SusMat最新文献 - Book学术

High‐performance porous transport layers for proton exchange membrane water electrolyzers 用于质子交换膜水电解器的高性能多孔传输层

IF 18.7 1区材料科学

SusMat Pub Date : 2024-07-18 DOI: 10.1002/sus2.230

Youkun Tao, Minhua Wu, Meiqi Hu, Xihua Xu, M. I. Abdullah, Jing Shao, Haijiang Wang

{"title":"High‐performance porous transport layers for proton exchange membrane water electrolyzers","authors":"Youkun Tao, Minhua Wu, Meiqi Hu, Xihua Xu, M. I. Abdullah, Jing Shao, Haijiang Wang","doi":"10.1002/sus2.230","DOIUrl":"https://doi.org/10.1002/sus2.230","url":null,"abstract":"Hydrogen is a favored alternative to fossil fuels due to the advantages of cleanliness, zero emissions, and high calorific value. Large‐scale green hydrogen production can be achieved using proton exchange membrane water electrolyzers (PEMWEs) with utilization of renewable energy. The porous transport layer (PTL), positioned between the flow fields and catalyst layers (CLs) in PEMWEs, plays a critical role in facilitating water/gas transport, enabling electrical/thermal conduction, and mechanically supporting CLs and membranes. Superior corrosion resistance is essential as PTL operates in acidic media with oxygen saturation and high working potential. This paper covers the development of high‐performance titanium‐based PTLs for PEMWEs. The heat/electrical conduction and mass transport mechanisms of PTLs and how they affect the overall performances are reviewed. By carefully designing and controlling substrate microstructure, protective coating, and surface modification, the performance of PTL can be regulated and optimized. The two‐phase mass transport characteristics can be enhanced by fine‐tuning the microstructure and surface wettability of PTL. The addition of a microporous top‐layer can effectively improve PTL|CL contact and increase the availability of catalytic sites. The anticorrosion coatings, which are crucial for chemical stability and conductivity of the PTL, are compared and analyzed in terms of composition, fabrication, and performance.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":18.7,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141827709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advanced carbon nitride‐based single‐atom photocatalysts 基于氮化碳的先进单原子光催化剂

IF 18.7 1区材料科学

SusMat Pub Date : 2024-07-18 DOI: 10.1002/sus2.229

Zifan Zhang, Kun Xiang, Haitao Wang, Xin Li, J. Zou, Guijie Liang, Jizhou Jiang

{"title":"Advanced carbon nitride‐based single‐atom photocatalysts","authors":"Zifan Zhang, Kun Xiang, Haitao Wang, Xin Li, J. Zou, Guijie Liang, Jizhou Jiang","doi":"10.1002/sus2.229","DOIUrl":"https://doi.org/10.1002/sus2.229","url":null,"abstract":"Single‐atom catalysts (SACs) have rapidly become a hot topic in photocatalytic research due to their unique physical and chemical properties, high activity, and high selectivity. Among many semiconductor carriers, the special structure of carbon nitride (C3N4) perfectly meets the substrate requirements for stabilizing SACs; they can also compensate for the photocatalytic defects of C3N4 materials by modifying energy bands and electronic structures. Therefore, developing advanced C3N4‐based SACs is of great significance. In this review, we focus on elucidating efficient preparation strategies and the burgeoning photocatalytic applications of C3N4‐based SACs. We also outline prospective strategies for enhancing the performance of SACs and C3N4‐based SACs in the future. A comprehensive array of methodologies is presented for identifying and characterizing C3N4‐based SACs. This includes an exploration of potential atomic catalytic mechanisms through the simulation and regulation of atomic catalytic behaviors and the synergistic effects of single or multiple sites. Subsequently, a forward‐looking perspective is adopted to contemplate the future prospects and challenges associated with C3N4‐based SACs. This encompasses considerations, such as atomic loading, regulatory design, and the integration of machine learning techniques. It is anticipated that this review will stimulate novel insights into the synthesis of high‐load and durable SACs, thereby providing theoretical groundwork for scalable and controllable applications in the field.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":18.7,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141825814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tuning on passive interfacial cooling of covalent organic framework hydrogel for enhancing freshwater and electricity generation 调节共价有机框架水凝胶的被动界面冷却以提高淡水和发电能力

