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Development of multivariable model for predicting heating value of bio-dried refuse-derived fuel from municipal solid waste
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-13 DOI: 10.1016/j.biombioe.2025.107795
Abhisit Bhatsada , Suthum Patumsawad , Sirintornthep Towprayoon , Chart Chiemchaisri , Komsilp Wangyao
{"title":"Development of multivariable model for predicting heating value of bio-dried refuse-derived fuel from municipal solid waste","authors":"Abhisit Bhatsada ,&nbsp;Suthum Patumsawad ,&nbsp;Sirintornthep Towprayoon ,&nbsp;Chart Chiemchaisri ,&nbsp;Komsilp Wangyao","doi":"10.1016/j.biombioe.2025.107795","DOIUrl":"10.1016/j.biombioe.2025.107795","url":null,"abstract":"<div><div>Biodrying is a vital waste management method that reduces moisture content and enhances the energy value of refuse-derived fuel (RDF). This study presents a robust model for predicting RDF's final lower heating value (LHV), introducing a novel cross-domain heating value prediction approach. The model achieved optimal performance under aeration rates (AR) of 0.2–0.4 m<sup>3</sup>/kg/day, coupled with organic content (OC) values between 0.94 and 1.88 m<sup>3</sup>/kg OC/day, accurately predicting final LHV values ranging from 3500 to 4500 kcal/kg. Results revealed that non-interaction variables and two-variable interactions significantly influenced heat value prediction and biodrying performance, yielding a 76 % coefficient of determination. A biodrying energy conservation index, based on the organic carbon (C) to organic hydrogen (H) ratio, was developed to assess the interplay between AR and final LHV. Results demonstrated an inverse relationship between the organic C-to-H ratio and the final LHV, with C retention and H release (1.48–2.28 %) enhancing energy yield. This study advances the understanding of biodrying by integrating independent variables for predictive modeling and conceptual indices for energy conservation, establishing a foundation for optimizing operational parameters in waste-to-energy systems. The findings provide practical guidance for sustainable waste management and support the production of high-quality RDF for renewable energy applications.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107795"},"PeriodicalIF":5.8,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143611090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of particles size and density on the segregation of catalyst-sorbent mixtures for direct sorption-enhanced DME synthesis: Experimental and mathematical study
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-12 DOI: 10.1016/j.biombioe.2025.107764
Simona Renda, Jaime Soler, Javier Herguido, Miguel Menéndez
{"title":"Effect of particles size and density on the segregation of catalyst-sorbent mixtures for direct sorption-enhanced DME synthesis: Experimental and mathematical study","authors":"Simona Renda,&nbsp;Jaime Soler,&nbsp;Javier Herguido,&nbsp;Miguel Menéndez","doi":"10.1016/j.biombioe.2025.107764","DOIUrl":"10.1016/j.biombioe.2025.107764","url":null,"abstract":"<div><div>Direct sorption-enhanced dimethyl ether synthesis (SEDMES) is a promising process for the production of fuels from CO<sub>2</sub> sources. Using novel technologies, the process can be run exploiting the phenomena of particles segregation in a fluidized bed reactor. However, the knowledge on the solid movement and the segregation patterns is a mandatory preliminary step for the setup of the final application. In this study, we evaluated the impact of particles size and density on the segregation patterns, and we used the Gibilaro and Rowe (GR) model to analytically represent the experimental results. It was observed that the variation of both parameters influences segregation, even though a higher separation degree in a wider operating velocity range was observed when a higher density ratio was induced between the two solids. Through the experimental analysis, five possible bed configurations were identified, and a consideration was made on the aims of the GR model to adjust the mathematical representation to the present case. By considering the bottom portion of the bed as a jetsam-rich phase and not – as previously reported – as a segregated layer, a mass balance on the catalyst allowed to obtain a faithful analytical representation of the experimental segregation patterns.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107764"},"PeriodicalIF":5.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143600610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving high biomass of probiotic Enterococcus faecium by affordable culture media using response surface methodology
