Applied Clay Science最新文献

{"title":"Cronstedtite: H2 generation and new constraints on its formation conditions","authors":"Isabella Pignatelli ,&nbsp;Enrico Mugnaioli ,&nbsp;Régine Mosser-Ruck ,&nbsp;Mustapha Abdelmoula ,&nbsp;Jérôme Sterpenich","doi":"10.1016/j.clay.2024.107627","DOIUrl":"10.1016/j.clay.2024.107627","url":null,"abstract":"<div><div>This work investigated the formation conditions of cronstedtite, the most Fe-rich serpentine, using a steel autoclave lined with Teflon at 90 °C, over 167 days, allowing for in situ monitoring of pH, T and P, as well as for gas sampling. From a starting mineralogical mixture composed of quartz and metal iron, cronstedtite crystallized in association with, magnetite, akaganeite, ferrihydrite and amorphous silica. This mineralogical association was not observed in previous syntheses and it is likely related to the experimental conditions of this study. These conditions also affected the composition and structure (polytypic sequence and crystallinity degree) of cronstedtite, which are accurately characterized for the first time. Experimental data and thermodynamic modelling indicate that this Fe-serpentine formed under neutral conditions, -62 &lt; log<em>f</em>O₂ &lt; −59, and redox potential ranging from −0.46 to −0.41 Volts. During the experiment, H₂ was generated by iron oxidation in presence of water, explaining the increase of pressure in the autoclave until 6.8 bar at 90 °C. The total amount of H₂ generated was of 0.23 mol. The results of this study are useful to improve the understanding of cronstedtite formation in natural and anthropic environments. They also showed that formation conditions of cronstedtite seem to be compatible with those needed for hydrogenotrophic life, as previously supposed by other works.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107627"},"PeriodicalIF":5.3,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142651125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tea nanoparticles modified halloysite clay coated polyurethane sponge as multifunctional sensors","authors":"Kairui Tian,&nbsp;Xiangyu Chen,&nbsp;Xinyuan Zhou,&nbsp;Yuqian Xu,&nbsp;Mingxian Liu","doi":"10.1016/j.clay.2024.107589","DOIUrl":"10.1016/j.clay.2024.107589","url":null,"abstract":"<div><div>Tea, as one of the three major beverages in the world, has antioxidant, anti-cancer, inhibitory inflammation, immune regulation, diabetes prevention, antibacterial and other effects. In this study, black tea and FeCl₃·6H₂O were chelated to functionally modify the outer surface of halloysite clay nanotube (Hal). A new nanomaterial with excellent photothermal properties, tea nanoparticles@Hal, was successfully synthesized. Tea nanoparticles@Hal powder can raise to 225.8 °C in 25 s, and the corresponding solution can raise to 50.5 °C in 8 min with a photothermal efficiency of 77.3 %. The tea nanoparticles@Hal was assembled on the polyurethane (PU) sponges by simply soaking to prepare conductive sensor. The flexible sensor shows a fast response time (132.8 ms) and a long service time (400 cycles), which have wide range of applications. The resistance changes with the pressure is in a regular functional relationship, and the sensor can measure the weight of objects with high accuracy. In addition, the sensor can stably monitor various physiological activities of the human body. When finger is bent, the sensor can produce the difference output signals. The prepared tea nanoparticles@Hal/PU sensor has broad prospects in fields such as human-computer interaction and medical detection.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107589"},"PeriodicalIF":5.3,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142651127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multifunctional nanocomposites based on kaolinite/titania/iron applied to hydrogen peroxide production and bisphenol–A removal","authors":"Marcus Vinicius do Prado ,&nbsp;Vinicius Lima ,&nbsp;Larissa Oliveira ,&nbsp;Eduardo J. Nassar ,&nbsp;Liziane Marçal ,&nbsp;Emerson Henrique de Faria ,&nbsp;Miguel Angel Vicente ,&nbsp;Raquel Trujillano ,&nbsp;Leticia Santamaría ,&nbsp;Antonio Gil ,&nbsp;Sophia Korili ,&nbsp;Katia Jorge Ciuffi","doi":"10.1016/j.clay.2024.107622","DOIUrl":"10.1016/j.clay.2024.107622","url":null,"abstract":"<div><div>The rising global demand for hydrogen peroxide, recognized for its