Chemical Reviews最新文献

{"title":"Two-Dimensional Organic–Inorganic van der Waals Hybrids","authors":"Fucai Cui, Víctor García-López, Zhiyong Wang, Zhongzhong Luo, Daowei He, Xinliang Feng, Renhao Dong, Xinran Wang","doi":"10.1021/acs.chemrev.4c00565","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00565","url":null,"abstract":"Two-dimensional organic–inorganic (2DOI) van der Waals hybrids (vdWhs) have emerged as a groundbreaking subclass of layer-stacked (opto-)electronic materials. The development of 2DOI-vdWhs via systematically integrating inorganic 2D layers with organic 2D crystals at the molecular/atomic scale extends the capabilities of traditional 2D inorganic vdWhs, thanks to their high synthetic flexibility and structural tunability. Constructing an organic–inorganic hybrid interface with atomic precision will unlock new opportunities for generating unique interfacial (opto-)electronic transport properties by combining the strengths of organic and inorganic layers, thus allowing us to satisfy the growing demand for multifunctional applications. Here, this review provides a comprehensive overview of the latest advancements in the chemical synthesis, structural characterization, and numerous applications of 2DOI-vdWhs. Firstly, we introduce the chemistry and the physical properties of the recently rising organic 2D crystals (O2DCs), which feature crystalline 2D nanostructures comprising carbon-rich repeated units linked by covalent/noncovalent bonds and exhibit strong in-plane extended π-conjugation and weak interlayer vdWs interaction. Simultaneously, representative inorganic 2D crystals (I2DCs) are briefly summarized. After that, the synthetic strategies will be systematically summarized, including synthesizing single-component O2DCs with dimensional control and their vdWhs with I2DCs. With these synthetic approaches, the control in the dimension, the stacking modes, and the composition of the 2DOI-vdWhs will be highlighted. Subsequently, a special focus will be given on the discussion of the optical and electronic properties of the single-component 2D materials and their vdWhs, which will be closely relevant to their structures, so that we can establish a general structure–property relationship of 2DOI-vdWhs. In addition to these physical properties, the (opto-)electronic devices such as transistors, photodetectors, sensors, spintronics, and neuromorphic devices as well as energy devices will be discussed. Finally, we provide an outlook to discuss the key challenges for the 2DOI-vdWhs and their future development. This review aims to provide a foundational understanding and inspire further innovation in the development of next-generation 2DOI-vdWhs with transformative technological potential.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"33 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142841656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Correction to “Theory and Simulations of Ionic Liquids in Nanoconfinement”","authors":"Svyatoslav Kondrat, Guang Feng, Fernando Bresme, Michael Urbakh, Alexei A. Kornyshev","doi":"10.1021/acs.chemrev.4c00885","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00885","url":null,"abstract":"In the original article, there is a typo in eq 9, which is missing a prime symbol next to the summation. The prime symbol indicates that the summation in this equation runs only over odd integer numbers. Thus, the correct version of this equation is We recall that this equation describes the interaction energy between two ions located at the symmetry plane of a slit. The complete expression for arbitrary ion positions in slit pores can be found in ref (1). We additionally stress that this interaction energy converges to the Coulomb interaction energy in the limit of the distance between the charges <i>r</i> → 0 (<i>r</i>/<i>L</i> ≪ 1). This article references 1 other publications. This article has not yet been cited by other publications.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"79 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142841652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Covalent Proximity Inducers","authors":"Nir London","doi":"10.1021/acs.chemrev.4c00570","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00570","url":null,"abstract":"Molecules that are able to induce proximity between two proteins are finding ever increasing applications in chemical biology and drug discovery. The ability to introduce an electrophile and make such proximity inducers covalent can offer improved properties such as selectivity, potency, duration of action, and reduced molecular size. This concept has been heavily explored in the context of targeted degradation in particular for bivalent molecules, but recently, additional applications are reported in other contexts, as well as for monovalent molecular glues. This is a comprehensive review of reported covalent proximity inducers, aiming to identify common trends and current gaps in their discovery and application.