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-12 DOI: 10.1016/j.biombioe.2025.107796
Nazila Soleymanzadeh , Leila Babaei , Fatemeh Safaie , Bahram Tafaghodinia
{"title":"Achieving high biomass of probiotic Enterococcus faecium by affordable culture media using response surface methodology","authors":"Nazila Soleymanzadeh ,&nbsp;Leila Babaei ,&nbsp;Fatemeh Safaie ,&nbsp;Bahram Tafaghodinia","doi":"10.1016/j.biombioe.2025.107796","DOIUrl":"10.1016/j.biombioe.2025.107796","url":null,"abstract":"<div><div>By increased consumption of probiotics as health-improving supplements by humans and livestock, there is a necessity for cost-effective large-scale production of these beneficial microorganisms. A cost-efficient and optimal culture medium was designed for large-scale production of probiotic <em>E. faecium</em> and operating conditions were optimized using response surface methodology. A three-stage sequential optimization process was designed to optimize media composition and operating conditions.</div><div>The results showed that an economic combination of CSL and yeast extract at a ratio of 70:30 as nitrogen source and sucrose as carbon source could achieve a biomass yield of 1.5 × 10<sup>9</sup> CFU/mL. Further optimizations revealed the negligible effect of agitation and temperature, while the initial pH and phosphate buffer concentration significantly influenced the biomass yield. A confirmation experiment with culture medium composed of sucrose 20 g/L, CSL 8.4 g/L, yeast extract 3.6 g/L, phosphate buffer 0.06 M under the initial pH of 8.0, and temperature of 32.5 °C obtained a final biomass concentration of 1.9 × 10<sup>9</sup> CFU/mL. The scaled up processes in 10-L and 75-L fermenters under the optimized conditions successfully produced biomass yields of 2 × 10<sup>9</sup> and 3 × 10<sup>9</sup> CFU/mL, respectively. These findings showed the feasibility of formulating an innovative and cost-effective culture medium with readily available ingredients to achieve high biomass concentrations of probiotics.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107796"},"PeriodicalIF":5.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143611087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valorization of agave bagasse as a bio-template for circular economy: Applications in energy conversion, metabolite production, and sustainable material synthesis
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-12 DOI: 10.1016/j.biombioe.2025.107797
Walter M. Warren-Vega , Rocío Fonseca-Aguiñaga , Carlos F. López de la Cruz , Armando Campos-Rodríguez , Ana I. Zárate Guzmán , Luis A. Romero Cano
{"title":"Valorization of agave bagasse as a bio-template for circular economy: Applications in energy conversion, metabolite production, and sustainable material synthesis","authors":"Walter M. Warren-Vega ,&nbsp;Rocío Fonseca-Aguiñaga ,&nbsp;Carlos F. López de la Cruz ,&nbsp;Armando Campos-Rodríguez ,&nbsp;Ana I. Zárate Guzmán ,&nbsp;Luis A. Romero Cano","doi":"10.1016/j.biombioe.2025.107797","DOIUrl":"10.1016/j.biombioe.2025.107797","url":null,"abstract":"<div><div>Agave bagasse corresponds to the main solid waste generated in the production of agave alcoholic beverages. According to its composition, this material can be considered as a biological template useful to guide the synthesis of new products, services and materials. In this sense, the present communication represents the physicochemical characterization of agave bagasse as well as the compilation of recent applications that have been reported in the literature. Several strategies have been considered to reuse these residues for many purposes such as energy conversion and management, substrate for metabolite production, and for material applications.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107797"},"PeriodicalIF":5.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143600788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Co-biosynthesis of exopolysaccharide and poly-3-hydroxybutyrate using a versatile strain Paracoccus sp. TH21-44: Antioxidant potential and fermentation model
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-12 DOI: 10.1016/j.biombioe.2025.107793
