Chemical Reviews最新文献_第4页

Silver Anniversary of the Renaissance in Metallocorrole Chemistry. 金属或角色化学文艺复兴五十周年纪念。

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-03-12 Epub Date: 2025-02-12 DOI: 10.1021/acs.chemrev.4c00764

Atif Mahammed, Harry B Gray, Zeev Gross

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引用次数: 0

Perovskite Type ABO3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects 光催化、电催化和固体氧化物燃料电池中的钙钛矿型ABO3氧化物：技术现状和未来展望

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-03-12 DOI: 10.1021/acs.chemrev.4c0055310.1021/acs.chemrev.4c00553

Muhammad Humayun, Zhishan Li, Muhammad Israr, Abbas Khan, Wei Luo*, Chundong Wang* and Zongping Shao*,

{"title":"Perovskite Type ABO3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects","authors":"Muhammad Humayun, Zhishan Li, Muhammad Israr, Abbas Khan, Wei Luo*, Chundong Wang* and Zongping Shao*, ","doi":"10.1021/acs.chemrev.4c0055310.1021/acs.chemrev.4c00553","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00553https://doi.org/10.1021/acs.chemrev.4c00553","url":null,"abstract":"Since photocatalytic and electrocatalytic technologies are crucial for tackling the energy and environmental challenges, significant efforts have been put into exploring advanced catalysts. Among them, perovskite type ABO3 oxides show great promising catalytic activities because of their flexible physical and chemical properties. In this review, the fundamentals and recent progress in the synthesis of perovskite type ABO3 oxides are considered. We describe the mechanisms for electrocatalytic oxygen evolution reactions (OER), oxygen reduction reactions (ORR), hydrogen evolution reactions (HER), nitrogen reduction reactions (NRR), carbon dioxide reduction reactions (CO2RR), and metal–air batteries in details. Furthermore, the photocatalytic water splitting, CO2 conversion, pollutant degradation, and nitrogen fixation are reviewed as well. We also stress the applications of perovskite type ABO3 oxides in solid oxide fuel cells (SOFs). Finally, the optimization of perovskite type ABO3 oxides for applications in various fields and an outlook on the current and future challenges are depicted. The aim of this review is to present a broad overview of the recent advancements in the development of perovskite type ABO3 oxides-based catalysts and their applications in energy conversion and environmental remediation, as well as to present a roadmap for future development in these hot research areas.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 6","pages":"3165–3241 3165–3241"},"PeriodicalIF":51.4,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

From Ab Initio to Instrumentation: A Field Guide to Characterizing Multivalent Liquid Electrolytes 从从头算到仪器仪表：多价液体电解质表征的现场指南

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-03-10 DOI: 10.1021/acs.chemrev.4c00380

Glenn R. Pastel, Travis P. Pollard, Oleg Borodin, Marshall A. Schroeder

引用次数: 0

From Ab Initio to Instrumentation: A Field Guide to Characterizing Multivalent Liquid Electrolytes 从从头算到仪器仪表：多价液体电解质表征的现场指南

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-03-10 DOI: 10.1021/acs.chemrev.4c0038010.1021/acs.chemrev.4c00380

Glenn R. Pastel, Travis P. Pollard, Oleg Borodin* and Marshall A. Schroeder*,

{"title":"From Ab Initio to Instrumentation: A Field Guide to Characterizing Multivalent Liquid Electrolytes","authors":"Glenn R. Pastel, Travis P. Pollard, Oleg Borodin* and Marshall A. Schroeder*, ","doi":"10.1021/acs.chemrev.4c0038010.1021/acs.chemrev.4c00380","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00380https://doi.org/10.1021/acs.chemrev.4c00380","url":null,"abstract":"In this field guide, we outline empirical and theory-based approaches to characterize the fundamental properties of liquid multivalent-ion battery electrolytes, including (i) structure and chemistry, (ii) transport, and (iii) electrochemical properties. When detailed molecular-scale understanding of the multivalent electrolyte behavior is insufficient we use examples from well-studied lithium-ion electrolytes. In recognition that coupling empirical and theory-based techniques is highly effective, but often nontrivial, we also highlight recent electrolyte characterization efforts that uncover a more comprehensive and nuanced understanding of the underlying structures, processes, and reactions that drive performance and system-level behavior. We hope the insights from these discussions will guide the design of future electrolyte studies, accelerate development of next-generation multivalent-ion batteries through coupling of modeling with experiments, and help to avoid pitfalls and ensure reproducibility of modeling results.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 6","pages":"3059–3164 3059–3164"},"PeriodicalIF":51.4,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations 碘芳烃活化：向绿色和可持续转型迈进

