Composites Science and Technology最新文献

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Highly sensitive mechanochromism and high-contrast multicolor switching in epoxy nanocomposites for stress visualization and damage monitoring 用于应力可视化和损伤监测的环氧纳米复合材料的高灵敏度机械变色和高对比度多色开关
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-14 DOI: 10.1016/j.compscitech.2025.111184
Zaiping Zou , Jiajun Li , Yingsheng Lai , Mao Chen , Yinyu Zhang , Yeping Wu , Xiuli Zhao , Zhongtao Chen
{"title":"Highly sensitive mechanochromism and high-contrast multicolor switching in epoxy nanocomposites for stress visualization and damage monitoring","authors":"Zaiping Zou ,&nbsp;Jiajun Li ,&nbsp;Yingsheng Lai ,&nbsp;Mao Chen ,&nbsp;Yinyu Zhang ,&nbsp;Yeping Wu ,&nbsp;Xiuli Zhao ,&nbsp;Zhongtao Chen","doi":"10.1016/j.compscitech.2025.111184","DOIUrl":"10.1016/j.compscitech.2025.111184","url":null,"abstract":"<div><div>Epoxy resins are widely used in coatings and composites due to their excellent comprehensive properties, but they also present new challenges in stress sensing and damage detection. Mechanochromism, which implies that a material can change color in response to mechanical stimulation, could be a potential tool to solve this problem. However, researches on mechanochromic polymers have primarily focused on elastomers and gels. For rigid epoxy thermosets, it is still difficult to achieve significant mechanochromism, let alone multicolor changes under different mechanical stimuli. In this study, SiO<sub>2</sub> nanoparticles (NPs) are introduced into a rhodamine (Rh)-modified epoxy system to improve its mechanochromic response. When the nanocomposite is mechanically stimulated, concentrated stress around the heterogeneous interfaces induces massive ring-opening reactions of Rh in these areas, resulting in a vivid red color change. In addition, direct observation of the stress-concentration effect near the rigid particles is realized by using the visualization properties of the Rh moiety, and combined with finite element analysis to elucidate the enhancement mechanism of the mechanochromism. Furthermore, how the NPs affect multicolor mechanochromism of epoxy thermosets is also investigated. Nanocomposites with two different mechanochromophores exhibit stress- and time-dependent five-color variations due to the different activation of the Rh and disulfide moieties, whereas samples without NPs only show a triple-color change with lower contrast. This strategy is suitable for use in practical applications owning to its ability to display the stress intensity and stress history of a material through high-contrast multicolor switching. Several proof-of-concept scenarios are presented.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111184"},"PeriodicalIF":8.3,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143844844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Arch-inspired flexible dual-mode sensor with ultra-high linearity based on carbon nanomaterials/conducting polymer composites for bioelectronic monitoring and thermal perception 基于碳纳米材料/导电聚合物复合材料的具有超高线性度的拱形启发式柔性双模传感器,用于生物电子监测和热感知
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-11 DOI: 10.1016/j.compscitech.2025.111182
Chaoyue Chen , Peng Wang , Weiqiang Hong , Xiaowen Zhu , Jianhong Hao , Congguang He , Hao Hou , Deli Kong , Tianqi Liu , Yunong Zhao , Xiaohui Guo
{"title":"Arch-inspired flexible dual-mode sensor with ultra-high linearity based on carbon nanomaterials/conducting polymer composites for bioelectronic monitoring and thermal perception","authors":"Chaoyue Chen ,&nbsp;Peng Wang ,&nbsp;Weiqiang Hong ,&nbsp;Xiaowen Zhu ,&nbsp;Jianhong Hao ,&nbsp;Congguang He ,&nbsp;Hao Hou ,&nbsp;Deli Kong ,&nbsp;Tianqi Liu ,&nbsp;Yunong Zhao ,&nbsp;Xiaohui Guo","doi":"10.1016/j.compscitech.2025.111182","DOIUrl":"10.1016/j.compscitech.2025.111182","url":null,"abstract":"<div><div>With the rapid development of nanocomposites-based wearable electronic devices, there has been a significant increase in demand for flexible strain sensors capable of detecting mechanical force and temperature. Currently, the high linearity and wide sensing range of strain sensors are difficult to achieve. Herein, a flexible strain/temperature sensor (FSTS) is developed based on arch-inspired