Bowen Ma , Leizhen Zhao , Xiaobing He , Shuai Zhao , Feng Huang , Jia Zhou , Tawatchai Sumpradit , Jianhang Qu
{"title":"Co-biosynthesis of exopolysaccharide and poly-3-hydroxybutyrate using a versatile strain Paracoccus sp. TH21-44: Antioxidant potential and fermentation model","authors":"Bowen Ma ,&nbsp;Leizhen Zhao ,&nbsp;Xiaobing He ,&nbsp;Shuai Zhao ,&nbsp;Feng Huang ,&nbsp;Jia Zhou ,&nbsp;Tawatchai Sumpradit ,&nbsp;Jianhang Qu","doi":"10.1016/j.biombioe.2025.107793","DOIUrl":"10.1016/j.biombioe.2025.107793","url":null,"abstract":"<div><div>The sole disadvantage of microbial fermentation products imposes a specific limitation on industrial production, secretion of extracellular exopolysaccharide (EPS) by synergy with intracellular accumulation of polyhydroxyalkanoates (PHAs) can maximize sustainable adaptability. In this study, a high-performing EPS-producing strain TH21-44 was isolated in conjunction with PHAs fermentation. The metabolically diverse bacterium TH21-44 was identified as <em>Paracoccus</em> sp. based on the taxonomic analysis. The genes and metabolic pathways involved in the synthesis of poly-3-hydroxybutyrate (PHB) and EPS were comprehensively characterized through draft genome sequencing. PHAs synthase is classified as class Ⅰ and glycosyl transferases involved in the EPS synthesis have been detected. Foremost, the combined fermentation capacity was further enhanced by adjusting the process parameters. The maximum concentrations of PHB (168.26 mg L<sup>−1</sup>) and EPS (191.11 mg L<sup>−1</sup>) were achieved when C/N ratio was established at 15:1, using 10 g L<sup>−1</sup> glucose as substrate after 48 h of cultivation. Accordingly, the purified EPS was evaluated for cytotoxicity and oxidative stress with a view to food fields, and obtained PHB properties were detected to fit the appropriate application scenarios. This study established a foundational process for the co-synthesis of EPS and PHB, and offered a novel perspective on leveraging the metabolic potential of functional microorganisms.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107793"},"PeriodicalIF":5.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143611088","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microwave-assisted torrefaction of lignocellulosic biomass: A critical review of its role in sustainable energy
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-12 DOI: 10.1016/j.biombioe.2025.107777
Ramesh Potnuri , Chinta Sankar Rao , Maheswata Lenka , Veluru Sridevi , Tanmay Basak
{"title":"Microwave-assisted torrefaction of lignocellulosic biomass: A critical review of its role in sustainable energy","authors":"Ramesh Potnuri ,&nbsp;Chinta Sankar Rao ,&nbsp;Maheswata Lenka ,&nbsp;Veluru Sridevi ,&nbsp;Tanmay Basak","doi":"10.1016/j.biombioe.2025.107777","DOIUrl":"10.1016/j.biombioe.2025.107777","url":null,"abstract":"<div><div>Lignocellulosic biomass is a promising renewable energy source that can help reduce reliance on fossil fuels. However, its raw form presents challenges for practical use. To overcome this, the Microwave-assisted torrefaction (MAT) process has emerged as a successful method for enhancing the quality of biomass and generating energy. This article aims to provide a comprehensive review of recent scientific research on MAT of biomass. It explores torrefaction indices and discusses the impact of key parameters such as biomass composition, temperature, residence time, heating rate, particle size, and microwave power on MAT. The article also addresses potential applications and challenges associated with MAT. Furthermore, it evaluates the hurdles in achieving compatibility, acceptability, and sustainability of the process, along with future directions to realize economic benefits even in small-scale applications. Ultimately, MAT holds promise as an energy-efficient approach to enhance the effectiveness of biomass utilization.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107777"},"PeriodicalIF":5.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143600787","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable innovation in activated carbon-based temperature controlled surface technologies
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-11 DOI: 10.1016/j.biombioe.2025.107760
Mehmet Selcuk Erdogan , Muhammed Bekmezci , Ramazan Bayat , Fatih Sen
