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Plastic litter is a part of the carbon cycle in an urban river: Microplastic and macroplastic accumulate with organic matter in floating debris rafts. 塑料垃圾是城市河流碳循环的一部分:微塑料和大塑料与有机物一起积聚在漂浮的碎屑筏中。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11116
Timothy J Hoellein, Bailey A Schwenk, Elizabeth M Kazmierczak, Fritz Petersen
{"title":"Plastic litter is a part of the carbon cycle in an urban river: Microplastic and macroplastic accumulate with organic matter in floating debris rafts.","authors":"Timothy J Hoellein, Bailey A Schwenk, Elizabeth M Kazmierczak, Fritz Petersen","doi":"10.1002/wer.11116","DOIUrl":"https://doi.org/10.1002/wer.11116","url":null,"abstract":"<p><p>Watershed models of plastic export from rivers to oceans have large uncertainties, and improvements require direct measurements of riverine macroplastic (>5 mm) and microplastic (<5 mm). Also, plastic represents allochthonous carbon inputs to rivers but is rarely measured as carbon mass. We quantified plastic and organic matter within floating debris rafts and open water in an urban river. Macroplastics only occurred in debris rafts. Microplastics had higher concentrations in debris rafts relative to open water. Across sites, organic matter was positively correlated with microplastics and macroplastics. Last, carbon in plastic was 40% of the carbon mass in coarse particulate organic matter in debris rafts. Floating plastic litter accumulates with particulate organic matter in debris rafts. Plastic is an overlooked and ecological meaningful component of carbon standing stocks in urban rivers. Results will inform improved carbon budget calculation in rivers and watershed models of plastic export. PRACTITIONER POINTS: Plastic particles floating on the surface of an urban river accumulate in debris rafts compared to open water in terms of count and mass. Abundance and composition of plastic particles in debris rafts were distinct from those in open water areas. Plastic litter as units of carbon mass was in the same order of magnitude as carbon mass in course particulate organic matter. Plastic litter moves in similar ways to naturally occurring organic particles and should be measured as a part of the riverine carbon cycle.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11116"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142112522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microplastic evidence assessment from water and sediment sampling in a shallow tropical lake. 从热带浅水湖泊的水和沉积物取样中评估微塑料证据。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11123
Samuel Macario Padilla-Jimenez, Rodrigo Moncayo-Estrada, Daniel Tapia Maruri, Dioselina Álvarez-Bernal
{"title":"Microplastic evidence assessment from water and sediment sampling in a shallow tropical lake.","authors":"Samuel Macario Padilla-Jimenez, Rodrigo Moncayo-Estrada, Daniel Tapia Maruri, Dioselina Álvarez-Bernal","doi":"10.1002/wer.11123","DOIUrl":"https://doi.org/10.1002/wer.11123","url":null,"abstract":"<p><p>Microplastics (MPs) severely threaten inland waterbodies due to the direct impact of human activities. In the present study, spatial and temporal patterns of MPs in a shallow tropical lake were assessed, describing their size, morphology, and polymer types. Water and sediment samples were collected from Lake Chapala during three seasons, and MPs were quantified with a stereomicroscope. The structure, elemental composition, and polymeric composition were determined via environmental scanning electron microscopy and Fourier transform infrared spectroscopy. The highest average concentration of microplastics in Lake Chapala was detected during the low-water period in April 2022 (2.35 items/L), exceeding the July 2022 rainy season concentration (1.8 items/L) by 0.25 items/L, and sediment concentrations were also higher in April 2022 (219 items/kg) compared to July 2022 (210 items/kg). This study highlights the significant pollution of Lake Chapala with microplastics, emphasizing the need for urgent measures to manage plastic waste and mitigate its environmental impact on aquatic ecosystems. PRACTITIONER POINTS: Microplastic contamination was evaluated in Lake Chapala. The distribution profiles of microplastics were different in each area. Heavy metals osmium, tellurium, and rhodium were found associated with the PMs. Polymers were found in this study.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11123"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142120695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimized Ginkgo leaf biochar: An efficient adsorbent for 2,4-D herbicide removal from wastewater. 优化的银杏叶生物炭:去除废水中 2,4-D 除草剂的高效吸附剂。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11124
