Composites Science and Technology最新文献

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Assessing the validity of micro-pillar compression for determining strength and stiffness of carbon fibres 评价微柱压缩法测定碳纤维强度和刚度的有效性
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-09-06 DOI: 10.1016/j.compscitech.2025.111362
V. Keryvin , M. Ueda , G. Kermouche , Y. Marthouret , S. Sao-Joao
{"title":"Assessing the validity of micro-pillar compression for determining strength and stiffness of carbon fibres","authors":"V. Keryvin ,&nbsp;M. Ueda ,&nbsp;G. Kermouche ,&nbsp;Y. Marthouret ,&nbsp;S. Sao-Joao","doi":"10.1016/j.compscitech.2025.111362","DOIUrl":"10.1016/j.compscitech.2025.111362","url":null,"abstract":"<div><div>The longitudinal compressive mechanical behaviour of polyacrylonitrile (PAN)-precursor T300 carbon fibres was assessed using micro-pillar compression testing, with direct comparison to published data on entire fibre compression. Micro-pillars, fabricated via focused ion beam (FIB) milling, exhibited compressive modulus, strength, and failure strain values closely matching those of whole fibres, thereby validating this microscale technique for accurate stiffness and strength measurements. A progressive reduction in stiffness with increasing compressive strain — indicative of non-linear elasticity — was directly observed and quantified under compression for the first time. Although the failure modes of micro-pillars differed from those of intact fibres, the results support the hypothesis of a mechanically homogeneous fibre microstructure and suggest the presence of a stabilising outer sheath that delays failure initiation. These findings reinforce the methodological basis for small-scale mechanical testing of carbon fibres and carry implications for multiscale modelling and the prediction of compressive strength in unidirectional composite plies.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"272 ","pages":"Article 111362"},"PeriodicalIF":9.8,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145020724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-network aramid nanofibers/cellulose Nanofibers/MXene aerogels for lightweight, pulse electromagnetic interference shielding 双网芳纶纳米纤维/纤维素纳米纤维/MXene气凝胶轻量化,脉冲电磁干扰屏蔽
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-09-06 DOI: 10.1016/j.compscitech.2025.111373
Shuaijie Liu , Tianyi Zhang , Bowen Tan , Jinglun Guo , Wei Zhong , Nannan Chen , Han Zou , Le Cao , Xuqing Liu
{"title":"Dual-network aramid nanofibers/cellulose Nanofibers/MXene aerogels for lightweight, pulse electromagnetic interference shielding","authors":"Shuaijie Liu ,&nbsp;Tianyi Zhang ,&nbsp;Bowen Tan ,&nbsp;Jinglun Guo ,&nbsp;Wei Zhong ,&nbsp;Nannan Chen ,&nbsp;Han Zou ,&nbsp;Le Cao ,&nbsp;Xuqing Liu","doi":"10.1016/j.compscitech.2025.111373","DOIUrl":"10.1016/j.compscitech.2025.111373","url":null,"abstract":"<div><div>Achieving effective shielding against high-power electromagnetic pulses (HEMPs) without compromising mass is critical for aerospace, defence and wearable systems, yet remains elusive for most lightweight materials. In this work, we present a multifunctional composite aerogel constructed from aramid nanofibers (ANFs), cellulose nanofibers (CNF), and MXene nanosheets. A dual-network architecture is formed through hydrogen bonding and electrostatic interactions, yielding a highly porous structure with integrated strength, flexibility, and electrical functionality. The aerogel exhibits an exceptional compressive stress of 0.48 MPa at 60 % strain, broadband shielding effectiveness exceeding 90 dB in the X-band (with &gt;90 % absorption contribution), and thermal stability up to 150 °C. Conventional shielding metrics based on continuous-wave (CW) frequency-domain evaluations often fail to capture material behavior under such scenarios. To evaluate the aerogel's transient protection capabilities, we further employed time-domain shielding effectiveness (TDSE) simulations based on finite-difference time-domain (FDTD) modeling. The results confirm strong suppression of electric field peaks, derivatives, and energy flux under EMP-like illumination, demonstrating the aerogel's viability in pulse-rich environments such as aerospace and defense systems. This study offers a versatile and scalable platform for engineering aerogels with high-performance electromagnetic resilience, bridging the gap between material design and real-world operational requirements.