{"title":"Sustainable innovation in activated carbon-based temperature controlled surface technologies","authors":"Mehmet Selcuk Erdogan ,&nbsp;Muhammed Bekmezci ,&nbsp;Ramazan Bayat ,&nbsp;Fatih Sen","doi":"10.1016/j.biombioe.2025.107760","DOIUrl":"10.1016/j.biombioe.2025.107760","url":null,"abstract":"<div><div>In this study, an environmentally friendly, sustainable, and low-cost carbon-based thermal paint was developed from activated carbon (AC) obtained from the waste product of coffee beans ground by modern coffee machines. With the developed dye, it is aimed to decrease environmental pollution and to obtain an advanced technology product. The production of AC used in the developed dye was carried out with a microwave oven (MWO) system, which provides faster production in large quantities. The resulting AC was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy analysis. AC is combined with natural resin (gum Arabic) and binders (sodium silicate, polyvinyl alcohol) to obtain customized thermal paint recipes. The heat paint was applied to the plasterboard surfaces in five coats with a typical thin paintbrush. The electrically, and thermally conductive paint has a structure that can be easily applied to various surfaces and can produce heat with low-voltage electric current. The paint mixture was monitored with a thermal camera system on 5 × 5 cm<sup>2</sup>, 10 × 5 cm<sup>2</sup>, and 15 × 5 cm<sup>2</sup> plates at 8/10/12 V voltage for 1 h. The temperature measured by the camera increased from approximately 24° C–35° C when 12 V was applied on a 10 × 5 cm<sup>2</sup> plasterboard for 1 h. This study presents a novel, low-cost, high-volume, and sustainable method for producing AC-based thermal paint using coffee bean biomass waste, which has not been previously investigated in the literature to the best of our knowledge.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107760"},"PeriodicalIF":5.8,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143592814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lifecycle implications and mechanical properties of carbonated biomass ashes as carbon-storing supplementary cementitious materials
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-11 DOI: 10.1016/j.biombioe.2025.107772
Patrick R. Cunningham , Li Wang , Seth Kane , Alyson Kim , Bryan M. Jenkins , Sabbie A. Miller
{"title":"Lifecycle implications and mechanical properties of carbonated biomass ashes as carbon-storing supplementary cementitious materials","authors":"Patrick R. Cunningham ,&nbsp;Li Wang ,&nbsp;Seth Kane ,&nbsp;Alyson Kim ,&nbsp;Bryan M. Jenkins ,&nbsp;Sabbie A. Miller","doi":"10.1016/j.biombioe.2025.107772","DOIUrl":"10.1016/j.biombioe.2025.107772","url":null,"abstract":"<div><div>Methods to sequester and store atmospheric CO<sub>2</sub> are critical to combat climate change. Alkaline-rich bioashes are potential carbon fixing materials. This work investigates potential co-benefits from mineralizing carbon in biomass ashes and partially replacing high embodied greenhouse gas (GHG) Portland cement (PC) in cement-based materials with these ashes. Specifically, rice hull ash (RHA), wheat straw ash (WSA), and sugarcane bagasse ash (SBA) were treated to mineralize carbon, and their experimental carbon content was compared to modeled potential carbonation. To understand changes in the cement-based storage materials, mortars made with CO<sub>2</sub>-treated WSA and RHA were experimentally compared to PC-only mortars and mortars made with ashes without prior CO<sub>2</sub> treatment. Life cycle assessment methodology was applied to understand potential reductions in GHG emissions. The modeled carbonation was ∼18 g-CO<sub>2</sub>/kg-RHA and ∼180 g-CO<sub>2</sub>/kg-WSA. Ashes oxidized at 500 °C had the largest measured carbon content (5.4 g-carbon/kg-RHA and 35.3 g-carbon/kg-WSA). This carbon appeared to be predominantly residual from the biomass. Isothermal calorimetry showed RHA-PC pastes had similar heat of hydration to PC-pastes, while WSA-PC pastes exhibited an early (at ∼1.5 min) endothermic dip. Mortars with 5 % and 15 % RHA replacement had 1–12 % higher compressive strength at 28 days than PC-only mortars, and milled WSA mortars with 5 % replacement had 3 % higher strength. A loss in strength was noted for the milled 15 % WSA, the CO<sub>2</sub>-treated 5 %, and the 15 % WSA mortars. Modeled reductions in GHG emissions from CO<sub>2</sub>-treated ashes were, however, marginal (&lt;1 %) relative to the untreated ashes.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107772"},"PeriodicalIF":5.8,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143592816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of biodiesel from Cyperus esculentus seed oil: Investigation of temperature effect on the transesterification kinetics and bond structure