eco–friendly properties, underscores the need for greener synthesis methods. Traditional production processes pose environmental risks, while direct synthesis faces challenges like water formation, explosion hazards, and stability issues, limiting industrial application. On the other hand, Bisphenol A (BPA), an endocrine disruptor widely used in plastics, presents significant environmental and health concerns due to its potential leaching into food and water. The present work introduces efficient and selective photocatalysts aimed at sustainable hydrogen peroxide synthesis and BPA degradation. Both processes were enhanced by the synergistic properties of Fe₂O₃–TiO₂ nanoparticles dispersed within a kaolinite matrix. The Fe₂O₃–TiO₂ photocatalysts, characterized by photoluminescence spectroscopy and X–ray diffraction, showed reduced emission upon iron incorporation and anatase presence on the kaolinite surface. The photocatalytic activity was evaluated through hydroxylation of terephthalic acid, revealing a 127 μmol/L min hydroxylation rate for the <em>KaFeTi400</em> sample. BPA degradation studies indicated optimal performance in acidic conditions, achieving 96 % removal in 2 h and 98 % in 4 h, with the addition of H₂O₂ enhancing efficiency. Further, the photocatalyst facilitated benzyl alcohol oxidation to benzaldehyde, demonstrating a H₂O₂ production rate of 120 μmol. These findings highlight the multifunctional capabilities and environmental benefits of the photocatalyst, underscoring its potential for sustainable hydrogen peroxide synthesis and broader applications in environmental remediation. The catalysts address the pressing challenges associated with hydrogen peroxide synthesis and pollutant removal, particularly in the context of sustainability and environmental impact.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107622"},"PeriodicalIF":5.3,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142593190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design and characterization of multicolor water-repellent coatings: Impact of alkyl chain length on surface properties","authors":"Ceren Özcan Diker,&nbsp;Osman Duman,&nbsp;Sibel Tunç","doi":"10.1016/j.clay.2024.107626","DOIUrl":"10.1016/j.clay.2024.107626","url":null,"abstract":"<div><div>Fabrication of functional colored water-repellent surfaces is very important for many industrial applications. Here, various colorful surface coating materials having water repellent property, chemical, thermal and UV light resistance and self-cleaning property were prepared using activated halloysite nanotube loaded with dye (A-Hal/dye), different alkoxysilanes (methyltriethoxysilane (MTES), octyltriethoxysilane (OTES) and hexadecyltrimethoxysilane (HDTMS)), and tetraethoxysilane and their coatings were performed on various substrates to determine the effect of alkyl chain length of alkoxysilane compound used in the coating formulation on the surface properties of colorful surfaces. Characterization studies of the synthesized surfaces or coated materials were performed using electron microscopy (TEM and SEM), SEM-mapping, FTIR, XRD, XPS and thermal gravimetic analysis techniques. Water contact angle (WCA) of glass surfaces coated with A-Hal/MB/MTES, A-Hal/MB/OTES and A-Hal/MB/HDTMS materials was found to be 148.0, 156.2 and 159.3°, respectively. The use of an alkoxysilane compound with long functional alkyl chain group in the coating formulation improved the water-repellent property of surface, while it slightly weakened the mechanical stability of the colorful surface. Polydimethylsiloxane (PDMS) coating, which were applied on colorful surfaces, improved the mechanical, thermal, chemical and environmental stability of coating, but decreased the water-repellent property of coated colorful surfaces. Fabricated coating materials having different colors were successfully used to coat various substrates such as glass, filter paper, wood, and cotton fabric. The results of this study show that A-Hal/dye/HDTMS coating materials prepared here are of a great potential in the fabrication of functional surface coatings.