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Strategies and Prospects for High-Performance Te-Free Thermoelectric Materials
IF 62.1 1区 化学
Chemical Reviews Pub Date : 2025-03-19 DOI: 10.1021/acs.chemrev.4c00786
Hongwei Ming, Zhong-Zhen Luo, Zhigang Zou, Mercouri G. Kanatzidis
{"title":"Strategies and Prospects for High-Performance Te-Free Thermoelectric Materials","authors":"Hongwei Ming, Zhong-Zhen Luo, Zhigang Zou, Mercouri G. Kanatzidis","doi":"10.1021/acs.chemrev.4c00786","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00786","url":null,"abstract":"Thermoelectric materials hold great potential for direct conversion of ubiquitous waste heat into electricity. However, their commercialization is hindered by low efficiency, reliance on rare and expensive Te, and limited stability under operating conditions. This review explores recent advances in novel strategies for achieving high thermoelectric performance and stability in Te-free inorganic bulk materials. First, we discuss diverse innovative techniques aimed at substantially enhancing electrical transport properties. These methods encompass strategies such as charge carrier engineering, band convergence, band inversion, valley anisotropy, multiband synglisis, and the incorporation of resonant levels or midgap states. Then we focus on strategies to reduce lattice thermal conductivity, including phonon scattering induced by multidimensional defects, off-center doping, resonance scattering, and lattice softening. Additionally, this review presents strategies for decoupling electron and phonon transport to enhance the thermoelectric performance of materials further. The strategies include interface engineering, crystal symmetry manipulation, high-entropy engineering and nanostructuring, high-pressure technology, and magnetically enhanced thermoelectrics. Moreover, we highlight novel strategies for improving the chemical and thermal stability of materials under operating conditions. Last, we discuss current controversies and challenges and suggest future directions for further research to improve the thermoelectric performance of Te-free bulk materials.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"20 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143654137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
4D Printing: A Comprehensive Review of Technologies, Materials, Stimuli, Design, and Emerging Applications
IF 62.1 1区 化学
Chemical Reviews Pub Date : 2025-03-19 DOI: 10.1021/acs.chemrev.4c00070
Aixiang Ding, Fang Tang, Eben Alsberg
{"title":"4D Printing: A Comprehensive Review of Technologies, Materials, Stimuli, Design, and Emerging Applications","authors":"Aixiang Ding, Fang Tang, Eben Alsberg","doi":"10.1021/acs.chemrev.4c00070","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00070","url":null,"abstract":"4D printing is a groundbreaking technology that seamlessly integrates additive manufacturing with smart materials, enabling the creation of multiscale objects capable of changing shapes and/or functions in a controlled and programmed manner in response to applied energy inputs. Printing technologies, mathematical modeling, responsive materials, stimuli, and structural design constitute the blueprint of 4D printing, all of which have seen rapid advancement in the past decade. These advancements have opened up numerous possibilities for dynamic and adaptive structures, finding potential use in healthcare, textiles, construction, aerospace, robotics, photonics, and electronics. However, current 4D printing primarily focuses on proof-of-concept demonstrations. Further development is necessary to expand the range of accessible materials and address fabrication complexities for widespread adoption. In this paper, we aim to deliver a comprehensive review of the state-of-the-art in 4D printing, probing into shape programming, exploring key aspects of resulting constructs including printing technologies, materials, structural design, morphing mechanisms, and stimuli-responsiveness, and elaborating on prominent applications across various fields. Finally, we discuss perspectives on limitations, challenges, and future developments in the realm of 4D printing. While the potential of this technology is undoubtedly vast, continued research and innovation are essential to unlocking its full capabilities and maximizing its real-world impact.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"21 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143660855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