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"70 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142841651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nondestructive Analysis of Commercial Batteries","authors":"Wenhua Zuo, Rui Liu, Jiyu Cai, Yonggang Hu, Manar Almazrouei, Xiangsi Liu, Tony Cui, Xin Jia, Emory Apodaca, Jakob Alami, Zonghai Chen, Tianyi Li, Wenqian Xu, Xianghui Xiao, Dilworth Parkinson, Yong Yang, Gui-Liang Xu, Khalil Amine","doi":"10.1021/acs.chemrev.4c00566","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00566","url":null,"abstract":"Electrochemical batteries play a crucial role for powering portable electronics, electric vehicles, large-scale electric grids, and future electric aircraft. However, key performance metrics such as energy density, charging speed, lifespan, and safety raise significant consumer concerns. Enhancing battery performance hinges on a deep understanding of their operational and degradation mechanisms, from material composition and electrode structure to large-scale pack integration, necessitating advanced characterization methods. These methods not only enable improved battery performance but also facilitate early detection of substandard or potentially hazardous batteries before they cause serious incidents. This review comprehensively examines the operational principles, applications, challenges, and prospects of cutting-edge characterization techniques for commercial batteries, with a specific focus on in situ and operando methodologies. Furthermore, it explores how these powerful tools have elucidated the operational and degradation mechanisms of commercial batteries. By bridging the gap between advanced characterization techniques and commercial battery technologies, this review aims to guide the design of more sophisticated experiments and models for studying battery degradation and enhancement.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"60 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering Phages to Fight Multidrug-Resistant Bacteria","authors":"Huan Peng, Irene A. Chen, Udi Qimron","doi":"10.1021/acs.chemrev.4c00681","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00681","url":null,"abstract":"Facing the global “superbug” crisis due to the emergence and selection for antibiotic resistance, phages are among the most promising solutions. Fighting multidrug-resistant bacteria requires precise diagnosis of bacterial pathogens and specific cell-killing. Phages have several potential advantages over conventional antibacterial agents such as host specificity, self-amplification, easy production, low toxicity as well as biofilm degradation. However, the narrow host range, uncharacterized properties, as well as potential risks from exponential replication and evolution of natural phages, currently limit their applications. Engineering phages can not only enhance the host bacteria range and improve phage efficacy, but also confer new functions. This review first summarizes major phage engineering techniques including both chemical modification and genetic engineering. Subsequent sections discuss the applications of engineered phages for bacterial pathogen detection and ablation through interdisciplinary approaches of synthetic biology and nanotechnology. We discuss future directions and persistent challenges in the ongoing exploration of phage engineering for pathogen control.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"25 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Octadecanoids: Synthesis and Bioactivity of 18-Carbon Oxygenated Fatty Acids in Mammals, Bacteria, and Fungi","authors":"Johanna Revol-Cavalier, Alessandro Quaranta, John W. Newman, Alan R. Brash, Mats Hamberg, Craig E. Wheelock","doi":"10.1021/acs.chemrev.3c00520","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00520","url":null,"abstract":"The octadecanoids are a broad class of lipids consisting of the oxygenated products of 18-carbon fatty acids. Originally referring to production of the phytohormone jasmonic acid, the octadecanoid pathway has been expanded to include products of all 18-carbon fatty acids. Octadecanoids are formed biosynthetically in mammals via cyclooxygenase (COX), lipoxygenase (LOX), and cytochrome P450 (CYP) activity, as well as nonenzymatically by photo- and autoxidation mechanisms. While octadecanoids are well-known mediators in plants, their