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107626"},"PeriodicalIF":5.3,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142593191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of amino-functionalized CoAl-LDH/palygorskite hierarchical composites for CO2 capture","authors":"Shixiang Zuo ,&nbsp;Min Sun ,&nbsp;Weifeng Gong ,&nbsp;Tongtong Tang ,&nbsp;Xuhua Ye ,&nbsp;Wenjie Liu ,&nbsp;Ngie Hing Wong ,&nbsp;Rong Xu ,&nbsp;Guihua Chen ,&nbsp;Chao Yao ,&nbsp;Haoguan Gui ,&nbsp;Xiazhang Li","doi":"10.1016/j.clay.2024.107625","DOIUrl":"10.1016/j.clay.2024.107625","url":null,"abstract":"<div><div>Layered double hydroxides (LDH) are regarded as an outstanding adsorbent with the ability to capture CO₂. Nevertheless, the stacking and curling of CoAl-LDH significantly impact the CO₂ adsorption performance. In this study, CoAl-LDH were synthesized on a rigid palygorskite (Pal) framework to form a hierarchical CoAl-LDH/Pal composite, which effectively reduced the original particle size of CoAl-LDH and addressed the drawbacks. Subsequently, polyethylene imine (PEI) was impregnated onto the surface of CoAl-LDH/Pal to fabricate PEI/CoAl-LDH/Pal adsorbent, further improving the CO₂ capture performance. Finally, the mechanism of CO₂ adsorption was also elaborated. The PEI/CoAl-LDH/Pal demonstrated a higher equilibrium adsorption capacity and a longer breakthrough time for CO₂ capture, with the adsorption capacity reaching 158.8 mg/g and increasing by 8 times compared to that of CoAl-LDH/Pal. Herein, CO₂ was adsorbed on the surface of PEI/CoAl-LDH/Pal in the forms of bicarbonate and amino carboxylate. Additionally, PEI/CoAl-LDH/Pal exhibited excellent regeneration performance and maintained the adsorption capacity over 9 cycles, which is anticipated to be a promising candidate for CO₂ capture.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107625"},"PeriodicalIF":5.3,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142586269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic leaching of lithium from clay-type lithium ore using sulfuric acid and oxalic acid","authors":"Fengyuan Wang,&nbsp;Min Yang,&nbsp;Yuchun Yang,&nbsp;Yanling Tian","doi":"10.1016/j.clay.2024.107623","DOIUrl":"10.1016/j.clay.2024.107623","url":null,"abstract":"<div><div>With the escalating market demand for lithium, the development and efficient utilization of lithium resources have become crucial. This study introduced a method for leaching lithium from raw clay-type lithium ores using a composite sulfuric acid oxalic acid system. The experimental results revealed that the optimal conditions for the leaching process included roasting temperature of 600 °C, sulfuric acid concentration of 0.8 mol/L, liquid-solid ratio of 5 mL/g, leaching temperature of 90 °C, leaching duration of 90 min, and oxalic acid dosage of 2 g. Under these conditions, the leaching efficiency of lithium reached 93.45 %. The structural changes during the lithium leaching process and leaching mechanism were analyzed by XRD, SEM, TOF-SIMS. It was found that the minerals after mixed-acid leaching showed a loose morphology, a decrease in the average particle size, and a significant increase in the specific surface area as well as the pore volume, leading to improved lithium leaching efficiency. Furthermore, the mechanism underlying the mixed-acid leaching of lithium from clay-type lithium ores was explored. According to this mechanism, sulfuric acid first dissociated H⁺, which disrupted the mineral structure, allowing further destruction by oxalic acid. During this process, Li⁺ was continuously replaced by H⁺ and reacted with C₂O₄²⁻ dissociated from oxalic acid to form water-soluble Li₂C₂O₄.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107623"},"PeriodicalIF":5.3,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Maximizing the efficiency of layered double hydroxides as a slow-release phosphate fertilizer: A study on the impact of plant growth-promoting rhizobacteria","authors":"Amir Hassanzadeh ,&nbsp;Mohsen Hamidpour ,&nbsp;Payman Abbaszadeh Dahaji ,&nbsp;Abdolreza Akhgar ,&nbsp;Khalil Kariman","doi":"10.1016/j.clay.2024.107620","DOIUrl":"10.1016/j.clay.2024.107620","url":null,"abstract":"<div><div>Layered double hydroxides (LDH) have gained considerable attention for their potential application in agriculture, serving as a slow-release source of essential nutrients for plants. This study aimed to investigate the effects of Mg-Al-LDH materials (with M²⁺/M³⁺ ratios of 2:1 and 3:1) intercalated with phosphate, both with and without the presence of two plant growth-promoting rhizobacteria (PGPR) strains, on