4D Printing: A Comprehensive Review of Technologies, Materials, Stimuli, Design, and Emerging Applications
IF 51.4 1区 化学
Chemical Reviews Pub Date : 2025-03-19 DOI: 10.1021/acs.chemrev.4c0007010.1021/acs.chemrev.4c00070
Aixiang Ding*, Fang Tang and Eben Alsberg*, 
{"title":"4D Printing: A Comprehensive Review of Technologies, Materials, Stimuli, Design, and Emerging Applications","authors":"Aixiang Ding*,&nbsp;Fang Tang and Eben Alsberg*,&nbsp;","doi":"10.1021/acs.chemrev.4c0007010.1021/acs.chemrev.4c00070","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00070https://doi.org/10.1021/acs.chemrev.4c00070","url":null,"abstract":"<p >4D printing is a groundbreaking technology that seamlessly integrates additive manufacturing with smart materials, enabling the creation of multiscale objects capable of changing shapes and/or functions in a controlled and programmed manner in response to applied energy inputs. Printing technologies, mathematical modeling, responsive materials, stimuli, and structural design constitute the blueprint of 4D printing, all of which have seen rapid advancement in the past decade. These advancements have opened up numerous possibilities for dynamic and adaptive structures, finding potential use in healthcare, textiles, construction, aerospace, robotics, photonics, and electronics. However, current 4D printing primarily focuses on proof-of-concept demonstrations. Further development is necessary to expand the range of accessible materials and address fabrication complexities for widespread adoption. In this paper, we aim to deliver a comprehensive review of the state-of-the-art in 4D printing, probing into shape programming, exploring key aspects of resulting constructs including printing technologies, materials, structural design, morphing mechanisms, and stimuli-responsiveness, and elaborating on prominent applications across various fields. Finally, we discuss perspectives on limitations, challenges, and future developments in the realm of 4D printing. While the potential of this technology is undoubtedly vast, continued research and innovation are essential to unlocking its full capabilities and maximizing its real-world impact.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 7","pages":"3663–3771 3663–3771"},"PeriodicalIF":51.4,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143798891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controlling Stereoselectivity with Noncovalent Interactions in Chiral Phosphoric Acid Organocatalysis
IF 62.1 1区 化学
Chemical Reviews Pub Date : 2025-03-18 DOI: 10.1021/acs.chemrev.4c00869
Isaiah O. Betinol, Yutao Kuang, Brian P. Mulley, Jolene P. Reid
{"title":"Controlling Stereoselectivity with Noncovalent Interactions in Chiral Phosphoric Acid Organocatalysis","authors":"Isaiah O. Betinol, Yutao Kuang, Brian P. Mulley, Jolene P. Reid","doi":"10.1021/acs.chemrev.4c00869","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00869","url":null,"abstract":"Chiral phosphoric acids (CPAs) have emerged as highly effective Brønsted acid catalysts in an expanding range of asymmetric transformations, often through novel multifunctional substrate activation modes. Versatile and broadly appealing, these catalysts benefit from modular and tunable structures, and compatibility with additives. Given the unique types of noncovalent interactions (NCIs) that can be established between CPAs and various reactants─such as hydrogen bonding, aromatic interactions, and van der Waals forces─it is unsurprising that these catalyst systems have become a promising approach for accessing diverse chiral product outcomes. This review aims to provide an in-depth exploration of the mechanisms by which CPAs impart stereoselectivity, positioning NCIs as the central feature that connects a broad spectrum of catalytic reactions. Spanning literature from 2004 to 2024, it covers nucleophilic additions, radical transformations, and atroposelective bond formations, highlighting the applicability of CPA organocatalysis. Special emphasis is placed on the structural and mechanistic features that govern CPA–substrate interactions, as well as the tools and techniques developed to enhance our understanding of their catalytic behavior. In addition to emphasizing mechanistic details and stereocontrolling elements in individual reactions, we have carefully structured this review to provide a natural progression from these specifics to a broader, class-level perspective. Overall, these findings underscore the critical role of NCIs in CPA catalysis and their significant contributions to advancing asymmetric synthesis.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"91 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143654135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controlling Stereoselectivity with Noncovalent Interactions in Chiral Phosphoric Acid Organocatalysis