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"272 ","pages":"Article 111373"},"PeriodicalIF":9.8,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145047523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel composite material of aramid fiber-reinforced polyurea elastomer matrix: mechanical properties and ballistic performance 一种新型芳纶纤维增强聚脲弹性体复合材料:力学性能和弹道性能
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-09-05 DOI: 10.1016/j.compscitech.2025.111370
Zhiyuan Wang , Lihong Yang , Shijie Yang , Peng Liu , Linzhi Wu
{"title":"A novel composite material of aramid fiber-reinforced polyurea elastomer matrix: mechanical properties and ballistic performance","authors":"Zhiyuan Wang ,&nbsp;Lihong Yang ,&nbsp;Shijie Yang ,&nbsp;Peng Liu ,&nbsp;Linzhi Wu","doi":"10.1016/j.compscitech.2025.111370","DOIUrl":"10.1016/j.compscitech.2025.111370","url":null,"abstract":"<div><div>A novel aramid fiber-reinforced composite with a polyurea elastomer matrix was fabricated and systematically evaluated for its mechanical properties and ballistic performance. Five groups of composite laminates with different polyurea contents, together with a reference epoxy-based laminate, were prepared. A series of quasi-static mechanical tests and ballistic impact experiments were then performed on these laminates. Furthermore, Multi scale finite element simulations were conducted to investigate the impact response and failure mechanisms. The results demonstrate that the incorporation of polyurea as the matrix markedly enhances the energy absorption capacity, deformability, and ballistic resistance of the composite laminates compared to epoxy-based laminates. A polyurea content of 20 % was identified as providing the optimal balance between mechanical strength and toughness, resulting in the higher ballistic limit and specific energy absorption. The polyurea matrix enables greater fiber deformation and a more extensive stress distribution during impact, thereby enhancing energy dissipation. These findings indicate that polyurea elastomer matrix confers substantial advantages for the design of advanced, lightweight ballistic protective composites.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111370"},"PeriodicalIF":9.8,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145004002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elevating the performance of bio-based epoxidized natural rubber/natural rubber/silica nanocomposites via strategic manipulation of silica phase-selective distribution 通过调控二氧化硅相选择分布提高生物基环氧化天然橡胶/天然橡胶/二氧化硅纳米复合材料性能
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-09-05 DOI: 10.1016/j.compscitech.2025.111372
Zixuan Wang , Ruoyu Wang , Yanguo Li , Yanjin Zhu , Weixiao Song , Xiaohui Wu , Guo-Hua Hu , Liqun Zhang
{"title":"Elevating the performance of bio-based epoxidized natural rubber/natural rubber/silica nanocomposites via strategic manipulation of silica phase-selective distribution","authors":"Zixuan Wang ,&nbsp;Ruoyu Wang ,&nbsp;Yanguo Li ,&nbsp;Yanjin Zhu ,&nbsp;Weixiao Song ,&nbsp;Xiaohui Wu ,&nbsp;Guo-Hua Hu ,&nbsp;Liqun Zhang","doi":"10.1016/j.compscitech.2025.111372","DOIUrl":"10.1016/j.compscitech.2025.111372","url":null,"abstract":"<div><div>Epoxidized natural rubber (ENR) combines the excellent elasticity and mechanical strength of natural rubber (NR) with the polarity, oil resistance, and wet skid resistance imparted by the introduction of epoxy groups. In particular, ENR show strong affinity with silica, endowing it great development potential in the field of green tires. However, in the silica-based composite system, ENR and NR is incompatible and forms a phase-separated structure, hindering the performance improvement of the composite. In this work, silane coupling agent bis(γ-triethoxysilylpropyl) tetrasulfide (TESPT) was pre-incorporated into NR to prepare NR-TESPT masterbatch to improve the