups and milieus - is introduced. Drawing on data from a representative online survey integrated into the Cube, the authors quantitatively assess the Austrian population's affinity for the circular economy. Additionally, the study tests incentives and nudging strategies in specific contexts, statistically identifying the determinants of circular economy affinity and their significance.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146539"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Production of natural fertilizers with sludge digestate by mineral-based struvite crystallization and organic binding 矿基鸟粪石结晶有机结合污泥消化生产天然肥料
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146599
Aysha Iftikhar , Wendong Tao
{"title":"Production of natural fertilizers with sludge digestate by mineral-based struvite crystallization and organic binding","authors":"Aysha Iftikhar ,&nbsp;Wendong Tao","doi":"10.1016/j.jclepro.2025.146599","DOIUrl":"10.1016/j.jclepro.2025.146599","url":null,"abstract":"<div><div>With phosphate rock reserves getting quickly depleted, there is a pressing need to reclaim phosphorus from wastewater. The existing technologies for recovering phosphate from wastewater as struvite granules bear the high costs of chemicals and slow growth of struvite crystals. Moreover, the recovered struvite cannot be used as fertilizers for organic production in the US because chemicals are added to increase wastewater pH and supplement magnesium. This study advances a novel chemical-free approach for recovering struvite from sludge digestate as granular natural fertilizers that have great potential to be allowed for use in certified organic production. First, simple air stripping and gravity settling were applied to raise pH and precipitate Mg<sup>2+</sup>-competing cations in filtrate of sludge digestate. Mineral products (calcined magnesite and Epsomite) were then added to the pretreated filtrate in a 21.5-L air-lift crystallizer for only 45 min of struvite crystallization and settling. 90.2–95.6 % of phosphate was removed from the pretreated filtrate. With pretreatment, the purity of struvite crystals reached 93.5 %. The crystals were pressed into granules with organic binders (xanthan gum and guar gum) allowed for organic production. The granules made at struvite crystals: guar gum: water weight ratio of 10 : 0.8: 5.4 had physical properties close to those of commercial triple superphosphate. Guaranteed analysis showed that the granular natural struvite fertilizers had an N-P-K grade of 5–26-0. This mini-pilot study demonstrated a novel approach to reduce the cost of struvite recovery while opening a new marketplace for the recovered fertilizers.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146599"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimized O2/CO2–fuel atmosphere for the synergistic–Removal of aromatic hydrocarbons and nitrogen oxides from lignite combustion 优化O2/ co2 -燃料气氛协同去除褐煤燃烧产生的芳烃和氮氧化物
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146618
Yongfeng Zhang , Tao Dong , Haiyan Wang , Xiaowei Zhang , Yinmin Zhang , Yanbing Gong , Zhifei Hao
{"title":"Optimized O2/CO2–fuel atmosphere for the synergistic–Removal of aromatic hydrocarbons and nitrogen oxides from lignite combustion","authors":"Yongfeng Zhang ,&nbsp;Tao Dong ,&nbsp;Haiyan Wang ,&nbsp;Xiaowei Zhang ,&nbsp;Yinmin Zhang ,&nbsp;Yanbing Gong ,&nbsp;Zhifei Hao","doi":"10.1016/j.jclepro.2025.146618","DOIUrl":"10.1016/j.jclepro.2025.146618","url":null,"abstract":"<div><div>The generation of carcinogenic aromatic hydrocarbons and nitrogen oxides (NO<sub>x</sub>) during lignite combustion poses considerable risks to both environmental quality and human health. Oxy–fuel combustion has emerged as a promising technology for the synergistic control of pollutants. However, the underlying mechanisms remain insufficiently understood. This study integrates experimental and theoretical methodologies to elucidate the dual–inhibition pathways of representative aromatic hydrocarbons and NO<sub>x</sub> occurring in O<sub>2</sub>–CO<sub>2</sub> atmospheres. Based on the results of Fourier transform infrared and thermogravimetric analysis, it is observed that the optimized 35 %O<sub>2</sub>–65 %CO<sub>2</sub> atmospheres most effectively suppress the formation of naphthalene, styrene, and thermal NO<sub>x</sub> by approximately 73 %, 65 %, and 86 %, respectively, compared with the traditional O<sub>2</sub>–N<sub>2</sub> atmospheres. Furthermore, the degradation pathways of aromatic hydrocarbons and NO<sub>x</sub> under O<sub>2</sub>–N<sub>2</sub> and O<sub>2</sub>–CO<sub>2</sub> atmospheres are thoroughly investigated. It is found that under O<sub>2</sub>–N<sub>2</sub> atmospheres, H•–mediated fuel nitrogen chemistry pathways promote the formation of NO<sub>x</sub> precursors. Conversely, under the O<sub>2</sub>–CO<sub>2</sub> atmospheres, both the polymerization of aromatic hydrocarbons and the formation of NO<sub>x</sub> are effectively suppressed through a triple mechanism involving H• extraction, delayed oxidation and HO<sub>2</sub>• generation. Subsequently, quantitative chemical calculations further confirm this finding. The introduction of CO<sub>2</sub> can significantly reduce the activation energy of the H• generation reaction (68.2 kJ/mol for O<sub>2</sub>–N<sub>2</sub> atmospheres vs. 37.5 kJ/mol for O<sub>2</sub>–CO<sub>2</sub> atmospheres) and alter the reaction pathway, thereby enhancing the inhibition of aromatic hydrocarbons and NO<sub>x</sub>. This technique has crucial implications for air quality management and contributes to enabling clean lignite use in addition to mitigating greenhouse gas effects.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146618"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Expediting circular systems for sustainable circular society: Challenges and opportunities for design at the production consumption intersection 加速循环系统实现可持续循环社会:生产与消费交叉点设计的挑战与机遇
IF 1 1区 环境科学与生态学
Journal of Cleaner Production Pub Date : 2025-09-12 DOI: 10.1016/j.jclepro.2025.146567
Susan Evans
{"title":"Expediting circular systems for sustainable circular society: Challenges and opportunities for design at the production consumption intersection","authors":"Susan Evans","doi":"10.1016/j.jclepro.2025.146567","DOIUrl":"10.1016/j.jclepro.2025.146567","url":null,"abstract":"","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"525 ","pages":"Article 146567"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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