Applied Catalysis B: Environmental最新文献_第8页

Surface-bonded water in h-BN for synergistically triggering catalytic activity to hydrogen generation from ammonia borane via coordination dissociation h-BN中的表面键合水通过配位解离协同触发氨硼生成氢的催化活性

1区化学

Applied Catalysis B: Environmental Pub Date : 2025-07-25 DOI: 10.1016/j.apcatb.2025.125729

Huanhuan Zhang, Shuling Liu, Ruofan Shen, Saima Ashraf, Sehrish Mehdi, Shuyan Guan, Yanping Fan, Zhikun Peng, Jianchun Jiang, Baozhong Liu, Yongfeng Wang, Yanyan Liu, Baojun Li

{"title":"Surface-bonded water in h-BN for synergistically triggering catalytic activity to hydrogen generation from ammonia borane via coordination dissociation","authors":"Huanhuan Zhang, Shuling Liu, Ruofan Shen, Saima Ashraf, Sehrish Mehdi, Shuyan Guan, Yanping Fan, Zhikun Peng, Jianchun Jiang, Baozhong Liu, Yongfeng Wang, Yanyan Liu, Baojun Li","doi":"10.1016/j.apcatb.2025.125729","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.125729","url":null,"abstract":"Developing catalysts with efficient activity to the reaction systems with water dissociation represents a significant and challenging mission in chemistry. Herein, CoP nanosheets supported on h-BN with surface-bonded water (CoP/h-BN OH ) is designed through a P-inducing strategy to stimulate the activity toward hydrogen generation. Hydroxyl functional groups (−OH) binds to B sites preferentially on h-BN surface during the process of surface hydroxylation to form B OH . The P-inducing strategy modulates the electronic configuration nearby Co and combines with B OH to facilitate the catalytic activity. The optimal catalyst exhibits a state-of-the-art turnover frequency (TOF) of 43 min −1 with considerable stability in NH 3 BH 3 hydrolysis. The rapid hydrogen generation during NH 3 BH 3 hydrolysis is ascribed to the integration of the active sites of B OH and CoP. Both experiments and theory demonstrate that reactant molecules (NH 3 BH 3 and H 2 O) adsorption and dissociation are mediated by the existence of B OH and CoP dual-active sites (B OH activates H 2 O, Co-P activates NH 3 BH 3 ). This work sheds fresh light on the design of efficient non-noble catalysts and motivates the exploration of hydrogen energy utilization technologies. CoP nanosheet supported on h-BN with surface-bonded water (CoP/h-BN OH ) is designed through a P-inducing strategy to stimulate the catalytic activity toward hydrogen generation. The catalyst exhibits a superior kinetics with favorable stability in hydrogen generation from ammonia borane hydrolysis. • CoP supported on h-BN with surface-bonded water was designed via a P-inducing strategy. • A TOF of 43 min −1 was achieved for NH 3 BH 3 hydrolysis on dual-active sites. • DFT calculation revealed the catalytic mechanism of B OH and CoP in hydrolysis reaction.","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"379 1","pages":"125729-125729"},"PeriodicalIF":0.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Selective recognition and activation for accelerated decarboxylation and C–F bond cleavage of perfluorooctanoic acid 全氟辛酸加速脱羧和C-F键裂解的选择性识别和激活

1区化学

Applied Catalysis B: Environmental Pub Date : 2025-07-25 DOI: 10.1016/j.apcatb.2025.125735

Ziwen An, Qihao Xie, Shaohan Xu, Baoling Niu, Ling-Zhi Sun, Jingui Zheng, Guohua Zhao

引用次数: 3

Self-reconstructing amorphous high-entropy oxides for CO2-free methanol electroreforming and hydrogen generation 用于无二氧化碳甲醇电重整和制氢的自重构无定形高熵氧化物

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Applied Catalysis B: Environmental Pub Date : 2025-07-22 DOI: 10.1016/j.apcatb.2025.125721

Xi Liu, Xueting Zhao, Zhiwen Lu, Kai Chen, Jiyuan Gao, Huibing Wang, Junxiang Chen, Zhenhai Wen

引用次数: 3

Synergistic doping and defect engineering of CoS2 building electron cycle sites Co−N−Fe···SV for enhanced Fenton-like reaction Co - N - Fe···SV的协同掺杂与缺陷工程

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Applied Catalysis B: Environmental Pub Date : 2025-07-22 DOI: 10.1016/j.apcatb.2025.125719

Zhimo Fang, Yuan Liang, Zepeng Zeng, Haotian Bai, Zhou Zhou, Lin Zhang, Bin Hu, Yang ShiGuan, Jihong Li, Qiang Lü

引用次数: 2

Asymmetrically coordinated Ru-O site facilitates H2 heterolytic cleavage for efficient green reductive amination of octanol to octylamine: A mechanistic investigation 不对称配位的Ru-O位点促进H2异裂裂解，使辛醇绿色还原胺化成为辛胺：机理研究