affinity between the NR and silica. NR-TESPT masterbatch with different TESPT content were prepared and mixed with ENR and silica to fabricate ENR/NR/silica (ENR/NR-xT) composites. The phase-selective dispersion mechanism of silica in the ENR and NR matrix was observed by AFM-Nano-FTIR and TEM. The results shows that both the ENR phase and the NR-TESPT phase can form strong coupling interactions with silica. And a double-coupling structure of epoxy-silanol and silanol-TESPT-double bond is formed to enhance the uniform silica dispersion and the comprehensive properties of composites. The ENR/NR-4T composite exhibits significant performance improvements compared to the NR-6T composite, with a 115 % increase in anti-wet skid performance, a 30.9 % increase in tensile strength, and a 61.9 % increase in tear strength.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111372"},"PeriodicalIF":9.8,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145019199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A SCA-based concurrent multiscale thermo-mechanical model for transient thermal ablative and mechanical damage properties of SiFPRCs 基于sca的sifrcs瞬态热烧蚀和力学损伤多尺度并行模型研究
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-09-05 DOI: 10.1016/j.compscitech.2025.111368
Shuo Cao , Yiqi Mao , Wenyang Liu , Shujuan Hou
{"title":"A SCA-based concurrent multiscale thermo-mechanical model for transient thermal ablative and mechanical damage properties of SiFPRCs","authors":"Shuo Cao ,&nbsp;Yiqi Mao ,&nbsp;Wenyang Liu ,&nbsp;Shujuan Hou","doi":"10.1016/j.compscitech.2025.111368","DOIUrl":"10.1016/j.compscitech.2025.111368","url":null,"abstract":"<div><div>Accurate numerical simulation of the ablation process in silica fiber-reinforced phenolic resin composites (SiFPRCs) is critical for advanced thermal protection applications. However, conventional dual-scale finite element (FE<sup>2</sup>) methods incur prohibitive computational costs when capturing the strongly nonlinear responses induced by multiple dissipative mechanisms during thermochemical ablation. To address this issue, we propose a dual-scale framework (FEM-SCA) that integrates the finite element method (FEM) with self-consistent clustering analysis (SCA). At the macroscopic level, FEM captures the overall thermo-mechanical response, while nested mesoscale representative volume elements (RVEs) are solved using the SCA to capture dissipative processes, including heat radiation, phenolic resin pyrolysis, thermal blocking, silica fiber phase transitions, carbon-silicon reaction, and mechanical degradation. A staggered incremental scheme enables efficient transient coupling across scales. Validation against FE<sup>2</sup> benchmarks demonstrates that FEM-SCA reproduces thermal conduction and pyrolysis behavior with &lt;5 % error, while reducing computational cost by over two orders of magnitude. The proposed framework offers a computationally efficient and physically grounded approach for simulating ablation in woven composites.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"272 ","pages":"Article 111368"},"PeriodicalIF":9.8,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145047521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A mesoscopic modeling scheme for 3D virtual testing of woven prepregs during forming processes 编织预浸料成形过程三维虚拟测试的细观建模方案
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-09-01 DOI: 10.1016/j.compscitech.2025.111364
Deyong Sun , Meiyu Liu , Chongrui Tang , Yuncong Feng , Qingbin Zheng , Weizhao Zhang
{"title":"A mesoscopic modeling scheme for 3D virtual testing of woven prepregs during forming processes","authors":"Deyong Sun ,&nbsp;Meiyu Liu ,&nbsp;Chongrui Tang ,&nbsp;Yuncong Feng ,&nbsp;Qingbin Zheng ,&nbsp;Weizhao Zhang","doi":"10.1016/j.compscitech.2025.111364","DOIUrl":"10.1016/j.compscitech.2025.111364","url":null,"abstract":"<div><div>Accurate simulation of the forming processes of woven prepregs at the macroscale requires input of comprehensive material parameters that are typically obtained through extensive experimental characterization, which is resource-intensive and time-consuming. As improvement, an innovative