bionic structure and multi-walled carbon nanotubes/carbon black/polyaniline/silicone rubber nanocomposites. The prepared FSTS has both strain and temperature sensing capabilities. It functions as a FSTS with a high sensitivity of 3.432 and an ultra-low lower limit of detection (0.1 % strain). The wide linear detection range (0–190 % strain range) and ultra-high linearity (0.996) are realized simultaneously. These properties are attributed to arch-like fingerprint structure and multi-dimensional mixed materials. In addition, the designed FSTS has a resistive temperature coefficient of up to 57.301, a linearity of 0.999 over an ultra-wide temperature range (25–120 °C), and fine repeatability. Due to its improved sensing capabilities, FSTS can be applied to recognize sign language movements and intelligently temperature monitoring. This work introduces a novel approach to consider both linearity and sensing range, which has the potential to accelerate the development of composites-based strain sensor.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111182"},"PeriodicalIF":8.3,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143855889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aramid nanofibers/polyimide aerogel with multi-dimensional structure for noise reduction and thermal insulation 具有多维结构的芳纶纳米纤维/聚酰亚胺气凝胶用于降噪和隔热
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-07 DOI: 10.1016/j.compscitech.2025.111181
Yuanlong Meng , Jieyu Xue , Weizhen Huang , Liping Liu , Yuanrong Ding , Xuhong Yang , Zhou Chen , Yong Yang
{"title":"Aramid nanofibers/polyimide aerogel with multi-dimensional structure for noise reduction and thermal insulation","authors":"Yuanlong Meng ,&nbsp;Jieyu Xue ,&nbsp;Weizhen Huang ,&nbsp;Liping Liu ,&nbsp;Yuanrong Ding ,&nbsp;Xuhong Yang ,&nbsp;Zhou Chen ,&nbsp;Yong Yang","doi":"10.1016/j.compscitech.2025.111181","DOIUrl":"10.1016/j.compscitech.2025.111181","url":null,"abstract":"<div><div>Noise pollution poses a significant impact on both physical and mental health of humans. Traditional acoustic materials often enhance their performance by increasing their weight, which is incompatible with the requirements of lightweight design. In this study, aramid nanofiber (ANF) is synthesized via using electrospinning, and a blend of polyimide (PI) precursor solution and ANFs are utilized to facilitate the self-assembly of ANF/PI aerogel (APA). By adjusting the content of ANFs and PI, porous network structures are achieved without augmenting the overall density, while maintaining a superior sound absorption performance. Notably, APA exhibits a noise reduction coefficient (NRC) of 0.53 and a sound transmission loss (STL) of 14 dB at 6300 Hz. Furthermore, the incorporation of ANFs and PI provides the aerogels with robust mechanical and physical properties, including only 10 % plastic deformation after 300 compression cycles, exceptional hydrophobicity with a water contact angle of 139°, and low thermal conductivity of 0.0343 W m<sup>−1</sup> K<sup>−1</sup> at room temperature. This research presents a feasible design approach for the creation of lightweight, efficient, and multifunctional ANF/PI aerogels.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"266 ","pages":"Article 111181"},"PeriodicalIF":8.3,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143816827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-fidelity data fusion for inelastic woven composites: Combining recurrent neural networks with transfer learning 非弹性编织复合材料的多保真度数据融合:递归神经网络与迁移学习的结合
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-05 DOI: 10.1016/j.compscitech.2025.111163
Ehsan Ghane , Martin Fagerström , Mohsen Mirkhalaf
