Grace E. B. Redwine, Wade A. Braunecker* and Thomas Gennett*,
{"title":"","authors":"Grace E. B. Redwine, Wade A. Braunecker* and Thomas Gennett*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":29798,"journal":{"name":"ACS Materials Au","volume":"5 2","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":5.7,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsmaterialsau.4c00109","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144430895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Paul D. Goring, Amelia Newman, Christopher W. Jones* and Shelley D. Minteer*,
{"title":"","authors":"Paul D. Goring, Amelia Newman, Christopher W. Jones* and Shelley D. Minteer*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":29798,"journal":{"name":"ACS Materials Au","volume":"5 2","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":5.7,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsmaterialsau.5c00021","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144430897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fnu Gorky, Vashanti Storr, Jacek B. Jasinski and Maria L. Carreon*,
{"title":"","authors":"Fnu Gorky, Vashanti Storr, Jacek B. Jasinski and Maria L. Carreon*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":29798,"journal":{"name":"ACS Materials Au","volume":"5 2","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":5.7,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsmaterialsau.4c00159","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144358553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials AuPub Date : 2025-03-05DOI: 10.1021/acsmaterialsau.5c0002410.1021/acsmaterialsau.5c00024
Pieremanuele Canepa*,
{"title":"Correction to “Pushing Forward Simulation Techniques of Ion Transport in Ion Conductors for Energy Materials”","authors":"Pieremanuele Canepa*, ","doi":"10.1021/acsmaterialsau.5c0002410.1021/acsmaterialsau.5c00024","DOIUrl":"https://doi.org/10.1021/acsmaterialsau.5c00024https://doi.org/10.1021/acsmaterialsau.5c00024","url":null,"abstract":"","PeriodicalId":29798,"journal":{"name":"ACS Materials Au","volume":"5 3","pages":"609 609"},"PeriodicalIF":5.7,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsmaterialsau.5c00024","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143940778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials AuPub Date : 2025-03-05eCollection Date: 2025-05-14DOI: 10.1021/acsmaterialsau.5c00024
Pieremanuele Canepa
{"title":"Correction to \"Pushing Forward Simulation Techniques of Ion Transport in Ion Conductors for Energy Materials\".","authors":"Pieremanuele Canepa","doi":"10.1021/acsmaterialsau.5c00024","DOIUrl":"https://doi.org/10.1021/acsmaterialsau.5c00024","url":null,"abstract":"<p><p>[This corrects the article DOI: 10.1021/acsmaterialsau.2c00057.].</p>","PeriodicalId":29798,"journal":{"name":"ACS Materials Au","volume":"5 3","pages":"609"},"PeriodicalIF":5.7,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12082348/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144094951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials AuPub Date : 2025-03-04DOI: 10.1021/acsmaterialsau.4c0017210.1021/acsmaterialsau.4c00172
Grace M.O. Tieman, Fatima Shatila, Stefania Ceschia, Jeremy E. Wulff and Heather L. Buckley*,
{"title":"Photobleaching of Light-Activated Porphyrin-Functionalized Plastic Coupons for Potential Antimicrobial Applications","authors":"Grace M.O. Tieman, Fatima Shatila, Stefania Ceschia, Jeremy E. Wulff and Heather L. Buckley*, ","doi":"10.1021/acsmaterialsau.4c0017210.1021/acsmaterialsau.4c00172","DOIUrl":"https://doi.org/10.1021/acsmaterialsau.4c00172https://doi.org/10.1021/acsmaterialsau.4c00172","url":null,"abstract":"<p >Developing greener alternatives for harmful conventional cleaning agents is an important focus for preventing negative impacts on both the environment and human health. One potential alternative of interest is photodynamic inactivation (PDI), where a photosensitizing molecule is used to generate singlet oxygen (<sup>1</sup>O<sub>2</sub>) and other reactive oxygen species (ROS). ROS, <sup>1</sup>O<sub>2</sub> in particular, are known