Chemical Reviews最新文献_第5页

Microenvironment Engineering of Heterogeneous Catalysts for Liquid-Phase Environmental Catalysis 用于液相环境催化的异质催化剂微环境工程

IF 62.1 1区化学

Chemical Reviews Pub Date : 2024-10-09 DOI: 10.1021/acs.chemrev.4c00276

Zhong-Shuai Zhu, Shuang Zhong, Cheng Cheng, Hongyu Zhou, Hongqi Sun, Xiaoguang Duan, Shaobin Wang

{"title":"Microenvironment Engineering of Heterogeneous Catalysts for Liquid-Phase Environmental Catalysis","authors":"Zhong-Shuai Zhu, Shuang Zhong, Cheng Cheng, Hongyu Zhou, Hongqi Sun, Xiaoguang Duan, Shaobin Wang","doi":"10.1021/acs.chemrev.4c00276","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00276","url":null,"abstract":"Environmental catalysis has emerged as a scientific frontier in mitigating water pollution and advancing circular chemistry and reaction microenvironment significantly influences the catalytic performance and efficiency. This review delves into microenvironment engineering within liquid-phase environmental catalysis, categorizing microenvironments into four scales: atom/molecule-level modulation, nano/microscale-confined structures, interface and surface regulation, and external field effects. Each category is analyzed for its unique characteristics and merits, emphasizing its potential to significantly enhance catalytic efficiency and selectivity. Following this overview, we introduced recent advancements in advanced material and system design to promote liquid-phase environmental catalysis (e.g., water purification, transformation to value-added products, and green synthesis), leveraging state-of-the-art microenvironment engineering technologies. These discussions showcase microenvironment engineering was applied in different reactions to fine-tune catalytic regimes and improve the efficiency from both thermodynamics and kinetics perspectives. Lastly, we discussed the challenges and future directions in microenvironment engineering. This review underscores the potential of microenvironment engineering in intelligent materials and system design to drive the development of more effective and sustainable catalytic solutions to environmental decontamination.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"33 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142385885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Aggregation-Induced Emission Luminogen: Role in Biopsy for Precision Medicine 聚合诱导发光剂：活组织检查在精准医疗中的作用

IF 62.1 1区化学

Chemical Reviews Pub Date : 2024-10-08 DOI: 10.1021/acs.chemrev.4c00244

Yanhong Duo, Lei Han, Yaoqiang Yang, Zhifeng Wang, Lirong Wang, Jingyi Chen, Zhongyuan Xiang, Juyoung Yoon, Guanghong Luo, Ben Zhong Tang

{"title":"Aggregation-Induced Emission Luminogen: Role in Biopsy for Precision Medicine","authors":"Yanhong Duo, Lei Han, Yaoqiang Yang, Zhifeng Wang, Lirong Wang, Jingyi Chen, Zhongyuan Xiang, Juyoung Yoon, Guanghong Luo, Ben Zhong Tang","doi":"10.1021/acs.chemrev.4c00244","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00244","url":null,"abstract":"Biopsy, including tissue and liquid biopsy, offers comprehensive and real-time physiological and pathological information for disease detection, diagnosis, and monitoring. Fluorescent probes are frequently selected to obtain adequate information on pathological processes in a rapid and minimally invasive manner based on their advantages for biopsy. However, conventional fluorescent probes have been found to show aggregation-caused quenching (ACQ) properties, impeding greater progresses in this area. Since the discovery of aggregation-induced emission luminogen (AIEgen) have promoted rapid advancements in molecular bionanomaterials owing to their unique properties, including high quantum yield (QY) and signal-to-noise ratio (SNR), etc. This review seeks to present the latest advances in AIEgen-based biofluorescent probes for biopsy in real or artificial samples, and also the key properties of these AIE probes. This review is divided into: (i) tissue biopsy based on smart AIEgens, (ii) blood sample biopsy based on smart AIEgens, (iii) urine sample biopsy based on smart AIEgens, (iv) saliva sample biopsy based on smart AIEgens, (v) biopsy of other liquid samples based on smart AIEgens, and (vi) perspectives and conclusion. This review could provide additional guidance to motivate interest and bolster more innovative ideas for further exploring the applications of various smart AIEgens in precision medicine.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"7 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142385457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Expanding the Genetic Code of Bioelectrocatalysis and Biomaterials 扩展生物电催化和生物材料的基因密码