{"title":"Multi-fidelity data fusion for inelastic woven composites: Combining recurrent neural networks with transfer learning","authors":"Ehsan Ghane ,&nbsp;Martin Fagerström ,&nbsp;Mohsen Mirkhalaf","doi":"10.1016/j.compscitech.2025.111163","DOIUrl":"10.1016/j.compscitech.2025.111163","url":null,"abstract":"<div><div>Surrogate deep learning models provide an efficient solution for reducing the computational demands of homogenizing complex meso-scale woven composites to study their elasto-plastic mechanical behaviors. This research introduces a comprehensive framework using transfer learning that combines data from a mean-field homogenization approach with high-fidelity full-field simulations. In a design space characterized by diverse loading conditions and micro-scale constitutive material properties, the goal is to address the challenges of generating sufficient datasets for training a data-hungry gated recurrent neural network (GRU). Multiple datasets of varying precision are generated and used, containing multi-axial stress–strain responses under two load types: random walking and proportional cyclic loading. Moreover, this study emphasizes the importance of temporal correlations in the dataset, which align with the physically path-dependent behavior of most non-linear materials, and demonstrates that temporal correlations are crucial for training time-series models. These correlations also provide the foundation for data augmentation using a linear interpolation technique within time-series stress analyses, enabling accurate predictions of homogenized meso-scale stresses based on strain trajectories and microstructural properties. Results demonstrate that integrating transfer learning with neural networks successfully incorporates a limited number of high-fidelity data with more accessible but low-fidelity data. With this framework, surrogate models for predicting the complex behavior of woven composites will be accurate and efficient, marking an important advancement in material modeling.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"267 ","pages":"Article 111163"},"PeriodicalIF":8.3,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143828708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A structure-integrated nanocomposite sensor system capable of simultaneous measurement of omnidirectional strain and temperature 一种能同时测量全向应变和温度的结构集成纳米复合材料传感器系统
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-05 DOI: 10.1016/j.compscitech.2025.111165
Sumin Lee, Jeonyoon Lee
{"title":"A structure-integrated nanocomposite sensor system capable of simultaneous measurement of omnidirectional strain and temperature","authors":"Sumin Lee,&nbsp;Jeonyoon Lee","doi":"10.1016/j.compscitech.2025.111165","DOIUrl":"10.1016/j.compscitech.2025.111165","url":null,"abstract":"<div><div>Strain-based structural health monitoring (SHM) systems are widely used for composite structures, given the unpredictable failure mechanisms associated with their heterogeneous nature. However, conventional strain sensors are constrained by their unidirectional sensitivity and their inability to differentiate strain from temperature effects without additional sensors, leading to complex configurations and extensive wiring. To overcome these limitations, a carbon nanotube (CNT)-based omnidirectional sensing system was developed as a structurally integrated nanocomposite surfacing layer for composite structures. This novel sensor system enables the detection of strain in all directions using a single nanocomposite sensor, while simultaneously measuring temperature to isolate its effects. Experimental results demonstrated that the sensor accurately measured the full in-plane strain tensor under tensile loading, closely aligning with reference data from a 3-element strain gauge rosette. It also exhibited high temperature accuracy, with a maximum error of 0.3%. By reducing the number of required sensors and wiring while maintaining precise measurements, this nanocomposite sensor system significantly simplifies SHM configurations. These findings underscore the potential of the CNT-based sensing system as a streamlined, efficient solution for aerospace and other advanced applications requiring reliable, multi-functional SHM systems.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"266 ","pages":"Article 111165"},"PeriodicalIF":8.3,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intrabead and interbead fracture analysis of large area additive manufactured polymer and polymer composites 大面积增材制造聚合物及聚合物复合材料的头内和头间断裂分析
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-04 DOI: 10.1016/j.compscitech.2025.111173
Arief Yudhanto, Neshat Sayah, Douglas E. Smith