maize growth and the uptake of phosphorus (P), magnesium (Mg), and manganese (Mn). The LDH materials were synthesized, and their properties were assessed by X-ray diffraction (XRD) patterns, Fourier-transform infrared (FT-IR) spectra, and elemental analysis. In an in vitro experiment, the P solubilization capacity of five PGPR strains was evaluated, and the two most effective strains (<em>Bacillus anthracis</em>: B1 &amp; <em>Pseudomonas</em> sp.: B2) were selected for the subsequent pot trials (greenhouse). In the pot experiment, the effectiveness of these two bacterial strains was evaluated in relation to the availability of P for maize plants from specific quantities of Mg-Al-LDH-P (2:1) and Mg-Al-LDH-P (3:1) materials amended in 500 g of soil, providing P concentrations of 0, 50, and 100 mg kg⁻¹. A treatment of triple superphosphate (TSP) was also included as a fast-release P source (50 mg P kg⁻¹). Irrespective of the type of LDH used, the application of LDHs significantly increased the shoot and root biomass of maize plants; the LDH effect was similar or even higher than that of the TSP, driven by the LDH type and P content. The application of LDHs and TSP resulted in higher shoot P concentration in maize plants compared to the untreated control. Inoculation with both bacterial strains increased the shoot P concentration of maize plants in the absence of any P treatments. Moreover, both bacterial strains increased the shoot P concentration of plants in LDH 2:1 (100 mg P kg⁻¹) and TSP treatments, indicating synergistic interactions between PGPR and LDH 2:1 and TSP (while no synergism was found between PGPR and other LDH treatments). Without any LDH/TSP application, only the B1 strain increased the shoot and root biomass of plants compared to the non-inoculated control. In terms of shoot biomass, no synergistic effects were observed in any PGPR-LDH combinations compared to the individual application of PGPR and LDH, which could possibly be due to the short growth period (40 days) of plants. Overall, this study suggests that LDH (2,1) and LDH (3,1) can effectively serve as a P source for enhancing plant growth under P deficiency conditions. Furthermore, the results underscore the potential of PGPR strains to release P from P-containing LDH compounds, which could vary based on the molar ratios of metal cations in LDHs.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107620"},"PeriodicalIF":5.3,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142578315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption behaviors of U(VI) in aqueous solution by cetyltrimethylammonium bromide modified montmorillonite-hydroxyapatite composite adsorbent","authors":"Ting Xiong,&nbsp;Bowen Zheng,&nbsp;Keding Li,&nbsp;Lin Zhang,&nbsp;Shuai Zhang","doi":"10.1016/j.clay.2024.107609","DOIUrl":"10.1016/j.clay.2024.107609","url":null,"abstract":"<div><div>In this task, a novel montmorillonite composite (CMH) was successfully prepared by surfactant modifying with cetyltrimethylammonium bromide (CTAB) and compounding with hydroxyapatite (HAP). In contrast to nature montmorillonite (MMT), CMH showed better U(VI) adsorption properties (<em>R</em> &gt; 99 %) in a wide adsorbent dose range (0.2 to 1.0 mg/L) with the initial U(VI) concentration of 10 mg/L at pH = 5.0 and <em>T</em> = 298 K. The adsorption capacity of CMH for U(VI) reached 678.6 mg/g, which was much higher than most of reported clay-based adsorbents, suggesting that the adsorption performances of CMH were at the upper-middle level among clay-based adsorbents. In addition, CMH also performed good recoverability with the adsorption efficiency of 96.2 % after five cycles and could still maintain relatively high U(VI) adsorption capacity even during complex water system, which was expected to be used for adsorbing U(VI) from various water environment. In terms of the differences in morphology, structure and composition between MMT and CMH, the excellent U(VI) adsorption performances of CMH could be explained by the rougher surface, larger interlayer spacing and more pores and functional groups, thus providing more binding sites. The adsorption mechanism involved electrostatic interaction, ion exchange and complexation. This job supplied a novel opinion for the explore of low cost and highly efficient adsorbent synthesis for U(VI) adsorption.