IF 18.7 1区材料科学

SusMat Pub Date : 2024-07-17 DOI: 10.1002/sus2.231

Jianfei Wu, Ziwei Cui, Yuxuan Su, Dongfang Wu, Jundie Hu, J. Qu, Jianzhang Li, Fangyuan Kang, Dan Tian, Qichun Zhang, Yahui Cai

{"title":"Tuning on passive interfacial cooling of covalent organic framework hydrogel for enhancing freshwater and electricity generation","authors":"Jianfei Wu, Ziwei Cui, Yuxuan Su, Dongfang Wu, Jundie Hu, J. Qu, Jianzhang Li, Fangyuan Kang, Dan Tian, Qichun Zhang, Yahui Cai","doi":"10.1002/sus2.231","DOIUrl":"https://doi.org/10.1002/sus2.231","url":null,"abstract":"Developing an efficient freshwater and electricity co‐generation device (FECGD) can solve the shortage of freshwater and electricity. However, the poor salt resistance and refrigeration properties of the materials for FECGD put big challenges in the efficient and stable operation of these devices. To address these issues, we propose the covalent organic framework (COF) confined co‐polymerization strategy to prepare COF‐modified acrylamide cationic hydrogels (ACH‐COF), where hydrogen bonding interlocking between negatively charged polymer chains and COF pores can form a salt resistant hydrogel for stabilizing tunable passive interfacial cooling (TPIC). The FECPDs based on the TPIC and salt resistance of ACH‐COF display a maximum output power density of 2.28 W m−2, which is 4.3 times higher than that of a commercial thermoelectric generator under one solar radiation. The production rate of freshwater can reach 2.74 kg m−2 h−1. Our results suggest that the high efficiency and scalability of the FECGD can hold the promise of alleviating freshwater and power shortages.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":18.7,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141828761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable development of electroencephalography materials and technology 脑电图材料和技术的可持续发展

IF 28.4 1区材料科学

SusMat Pub Date : 2024-04-15 DOI: 10.1002/sus2.195

Ling Xiong, Nannan Li, Yiwu Luo, Lei Chen

{"title":"Sustainable development of electroencephalography materials and technology","authors":"Ling Xiong, Nannan Li, Yiwu Luo, Lei Chen","doi":"10.1002/sus2.195","DOIUrl":"https://doi.org/10.1002/sus2.195","url":null,"abstract":"Electroencephalogram (EEG) is one of the most important bioelectrical signals related to brain activity and plays a crucial role in clinical medicine. Driven by continuously expanding applications, the development of EEG materials and technology has attracted considerable attention. However, systematic analysis of the sustainable development of EEG materials and technology is still lacking. This review discusses the sustainable development of EEG materials and technology. First, the developing course of EEG is introduced to reveal its significance, particularly in clinical medicine. Then, the sustainability of the EEG materials and technology is discussed from two main aspects: integrated systems and EEG electrodes. For integrated systems, sustainability has been focused on the developing trend toward mobile EEG systems and big‐data monitoring/analyzing of EEG signals. Sustainability is related to miniaturized, wireless, portable, and wearable systems that are integrated with big‐data modeling techniques. For EEG electrodes and materials, sustainability has been comprehensively analyzed from three perspectives: performance of different material/structural categories, sustainable materials for EEG electrodes, and sustainable manufacturing technologies. In addition, sustainable applications of EEG have been presented. Finally, the sustainable development of EEG materials and technology in recent decades is summarized, revealing future possible research directions as well as urgent challenges.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":28.4,"publicationDate":"2024-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140703231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synergistic redox reactions toward co‐production of H2O2 and value‐added chemicals: Dual‐functional photocatalysis to achieving sustainability 协同氧化还原反应，共同生产 H2O2 和高附加值化学品：实现可持续发展的双功能光催化技术