role in the regulation of mammalian biological processes has been generally neglected. However, there have been significant advancements in recognizing the importance of these compounds in mammals and their involvement in the mediation of inflammation, nociception, and cell proliferation, as well as in immuno- and tissue modulation, coagulation processes, hormone regulation, and skin barrier formation. More recently, the gut microbiome has been shown to be a significant source of octadecanoid biosynthesis, providing additional biosynthetic routes including hydratase activity (e.g., CLA-HY, FA-HY1, FA-HY2). In this review, we summarize the current field of octadecanoids, propose standardized nomenclature, provide details of octadecanoid preparation and measurement, summarize the phase-I metabolic pathway of octadecanoid formation in mammals, bacteria, and fungi, and describe their biological activity in relation to mammalian pathophysiology as well as their potential use as biomarkers of health and disease.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"87 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation","authors":"John Marques Dos Santos, David Hall, Biju Basumatary, Megan Bryden, Dongyang Chen, Praveen Choudhary, Thomas Comerford, Ettore Crovini, Andrew Danos, Joydip De, Stefan Diesing, Mahni Fatahi, Máire Griffin, Abhishek Kumar Gupta, Hassan Hafeez, Lea Hämmerling, Emily Hanover, Janine Haug, Tabea Heil, Durai Karthik, Shiv Kumar, Oliver Lee, Haoyang Li, Fabien Lucas, Campbell Frank Ross Mackenzie, Aminata Mariko, Tomas Matulaitis, Francis Millward, Yoann Olivier, Quan Qi, Ifor D. W. Samuel, Nidhi Sharma, Changfeng Si, Leander Spierling, Pagidi Sudhakar, Dianming Sun, Eglė Tankelevičiu̅tė, Michele Duarte Tonet, Jingxiang Wang, Tao Wang, Sen Wu, Yan Xu, Le Zhang, Eli Zysman-Colman","doi":"10.1021/acs.chemrev.3c00755","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00755","url":null,"abstract":"Since the seminal report by Adachi and co-workers in 2012, there has been a veritable explosion of interest in the design of thermally activated delayed fluorescence (TADF) compounds, particularly as emitters for organic light-emitting diodes (OLEDs). With rapid advancements and innovation in materials design, the efficiencies of TADF OLEDs for each of the primary color points as well as for white devices now rival those of state-of-the-art phosphorescent emitters. Beyond electroluminescent devices, TADF compounds have also found increasing utility and applications in numerous related fields, from photocatalysis, to sensing, to imaging and beyond. Following from our previous review in 2017 ( <cite><i>Adv. Mater.</i></cite> <span>2017</span>, 1605444), we here comprehensively document subsequent advances made in TADF materials design and their uses from 2017–2022. Correlations highlighted between structure and properties as well as detailed comparisons and analyses should assist future TADF materials development. The necessarily broadened breadth and scope of this review attests to the bustling activity in this field. We note that the rapidly expanding and accelerating research activity in TADF material development is indicative of a field that has reached adolescence, with an exciting maturity still yet to come.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"9 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142816432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Introduction to Green Hydrogen","authors":"Shannon W. Boettcher*,&nbsp;","doi":"10.1021/acs.chemrev.4c0078710.1021/acs.chemrev.4c00787","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00787https://doi.org/10.1021/acs.chemrev.4c00787","url":null,"abstract":"","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"124 23","pages":"13095–13098 13095–13098"},"PeriodicalIF":51.4,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142842031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Introduction to Green Hydrogen","authors":"Shannon W. Boettcher","doi":"10.1021/acs.chemrev.4c00787","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00787","url":null,"abstract":"Published as part of &lt;i&gt;Chemical Reviews&lt;/i&gt; special issue “Green Hydrogen”. Green hydrogen, produced through water electrolysis powered by renewable energy, is an essential component of future global energy systems. In this thematic issue of &lt;i&gt;Chemical Reviews&lt;/i&gt;, we present a collection of reviews on some of the key research topics related to the design of components and understanding of the elementary processes in current and emerging water-electrolysis technologies. Green hydrogen is produced through water electrolysis powered by renewable energy sources, such