IF 62.1 1区化学

Chemical Reviews Pub Date : 2024-10-08 DOI: 10.1021/acs.chemrev.4c00077

Yonatan Chemla, Federico Kaufman, Miriam Amiram, Lital Alfonta

引用次数: 0

Noncanonical Amino Acids: Bringing New-to-Nature Functionalities to Biocatalysis 非典型氨基酸：为生物催化带来新的自然功能性

IF 62.1 1区化学

Chemical Reviews Pub Date : 2024-09-27 DOI: 10.1021/acs.chemrev.4c00136

Bart Brouwer, Franco Della-Felice, Jan Hendrik Illies, Emilia Iglesias-Moncayo, Gerard Roelfes, Ivana Drienovská

引用次数: 0

Hydrate Technologies for CO₂ Capture and Sequestration: Status and Perspectives. 二氧化碳捕集与封存的水合物技术：现状与展望》。

IF 51.4 1区化学

Chemical Reviews Pub Date : 2024-09-25 Epub Date: 2024-08-27 DOI: 10.1021/acs.chemrev.2c00777

Pengfei Wang, Yun Li, Ningru Sun, Songbai Han, Xiaomeng Wang, Qinqin Su, Yanjun Li, Jian He, Xiaohui Yu, Shiyu Du, Joseph S Francisco, Jinlong Zhu, Yusheng Zhao

{"title":"Hydrate Technologies for CO2 Capture and Sequestration: Status and Perspectives.","authors":"Pengfei Wang, Yun Li, Ningru Sun, Songbai Han, Xiaomeng Wang, Qinqin Su, Yanjun Li, Jian He, Xiaohui Yu, Shiyu Du, Joseph S Francisco, Jinlong Zhu, Yusheng Zhao","doi":"10.1021/acs.chemrev.2c00777","DOIUrl":"10.1021/acs.chemrev.2c00777","url":null,"abstract":"CO2 capture and sequestration based on hydrate technology are considered supplementary approaches for reducing carbon emissions and mitigating the greenhouse effect. Direct CO2 hydrate formation and CH4 gas substitution in natural gas hydrates are two of the main methods used for the sequestration of CO2 in hydrates. In this Review, we introduce the crystal structures of CO2 hydrates and CO2-mixed gas hydrates and summarize the interactions between the CO2 molecules and clathrate hydrate/H2O frames. In particular, we focus on the role of diffraction techniques in analyzing hydrate structures. The kinetic and thermodynamic properties then are introduced from micro/macro perspectives. Furthermore, the replacement of natural gas with CO2/CO2-mixed gas is discussed comprehensively in terms of intermolecular interactions, influencing factors, and displacement efficiency. Based on the analysis of related costs, risks, and policies, the economics of CO2 capture and sequestration based on hydrate technology are explained. Moreover, the difficulties and challenges at this stage and the directions for future research are described. Finally, we investigate the status of recent research related to CO2 capture and sequestration based on hydrate technology, revealing its importance in carbon emission reduction.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":" ","pages":"10363-10385"},"PeriodicalIF":51.4,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142071267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hybrid Integration of Wearable Devices for Physiological Monitoring. 用于生理监测的可穿戴设备的混合集成。

IF 51.4 1区化学

Chemical Reviews Pub Date : 2024-09-25 Epub Date: 2024-08-27 DOI: 10.1021/acs.chemrev.3c00471

Yu Zhang, Xin Ting Zheng, Xiangyu Zhang, Jieming Pan, Aaron Voon-Yew Thean

{"title":"Hybrid Integration of Wearable Devices for Physiological Monitoring.","authors":"Yu Zhang, Xin Ting Zheng, Xiangyu Zhang, Jieming Pan, Aaron Voon-Yew Thean","doi":"10.1021/acs.chemrev.3c00471","DOIUrl":"10.1021/acs.chemrev.3c00471","url":null,"abstract":"Wearable devices can provide timely, user-friendly, non- or minimally invasive, and continuous monitoring of human health. Recently, multidisciplinary scientific communities have made significant progress regarding fully integrated wearable devices such as sweat wearable sensors, saliva sensors, and wound sensors. However, the translation of these wearables into markets has been slow due to several reasons associated with the poor system-level performance of integrated wearables. The wearability consideration for wearable devices compromises many properties of the wearables. Besides, the limited power capacity of wearables hinders continuous monitoring for extended duration. Furthermore, peak-power operations for intensive computations can quickly create thermal issues in the compact form factor that interfere with wearability and sensor operations. Moreover, wearable devices are constantly subjected to environmental, mechanical, chemical, and electrical interferences and variables that can invalidate the collected data. This generates the need for sophisticated data analytics to contextually identify, include, and exclude data points per multisensor fusion to enable accurate data interpretation. This review synthesizes the challenges surrounding the wearable device integration from three aspects in terms of hardware, energy, and data, focuses on a discussion about hybrid integration of wearable devices, and seeks to provide comprehensive guidance for designing fully functional and stable wearable devices.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":" ","pages":"10386-10434"},"PeriodicalIF":51.4,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142071266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cracking the Code: Reprogramming the Genetic Script in Prokaryotes and Eukaryotes to Harness the Power of Noncanonical Amino Acids. 破解密码：重编原核生物和真核生物的基因脚本，利用非规范氨基酸的力量。