1区化学

Applied Catalysis B: Environmental Pub Date : 2025-07-17 DOI: 10.1016/j.apcatb.2025.125708

Zhexi Gao, Qian Wang, Haoran Ma, Huifang Wu, Richard Lewis, Dave Willock, Ouardia Akdim, Junting Feng, Graham J. Hutchings

{"title":"Asymmetrically coordinated Ru-O site facilitates H2 heterolytic cleavage for efficient green reductive amination of octanol to octylamine: A mechanistic investigation","authors":"Zhexi Gao, Qian Wang, Haoran Ma, Huifang Wu, Richard Lewis, Dave Willock, Ouardia Akdim, Junting Feng, Graham J. Hutchings","doi":"10.1016/j.apcatb.2025.125708","DOIUrl":"https://doi.org/10.1016/j.apcatb.2025.125708","url":null,"abstract":"The catalytic reductive amination of octanol exhibits a promising and environmentally friendly pathway for the synthesis of octylamine, a compound with significant applications in the bulk and fine chemical sectors. However, the complexity of this reaction lies in the necessity of a catalyst that can simultaneously facilitate both the dehydrogenation and hydrogenation steps, occurring during the reaction. Herein, we have addressed this issue by designing a Ru@TiOx/Mg9Al6Ti6Ox catalyst with Ru-Ru and Ru-O asymmetric coordination structure that leads to 100 % octanol conversion, 94.6 % octylamine selectivity and a turn over frequency of 73.41 h−1, while maintaining the same activity for 4 consecutive cycles. Those performances, firmly positioning our catalyst among the most advanced and efficient catalysts reported to date. Using EXAFS, in situ FTIR, kinetic isotope experiments, and DFT calculations, we proposed a mechanism where Ru-O coordination structure promote the heterolytic cleavage of H2, producing highly active H+/H- species that can achieve efficient hydrogenation without hindering the dehydrogenation process. This work not only provides a promising catalyst for industrial application, but presents a valuable catalyst design strategy that involves complex tandem dehydrogenation/hydrogenation reactions.","PeriodicalId":244,"journal":{"name":"Applied Catalysis B: Environmental","volume":"379 1","pages":"125708-125708"},"PeriodicalIF":0.0,"publicationDate":"2025-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 5

Modulating adsorption configuration of intermediates on Cu-In dual-atom catalyst for boosted urea electrosynthesis Cu-In双原子催化剂对尿素电合成中间体吸附构型的调节

1区化学

Applied Catalysis B: Environmental Pub Date : 2025-07-17 DOI: 10.1016/j.apcatb.2025.125710

Leyi Chen, Shuai Yang, Songyuan Yao, Zhihao Si, Guiqiang Ding, Peng Zhan, Jing Song, Meng Cui, Lu Lu, Peiyong Qin

引用次数: 5

Strong hetero-interfacial interactions mediated photocatalytic 3-electron oxygen reduction to hydroxyl radicals for wastewater decontamination 强异界面相互作用介导光催化3-电子氧还原为羟基自由基用于废水去污

1区化学

Applied Catalysis B: Environmental Pub Date : 2025-07-15 DOI: 10.1016/j.apcatb.2025.125688

Hao Du, Boxiong Shen, Rubin Huo, Yuxin Hui, Chao Chen, Aoxiang Liu, Zhe Zhang, Chunjuan Li, Bing‐Jie Ni, Derek Hao, Qi Wang

引用次数: 12

Boosting the glycerol tandem oxidation to glyceric acid via the rate determination step alteration 通过速率测定步骤的改变促进甘油串联氧化生成甘油酸

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Applied Catalysis B: Environmental Pub Date : 2025-07-04 DOI: 10.1016/j.apcatb.2025.125668

Yiwei Jiang, Mingbo Yang, Guandong Wu, Rui Ma, Dianqing Li, Yufei He

引用次数: 2

Pd-modified Bi2O3 catalyst for efficient CO2 electrolysis to formic acid 钯改性Bi2O3催化剂用于CO2电解制甲酸

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Applied Catalysis B: Environmental Pub Date : 2025-07-02 DOI: 10.1016/j.apcatb.2025.125649

Long Cheng, Rong Wang, Yaming Wang, Xingxia Yang, Yanxi Deng, Junhua Li

引用次数: 3

Dual-metal-catalyzed Fenton-like reaction on CdxZn1-xS @biochar: Mechanistic insights into sulfide-metal interactions for water purification CdxZn1-xS @生物炭上双金属催化的类芬顿反应：硫化物-金属相互作用对水净化的机理研究

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Applied Catalysis B: Environmental Pub Date : 2025-07-02 DOI: 10.1016/j.apcatb.2025.125654

Xiaohong Zhao, Jianhua Tong, Sai Bai, Jin Qian

引用次数: 14