finite element analysis (FEA) modeling scheme was developed at mesoscale for 3D virtual testing of the composite prepregs’ properties under the complex process condition. This modeling scheme was realized through the commercial finite element analysis software Abaqus/Explicit with a user-defined material subroutine (VUMAT). This modeling scheme employs micro-CT based geometry reconstruction, continuum elements and a transversely isotropic hyperelastic constitutive model to simulate yarns as continuous bodies. Physically meaningful parameters are input to the constitutive model to elucidate the deformation mechanism. A finite element (FE) homogenization technique based on reaction force was also established to facilitate correct meso-to-macro transfer of material properties for multiscale simulation, as well as comparison with experimental data, for the fabric composites. Once completed, simulation results from this FEA modeling scheme were validated against a series of experiments typically utilized to characterize prepregs being formed, including uniaxial tension, bias-extension and out-of-plane compaction. The validation demonstrates that this modeling scheme can accurately capture key 3D deformation of the woven composite prepregs at mesoscale under various process conditions, providing a comprehensive tool to numerically identify forming behavior of the prepregs while minimizing the expensive experiments.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111364"},"PeriodicalIF":9.8,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144925129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiscale investigation of torsional failure mechanisms in 3D braided carbon fiber composite shafts via integrated CT, 3D-DIC, and AE analysis 基于集成CT、3D- dic和AE分析的三维编织碳纤维复合材料轴扭转破坏机制的多尺度研究
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-08-30 DOI: 10.1016/j.compscitech.2025.111366
Jikang Li , Zheng Liu , Xuecheng Liu , Zhe Zhang , Xu Chen
{"title":"Multiscale investigation of torsional failure mechanisms in 3D braided carbon fiber composite shafts via integrated CT, 3D-DIC, and AE analysis","authors":"Jikang Li ,&nbsp;Zheng Liu ,&nbsp;Xuecheng Liu ,&nbsp;Zhe Zhang ,&nbsp;Xu Chen","doi":"10.1016/j.compscitech.2025.111366","DOIUrl":"10.1016/j.compscitech.2025.111366","url":null,"abstract":"<div><div>This study systematically investigated the torsional damage evolution and failure mechanisms of 3D braided carbon fiber/epoxy resin composites through an integrated multiscale methodology combining static torsion mechanical testing, computed tomography (CT) damage analysis, three-dimensional digital image correlation (3D-DIC), and acoustic emission (AE) monitoring. Experimental results revealed that the 3D braided carbon fiber-reinforced composite specimens exhibited approximately linear elastic behavior during torsion. An increase in braiding angle (15°–45°) enhanced shear modulus and strength by 67 %, but reduced failure strain to 0.61 % while shifting the failure mode dominance from ductile matrix deformation to brittle fiber fracture. CT analysis demonstrated that compressive fiber bundle failure governed mechanical performance, with damage progression initiating as interfacial debonding (at 60 % load), progressing through crack bifurcation (at 80 % load), and culminating in fiber buckling failure. 3D-DIC quantitatively characterized the strain heterogeneity regulated by braiding topology, showing that maximum shear strain decreased by 67 % with increasing braiding angles. Notably, 45° specimens developed mesh-like strain distribution pattern, revealing the directional regulation of load transfer paths through spatial fiber entanglement. The proposed AE signal processing framework integrating Hilbert-Huang transform with frequency-domain calibration techniques successfully identified three characteristic damage modes: matrix cracking (100–200 kHz), interface debonding (200–320 kHz), and fiber fracture (320–420 kHz). Statistical analysis indicated matrix damage dominated the failure process (75.5–80 % contribution), occurring during early loading stages, whereas fiber failure emerged near final rupture. Higher braiding angles were found to suppress matrix damage through enhanced fiber interlocking effects.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111366"},"PeriodicalIF":9.8,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144921172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pyrolysis-driven progressive microstructural degradation in carbon/phenolic needle-punched composites 热解驱动的碳/酚醛针刺复合材料的渐进微观结构降解