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-11 DOI: 10.1016/j.biombioe.2025.107766
Chukwunonso O. Aniagor , Ozioma J. Anekwe-Nwekeaku , Blessing I. Tabugbo
{"title":"Synthesis of biodiesel from Cyperus esculentus seed oil: Investigation of temperature effect on the transesterification kinetics and bond structure","authors":"Chukwunonso O. Aniagor ,&nbsp;Ozioma J. Anekwe-Nwekeaku ,&nbsp;Blessing I. Tabugbo","doi":"10.1016/j.biombioe.2025.107766","DOIUrl":"10.1016/j.biombioe.2025.107766","url":null,"abstract":"<div><div>This study investigates the acid-catalyzed transesterification of <em>Cyperus esculentus</em> (<em>C. esculentus</em>) seed oil into biodiesel. The influence of temperature of the transesterification reaction system, volume of catalyst and reaction time on the % biodiesel yield was evaluated in batch mode. The fuel properties of the biodiesel and hydrocarbon diesel were also evaluated using ASTM standards and further compared. The maximum biodiesel yield of 92 % was achieved at a catalyst volume of 10 mL, a reaction time of 60 min, and a temperature of 40 °C. The resulting biodiesel displayed a higher flash point (94 °C) and viscosity but had a lower calorific value (44,752 kJ/kg) relative to the hydrocarbon diesel. Elemental analysis revealed low heavy metal content compared to the hydrocarbon diesel, thus suggesting a lower negative environmental impact. The kinetic analysis identified the second-order transesterification equation as the model of best fit, with the observation of improved R<sup>2</sup> values at higher reaction temperatures. The study thus concludes that biodiesel is viable for biodiesel production due to its moderate molecular mass and favourable physicochemical properties.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107766"},"PeriodicalIF":5.8,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143592817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of dry and wet torrefaction pretreatment on the physicochemical structure of corn stover-derived porous carbon and its performance in supercapacitor applications
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-03-10 DOI: 10.1016/j.biombioe.2025.107773
Weijie Yan , Zhenjie Sun , Kaiming Dong , Feiqiang Guo
{"title":"Effects of dry and wet torrefaction pretreatment on the physicochemical structure of corn stover-derived porous carbon and its performance in supercapacitor applications","authors":"Weijie Yan ,&nbsp;Zhenjie Sun ,&nbsp;Kaiming Dong ,&nbsp;Feiqiang Guo","doi":"10.1016/j.biombioe.2025.107773","DOIUrl":"10.1016/j.biombioe.2025.107773","url":null,"abstract":"<div><div>This study used corn stover as raw materials, employed dry torrefaction and wet torrefaction pretreatment methods combined with KOH activation, and successfully synthesized high-value-added porous carbon materials. Dry torrefaction significantly increased the specific surface area of the porous carbon material to 3657.35 m<sup>2</sup> g<sup>−1</sup> and formed a rich microporous and mesoporous structure, enabling it to exhibit a high specific capacitance of 418.5 F g<sup>−1</sup> at a current density of 0.5 A g<sup>−1</sup> in a three-electrode system. Wet torrefaction, by increasing the ash removal rate, enhancing the relative crystallinity of the porous carbon precursor, and improving thermal stability, significantly reduced the charge transfer resistance (R<sub>ct</sub> = 0.02 Ω). Despite the lower specific surface area (2143.70 m<sup>2</sup> g<sup>−1</sup>), it achieved a specific capacitance of 71.0 F g<sup>−1</sup> at a current density of 0.5 A g<sup>−1</sup> in a two-electrode system and a capacitance retention rate of 101.17 % after 25,000 cycles, demonstrating excellent cycling stability. Therefore, using dry and wet torrefaction pretreatment methods to regulate the structure and surface chemical properties of corn stover-based porous carbon demonstrates the great potential of corn stover as high-performance, low-cost electrode materials for supercapacitors.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107773"},"PeriodicalIF":5.8,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143579495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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