IF 51.4 1区化学

Chemical Reviews Pub Date : 2024-09-25 Epub Date: 2024-08-09 DOI: 10.1021/acs.chemrev.3c00878

Cosimo Jann, Sabrina Giofré, Rajanya Bhattacharjee, Edward A Lemke

{"title":"Cracking the Code: Reprogramming the Genetic Script in Prokaryotes and Eukaryotes to Harness the Power of Noncanonical Amino Acids.","authors":"Cosimo Jann, Sabrina Giofré, Rajanya Bhattacharjee, Edward A Lemke","doi":"10.1021/acs.chemrev.3c00878","DOIUrl":"10.1021/acs.chemrev.3c00878","url":null,"abstract":"Over 500 natural and synthetic amino acids have been genetically encoded in the last two decades. Incorporating these noncanonical amino acids into proteins enables many powerful applications, ranging from basic research to biotechnology, materials science, and medicine. However, major challenges remain to unleash the full potential of genetic code expansion across disciplines. Here, we provide an overview of diverse genetic code expansion methodologies and systems and their final applications in prokaryotes and eukaryotes, represented by Escherichia coli and mammalian cells as the main workhorse model systems. We highlight the power of how new technologies can be first established in simple and then transferred to more complex systems. For example, whole-genome engineering provides an excellent platform in bacteria for enabling transcript-specific genetic code expansion without off-targets in the transcriptome. In contrast, the complexity of a eukaryotic cell poses challenges that require entirely new approaches, such as striving toward establishing novel base pairs or generating orthogonally translating organelles within living cells. We connect the milestones in expanding the genetic code of living cells for encoding novel chemical functionalities to the most recent scientific discoveries, from optimizing the physicochemical properties of noncanonical amino acids to the technological advancements for their in vivo incorporation. This journey offers a glimpse into the promising developments in the years to come.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":" ","pages":"10281-10362"},"PeriodicalIF":51.4,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11441406/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141904973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Benzenoid Aromatics from Renewable Resources 从可再生资源中提取苯环芳烃

IF 62.1 1区化学

Chemical Reviews Pub Date : 2024-09-17 DOI: 10.1021/acs.chemrev.4c00087

Shasha Zheng, Zhenlei Zhang, Songbo He, Huaizhou Yang, Hanan Atia, Ali M. Abdel-Mageed, Sebastian Wohlrab, Eszter Baráth, Sergey Tin, Hero J. Heeres, Peter J. Deuss, Johannes G. de Vries

{"title":"Benzenoid Aromatics from Renewable Resources","authors":"Shasha Zheng, Zhenlei Zhang, Songbo He, Huaizhou Yang, Hanan Atia, Ali M. Abdel-Mageed, Sebastian Wohlrab, Eszter Baráth, Sergey Tin, Hero J. Heeres, Peter J. Deuss, Johannes G. de Vries","doi":"10.1021/acs.chemrev.4c00087","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00087","url":null,"abstract":"In this Review, all known chemical methods for the conversion of renewable resources into benzenoid aromatics are summarized. The raw materials that were taken into consideration are CO2; lignocellulose and its constituents cellulose, hemicellulose, and lignin; carbohydrates, mostly glucose, fructose, and xylose; chitin; fats and oils; terpenes; and materials that are easily obtained via fermentation, such as biogas, bioethanol, acetone, and many more. There are roughly two directions. One much used method is catalytic fast pyrolysis carried out at high temperatures (between 300 and 700 °C depending on the raw material), which leads to the formation of biochar; gases, such as CO, CO2, H2, and CH4; and an oil which is a mixture of hydrocarbons, mostly aromatics. The carbon selectivities of this method can be reasonably high when defined small molecules such as methanol or hexane are used but are rather low when highly oxygenated compounds such as lignocellulose are used. The other direction is largely based on the multistep conversion of platform chemicals obtained from lignocellulose, cellulose, or sugars and a limited number of fats and terpenes. Much research has focused on furan compounds such as furfural, 5-hydroxymethylfurfural, and 5-chloromethylfurfural. The conversion of lignocellulose to xylene via 5-chloromethylfurfural and dimethylfuran has led to the construction of two large-scale plants, one of which has been operational since 2023.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"136 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142235457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mechanical Regulation of Polymer Gels 聚合物凝胶的机械调节