IF 28.4 1区材料科学

SusMat Pub Date : 2024-04-11 DOI: 10.1002/sus2.192

Brenden Jing Su, J. J. Foo, Grayson Zhi Sheng Ling, Wee‐Jun Ong

{"title":"Synergistic redox reactions toward co‐production of H2O2 and value‐added chemicals: Dual‐functional photocatalysis to achieving sustainability","authors":"Brenden Jing Su, J. J. Foo, Grayson Zhi Sheng Ling, Wee‐Jun Ong","doi":"10.1002/sus2.192","DOIUrl":"https://doi.org/10.1002/sus2.192","url":null,"abstract":"Integrating H2O2 evolution with oxidative organic synthesis in a semiconductor‐driven photoredox reaction is highly attractive since H2O2 and high‐value chemicals can be concurrently produced using solar light as the only energy input. The dual‐functional photocatalytic approach, free from sacrificial agents, enables simultaneous production of H2O2 and high‐value organic chemicals. This strategy promises a green and sustainable organic synthesis with minimal greenhouse gas emissions. In this review, we first elucidate the fundamental principles of cooperative photoredox integration of H2O2 synthesis and selective organic oxidation with simultaneous utilization of photoexcited electrons and holes over semiconductor‐based photocatalysts. Afterwards, a thorough review on the recent advancements of cooperative photoredox synthesis of H2O2 and value‐added chemicals is presented. Notably, in‐depth discussions and insights into the techniques for unravelling the photoredox reaction mechanisms are elucidated. Finally, critical challenges and prospects in this thriving field are comprehensively discussed. It is envisioned that this review will serve as a pivotal guidance on the rational design of such dual‐functional photocatalytic system, thereby further stimulating the development of economical and environmentally benign H2O2 and high‐value chemicals production.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":28.4,"publicationDate":"2024-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140714286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A three‐way electrolyte with ternary solvents for high‐energy‐density and long‐cycling lithium–sulfur pouch cells 用于高能量密度和长循环锂硫袋电池的三元溶剂电解质

IF 28.4 1区材料科学

SusMat Pub Date : 2024-04-01 DOI: 10.1002/sus2.200

Zheng Li, Legeng Yu, Chen-Xi Bi, Xi‐Yao Li, Jin Ma, Xiang Chen, Xue‐Qiang Zhang, Aibing Chen, Haoting Chen, Zuoru Zhang, Li-zhen Fan, Bo‐Quan Li, Cheng Tang, Qiang Zhang

引用次数: 0

Photo‐enhanced uranium recovery from spent fuel reprocessing wastewater via S‐scheme 2D/0D C3N5/Fe2O3 heterojunctions 通过 S 型 2D/0D C3N5/Fe2O3 异质结从乏燃料后处理废水中进行光增强铀回收