as wind, solar, or hydropower, or possibly nuclear energy, resulting in low carbon emissions. (1) While the CO&lt;sub&gt;2&lt;/sub&gt; equivalent per kilogram of hydrogen produced (kgCO&lt;sub&gt;2&lt;/sub&gt;e/kgH&lt;sub&gt;2&lt;/sub&gt;) depends on many factors and requires a lifecycle analysis to assess, the U.S. Department of Energy’s Section 45 V tax credit targets green hydrogen at below 0.45 kgCO&lt;sub&gt;2&lt;/sub&gt;e/kgH&lt;sub&gt;2&lt;/sub&gt;. (2) This requires minimizing emissions throughout the entire production process, including electricity use and upstream activities. These emissions are much lower than “gray” hydrogen from reforming natural gas (CH&lt;sub&gt;4&lt;/sub&gt; + 2H&lt;sub&gt;2&lt;/sub&gt;O → CO&lt;sub&gt;2&lt;/sub&gt; + 4H&lt;sub&gt;2&lt;/sub&gt;) with ∼10 kgCO&lt;sub&gt;2&lt;/sub&gt;e/kgH&lt;sub&gt;2&lt;/sub&gt; and “blue” hydrogen using natural gas with carbon capture and ∼4 kgCO&lt;sub&gt;2&lt;/sub&gt;e/kgH&lt;sub&gt;2&lt;/sub&gt;. (3) Green hydrogen can dramatically reduce carbon-dioxide emissions associated with transportation and heavy industry. In transportation, hydrogen will be used where direct electrification is challenging, for example in aviation, shipping, and trucking. How the hydrogen is used will depend on the scale and cost of the (currently expensive) infrastructure to store and transport hydrogen. Pipelines are in principle cost-effective, but retrofitting existing natural-gas infrastructure is difficult (in part due to metals embrittlement discussed in this issue (4)). Hydrogen can also be combined with captured CO&lt;sub&gt;2&lt;/sub&gt; in efficient thermochemical processes to produce hydrocarbons, such as methanol or synthetic aviation fuels. (5) These renewable fuels can displace conventional fossil fuels without requiring major infrastructure changes, but CO&lt;sub&gt;2&lt;/sub&gt; capture (not discussed here) is an issue. (6) Hydrogen is also essential for the production and upgrading of biofuels, particularly synthetic fuels derived from renewable biomass. Substantial amounts of hydrogen─roughly &lt;sup&gt;1&lt;/sup&gt;/&lt;sub&gt;2&lt;/sub&gt;H&lt;sub&gt;2&lt;/sub&gt; per carbon atom─in the resulting fuel are used to remove heteroatoms via hydro-deoxygenation, hydro-desulfurization, and hydro-denitrogenation processes. (7) Green hydrogen is likely to serve important roles in the future fully renewable electric grid that must deal with intermittent wind and solar generation on the daily, seasonal, and decadal time scales. (8,9) When energy storage is needed to fill gaps in production over multiple days, electricity generation from fuel ce","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"77 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142805181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Bacterial Metallostasis: Metal Sensing, Metalloproteome Remodeling, and Metal Trafficking","authors":"Daiana A. Capdevila, Johnma J. Rondón, Katherine A. Edmonds, Joseph S. Rocchio, Matias Villarruel Dujovne, David P. Giedroc","doi":"10.1021/acs.chemrev.4c00264","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00264","url":null,"abstract":"Transition metals function as structural and catalytic cofactors for a large diversity of proteins and enzymes that collectively comprise the metalloproteome. Metallostasis considers all cellular processes, notably metal sensing, metalloproteome remodeling, and trafficking (or allocation) of metals that collectively ensure the functional integrity and adaptability of the metalloproteome. Bacteria employ both protein and RNA-based mechanisms that sense intracellular transition metal bioavailability and orchestrate systems-level outputs that maintain metallostasis. In this review, we contextualize metallostasis by briefly discussing the metalloproteome and specialized roles that metals play in biology. We then offer a comprehensive perspective on the diversity of metalloregulatory proteins and metal-sensing riboswitches, defining general principles within each sensor superfamily that capture how specificity is encoded in the sequence, and how selectivity can be leveraged in downstream synthetic biology and biotechnology applications. This is followed by a discussion of recent work that highlights selected metalloregulatory outputs, including metalloproteome remodeling and metal allocation by metallochaperones to both client proteins and compartments. We close by briefly discussing places where more work is needed to fill in gaps in our understanding of metallostasis.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"8 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142805266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}