Chemical Reviews最新文献_第3页

Quantum Measurement for Quantum Chemistry on a Quantum Computer 量子化学在量子计算机上的量子测量。

IF 55.8 1区化学

Chemical Reviews Pub Date : 2025-07-21 DOI: 10.1021/acs.chemrev.5c00055

Smik Patel, Praveen Jayakumar, Tzu-Ching Yen and Artur F. Izmaylov*,

{"title":"Quantum Measurement for Quantum Chemistry on a Quantum Computer","authors":"Smik Patel, Praveen Jayakumar, Tzu-Ching Yen and Artur F. Izmaylov*, ","doi":"10.1021/acs.chemrev.5c00055","DOIUrl":"10.1021/acs.chemrev.5c00055","url":null,"abstract":"Quantum chemistry is among the most promising applications of quantum computing, offering the potential to solve complex electronic structure problems more efficiently than classical approaches. A critical component of any quantum algorithm is the measurement step, where the desired properties are extracted from a quantum computer. This review focuses on recent advancements in quantum measurement techniques tailored for quantum chemistry, particularly within the second quantized framework suitable for current and near-term quantum hardware. We provide a comprehensive overview of measurement strategies developed primarily for the Variational Quantum Eigensolver (VQE) and its derivatives. These strategies address the inherent challenges posed by the complexity of the electronic Hamiltonian operator. Additionally, we examine methods for estimating excited states and one- and two-electron properties, extending the applicability of quantum algorithms to broader chemical phenomena. Key aspects of the review include approaches for constructing measurement operators with reduced classical preprocessing and quantum implementation costs, techniques to minimize the number of measurements required for a given accuracy, and error mitigation strategies that leverage symmetries and other properties of the measurement operators. Furthermore, we explore measurement schemes rooted in Quantum Phase Estimation (QPE), which are expected to become viable with the advent of fault-tolerant quantum computing. This review emphasizes foundational concepts and methodologies rather than numerical benchmarks, serving as a resource for researchers aiming to enhance the efficiency and accuracy of quantum measurements in quantum chemistry.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 16","pages":"7490–7524"},"PeriodicalIF":55.8,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Selective Fluorination of Complex Molecules: Late-Stage Functionalization. 复杂分子的选择性氟化：后期功能化。

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-07-21 DOI: 10.1021/acs.chemrev.5c00363

Muyuan Wang, Jonah Ruskin, Joseph Marques, Nathaniel Garrison, Thomas Lectka

{"title":"Selective Fluorination of Complex Molecules: Late-Stage Functionalization.","authors":"Muyuan Wang, Jonah Ruskin, Joseph Marques, Nathaniel Garrison, Thomas Lectka","doi":"10.1021/acs.chemrev.5c00363","DOIUrl":"https://doi.org/10.1021/acs.chemrev.5c00363","url":null,"abstract":"It has been more than 160 years since chemists first performed fluorination reactions on organic molecules. Scores of fluorination reagents and hundreds of worthwhile methods have been developed over the intervening years. Meanwhile, workers in the field are increasingly aware of the benefits of incorporating fluorine atoms into bioactive molecules. Therefore, the emergence of \"late-stage fluorination\" in the first decade of the 21st century is both natural and well-justified─an extant compound, off the shelf, can be converted more efficiently to a fluorinated product than through a de novo approach. It is worth noting that chemists' attempts to fluorinate complex molecules began sporadically decades ago before the concept of \"late-stage\" was first proposed. In this Perspective, we aim to present a comprehensive series of late-stage fluorination strategies, with the spotlight primarily focused on single-atom modifications of complex molecules (although incidental examples of polyfluorination are addressed), including natural products, analogues, and pharmaceuticals. Both the nucleophilic and electrophilic sources of fluorine are examined.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":" ","pages":""},"PeriodicalIF":51.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144681667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrolyte Evolution for Flexible Energy Storage Systems: From Liquid to Solid, from Rigid to Soft, and from Organic to Aqueous 柔性储能系统的电解质演变：从液体到固体，从刚性到软，从有机到水性。