{"title":"Intrabead and interbead fracture analysis of large area additive manufactured polymer and polymer composites","authors":"Arief Yudhanto,&nbsp;Neshat Sayah,&nbsp;Douglas E. Smith","doi":"10.1016/j.compscitech.2025.111173","DOIUrl":"10.1016/j.compscitech.2025.111173","url":null,"abstract":"<div><div>Large-Area Additive Manufacturing (LAAM) has seen increased application in manufacturing meter-scale, polymeric composite structural parts, especially for tooling and fixturing. Unfortunately, LAAM introduces manufacturing-induced defects in printed composites, e.g., intrabead microvoids and poor interbead adhesion that are not otherwise seen when traditional manufacturing methods are used, causing degradation of mechanical and fracture properties. In this paper, the fracture behavior of neat acrylonitrile butadiene styrene (ABS) and short carbon fiber-reinforced ABS (CF/ABS) fabricated by LAAM is compared and analyzed by evaluating their energy release rate <span><math><msub><mrow><mi>G</mi></mrow><mrow><mi>I</mi><mi>c</mi></mrow></msub></math></span> and fracture mechanisms. A double cantilever beam with doublers (DCB-D) test for single-bead, double-bead, and multiple-bead configurations is developed by incorporating rigid doublers to reduce the compressive failure at the crack tip, allowing for the measurement of crack propagation. A new data reduction method for these configurations is derived to remove the doubler effect from the <span><math><msub><mrow><mi>G</mi></mrow><mrow><mi>I</mi><mi>c</mi></mrow></msub></math></span> calculation, producing ‘pure’ intrabead and interbead <span><math><msub><mrow><mi>G</mi></mrow><mrow><mi>I</mi><mi>c</mi></mrow></msub></math></span> values. We show that CF/ABS is more damage tolerant than ABS at the intrabead level, but less damage tolerant than ABS at the interbead level. The development of plastic ligaments in ABS helps dissipate additional strain energy, improving the overall energy release rate. The experimental fracture test approach developed here is expected to provide mechanistic insight into their damage tolerance capability, accelerating the qualification process of LAAM-produced polymer and polymer composites.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"266 ","pages":"Article 111173"},"PeriodicalIF":8.3,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143776351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interface-driven structural engineering of polypropylene carbonate-modified MgO composites for enhanced thermal conductivity 碳酸盐改性MgO复合材料导热性能界面驱动结构工程研究
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-03 DOI: 10.1016/j.compscitech.2025.111177
Ye-Ji Lee, Ji Young Park, Hong-Baek Cho, Yong-Ho Choa
{"title":"Interface-driven structural engineering of polypropylene carbonate-modified MgO composites for enhanced thermal conductivity","authors":"Ye-Ji Lee,&nbsp;Ji Young Park,&nbsp;Hong-Baek Cho,&nbsp;Yong-Ho Choa","doi":"10.1016/j.compscitech.2025.111177","DOIUrl":"10.1016/j.compscitech.2025.111177","url":null,"abstract":"<div><div>As electric vehicle (EV) batteries evolve toward higher energy densities, the demand for advanced thermal interface materials (TIMs) with high thermal conductivity (TC), superior mechanical strength, and anti-hydration properties becomes critical. TIMs must effectively dissipate heat while maintaining structural integrity under harsh thermal and humid conditions to ensure long-term reliability. In this study, we developed a high-performance epoxy composite incorporating thermally and chemically engineered magnesium oxide (MgO) fillers. The MgO was modified via thermal treatment and polypropylene carbonate (PPC) surface functionalization, forming a 365 nm hydrophobic coating layer while increasing the average grain size from 0.9 μm to 22 μm. This novel approach significantly mitigated Mg(OH)<sub>2</sub> formation after 120 h in deionized water at 50 °C.Furthermore, the interface engineering between PPC-modified MgO and epoxy enhanced phonon transport while reducing interfacial resistance, leading to a 65 % increase in tensile stress and a TC enhancement from 1.192 W/mK to 2.036 W/mK. By optimizing the high-density packaging (HDP) process, we achieved an unprecedented TC of 9.22 W/mK at a filler content of 75.1 vol%, surpassing conventional epoxy-based TIMs. This study demonstrates a synergistic strategy combining grain boundary engineering, interfacial optimization, and dense filler packing to develop next-generation TIMs.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"266 ","pages":"Article 111177"},"PeriodicalIF":8.3,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enabling multifunctional bio-based waterborne polyurethane through polyphenol-mediated assembly of zirconium phosphate nanoplatelets for patternable coating 通过多酚介导的磷酸锆纳米片组装实现多功能生物基水性聚氨酯