IF 51.4 1区 化学
Chemical Reviews Pub Date : 2025-03-18 DOI: 10.1021/acs.chemrev.4c0086910.1021/acs.chemrev.4c00869
Isaiah O. Betinol, Yutao Kuang, Brian P. Mulley and Jolene P. Reid*, 
{"title":"Controlling Stereoselectivity with Noncovalent Interactions in Chiral Phosphoric Acid Organocatalysis","authors":"Isaiah O. Betinol,&nbsp;Yutao Kuang,&nbsp;Brian P. Mulley and Jolene P. Reid*,&nbsp;","doi":"10.1021/acs.chemrev.4c0086910.1021/acs.chemrev.4c00869","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00869https://doi.org/10.1021/acs.chemrev.4c00869","url":null,"abstract":"<p >Chiral phosphoric acids (CPAs) have emerged as highly effective Brønsted acid catalysts in an expanding range of asymmetric transformations, often through novel multifunctional substrate activation modes. Versatile and broadly appealing, these catalysts benefit from modular and tunable structures, and compatibility with additives. Given the unique types of noncovalent interactions (NCIs) that can be established between CPAs and various reactants─such as hydrogen bonding, aromatic interactions, and van der Waals forces─it is unsurprising that these catalyst systems have become a promising approach for accessing diverse chiral product outcomes. This review aims to provide an in-depth exploration of the mechanisms by which CPAs impart stereoselectivity, positioning NCIs as the central feature that connects a broad spectrum of catalytic reactions. Spanning literature from 2004 to 2024, it covers nucleophilic additions, radical transformations, and atroposelective bond formations, highlighting the applicability of CPA organocatalysis. Special emphasis is placed on the structural and mechanistic features that govern CPA–substrate interactions, as well as the tools and techniques developed to enhance our understanding of their catalytic behavior. In addition to emphasizing mechanistic details and stereocontrolling elements in individual reactions, we have carefully structured this review to provide a natural progression from these specifics to a broader, class-level perspective. Overall, these findings underscore the critical role of NCIs in CPA catalysis and their significant contributions to advancing asymmetric synthesis.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 8","pages":"4184–4286 4184–4286"},"PeriodicalIF":51.4,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-Ferrocene-Based Ligands: From Design to Applications
IF 51.4 1区 化学
Chemical Reviews Pub Date : 2025-03-17 DOI: 10.1021/acs.chemrev.4c0029510.1021/acs.chemrev.4c00295
Axel Straube, Liridona Useini and Evamarie Hey-Hawkins*, 
{"title":"Multi-Ferrocene-Based Ligands: From Design to Applications","authors":"Axel Straube,&nbsp;Liridona Useini and Evamarie Hey-Hawkins*,&nbsp;","doi":"10.1021/acs.chemrev.4c0029510.1021/acs.chemrev.4c00295","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00295https://doi.org/10.1021/acs.chemrev.4c00295","url":null,"abstract":"<p >Despite the extensive literature on ferrocene chemistry, a comprehensive analysis of multiferrocene ligands is notably absent. Thus, this review presents an overview of multiferrocenyl-containing ligands, focusing on their synthesis, characterization, and applications in catalysis and sensing. These ligands offer unique properties, including redox activity and planar chirality, making them valuable in asymmetric catalysis and molecular electronics. The review covers the literature from the first synthesis of tris(ferrocenyl)phosphane in 1962 to current developments, including various ligand subsets, which contain at least two ferrocene units within their structure. Special attention is given to explaining the coordination chemistry, electrochemical behavior, and practical applications of these ligands. The aim of this undertaking is to fill gaps in knowledge and inspire further research by identifying areas for exploration. Notably, certain ligand families like TRAP (<i>trans</i>-spanning phosphane) ligands remain underexplored in terms of their electrochemical properties, highlighting opportunities for future investigation. Thus, this review provides a resource for researchers in the field, stimulating further advancements in multiferrocenyl ligand chemistry and its wide-ranging applications.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 6","pages":"3007–3058 3007–3058"},"PeriodicalIF":51.4,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00295","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-Ferrocene-Based Ligands: From Design to Applications