IF 55.8 1区化学

Chemical Reviews Pub Date : 2025-07-18 DOI: 10.1021/acs.chemrev.5c00036

Tao Shui, Yaojia Liang, Tomasz Wejrzanowski, Jiacheng Liu, Song-Zhu Kure-Chu, Takehiko Hihara, Tengfei Zhang*, Feifei Liang, Chao Sun, Wei She*, Wei Zhang* and Zheng Ming Sun*,

{"title":"Electrolyte Evolution for Flexible Energy Storage Systems: From Liquid to Solid, from Rigid to Soft, and from Organic to Aqueous","authors":"Tao Shui, Yaojia Liang, Tomasz Wejrzanowski, Jiacheng Liu, Song-Zhu Kure-Chu, Takehiko Hihara, Tengfei Zhang*, Feifei Liang, Chao Sun, Wei She*, Wei Zhang* and Zheng Ming Sun*, ","doi":"10.1021/acs.chemrev.5c00036","DOIUrl":"10.1021/acs.chemrev.5c00036","url":null,"abstract":"With the rapid development of modern electronic devices and the diversification of use scenarios, flexible energy storage systems (FESS) have gained widespread attention as an inseparable part of electronic devices. Electrolyte is considered as one of the most influential components of tremendous scientific and commercial interest in the performance of FESS. Electrolytes are undergoing tremendous structural variations from liquid to solid, rigid to flexible, and organic to aqueous to meet the evolving requirements for FESS. This review delineates the evolutionary trajectory of electrolyte development across three dimensions: transitioning from liquid to solid, from rigid to flexible, and from organic to aqueous formulations. Furthermore, it elucidates potential mechanisms influencing the electrochemical stability and interfacial properties of electrolytes, along with their impact on battery performance. Subsequently, various strategies are outlined to address these challenges and advance the development of FESS electrolytes. Lastly, the functionality and structural design, computation methods, compatibility (integration) of the FESS are evaluated, followed by a comprehensive summary and outlook. We believe this article will aid researchers in comprehending the underlying causes of these challenges and in designing cutting-edge flexible solid-state electrolytes for assembling FESS that exhibit compatibility and superior performance.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 15","pages":"7167–7222"},"PeriodicalIF":55.8,"publicationDate":"2025-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144661901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrical Stimulation of Cells: Drivers, Technology, and Effects 细胞电刺激：驱动、技术和效果。

IF 55.8 1区化学

Chemical Reviews Pub Date : 2025-07-17 DOI: 10.1021/acs.chemrev.4c00468

Kian Kadan-Jamal, Filip Wronowski, Amy Jin, Tobias E. Naegele, Viviana Rincón Montes, Xudong Tao, Antonio Dominguez-Alfaro, Chaeyeon Lee and George G. Malliaras*,

{"title":"Electrical Stimulation of Cells: Drivers, Technology, and Effects","authors":"Kian Kadan-Jamal, Filip Wronowski, Amy Jin, Tobias E. Naegele, Viviana Rincón Montes, Xudong Tao, Antonio Dominguez-Alfaro, Chaeyeon Lee and George G. Malliaras*, ","doi":"10.1021/acs.chemrev.4c00468","DOIUrl":"10.1021/acs.chemrev.4c00468","url":null,"abstract":"Exposure of cells to electric fields is used in applications as diverse as deep brain stimulation to treat the symptoms of Parkinson’s disease, tumor-treating fields to delay the progression of hard-to-treat cancers, and electroporation to deliver genetic materials to cells. It is also used to study the fundamental properties of electrically active cells and to induce changes in cell behavior, such as the directed outgrowth of neurites, that may one day find applications in the clinic. This review discusses some of the effects elicited on cells upon exposure to electric fields, both acutely and at longer time scales, and considers the underlying mechanisms proposed. It also provides an overview of the technology used to study the effects of exposure of cell to electric fields, including the different types of metal/electrolyte interfaces and the electrode materials used in in vitro and in vivo applications. The aim is to bring together concepts from different communities to highlight similarities, identify potential synergies, and create common ground that may lead to cross-fertilization and advances in the field.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 15","pages":"6874–6905"},"PeriodicalIF":55.8,"publicationDate":"2025-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.chemrev.4c00468","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144657854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-07-09