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-02 DOI: 10.1016/j.compscitech.2025.111178
Jiabo Shi , Xiaoyi Wu , Li Sheng , Meng Chen , Lei Shi , Yi Zhang , Jingyi Yang , Shumin Mao , Qiang Liu , Zhijun Zhou
{"title":"Enabling multifunctional bio-based waterborne polyurethane through polyphenol-mediated assembly of zirconium phosphate nanoplatelets for patternable coating","authors":"Jiabo Shi ,&nbsp;Xiaoyi Wu ,&nbsp;Li Sheng ,&nbsp;Meng Chen ,&nbsp;Lei Shi ,&nbsp;Yi Zhang ,&nbsp;Jingyi Yang ,&nbsp;Shumin Mao ,&nbsp;Qiang Liu ,&nbsp;Zhijun Zhou","doi":"10.1016/j.compscitech.2025.111178","DOIUrl":"10.1016/j.compscitech.2025.111178","url":null,"abstract":"<div><div>Sustainable bio-based waterborne polyurethane (WPU) has been widely used in a wide range of industrial applications owing to its favorable environmental safety and excellent properties. However, achieving superior mechanical properties and favorable multifunctionalities in bio-based WPU remains a considerable challenge. In this work, we proposed a facile and effective interfacial engineering strategy which was synergistically enabled via phosphoric acid-assisted exfoliation and polyphenol-mediated assembly of zirconium phosphate nanoplatelets (ZrP NPs) to prepare multifunctional castor oil-based supramolecular WPU composites for patternable leather coating. Tunable ZrP based supramolecular assemblies with the weight ratio of TA to pZrP NPs of 2.0 wt.% and pH &gt; 5.0 were fabricated to manipulate the assembly of the WPU molecules. Active TA molecules bound on the interfaces of ZrP NPs can function as organic junctions through the formation of hydrogen-bonding interactions between the phenolic groups of TA molecules and the functional groups of WPU molecules. Benefiting from this hydrogen-bonding-driven co-assembly, the resultant supramolecular WPU composite films not only exhibited excellent transparency and reinforced mechanical strengths, thermal stability, and flame-retardant properties, but also possessed photoluminescent properties suitable for patternable leather coating. For example, the peak heat release rate (PHRR) was decreased from 389.45 kW/m<sup>2</sup> to 199.75 kW/m<sup>2</sup>, and the total heat release (THR) was from 15.49 MJ/m<sup>2</sup> to 13.58 MJ/m<sup>2</sup>. We envision that this study contributes to the development of sustainable multifunctional bio-based WPU coatings with significant potential for advanced applications in information encryption and displays, etc.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"266 ","pages":"Article 111178"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Path planning for curved layer fused deposition modeling of continuous fiber reinforced structures with iso-void depth 等空隙深度连续纤维增强结构弯曲层熔融沉积建模路径规划
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-02 DOI: 10.1016/j.compscitech.2025.111179
Yuanzheng Zuo , Hongtao Wang , Ning Dai , Kanghui Zhou , Hongyu Chen , Jun Liu
{"title":"Path planning for curved layer fused deposition modeling of continuous fiber reinforced structures with iso-void depth","authors":"Yuanzheng Zuo ,&nbsp;Hongtao Wang ,&nbsp;Ning Dai ,&nbsp;Kanghui Zhou ,&nbsp;Hongyu Chen ,&nbsp;Jun Liu","doi":"10.1016/j.compscitech.2025.111179","DOIUrl":"10.1016/j.compscitech.2025.111179","url":null,"abstract":"<div><div>At present, additive manufacturing of continuous fiber-reinforced composites (CFRCs) mainly adopts planar fiber layout. The development of multi-axis additive manufacturing systems provides unprecedented opportunities for the fabrication of composite structures with non-planar fiber layouts. This paper explores a multi-axis curved layer fused deposition modeling (CLFDM) process for CFRCs. Based on the drum-shaped deposition cross-section, a curved layer theoretical deposition model with equal void depth that satisfies uniform overlap is