IF 62.1 1区 化学
Chemical Reviews Pub Date : 2025-03-17 DOI: 10.1021/acs.chemrev.4c00295
Axel Straube, Liridona Useini, Evamarie Hey-Hawkins
{"title":"Multi-Ferrocene-Based Ligands: From Design to Applications","authors":"Axel Straube, Liridona Useini, Evamarie Hey-Hawkins","doi":"10.1021/acs.chemrev.4c00295","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00295","url":null,"abstract":"Despite the extensive literature on ferrocene chemistry, a comprehensive analysis of multiferrocene ligands is notably absent. Thus, this review presents an overview of multiferrocenyl-containing ligands, focusing on their synthesis, characterization, and applications in catalysis and sensing. These ligands offer unique properties, including redox activity and planar chirality, making them valuable in asymmetric catalysis and molecular electronics. The review covers the literature from the first synthesis of tris(ferrocenyl)phosphane in 1962 to current developments, including various ligand subsets, which contain at least two ferrocene units within their structure. Special attention is given to explaining the coordination chemistry, electrochemical behavior, and practical applications of these ligands. The aim of this undertaking is to fill gaps in knowledge and inspire further research by identifying areas for exploration. Notably, certain ligand families like TRAP (<i>trans</i>-spanning phosphane) ligands remain underexplored in terms of their electrochemical properties, highlighting opportunities for future investigation. Thus, this review provides a resource for researchers in the field, stimulating further advancements in multiferrocenyl ligand chemistry and its wide-ranging applications.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"67 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143640009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solvent Co-Intercalation Reactions for Batteries and Beyond
IF 62.1 1区 化学
Chemical Reviews Pub Date : 2025-03-15 DOI: 10.1021/acs.chemrev.4c00805
Guillermo A. Ferrero, Gustav Åvall, Knut Janßen, Youhyun Son, Yuliia Kravets, Yanan Sun, Philipp Adelhelm
{"title":"Solvent Co-Intercalation Reactions for Batteries and Beyond","authors":"Guillermo A. Ferrero, Gustav Åvall, Knut Janßen, Youhyun Son, Yuliia Kravets, Yanan Sun, Philipp Adelhelm","doi":"10.1021/acs.chemrev.4c00805","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00805","url":null,"abstract":"Solvent co-intercalation is a process in which ions and solvents jointly intercalate into a layered electrode material during battery charging/discharging. It typically leads to rapid electrode degradation, but new findings show that it can be highly reversible, lasting several thousand cycles. Solvent co-intercalation has two important characteristics: (1) the charge transfer resistance is minimized as stripping of the solvation shell is eliminated and (2) the fact that solvents become part of the electrode reaction provides another means of designing electrode materials. The concept of solvent co-intercalation is chemically very diverse, as a single electrode material can host different types and numbers of solvents and ions. It is likely that many undiscovered combinations of electrode materials, solvents, and ions capable of solvent co-intercalation reactions exist, offering a largely unexplored chemical space for new materials. Co-intercalation can expand the crystal lattice (&gt;1 nm) to the extent that free solvents are present in the structure, forming a layered, “porous” material. This indicates that the concept has a much broader impact and relates to other research fields such as supercapacitors, layered nanostructures, and nanocatalysis. This Review covers the concept and current understanding of solvent co-intercalation reactions, characterization methods, advantages, limitations, and future research directions.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"8 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143627383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solvent Co-Intercalation Reactions for Batteries and Beyond
IF 51.4 1区 化学
