Siwei Fan, Yijie Liu, Yun Gao, Yang Liu, Yun Qiao, Li Li, Shu‐Lei Chou
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The design and synthesis of Prussian blue analogs as a sustainable cathode for sodium‐ion batteries
Sodium‐ion batteries (SIBs) present great appeal in various energy storage systems, especifically for stationary grid storage, on account of the abundance of sources and low cost. Unfortunately, the commercialization of SIBs is mainly limited by available electrode materials, especially for the cathodes. Prussian blue analogs (PBAs), emerge as a promising alternative for their structural feasibility in the application of SIBs. Decreasing the defects (vacancies and coordinated water) is an effective strategy to achieve superior electrochemical performance during the synthetic processes. Herein, we summarize crystal structures, synthetic methods, electrochemical mechanisms, and the influences of synthesis conditions of PBAs in detail. This comprehensive overview on the current research progresses of PBAs will give guides and directions to solve the existing problems for their application in SIBs.
期刊介绍:
SusMat aims to publish interdisciplinary and balanced research on sustainable development in various areas including materials science, engineering, chemistry, physics, and ecology. The journal focuses on sustainable materials and their impact on energy and the environment. The topics covered include environment-friendly materials, green catalysis, clean energy, and waste treatment and management. The readership includes materials scientists, engineers, chemists, physicists, energy and environment researchers, and policy makers. The journal is indexed in CAS, Current Contents, DOAJ, Science Citation Index Expanded, and Web of Science. The journal highly values innovative multidisciplinary research with wide impact.