to react with cellular membranes of bacteria, resulting in cellular death. Porphyrinoids are one of these known light sensitizing species. In this work, zinc(II) 5,10,15,20-tetrakis((<i>N</i>-4-[3-(trifluoromethyl)-3<i>H</i>-diazirin-3-yl]benzyl)-4-pyridyl)-21<i>H</i>,23<i>H</i>-porphine tetrabromide is covalently attached to polyethylene terephthalate (PET) via thermal activation of a diazirine to initiate a C–H insertion. With the porphyrin now covalently bonded to the PET, the functionalized PET was assessed at a range of light intensities on its ability to generate <sup>1</sup>O<sub>2</sub> and for antimicrobial activity against <i>Escherichia coli</i>; the results were found to be correlated. Because photobleaching and resultant loss of activity are one of the weaknesses of PDI, the material was further assessed for its ability to withstand various photobleaching conditions. The photobleaching conditions assessed were high intensity light in dry and underwater conditions and ambient light, along with a set of dark controls. Results indicate that after 2 weeks of high intensity irradiation, the material still mediates singlet oxygen generation, albeit less efficiently. This shows promise for the use of this approach as an alternative to conventional cleaning agents.</p>","PeriodicalId":29798,"journal":{"name":"ACS Materials Au","volume":"5 3","pages":"537–546 537–546"},"PeriodicalIF":5.7,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsmaterialsau.4c00172","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143940777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ACS Materials AuPub Date : 2025-03-04eCollection Date: 2025-05-14DOI: 10.1021/acsmaterialsau.4c00172
Grace M O Tieman, Fatima Shatila, Stefania Ceschia, Jeremy E Wulff, Heather L Buckley
{"title":"Photobleaching of Light-Activated Porphyrin-Functionalized Plastic Coupons for Potential Antimicrobial Applications.","authors":"Grace M O Tieman, Fatima Shatila, Stefania Ceschia, Jeremy E Wulff, Heather L Buckley","doi":"10.1021/acsmaterialsau.4c00172","DOIUrl":"10.1021/acsmaterialsau.4c00172","url":null,"abstract":"<p><p>Developing greener alternatives for harmful conventional cleaning agents is an important focus for preventing negative impacts on both the environment and human health. One potential alternative of interest is photodynamic inactivation (PDI), where a photosensitizing molecule is used to generate singlet oxygen (<sup>1</sup>O<sub>2</sub>) and other reactive oxygen species (ROS). ROS, <sup>1</sup>O<sub>2</sub> in particular, are known to react with cellular membranes of bacteria, resulting in cellular death. Porphyrinoids are one of these known light sensitizing species. In this work, zinc(II) 5,10,15,20-tetrakis((<i>N</i>-4-[3-(trifluoromethyl)-3<i>H</i>-diazirin-3-yl]benzyl)-4-pyridyl)-21<i>H</i>,23<i>H</i>-porphine tetrabromide is covalently attached to polyethylene terephthalate (PET) via thermal activation of a diazirine to initiate a C-H insertion. With the porphyrin now covalently bonded to the PET, the functionalized PET was assessed at a range of light intensities on its ability to generate <sup>1</sup>O<sub>2</sub> and for antimicrobial activity against <i>Escherichia coli</i>; the results were found to be correlated. Because photobleaching and resultant loss of activity are one of the weaknesses of PDI, the material was further assessed for its ability to withstand various photobleaching conditions. The photobleaching conditions assessed were high intensity light in dry and underwater conditions and ambient light, along with a set of dark controls. Results indicate that after 2 weeks of high intensity irradiation, the material still mediates singlet oxygen generation, albeit less efficiently. This shows promise for the use of this approach as an alternative to conventional cleaning agents.</p>","PeriodicalId":29798,"journal":{"name":"ACS Materials Au","volume":"5 3","pages":"537-546"},"PeriodicalIF":5.7,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12082355/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144095036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}