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-08-30 DOI: 10.1016/j.compscitech.2025.111367
Yu Chen , Yiqi Mao , Jinjin Wang , Fei Chang , Ran Tao
{"title":"Pyrolysis-driven progressive microstructural degradation in carbon/phenolic needle-punched composites","authors":"Yu Chen ,&nbsp;Yiqi Mao ,&nbsp;Jinjin Wang ,&nbsp;Fei Chang ,&nbsp;Ran Tao","doi":"10.1016/j.compscitech.2025.111367","DOIUrl":"10.1016/j.compscitech.2025.111367","url":null,"abstract":"<div><div>Carbon fiber-reinforced needle-punched composites are widely used in thermal protection systems; however, the elucidation of the structural damage mechanism caused by their heterogeneous materials and nonlinear thermodynamic behavior under extreme conditions remains unclear. To reveal the failure mechanisms of materials in high-temperature environments, this study systematically investigates pyrolysis-driven progressive microstructural degradation in carbon/phenolic needle-punched composites. Oxidation-kerosene ablation experiments were conducted at various temperatures, with the residual bending mechanical properties of the materials assessed through three-point bending tests combined with digital image correlation techniques. To track microstructural evolution, we performed X-ray computed tomography and scanning electron microscopy on the needle-punched composites. Complementary to experimental characterization, we developed a microstructural model of the needle-punched composite and simulated its damage under thermo-mechanical coupled degradation using Abaqus user-defined subroutines (UMAT and UMATHT), thereby elucidating pyrolysis-driven microstructural evolution. The results indicate that the degradation of the composites’ mechanical properties due to ablation pyrolysis is primarily attributed to the alteration of microstructural morphology, including fiber fracture, crack propagation, pore coalescence, and cavity formation induced by pyrolytic oxidation.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111367"},"PeriodicalIF":9.8,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144925124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-layer structural strategy in needle-punched fabrics for synergistic improving mechanical and thermal performance of nanoporous phenolic composites 针刺织物的双层结构策略协同提高纳米多孔酚醛复合材料的力学和热性能
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-08-30 DOI: 10.1016/j.compscitech.2025.111365
Hongxiang Cai , Bo Niu , Yaolan Li , Peiqi Yang , Yu Cao , Zhe Su , Yi Luo , Donghui Long
{"title":"Dual-layer structural strategy in needle-punched fabrics for synergistic improving mechanical and thermal performance of nanoporous phenolic composites","authors":"Hongxiang Cai ,&nbsp;Bo Niu ,&nbsp;Yaolan Li ,&nbsp;Peiqi Yang ,&nbsp;Yu Cao ,&nbsp;Zhe Su ,&nbsp;Yi Luo ,&nbsp;Donghui Long","doi":"10.1016/j.compscitech.2025.111365","DOIUrl":"10.1016/j.compscitech.2025.111365","url":null,"abstract":"<div><div>Needle-punched fabrics are widely utilized to reinforce ablative nanoporous phenolic composites (NPCs) due to their cost-effectiveness and design flexibility. However, achieving a structural design that synergistically optimizes both mechanical and thermal performance remains a significant challenge. This study aims to address this issue by developing a dual-layer needle-punched fabric structure consisting of a top high-density ablation layer and a bottom low-density insulation layer. NPCs with varying ablation layer thickness ratios (13 %, 33 %, and 53 %) are fabricated and systematically evaluated through macro-micro mechanical tests, heat transfer test, and systematic high-temperature ablation experiments. Results show that NPC with a 33 % ablation layer ratio achieves the highest tensile strength (42.6 ± 