Chemical Reviews最新文献

{"title":"Correction to “Theory and Simulations of Ionic Liquids in Nanoconfinement”","authors":"Svyatoslav Kondrat, Guang Feng, Fernando Bresme, Michael Urbakh, Alexei A. Kornyshev","doi":"10.1021/acs.chemrev.4c00885","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00885","url":null,"abstract":"In the original article, there is a typo in eq 9, which is missing a prime symbol next to the summation. The prime symbol indicates that the summation in this equation runs only over odd integer numbers. Thus, the correct version of this equation is We recall that this equation describes the interaction energy between two ions located at the symmetry plane of a slit. The complete expression for arbitrary ion positions in slit pores can be found in ref (1). We additionally stress that this interaction energy converges to the Coulomb interaction energy in the limit of the distance between the charges <i>r</i> → 0 (<i>r</i>/<i>L</i> ≪ 1). This article references 1 other publications. This article has not yet been cited by other publications.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"79 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142841652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Covalent Proximity Inducers","authors":"Nir London","doi":"10.1021/acs.chemrev.4c00570","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00570","url":null,"abstract":"Molecules that are able to induce proximity between two proteins are finding ever increasing applications in chemical biology and drug discovery. The ability to introduce an electrophile and make such proximity inducers covalent can offer improved properties such as selectivity, potency, duration of action, and reduced molecular size. This concept has been heavily explored in the context of targeted degradation in particular for bivalent molecules, but recently, additional applications are reported in other contexts, as well as for monovalent molecular glues. This is a comprehensive review of reported covalent proximity inducers, aiming to identify common trends and current gaps in their discovery and application.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"70 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142841651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Two-Dimensional Organic–Inorganic van der Waals Hybrids","authors":"Fucai Cui,&nbsp;Víctor García-López,&nbsp;Zhiyong Wang,&nbsp;Zhongzhong Luo,&nbsp;Daowei He,&nbsp;Xinliang Feng,&nbsp;Renhao Dong* and Xinran Wang*,&nbsp;","doi":"10.1021/acs.chemrev.4c0056510.1021/acs.chemrev.4c00565","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00565https://doi.org/10.1021/acs.chemrev.4c00565","url":null,"abstract":"<p >Two-dimensional organic–inorganic (2DOI) van der Waals hybrids (vdWhs) have emerged as a groundbreaking subclass of layer-stacked (opto-)electronic materials. The development of 2DOI-vdWhs via systematically integrating inorganic 2D layers with organic 2D crystals at the molecular/atomic scale extends the capabilities of traditional 2D inorganic vdWhs, thanks to their high synthetic flexibility and structural tunability. Constructing an organic–inorganic hybrid interface with atomic precision will unlock new opportunities for generating unique interfacial (opto-)electronic transport properties by combining the strengths of organic and inorganic layers, thus allowing us to satisfy the growing demand for multifunctional applications. Here, this review provides a comprehensive overview of the latest advancements in the chemical synthesis, structural characterization, and numerous applications of 2DOI-vdWhs. Firstly, we introduce the chemistry and the physical properties of the recently rising organic 2D crystals (O2DCs), which feature crystalline 2D nanostructures comprising carbon-rich repeated units linked by covalent/noncovalent bonds and exhibit strong in-plane extended π-conjugation and weak interlayer vdWs interaction. Simultaneously, representative inorganic 2D crystals (I2DCs) are briefly summarized. After that, the synthetic strategies will be systematically summarized, including synthesizing single-component O2DCs with dimensional control and their vdWhs with I2DCs. With these synthetic approaches, the control in the dimension, the stacking modes, and the composition of the 2DOI-vdWhs will be highlighted. Subsequently, a special focus will be given on the discussion of the optical and electronic properties of the single-component 2D materials and their vdWhs, which will be closely relevant to their structures, so that we can establish a general structure–property relationship of 2DOI-vdWhs. In addition to these physical properties, the (opto-)electronic devices such as transistors, photodetectors, sensors, spintronics, and neuromorphic devices as well as energy devices will be discussed. Finally, we provide an outlook to discuss the key challenges for the 2DOI-vdWhs and their future development. This review aims to provide a foundational understanding and inspire further innovation in the development of next-generation 2DOI-vdWhs with transformative technological potential.