Chemical Reviews Pub Date : 2025-03-15 DOI: 10.1021/acs.chemrev.4c0080510.1021/acs.chemrev.4c00805
Guillermo A. Ferrero*, Gustav Åvall, Knut Janßen, Youhyun Son, Yuliia Kravets, Yanan Sun and Philipp Adelhelm*, 
{"title":"Solvent Co-Intercalation Reactions for Batteries and Beyond","authors":"Guillermo A. Ferrero*,&nbsp;Gustav Åvall,&nbsp;Knut Janßen,&nbsp;Youhyun Son,&nbsp;Yuliia Kravets,&nbsp;Yanan Sun and Philipp Adelhelm*,&nbsp;","doi":"10.1021/acs.chemrev.4c0080510.1021/acs.chemrev.4c00805","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00805https://doi.org/10.1021/acs.chemrev.4c00805","url":null,"abstract":"<p >Solvent co-intercalation is a process in which ions and solvents jointly intercalate into a layered electrode material during battery charging/discharging. It typically leads to rapid electrode degradation, but new findings show that it can be highly reversible, lasting several thousand cycles. Solvent co-intercalation has two important characteristics: (1) the charge transfer resistance is minimized as stripping of the solvation shell is eliminated and (2) the fact that solvents become part of the electrode reaction provides another means of designing electrode materials. The concept of solvent co-intercalation is chemically very diverse, as a single electrode material can host different types and numbers of solvents and ions. It is likely that many undiscovered combinations of electrode materials, solvents, and ions capable of solvent co-intercalation reactions exist, offering a largely unexplored chemical space for new materials. Co-intercalation can expand the crystal lattice (&gt;1 nm) to the extent that free solvents are present in the structure, forming a layered, “porous” material. This indicates that the concept has a much broader impact and relates to other research fields such as supercapacitors, layered nanostructures, and nanocatalysis. This Review covers the concept and current understanding of solvent co-intercalation reactions, characterization methods, advantages, limitations, and future research directions.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 6","pages":"3401–3439 3401–3439"},"PeriodicalIF":51.4,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00805","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696450","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Perovskite Type ABO3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects
IF 62.1 1区 化学
Chemical Reviews Pub Date : 2025-03-12 DOI: 10.1021/acs.chemrev.4c00553
Muhammad Humayun, Zhishan Li, Muhammad Israr, Abbas Khan, Wei Luo, Chundong Wang, Zongping Shao
{"title":"Perovskite Type ABO3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects","authors":"Muhammad Humayun, Zhishan Li, Muhammad Israr, Abbas Khan, Wei Luo, Chundong Wang, Zongping Shao","doi":"10.1021/acs.chemrev.4c00553","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00553","url":null,"abstract":"Since photocatalytic and electrocatalytic technologies are crucial for tackling the energy and environmental challenges, significant efforts have been put into exploring advanced catalysts. Among them, perovskite type ABO<sub>3</sub> oxides show great promising catalytic activities because of their flexible physical and chemical properties. In this review, the fundamentals and recent progress in the synthesis of perovskite type ABO<sub>3</sub> oxides are considered. We describe the mechanisms for electrocatalytic oxygen evolution reactions (OER), oxygen reduction reactions (ORR), hydrogen evolution reactions (HER), nitrogen reduction reactions (NRR), carbon dioxide reduction reactions (CO<sub>2</sub>RR), and metal–air batteries in details. Furthermore, the photocatalytic water splitting, CO<sub>2</sub> conversion, pollutant degradation, and nitrogen fixation are reviewed as well. We also stress the applications of perovskite type ABO<sub>3</sub> oxides in solid oxide fuel cells (SOFs). Finally, the optimization of perovskite type ABO<sub>3</sub> oxides for applications in various fields and an outlook on the current and future challenges are depicted. The aim of this review is to present a broad overview of the recent advancements in the development of perovskite type ABO<sub>3</sub> oxides-based catalysts and their applications in energy conversion and environmental remediation, as well as to present a roadmap for future development in these hot research areas.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"16 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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