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-03-07 DOI: 10.1021/acs.chemrev.4c0080810.1021/acs.chemrev.4c00808

Toshifumi Dohi*, Elghareeb E. Elboray, Kotaro Kikushima, Koji Morimoto and Yasuyuki Kita*,

{"title":"Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations","authors":"Toshifumi Dohi*, Elghareeb E. Elboray, Kotaro Kikushima, Koji Morimoto and Yasuyuki Kita*, ","doi":"10.1021/acs.chemrev.4c0080810.1021/acs.chemrev.4c00808","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00808https://doi.org/10.1021/acs.chemrev.4c00808","url":null,"abstract":"Constructing chemical bonds under green sustainable conditions has drawn attention from environmental and economic perspectives. The dissociation of (hetero)aryl–halide bonds is a crucial step of most arylations affording (hetero)arene derivatives. Herein, we summarize the (hetero)aryl halides activation enabling the direct (hetero)arylation of trapping reagents and construction of highly functionalized (hetero)arenes under benign conditions. The strategies for the activation of aryl iodides are classified into (a) hypervalent iodoarene activation followed by functionalization under thermal/photochemical conditions, (b) aryl–I bond dissociation in the presence of bases with/without organic catalysts and promoters, (c) photoinduced aryl–I bond dissociation in the presence/absence of organophotocatalysts, (d) electrochemical activation of aryl iodides by direct/indirect electrolysis mediated by organocatalysts and mediators acting as electron shuttles, and (e) electrophotochemical activation of aryl iodides mediated by redox-active organocatalysts. These activation modes result in aryl iodides exhibiting diverse reactivity as formal aryl cations/radicals/anions and aryne precursors. The coupling of these reactive intermediates with trapping reagents leads to the facile and selective formation of C–C and C–heteroatom bonds. These ecofriendly, inexpensive, and functional group-tolerant activation strategies offer green alternatives to transition metal-based catalysis.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 6","pages":"3440–3550 3440–3550"},"PeriodicalIF":51.4,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00808","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations 碘芳烃活化：向绿色和可持续转型迈进

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-03-07 DOI: 10.1021/acs.chemrev.4c00808

Toshifumi Dohi, Elghareeb E. Elboray, Kotaro Kikushima, Koji Morimoto, Yasuyuki Kita

{"title":"Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations","authors":"Toshifumi Dohi, Elghareeb E. Elboray, Kotaro Kikushima, Koji Morimoto, Yasuyuki Kita","doi":"10.1021/acs.chemrev.4c00808","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00808","url":null,"abstract":"Constructing chemical bonds under green sustainable conditions has drawn attention from environmental and economic perspectives. The dissociation of (hetero)aryl–halide bonds is a crucial step of most arylations affording (hetero)arene derivatives. Herein, we summarize the (hetero)aryl halides activation enabling the direct (hetero)arylation of trapping reagents and construction of highly functionalized (hetero)arenes under benign conditions. The strategies for the activation of aryl iodides are classified into (a) hypervalent iodoarene activation followed by functionalization under thermal/photochemical conditions, (b) aryl–I bond dissociation in the presence of bases with/without organic catalysts and promoters, (c) photoinduced aryl–I bond dissociation in the presence/absence of organophotocatalysts, (d) electrochemical activation of aryl iodides by direct/indirect electrolysis mediated by organocatalysts and mediators acting as electron shuttles, and (e) electrophotochemical activation of aryl iodides mediated by redox-active organocatalysts. These activation modes result in aryl iodides exhibiting diverse reactivity as formal aryl cations/radicals/anions and aryne precursors. The coupling of these reactive intermediates with trapping reagents leads to the facile and selective formation of C–C and C–heteroatom bonds. These ecofriendly, inexpensive, and functional group-tolerant activation strategies offer green alternatives to transition metal-based catalysis.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"17 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Non-Nernstian Effects in Theoretical Electrocatalysis 理论电催化中的非能量效应

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-03-06 DOI: 10.1021/acs.chemrev.4c00803

Dipam Manish Patel, Georg Kastlunger

引用次数: 0

Advances in the Synthesis of Cyclopropylamines 环丙胺的合成研究进展

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-03-06 DOI: 10.1021/acs.chemrev.4c00674