IF 62.1 1区化学

Chemical Reviews Pub Date : 2024-09-16 DOI: 10.1021/acs.chemrev.3c00498

Chenggong Xu, Yi Chen, Siyang Zhao, Deke Li, Xing Tang, Haili Zhang, Jinxia Huang, Zhiguang Guo, Weimin Liu

{"title":"Mechanical Regulation of Polymer Gels","authors":"Chenggong Xu, Yi Chen, Siyang Zhao, Deke Li, Xing Tang, Haili Zhang, Jinxia Huang, Zhiguang Guo, Weimin Liu","doi":"10.1021/acs.chemrev.3c00498","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00498","url":null,"abstract":"The mechanical properties of polymer gels devote to emerging devices and machines in fields such as biomedical engineering, flexible bioelectronics, biomimetic actuators, and energy harvesters. Coupling network architectures and interactions has been explored to regulate supportive mechanical characteristics of polymer gels; however, systematic reviews correlating mechanics to interaction forces at the molecular and structural levels remain absent in the field. This review highlights the molecular engineering and structural engineering of polymer gel mechanics and a comprehensive mechanistic understanding of mechanical regulation. Molecular engineering alters molecular architecture and manipulates functional groups/moieties at the molecular level, introducing various interactions and permanent or reversible dynamic bonds as the dissipative energy. Molecular engineering usually uses monomers, cross-linkers, chains, and other additives. Structural engineering utilizes casting methods, solvent phase regulation, mechanochemistry, macromolecule chemical reactions, and biomanufacturing technology to construct and tailor the topological network structures, or heterogeneous modulus compositions. We envision that the perfect combination of molecular and structural engineering may provide a fresh view to extend exciting new perspectives of this burgeoning field. This review also summarizes recent representative applications of polymer gels with excellent mechanical properties. Conclusions and perspectives are also provided from five aspects of concise summary, mechanical mechanism, biofabrication methods, upgraded applications, and synergistic methodology.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"28 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142235458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mechanical Regulation of Polymer Gels 聚合物凝胶的机械调节

IF 51.4 1区化学

Chemical Reviews Pub Date : 2024-09-16 DOI: 10.1021/acs.chemrev.3c0049810.1021/acs.chemrev.3c00498

Chenggong Xu, Yi Chen, Siyang Zhao, Deke Li, Xing Tang, Haili Zhang, Jinxia Huang*, Zhiguang Guo* and Weimin Liu*,

{"title":"Mechanical Regulation of Polymer Gels","authors":"Chenggong Xu, Yi Chen, Siyang Zhao, Deke Li, Xing Tang, Haili Zhang, Jinxia Huang*, Zhiguang Guo* and Weimin Liu*, ","doi":"10.1021/acs.chemrev.3c0049810.1021/acs.chemrev.3c00498","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00498https://doi.org/10.1021/acs.chemrev.3c00498","url":null,"abstract":"The mechanical properties of polymer gels devote to emerging devices and machines in fields such as biomedical engineering, flexible bioelectronics, biomimetic actuators, and energy harvesters. Coupling network architectures and interactions has been explored to regulate supportive mechanical characteristics of polymer gels; however, systematic reviews correlating mechanics to interaction forces at the molecular and structural levels remain absent in the field. This review highlights the molecular engineering and structural engineering of polymer gel mechanics and a comprehensive mechanistic understanding of mechanical regulation. Molecular engineering alters molecular architecture and manipulates functional groups/moieties at the molecular level, introducing various interactions and permanent or reversible dynamic bonds as the dissipative energy. Molecular engineering usually uses monomers, cross-linkers, chains, and other additives. Structural engineering utilizes casting methods, solvent phase regulation, mechanochemistry, macromolecule chemical reactions, and biomanufacturing technology to construct and tailor the topological network structures, or heterogeneous modulus compositions. We envision that the perfect combination of molecular and structural engineering may provide a fresh view to extend exciting new perspectives of this burgeoning field. This review also summarizes recent representative applications of polymer gels with excellent mechanical properties. Conclusions and perspectives are also provided from five aspects of concise summary, mechanical mechanism, biofabrication methods, upgraded applications, and synergistic methodology.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"124 18","pages":"10435–10508 10435–10508"},"PeriodicalIF":51.4,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0