IF 28.4 1区材料科学

SusMat Pub Date : 2024-04-01 DOI: 10.1002/sus2.199

Qi Meng, Linzhen Wu, Xiaoyong Yang, Ying Xiong, Fanpeng Kong, Tao Duan

{"title":"Photo‐enhanced uranium recovery from spent fuel reprocessing wastewater via S‐scheme 2D/0D C3N5/Fe2O3 heterojunctions","authors":"Qi Meng, Linzhen Wu, Xiaoyong Yang, Ying Xiong, Fanpeng Kong, Tao Duan","doi":"10.1002/sus2.199","DOIUrl":"https://doi.org/10.1002/sus2.199","url":null,"abstract":"Re‐extracting environmentally transportable hexavalent uranium from wastewater produced by spent fuel reprocessing using the photocatalytic technology is a crucial strategy to avoid uranium pollution and recover nuclear fuel strategic resources. Here, we have designed S‐scheme 2D/0D C3N5/Fe2O3 heterojunction photocatalysts based on the built‐in electric field and the energy band bending theory, and have further revealed the immobilization process of hexavalent uranium conversion into relatively insoluble tetravalent uranium in terms of thermodynamics and kinetics. According to the results, the hexavalent uranium removal and recovery ratios in wastewater are as high as 93.38% and 83.58%, respectively. Besides, C3N5/Fe2O3 heterojunctions also exhibit satisfactory catalytic activity and selectivity even in the presence of excessive impurity cations (including Na+, K+, Ca2+, Mg2+, Sr2+, and Eu3+) or various organics (such as xylene, tributylphosphate, pyridine, tannic acid, citric acid, and oxalic acid). It is believed that this work can provide a potential opportunity for S‐scheme heterojunction photocatalysts to re‐enrich uranium from spent fuel wastewater.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":28.4,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140778232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Water‐facilitated targeted repair of degraded cathodes for sustainable lithium‐ion batteries 水促进对降解正极的定向修复，实现可持续锂离子电池

IF 28.4 1区材料科学

SusMat Pub Date : 2024-03-21 DOI: 10.1002/sus2.194

Jiao Lin, Xiaodong Zhang, Zhujie Li, Ersha Fan, Xiaowei Lv, Renjie Chen, Feng Wu, Li Li

{"title":"Water‐facilitated targeted repair of degraded cathodes for sustainable lithium‐ion batteries","authors":"Jiao Lin, Xiaodong Zhang, Zhujie Li, Ersha Fan, Xiaowei Lv, Renjie Chen, Feng Wu, Li Li","doi":"10.1002/sus2.194","DOIUrl":"https://doi.org/10.1002/sus2.194","url":null,"abstract":"Directly repairing end‐of‐life lithium‐ion battery cathodes poses significant challenges due to the diverse compositions of the wastes. Here, we propose a water‐facilitated targeted repair strategy applicable to various end‐of‐life batches and cathodes. The process involves initiating structural repair and reconstructing particle morphology in degraded LiMn2O4 (LMO) through an additional thermal drive post‐ambient water remanganization, achieving elemental repair. Compared to solid‐phase repair, the resulting LMO material exhibits superior electrochemical and kinetic characteristics. The theoretical analysis highlights the impact of Mn defects on the structural stability and electron transfer rate of degraded materials. The propensity of Mn ions to diffuse within the Mn layer, specifically occupying the Mn 16d site instead of the Li 8a site, theoretically supports the feasibility of ambient water remanganization. Moreover, this method proves effective in the relithiation of degraded layered cathode materials, yielding single crystals. By combining low energy consumption, environmental friendliness, and recyclability, our study proposes a sustainable approach to utilizing spent batteries. This strategy holds the potential to enable the industrial direct repair of deteriorated cathode materials.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":28.4,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140221621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrocatalytic synthesis of C–N coupling compounds from CO2 and nitrogenous species 利用二氧化碳和含氮物质电催化合成 C-N 偶联化合物

IF 28.4 1区材料科学

SusMat Pub Date : 2024-03-12 DOI: 10.1002/sus2.193

Zheng Zhang, Danyang Li, Yunchuan Tu, Jiao Deng, Huiting Bi, Yongchao Yao, Yan Wang, Tingshuai Li, Yongsong Luo, Shengjun Sun, D. Zheng, S. Carabineiro, Zhou Chen, Junjiang Zhu, Xuping Sun