constructed. A path planning method for continuous fiber curved layer is proposed based on the theoretical deposition model. The accurate equal error step size calculation is performed under the change of the surface normal curvature and the curve curvature, achieving interference-free and equal error printing path discretization. Using 6-axis robot integrated with a dual-nozzle printing system, continuous fiber CLFDM is realized through its multiple degrees of freedom. Verified by computer simulation and physical printing experiments, the algorithm in this paper has considerable feasibility for various surface shapes, effectively enabling the manufacturing of continuous fiber curved layers with high fiber volume fraction. Comparative results of mechanical experiments show that the failure loads of the uniformly overlapped continuous fiber curved layers increased by 39.8 % and 89.2 %, and the stiffness increased by 47.8 % and 73.2 %, respectively. This provides new insights for the exploration of composite materials with complex curved fiber layouts.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"266 ","pages":"Article 111179"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143785483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of hyperbranched polymer for advanced dental composites: Low shrinkage, high strength, and enhanced biocompatibility 用于高级牙科复合材料的超支化聚合物的构建:低收缩,高强度,增强生物相容性
IF 8.3 1区 材料科学
Composites Science and Technology Pub Date : 2025-04-02 DOI: 10.1016/j.compscitech.2025.111180
Qiyue Zhang, Ibrahim Abdalla, Athar Hassan, Kangni Wang, Danyue Wang, Jia Zheng, Ruili Wang, Bin Sun, Xiaoze Jiang, Meifang Zhu
{"title":"Construction of hyperbranched polymer for advanced dental composites: Low shrinkage, high strength, and enhanced biocompatibility","authors":"Qiyue Zhang,&nbsp;Ibrahim Abdalla,&nbsp;Athar Hassan,&nbsp;Kangni Wang,&nbsp;Danyue Wang,&nbsp;Jia Zheng,&nbsp;Ruili Wang,&nbsp;Bin Sun,&nbsp;Xiaoze Jiang,&nbsp;Meifang Zhu","doi":"10.1016/j.compscitech.2025.111180","DOIUrl":"10.1016/j.compscitech.2025.111180","url":null,"abstract":"<div><div>Dental restorative composites (DRCs) commonly result in secondary caries due to high polymerization shrinkage (PS) after curing and low strength property after long-term performance. To address this, a hyperbranched polymer (HBP) molecule named HTH, possessing rigid phenyl, cross-linkable methacrylate, and inter/intra molecular interactable urethane was synthesized via a one-step Michael addition and esterification process using 1,1,1-trimethylolpropane with N, <em>N</em>-di (2-hydroxyethyl)-3-aminopropyl meth-acrylate and then modified the hydroxyl terminals with 2-{[(3-isocyanato-4-methylphenyl) carbamoyl]oxy}ethyl 2-methylprop-2-enoate (TDI-HEMA). The obtained HTH molecule was characterized, and effect of the incorporation of HBP molecules utilized as one co-monomer was explored on the properties of DRCs prepared by fixed 25 wt% organic matrix constitute of bisphenol A-glycidyl methacrylate (Bis-GMA)/tri(ethylene glycol) dimethacrylate (TEGDMA) (weight ratio 50:50, referred to as 5B5T) and 75 wt% micro- and nano-hybrid silica (SiO<sub>2</sub>) fillers in details by Nuclear Magnetic Resonance spectroscopy (NMR), Fourier Transform Infrared Spectrometer (FT-IR), universal testing machine and density balance, etc. The measured results show: the HBP molecules, HTH, was synthesized successfully. The incorporation of HBP molecules reduces clearly the PS of DRCs, and the lowest PS of resultant DRCs could reach to 1.97 % by 20 wt% incorporation of HTH into 5B5T organic matrix and SiO<sub>2</sub> particle systems meanwhile their mechanical properties remained robust (compressive strength at 355.7 MPa) and achieved excellent biocompatibility. This construction of new type of HBP molecules bearing functional moieties similar Bis-GMA characteristics as co-monomer offers a promising light to develop novel commercialized DRCs with high strength property and low PS, seamlessly blending durability and functionality.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"266 ","pages":"Article 111180"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143783580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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