Philippe Bertus, Julien Caillé

{"title":"Advances in the Synthesis of Cyclopropylamines","authors":"Philippe Bertus, Julien Caillé","doi":"10.1021/acs.chemrev.4c00674","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00674","url":null,"abstract":"Cyclopropylamines are an important subclass of substituted cyclopropanes that combine the unique electronic and steric properties of cyclopropanes with the presence of a donor nitrogen atom. In addition to their presence in a diverse array of biologically active compounds, cyclopropylamines are utilized as important synthetic intermediates, particularly in ring-opening or cycloaddition reactions. Consequently, the synthesis of these compounds has constituted a significant research topic, as evidenced by the abundant published synthetic methods. In addition to the widely used Curtius rearrangement, classical cyclopropanation methods have been adapted to integrate a nitrogen function (Simmons–Smith reaction, metal-catalyzed reaction of diazo compounds on olefins, Michael-initiated ring-closure reactions) with significant advances in enantioselective synthesis. More recently, specific methods have been developed for the preparation of the aminocyclopropane moiety (Kulinkovich reactions applied to amides and nitriles, addition to cyclopropenes, metal-catalyzed reactions involving C–H functionalization, ...). The topic of this review is to present the different methods for the preparation of cyclopropylamine derivatives, with the aim of covering the methodological advances as best as possible, highlighting their scope, their stereochemical aspects and future trends.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"18 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143570075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Non-Nernstian Effects in Theoretical Electrocatalysis 理论电催化中的非能量效应

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-03-06 DOI: 10.1021/acs.chemrev.4c0080310.1021/acs.chemrev.4c00803

Dipam Manish Patel, and , Georg Kastlunger*,

{"title":"Non-Nernstian Effects in Theoretical Electrocatalysis","authors":"Dipam Manish Patel,  and , Georg Kastlunger*, ","doi":"10.1021/acs.chemrev.4c0080310.1021/acs.chemrev.4c00803","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00803https://doi.org/10.1021/acs.chemrev.4c00803","url":null,"abstract":"Electrocatalysis is one of the principal pathways for the transition to sustainable chemistry, promising greater energy efficiency and reduced emissions. As the field has grown, our theoretical understanding has matured. The influence of the applied potential on reactivity has developed from the first-order predictions based on the Nernst equation to the implicit inclusion of second-order effects including the interaction of reacting species with the interfacial electric field. In this review, we explore these non-Nernstian field effects in electrocatalysis, aiming to both understand and exploit them through theory and computation. We summarize the critical distinction between Nernstian and non-Nernstian effects and outline strategies to address the latter in theoretical studies. Subsequently, we examine the specific energetic contributions of the latter on capacitive and faradaic processes separately. We also underscore the importance of considering non-Nernstian effects in catalyst screening and mechanistic analysis. Finally, we provide suggestions on how to experimentally unravel these effects, offering insights into practical approaches for advancing the field.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 6","pages":"3378–3400 3378–3400"},"PeriodicalIF":51.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in the Synthesis of Cyclopropylamines 环丙胺的合成研究进展

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-03-06 DOI: 10.1021/acs.chemrev.4c0067410.1021/acs.chemrev.4c00674

Philippe Bertus*, and , Julien Caillé,

{"title":"Advances in the Synthesis of Cyclopropylamines","authors":"Philippe Bertus*,  and , Julien Caillé, ","doi":"10.1021/acs.chemrev.4c0067410.1021/acs.chemrev.4c00674","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00674https://doi.org/10.1021/acs.chemrev.4c00674","url":null,"abstract":"Cyclopropylamines are an important subclass of substituted cyclopropanes that combine the unique electronic and steric properties of cyclopropanes with the presence of a donor nitrogen atom. In addition to their presence in a diverse array of biologically active compounds, cyclopropylamines are utilized as important synthetic intermediates, particularly in ring-opening or cycloaddition reactions. Consequently, the synthesis of these compounds has constituted a significant research topic, as evidenced by the abundant published synthetic methods. In addition to the widely used Curtius rearrangement, classical cyclopropanation methods have been adapted to integrate a nitrogen function (Simmons–Smith reaction, metal-catalyzed reaction of diazo compounds on olefins, Michael-initiated ring-closure reactions) with significant advances in enantioselective synthesis. More recently, specific methods have been developed for the preparation of the aminocyclopropane moiety (Kulinkovich reactions applied to amides and nitriles, addition to cyclopropenes, metal-catalyzed reactions involving C–H functionalization, ...). The topic of this review is to present the different methods for the preparation of cyclopropylamine derivatives, with the aim of covering the methodological advances as best as possible, highlighting their scope, their stereochemical aspects and future trends.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 6","pages":"3242–3377 3242–3377"},"PeriodicalIF":51.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0