引用次数: 0

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-07-09

Qi Sun*, Hanping Wang, Juan Xie, Liying Wang, Junxi Mu, Junren Li, Yuhao Ren and Luhua Lai*,

引用次数: 0

Photonic Crystal Grating Resonance and Interfaces for Health Diagnostic Technologies 用于健康诊断技术的光子晶体光栅共振和接口。

IF 55.8 1区化学

Chemical Reviews Pub Date : 2025-07-09 DOI: 10.1021/acs.chemrev.4c00653

Seemesh Bhaskar, Weijing Wang, Hankeun Lee, Leyang Liu, Saurabh Umrao, Weinan Liu, Amanda Bacon, Joseph Tibbs, Kodchakorn Khemtonglang, Anqi Tan, Takhmina Ayupova, Wang-Chien Chen, Xing Wang and Brian T. Cunningham*,

{"title":"Photonic Crystal Grating Resonance and Interfaces for Health Diagnostic Technologies","authors":"Seemesh Bhaskar, Weijing Wang, Hankeun Lee, Leyang Liu, Saurabh Umrao, Weinan Liu, Amanda Bacon, Joseph Tibbs, Kodchakorn Khemtonglang, Anqi Tan, Takhmina Ayupova, Wang-Chien Chen, Xing Wang and Brian T. Cunningham*, ","doi":"10.1021/acs.chemrev.4c00653","DOIUrl":"10.1021/acs.chemrev.4c00653","url":null,"abstract":"The photonic crystal grating resonance (PCGR) technologies mark a significant advancement in early diagnostics of infectious diseases. Here we review the historical perspectives of the PCGR-based platform starting from the early 1900s, discussing the fundamental principles, fabrication strategies, properties, and multifaceted applications. We delve into the significance of grating-based PC interfaces, from the perspective of plasmonics, photonics, and hybrid photoplasmonic interfaces. Hybrid substrates combining PCGR with plasmonic films, dielectric mirrors, and gratings extend the versatility of these platforms. The relevance of PCGR substrates in sensing various bioanalytes, from microRNA to proteins and lipids, is discussed using several case studies. Multifaceted applications such as photonic resonator absorption microscopy (PRAM), photonic resonator interferometric scattering microscopy (PRISM), and photonic crystal enhanced fluorescence (PCEF) showcase the transformative impact of PCGR substrates in the biosensing portfolio. An added advantage of accessibility and convenience of these technologies stemming from integrating smartphone-based detection is succinctly captured. A comparative analysis of PCGR-based biosensing highlighting their strengths and limitations, paving the way for future scope and opportunities, is discussed reviewing the literature in the past 25 years. In conclusion, this review provides a comprehensive overview of PCGR technologies, offering insights into their current state, challenges, and prospects for future advancements.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 14","pages":"6435–6540"},"PeriodicalIF":55.8,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144586378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-07-09

Jie Xiao*, Xia Cao, Bernard Gridley, William Golden, Yuchen Ji, Stacey Johnson, Dongping Lu, Feng Lin, Jun Liu, Yijin Liu, Zhao Liu, Hemanth Neelgund Ramesh, Feifei Shi, Jeremy Schrooten, Mary J. Sims, Shijing Sun, Yuyan Shao, Alon Vaisman, Jihui Yang and M. Stanley Whittingham,

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IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-07-09

Hyeong Bin Rheem, Nayoung Kim, Duc Tai Nguyen, Ghanyatma Adi Baskoro, Jihun H. Roh, Jungkyu K. Lee, Beom Jin Kim* and Insung S. Choi*,

引用次数: 0

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-07-09

Max Buczek*, Zoe Moos, Alexander Gutsche, Stephan Menzel and Regina Dittmann,

引用次数: 0