Applied Catalysis B: Environmental最新文献

{"title":"Nanoconfinement-engineered sintering-resistant Pt–high-entropy alloy clusters for dehydrogenation","authors":"Xiaojin Tian, Shu Yuan, Panpan Wang, Bochen Zhao, Zequn Zhang, Pengfei Zhang","doi":"10.1016/j.apcatb.2025.126202","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126202","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126202-126202"},"PeriodicalIF":0.0,"publicationDate":"2025-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147910152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cd vacancies and Pt-Pd single atoms induced symmetry breaking in CdS for efficient piezo-photocatalytic hydrogen evolution","authors":"Haoqiang Feng, Yike Li, Xian Liu, Kang Wang, Qingyang Du, Ying-Ju Wang, Zhongjun Li","doi":"10.1016/j.apcatb.2025.126204","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126204","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126204-126204"},"PeriodicalIF":0.0,"publicationDate":"2025-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147895388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering W-O-Co interfacial electron bridge in transition metal phosphide/tungsten oxide heterostructure enables ampere-level hydrogen production from seawater electrolysis","authors":"Dong Yan, Xuetao Cheng, Xiaoxiao Dong, Yan Wang, Xianfeng Chang, Chenghui Xia, Yongcheng Jin, Chun‐Chao Hou","doi":"10.1016/j.apcatb.2025.126203","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126203","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126203-126203"},"PeriodicalIF":0.0,"publicationDate":"2025-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface and spatial engineering of ZnAl hollow multi-shelled structures for photothermal synergistic catalysis of glycerol carbonate synthesis","authors":"Hongpeng Zhang, Jie Wang, Jielin Huang, Haonan Duan, Li Dong, Suojiang Zhang","doi":"10.1016/j.apcatb.2025.126197","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126197","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126197-126197"},"PeriodicalIF":0.0,"publicationDate":"2025-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147922520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Kinetic elucidation of F-Niδ+-O coordination motifs enriched nickel oxide nanosheets for biomass valorization","authors":"Ye Chen, Xiaokang Sha, Junpo Guo, Xupo Liu, Meinan Chang, Jiayao Qiu, Jingru Zhang, Bowen Cai, Jiashu Tang, Yi Liu, Huaiyu Shao, Deli Wang","doi":"10.1016/j.apcatb.2025.126190","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126190","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126190-126190"},"PeriodicalIF":0.0,"publicationDate":"2025-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147917891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dynamic dissolution-reorganization of molybdenum triggers synergistic electrocatalysis on copper for efficient nitrate-to-ammonia conversion","authors":"Xuran Mao, Yanbing Huang, Yue Xiao, Xun Liu, Yan Pei, Qianwen Chen, X.H. Wang, Wen Guo, Hong‐Bing Yang, Fuxi Bao","doi":"10.1016/j.apcatb.2025.126187","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126187","url":null,"abstract":"Developing highly efficient and robust electrocatalysts to enhance the kinetics of electrochemical nitrate reduction reaction (NO 3 RR) to ammonia is crucial for realizing the conversion and storage of green electrochemical ammonia energy. Herein, we constructed a molybdenum-doped metallic copper electrocatalyst (Cu-Mo 0.2 /NF) and systematically investigated the pivotal role of molybdenum dynamic recombination in enhancing the kinetics of the NO 3 RR. In situ Raman spectroscopy, XPS and ICP-OES reveals that Mo dissolves during the NO 3 RR process and recombines into Mo 2 O 7 2- species, which are adsorbed onto the surface of the electrocatalyst. The experimental results combined with DFT calculations indicates that this dynamic dissolution, reorganization, and adsorption process of Mo significantly activates *NO 3 , thereby greatly enhancing the kinetics of *NO 3 reduction to *NO 2 . Furthermore, Differential electrochemical mass spectrometry (DEMS) and in situ attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) elucidate the NO 3 RR pathway: *NO 3 → *NO 2 → *NO → *NOH → *N → *NH → *NH 2 → *NH 3 . This reaction mechanism, which circumvents high-energy-barrier step (NO → N 2 O), endows the electrocatalyst with superior kinetics and high selectivity. Benefiting from the dynamic dissolution and redeposition of Mo and the advantages of the reaction pathway, the electrocatalyst achieves a record ammonia yield ( 1.55 mmol h -1 cm -2 ) with near-unity Faradaic efficiency ( 98.99% ), and 30 h stability. The Mo-doped metallic copper electrocatalyst supported on nickel foam (Cu-Mo 0.2 /NF) was designed. During the NO 3 RR process in alkaline media, Mo dissolves into the electrolyte and is subsequently transformed into adsorbed Mo 2 O 7 2- species on the electrocatalyst surface. The dynamic reconstruction of Mo 2 O 7 2- accelerates * NO 3 →* NO 2 kinetics for NO 3 RR, achieving a record ammonia yield of 1.55 mmol h -1 cm -2 with 98.99% Faraday efficiency. • The Cu-Mo 0.2 /NF was fabricated via a one-step electrodeposition method. • In situ Raman spectroscopy revealed the dissolution-redeposition mechanism of Mo. • The formed Mo 2 O 7 2- species can accelerate the * NO 3 → * NO 2 kinetics. • The electrocatalyst achieves an NH 3 yield of 1.55 mmol h -1 cm -2 with 98.99% FE. • In situ experiments (DEMS and ATR-FTIR) revealed the NO 3 RR pathway.","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126187-126187"},"PeriodicalIF":0.0,"publicationDate":"2025-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Iron-doped nickel hydroxide heterostructures derived from in-situ grown nickel complex nanotube arrays for efficient overall water splitting","authors":"Fang Wang, Qixiang Huang, Jiangzhuo Ren, Biying Zhang, Fangya Guo, Liangbin Xia, Ting Feng, Zhouqiu Jia, Shuoyang Wang, Fengzhang Ren, Zixu Sun, Andreu Cabot","doi":"10.1016/j.apcatb.2025.126182","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126182","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126182-126182"},"PeriodicalIF":0.0,"publicationDate":"2025-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147896761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boosting electron transfer in Lewis-acid MOF facilitates photoreduction of CO2 to ethanol","authors":"Lifei Liu, Luyuan Zhang, Xiaorui Du, Pengfei Li, Ruonan Wang, Yang Deng, Xia An, Xu Wu","doi":"10.1016/j.apcatb.2025.126183","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126183","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126183-126183"},"PeriodicalIF":0.0,"publicationDate":"2025-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147330577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Precisely tuned mesoporous Mn-Ti-Al oxide catalysts for highly efficient and selective low-temperature NOx reduction","authors":"Jingjing Liu, Mengyuan Zhang, Diru Liu, Yunbo Yu, Guangyan Xu, Hong He","doi":"10.1016/j.apcatb.2025.126167","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126167","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126167-126167"},"PeriodicalIF":0.0,"publicationDate":"2025-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147920807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boron crystal nanostructure induced *NH2 spilling over boron modified Cu catalyst to greatly enhance urea synthesis at a low overpotential","authors":"Yu-xin Xu, Xinyu Chen, Qixin Yuan, Yuhan Wu, Kui Wang, Kang Sun, Jianfang Zhang, Jingjie Wu, Jianchun Jiang, Mengmeng Fan","doi":"10.1016/j.apcatb.2025.126164","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.126164","url":null,"abstract":"","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"384 1","pages":"126164-126164"},"PeriodicalIF":0.0,"publicationDate":"2025-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}