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 1","pages":"445–520 445–520"},"PeriodicalIF":51.4,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143085426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Correction to “Theory and Simulations of Ionic Liquids in Nanoconfinement”","authors":"Svyatoslav Kondrat*,&nbsp;Guang Feng*,&nbsp;Fernando Bresme*,&nbsp;Michael Urbakh* and Alexei A. Kornyshev*,&nbsp;","doi":"10.1021/acs.chemrev.4c0088510.1021/acs.chemrev.4c00885","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00885https://doi.org/10.1021/acs.chemrev.4c00885","url":null,"abstract":"","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 1","pages":"521 521"},"PeriodicalIF":51.4,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00885","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143085257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nondestructive Analysis of Commercial Batteries","authors":"Wenhua Zuo, Rui Liu, Jiyu Cai, Yonggang Hu, Manar Almazrouei, Xiangsi Liu, Tony Cui, Xin Jia, Emory Apodaca, Jakob Alami, Zonghai Chen, Tianyi Li, Wenqian Xu, Xianghui Xiao, Dilworth Parkinson, Yong Yang, Gui-Liang Xu, Khalil Amine","doi":"10.1021/acs.chemrev.4c00566","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00566","url":null,"abstract":"Electrochemical batteries play a crucial role for powering portable electronics, electric vehicles, large-scale electric grids, and future electric aircraft. However, key performance metrics such as energy density, charging speed, lifespan, and safety raise significant consumer concerns. Enhancing battery performance hinges on a deep understanding of their operational and degradation mechanisms, from material composition and electrode structure to large-scale pack integration, necessitating advanced characterization methods. These methods not only enable improved battery performance but also facilitate early detection of substandard or potentially hazardous batteries before they cause serious incidents. This review comprehensively examines the operational principles, applications, challenges, and prospects of cutting-edge characterization techniques for commercial batteries, with a specific focus on in situ and operando methodologies. Furthermore, it explores how these powerful tools have elucidated the operational and degradation mechanisms of commercial batteries. By bridging the gap between advanced characterization techniques and commercial battery technologies, this review aims to guide the design of more sophisticated experiments and models for studying battery degradation and enhancement.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"60 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nondestructive Analysis of Commercial Batteries","authors":"Wenhua Zuo,&nbsp;Rui Liu,&nbsp;Jiyu Cai,&nbsp;Yonggang Hu,&nbsp;Manar Almazrouei,&nbsp;Xiangsi Liu,&nbsp;Tony Cui,&nbsp;Xin Jia,&nbsp;Emory Apodaca,&nbsp;Jakob Alami,&nbsp;Zonghai Chen,&nbsp;Tianyi Li,&nbsp;Wenqian Xu,&nbsp;Xianghui Xiao,&nbsp;Dilworth Parkinson,&nbsp;Yong Yang*,&nbsp;Gui-Liang Xu* and Khalil Amine*,&nbsp;","doi":"10.1021/acs.chemrev.4c0056610.1021/acs.chemrev.4c00566","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00566https://doi.org/10.1021/acs.chemrev.4c00566","url":null,"abstract":"<p >Electrochemical batteries play a crucial role for powering portable electronics, electric vehicles, large-scale electric grids, and future electric aircraft. However, key performance metrics such as energy density, charging speed, lifespan, and safety raise significant consumer concerns. Enhancing battery performance hinges on a deep understanding of their operational and degradation mechanisms, from material composition and electrode structure to large-scale pack integration, necessitating advanced characterization methods. These methods not only enable improved battery performance but also facilitate early detection of substandard or potentially hazardous batteries before they cause serious incidents. This review comprehensively examines the operational principles, applications, challenges, and prospects of cutting-edge characterization techniques for commercial batteries, with a specific focus on in situ and operando methodologies. Furthermore, it explores how these powerful tools have elucidated the operational and degradation mechanisms of commercial batteries. By bridging the gap between advanced characterization techniques and commercial battery technologies, this review aims to guide the design of more sophisticated experiments and models for studying battery degradation and enhancement.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 1","pages":"369–444 369–444"},"PeriodicalIF":51.4,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143085154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Octadecanoids: Synthesis and Bioactivity of 18-Carbon Oxygenated Fatty Acids in Mammals, Bacteria, and Fungi","authors":"Johanna Revol-Cavalier,&nbsp;Alessandro Quaranta,&nbsp;John W. Newman,&nbsp;Alan R. Brash,&nbsp;Mats Hamberg and Craig E. Wheelock*,&nbsp;","doi":"10.1021/acs.chemrev.3c0052010.1021/acs.chemrev.3c00520","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00520https://doi.org/10.1021/acs.chemrev.3c00520","url":null,"abstract":"<p >The octadecanoids are a broad class of lipids consisting of the oxygenated products of 18-carbon fatty acids. Originally referring to production of the phytohormone jasmonic acid, the octadecanoid pathway has been expanded to include products of all 18-carbon fatty acids. Octadecanoids are formed biosynthetically in mammals via cyclooxygenase (COX), lipoxygenase (LOX), and cytochrome P450 (CYP) activity, as well as nonenzymatically by photo- and autoxidation mechanisms. While octadecanoids are well-known mediators in plants, their role in the regulation of mammalian biological processes has been generally neglected. However, there have been significant advancements in recognizing the importance of these compounds in mammals and their involvement in the mediation of inflammation, nociception, and cell proliferation, as well as in immuno- and tissue modulation, coagulation processes, hormone regulation, and skin barrier formation. More recently, the gut microbiome has been shown to be a significant source of octadecanoid biosynthesis, providing additional biosynthetic routes including hydratase activity (e.g., CLA-HY, FA-HY1, FA-HY2). In this review, we summarize the current field of octadecanoids, propose standardized nomenclature, provide details of octadecanoid preparation and measurement, summarize the phase-I metabolic pathway of octadecanoid formation in mammals, bacteria, and fungi, and describe their biological activity in relation to mammalian pathophysiology as well as their potential use as biomarkers of health and disease.