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107609"},"PeriodicalIF":5.3,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142552242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Design of deep eutectic solvents modified palygorskite for selective recognition, mechanism study and stable preservation of quercetin","authors":"Rongpeng Yu ,&nbsp;Qinya Huang ,&nbsp;Zhiwei Ding ,&nbsp;Yiran Li ,&nbsp;Chaoyang Li ,&nbsp;Zhanchao Liu ,&nbsp;Yan Liu","doi":"10.1016/j.clay.2024.107621","DOIUrl":"10.1016/j.clay.2024.107621","url":null,"abstract":"<div><div>Considering the effect of secondary metabolites on quercetin (QC) separation and purification in plants, herein, four types of hydrophilic deep eutectic solvents (DESs) composed by organic acids and glycosyl-, quaternary ammonium- or alcohol-based hydrogen bond acceptors were designed and modified on the palygoskite (Pal) surface to improve the selectivity of QC via dispersive solid-phase extraction (D-SPE). The selectivity study followed the following order: Pal- [Choline chloride (ChCl)] [Levulinic acid (Lev)] &gt; Pal- [Glycerol (Gly)] [L-Proline (Pro)] &gt; Pal- [Glucose (Glu)] [D-lactic acid (Lac)] &gt; Pal- [Benzyl triethyl ammonium chloride (BTBAC)] [D-lactic acid (Lac)]. Based on the single-factor method, Response surface methodology (RSM) by using a Box-Behnken design (BBD) was applied to assess the mutual interactions and effects between the three factors and the optimized preparation conditions. The optimal nanoparticles (Pal- [ChCl] [Lev]) showed the best adsorption capacity for QC (29.81 mg/g) in the mixture of methanol and phosphate buffered solution (PBS) and high selectivity which was 1.95 times and 2.12 times that of luteolin and rutin hydrate, respectively. Mechanism exploration indicated that Pal-DESs selectively adsorbed QC via electrostatic interaction, π-π stacking and hydrogen bonds. Furthermore, the screened DES of ([ChCl] [Lev]) could act on QC aqueous solution to improve its solubility and stability during preservation. The proposed QC separation strategy centered on the guiding role of DESs in selective adsorption. Additional alternatives for the synthesis of high-efficiency and hydrophilic functional adsorbents for flavonoids were made available by this green DESs regulation concept.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107621"},"PeriodicalIF":5.3,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142552248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Fe-ZSM-5 zeolite from high iron-containing palygorskite with peroxidase-like catalytic performance","authors":"Fengya Ran ,&nbsp;Meng He ,&nbsp;Shiyong Sun ,&nbsp;Rui Lv ,&nbsp;Sen Lin ,&nbsp;Ke Wang ,&nbsp;Yevgeny Aleksandrovich Golubev ,&nbsp;Olga Borisovna Kotova ,&nbsp;Elena Leonidovna Kotova","doi":"10.1016/j.clay.2024.107619","DOIUrl":"10.1016/j.clay.2024.107619","url":null,"abstract":"<div><div>Zeolite products synthesized from mineral materials are receiving widespread attention, while there are few reports on the introduction of heteroatom metals from minerals into zeolites. Herein, the effects of different silicon sources, hydrothermal reaction time and the amount of template on the crystallisation of Fe-ZSM-5 were investigated. The morphology and structure of ZSM-5 were characterized by X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT-IR), X-ray electron spectroscopy (XPS) and scanning electron microscopy (SEM). The catalysis of 3,3′,5,5′-tetramethylbenzidine (TMB) by Fe-ZSM-5 was then carried out to evaluate its enzyme-like catalytic performance as a type of nanozyme catalyst. The results showed that Fe-ZSM-5 exhibited peroxidase-like activity, oxidizing TMB into a colored substance in the presence of hydrogen peroxide (H₂O₂). Kinetic analysis implied that, compared with natural horseradish peroxidase (HRP), Fe-ZSM-5 peroxidase mimics exhibit inferior affinity and enzymatic catalytic velocity towards the TMB substrate. However, it exhibited excellent stability under extreme pH, temperature, and ionic strength conditions. This work provides a possible reference for the construction of functional nanozymes using natural mineral resources.</div></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"262 ","pages":"Article 107619"},"PeriodicalIF":5.3,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142552241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}