0.82 MPa), owing to an optimal balance between load-bearing capacity and strain tolerance. In-situ micro-CT analysis under tensile loading reveals that the high-density ablation layer significantly enhances both strength and ductility by providing tightly woven fiber yarns. Heat transfer simulations indicate that the high-density layer serves as the primary heat conduction path, while the low-density layer effectively reduces overall thermal conductivity by limiting solid fiber heat transfer. Oxy-acetylene ablation tests at 2000 °C and 3200 °C demonstrate that the dual-layer structure reduces the linear ablation rate by approximately 25 % compared with single-layer NPCs, as the tightly woven ablation layer effectively withstands extreme heat flux. The present work offers new insights into the structural optimization of needle-punched fabric reinforced NPCs and provide design guidelines for advanced thermal protection materials in extreme aerospace environments.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111365"},"PeriodicalIF":9.8,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144932912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel high-temperature resistant Poly(arylene ether ketone) sizing agent containing graphene oxide: Achieve multiscale interfacial enhancement in CF/PEEK composites 含氧化石墨烯的新型耐高温聚芳醚酮施胶剂:在CF/PEEK复合材料中实现多尺度界面增强
IF 9.8 1区 材料科学
Composites Science and Technology Pub Date : 2025-08-29 DOI: 10.1016/j.compscitech.2025.111363
Xiaonan Ji , Huihuang Ma , Luo Luo , Chunhua Zhou , Qunfang Lin , Xiaodong Zhou
{"title":"A novel high-temperature resistant Poly(arylene ether ketone) sizing agent containing graphene oxide: Achieve multiscale interfacial enhancement in CF/PEEK composites","authors":"Xiaonan Ji ,&nbsp;Huihuang Ma ,&nbsp;Luo Luo ,&nbsp;Chunhua Zhou ,&nbsp;Qunfang Lin ,&nbsp;Xiaodong Zhou","doi":"10.1016/j.compscitech.2025.111363","DOIUrl":"10.1016/j.compscitech.2025.111363","url":null,"abstract":"<div><div>Optimizing the interfacial adhesion in carbon fiber reinforced polyether ether ketone (CF/PEEK) composites is crucial for their mechanical performance, yet conventional enhancement strategies often face limitations in thermal stability, compatibility, and environmental impact. To overcome these challenges, a novel aqueous poly(aryl ether ketone)-based sizing agent (FPEKC), functionalized with trifluoromethyl (-CF<sub>3</sub>) and phthalide moieties, was designed and synthesized through molecular engineering. The synthesized FPEKC exhibited outstanding thermal stability (T<sub>-5 %</sub> = 500.45 °C), ensuring excellent structural integrity throughout typical composite processing conditions (∼380 °C). The environmentally sustainable, water-based FPEKC-GO sizing agent prepared via an emulsion-solvent evaporation technique formed uniformly dispersed nanoparticles with an average diameter of approximately 60 nm. The intrinsic structural compatibility between FPEKC and the PEEK matrix facilitated extensive molecular diffusion and interchain entanglement at the interface. Additionally, the introduction of graphene oxide (GO) nanosheets into the FPEKC slurry established robust chemical interactions at the fiber-matrix interface, including hydrogen bonds and π-π stacking, as well as nanoscale mechanical interlocking, achieving multi-scale interface enhancement. The interfacial shear strength (IFSS) of the CF/PEEK composite material was remarkably enhanced by 65.56 %, reaching a value of 92.38 MPa. Furthermore, the composite sizing agent simultaneously improved the tensile strength of individual carbon fiber filaments by 5.56 %, effectively mitigating interfacial defects and stress concentrations. This research demonstrates an innovative multiscale interface engineering strategy, providing new insights and practical methodologies for developing environmentally friendly, high-performance CF/PEEK composites.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"271 ","pages":"Article 111363"},"PeriodicalIF":9.8,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144921171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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