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 1","pages":"1–90 1–90"},"PeriodicalIF":51.4,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.3c00520","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143084437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering Phages to Fight Multidrug-Resistant Bacteria","authors":"Huan Peng, Irene A. Chen, Udi Qimron","doi":"10.1021/acs.chemrev.4c00681","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00681","url":null,"abstract":"Facing the global “superbug” crisis due to the emergence and selection for antibiotic resistance, phages are among the most promising solutions. Fighting multidrug-resistant bacteria requires precise diagnosis of bacterial pathogens and specific cell-killing. Phages have several potential advantages over conventional antibacterial agents such as host specificity, self-amplification, easy production, low toxicity as well as biofilm degradation. However, the narrow host range, uncharacterized properties, as well as potential risks from exponential replication and evolution of natural phages, currently limit their applications. Engineering phages can not only enhance the host bacteria range and improve phage efficacy, but also confer new functions. This review first summarizes major phage engineering techniques including both chemical modification and genetic engineering. Subsequent sections discuss the applications of engineered phages for bacterial pathogen detection and ablation through interdisciplinary approaches of synthetic biology and nanotechnology. We discuss future directions and persistent challenges in the ongoing exploration of phage engineering for pathogen control.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"25 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Octadecanoids: Synthesis and Bioactivity of 18-Carbon Oxygenated Fatty Acids in Mammals, Bacteria, and Fungi","authors":"Johanna Revol-Cavalier, Alessandro Quaranta, John W. Newman, Alan R. Brash, Mats Hamberg, Craig E. Wheelock","doi":"10.1021/acs.chemrev.3c00520","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00520","url":null,"abstract":"The octadecanoids are a broad class of lipids consisting of the oxygenated products of 18-carbon fatty acids. Originally referring to production of the phytohormone jasmonic acid, the octadecanoid pathway has been expanded to include products of all 18-carbon fatty acids. Octadecanoids are formed biosynthetically in mammals via cyclooxygenase (COX), lipoxygenase (LOX), and cytochrome P450 (CYP) activity, as well as nonenzymatically by photo- and autoxidation mechanisms. While octadecanoids are well-known mediators in plants, their role in the regulation of mammalian biological processes has been generally neglected. However, there have been significant advancements in recognizing the importance of these compounds in mammals and their involvement in the mediation of inflammation, nociception, and cell proliferation, as well as in immuno- and tissue modulation, coagulation processes, hormone regulation, and skin barrier formation. More recently, the gut microbiome has been shown to be a significant source of octadecanoid biosynthesis, providing additional biosynthetic routes including hydratase activity (e.g., CLA-HY, FA-HY1, FA-HY2). In this review, we summarize the current field of octadecanoids, propose standardized nomenclature, provide details of octadecanoid preparation and measurement, summarize the phase-I metabolic pathway of octadecanoid formation in mammals, bacteria, and fungi, and describe their biological activity in relation to mammalian pathophysiology as well as their potential use as biomarkers of health and disease.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"87 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering Phages to Fight Multidrug-Resistant Bacteria","authors":"Huan Peng*,&nbsp;Irene A. Chen* and Udi Qimron*,&nbsp;","doi":"10.1021/acs.chemrev.4c0068110.1021/acs.chemrev.4c00681","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00681https://doi.org/10.1021/acs.chemrev.4c00681","url":null,"abstract":"<p >Facing the global “superbug” crisis due to the emergence and selection for antibiotic resistance, phages are among the most promising solutions. Fighting multidrug-resistant bacteria requires precise diagnosis of bacterial pathogens and specific cell-killing. Phages have several potential advantages over conventional antibacterial agents such as host specificity, self-amplification, easy production, low toxicity as well as biofilm degradation. However, the narrow host range, uncharacterized properties, as well as potential risks from exponential replication and evolution of natural phages, currently limit their applications. Engineering phages can not only enhance the host bacteria range and improve phage efficacy, but also confer new functions. This review first summarizes major phage engineering techniques including both chemical modification and genetic engineering. Subsequent sections discuss the applications of engineered phages for bacterial pathogen detection and ablation through interdisciplinary approaches of synthetic biology and nanotechnology. We discuss future directions and persistent challenges in the ongoing exploration of phage engineering for pathogen control.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 2","pages":"933–971 933–971"},"PeriodicalIF":51.4,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00681","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143084453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}