{"title":"Electrocatalytic synthesis of C–N coupling compounds from CO2 and nitrogenous species","authors":"Zheng Zhang, Danyang Li, Yunchuan Tu, Jiao Deng, Huiting Bi, Yongchao Yao, Yan Wang, Tingshuai Li, Yongsong Luo, Shengjun Sun, D. Zheng, S. Carabineiro, Zhou Chen, Junjiang Zhu, Xuping Sun","doi":"10.1002/sus2.193","DOIUrl":"https://doi.org/10.1002/sus2.193","url":null,"abstract":"The electrocatalytic synthesis of C–N coupling compounds from CO2 and nitrogenous species not only offers an effective avenue to achieve carbon neutrality and reduce environmental pollution, but also establishes a route to synthesize valuable chemicals, such as urea, amide, and amine. This innovative approach expands the application range and product categories beyond simple carbonaceous species in electrocatalytic CO2 reduction, which is becoming a rapidly advancing field. This review summarizes the research progress in electrocatalytic urea synthesis, using N2, NO2−, and NO3− as nitrogenous species, and explores emerging trends in the electrosynthesis of amide and amine from CO2 and nitrogen species. Additionally, the future opportunities in this field are highlighted, including electrosynthesis of amino acids and other compounds containing C–N bonds, anodic C–N coupling reactions beyond water oxidation, and the catalytic mechanism of corresponding reactions. This critical review also captures the insights aimed at accelerating the development of electrochemical C–N coupling reactions, confirming the superiority of this electrochemical method over the traditional techniques.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":28.4,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140250793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dendrite‐free Zn deposition initiated by nanoscale inorganic–organic coating‐modified 3D host for stable Zn‐ion battery 由纳米级无机-有机涂层修饰的三维宿主引发的无枝晶锌沉积，用于稳定的锌离子电池

IF 28.4 1区材料科学

SusMat Pub Date : 2024-03-04 DOI: 10.1002/sus2.189

Jiaming Dong, Junwen Duan, Ruirui Cao, Wang Zhang, Kangkang Fang, Hao Yang, Ying Liu, Zhitao Shen, Fumin Li, Rong Liu, Mengqi Jin, Longhui Lei, Huilin Li, Chong Chen

{"title":"Dendrite‐free Zn deposition initiated by nanoscale inorganic–organic coating‐modified 3D host for stable Zn‐ion battery","authors":"Jiaming Dong, Junwen Duan, Ruirui Cao, Wang Zhang, Kangkang Fang, Hao Yang, Ying Liu, Zhitao Shen, Fumin Li, Rong Liu, Mengqi Jin, Longhui Lei, Huilin Li, Chong Chen","doi":"10.1002/sus2.189","DOIUrl":"https://doi.org/10.1002/sus2.189","url":null,"abstract":"A 3D nanostructured scaffold as the host for zinc enables effective inhibition of anodic dendrite growth. However, the increased electrode/electrolyte interface area provided by using 3D matrices exacerbates the passivation and localized corrosion of the Zn anode, ultimately bringing about the degradation of the electrochemical performance. Herein, a nanoscale coating of inorganic–organic hybrid (α‐In2Se3‐Nafion) onto a flexible carbon nanotubes (CNTs) framework (ISNF@CNTs) is designed as a Zn plating/stripping scaffold to ensure uniform Zn nucleation, thus achieving a dendrite‐free and durable Zn anode. The introduced inorganic–organic interfacial layer is dense and sturdy, which hinders the direct exposure of deposited Zn to electrolytes and mitigates the side reactions. Meanwhile, the zincophilic nature of ISNF can largely reduce the nucleation energy barrier and promote the ion‐diffusion transportation. Consequently, the ISNF@CNTs@Zn electrode exhibits a low‐voltage hysteresis and a superior cycling life (over 1500 h), with dendrite‐free Zn‐plating behaviors in a typical symmetrical cell test. Additionally, the superior feature of ISNF@CNTs@Zn anode is further demonstrated by Zn‐MnO2 cells in both coin and flexible quasi‐solid‐state configurations. This work puts forward an inspired remedy for advanced Zn‐ion batteries.","PeriodicalId":29781,"journal":{"name":"SusMat","volume":null,"pages":null},"PeriodicalIF":28.4,"publicationDate":"2024-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140266496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0