Wenyu Ma, Rui Song, Yujiao Wang, Xiaoyan Cui, Yumei Yan, Zhili Liu, Xiaojun Wang, Haixiang Gao, Runhua Lua, Wenfeng Zhou
{"title":"Optimized Ginkgo leaf biochar: An efficient adsorbent for 2,4-D herbicide removal from wastewater.","authors":"Wenyu Ma, Rui Song, Yujiao Wang, Xiaoyan Cui, Yumei Yan, Zhili Liu, Xiaojun Wang, Haixiang Gao, Runhua Lua, Wenfeng Zhou","doi":"10.1002/wer.11124","DOIUrl":"https://doi.org/10.1002/wer.11124","url":null,"abstract":"<p><p>This research exploited biochar, sourced from Ginkgo leaves (GLs), to facilitate the adsorption of 2,4-dichlorophenoxyacetic acid (2,4-D) in aqueous environments. The results reveal that GL biochar, activated with ZnCl<sub>2</sub> at a temperature of 500°C (500-ZGBC), demonstrated the greatest specific surface area (S<sub>BET</sub>) of 536.0 m<sup>2</sup> g<sup>-1</sup> for 2,4-D adsorption. The biochar's properties, including specific surface area, morphology, structure, thermal stability, and functional groups, were analyzed. Additionally, studies of kinetic and isotherm profiles were conducted, yielding the highest recorded adsorption capacity of 281.8 mg g<sup>-1</sup>. Pore filling, hydrogen bonding, π-π interactions, surface complexation with Zn groups, and electrostatic interactions contribute significantly to the adsorption performance of 500-ZGBC for 2,4-D. Optimal adsorption was determined to occur at pH 2.117, with a dose of 0.4230 g L<sup>-1</sup> of 500-ZGBC, and an initial concentration of 2,4-D at 294.7 mg L<sup>-1</sup>, as evidenced by the application of the response surface method (RSM). PRACTITIONER POINTS: Premium pharmaceutical-grade biochar, derived from Ginkgo leaves, boasting a S<sub>BET</sub> of 536.0 m<sup>2</sup> g<sup>-1</sup> was produced. An absorption capacity reaching 281.8 mg g<sup>-1</sup> was observed in Ginkgo leaf biochar for 2,4-dichlorophenoxyacetic acid (2,4-D) adsorption. The adsorption procedure was refined through the employment of response surface methodology.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11124"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142296653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring the characteristics of polyacrylonitrile nanofiltration membranes for nickel removal from wastewater: The influence of binary solvents and pore-forming agents. 调整聚丙烯腈纳滤膜的特性以去除废水中的镍:二元溶剂和孔隙形成剂的影响。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11126
Mehrdad Ghahghaei, Alex Tawanda Kuvarega, Seyed Saeid Hosseini
{"title":"Tailoring the characteristics of polyacrylonitrile nanofiltration membranes for nickel removal from wastewater: The influence of binary solvents and pore-forming agents.","authors":"Mehrdad Ghahghaei, Alex Tawanda Kuvarega, Seyed Saeid Hosseini","doi":"10.1002/wer.11126","DOIUrl":"https://doi.org/10.1002/wer.11126","url":null,"abstract":"<p><p>This work presents the results of an investigation on the physiochemical and structural characteristics of polyacrylonitrile (PAN) nanofiltration (NF) membranes prepared using a novel concept of binary solvents for nickel (Ni) removal from wastewater streams. The thermodynamic and kinetic aspects are emphasized aiming to optimize dope formulation, membrane performance, and durability. The fabricated membranes were characterized by scanning electron microscopy (SEM), porosimetry, tensile stress/strain, and flux and rejection. Results revealed that the use of an equal (1:1) mixture of n-methyl-2-pyrrolidone (NMP) and dimethylformamide (DMF) as dope solvents led to the formation of membranes with enhanced performance, offering pure water flux of 2.33 L·m<sup>-2</sup>·h<sup>-1</sup>·bar<sup>-1</sup> and Ni rejection of 90.84%. Moreover, the incorporation of 0.5 wt.% PEG as a pore-forming agent to the dope solution further boosted pure water flux to 4.97 L·m<sup>-2</sup>·h<sup>-1</sup>·bar<sup>-1</sup> with negligible impact on Ni rejection. Besides attractive performance, the adopted strategy offered membranes of exceptionally high flexibility with no sign of defect or failure especially during module fabrication and testing enabling smooth and hassle-free scale-up and extension to other applications. PRACTITIONER POINTS: Optimized solvent mixture: A 1:1 blend of n-methyl-2-pyrrolidone (NMP) and dimethylformamide (DMF) as solvents resulted in enhanced membrane performance. High flux and Ni rejection: The fabricated membranes exhibited a pure water flux of 2.33 L·m<sup>-2</sup>·h<sup>-1</sup>·bar<sup>-1</sup> and a remarkable Ni rejection of 90.84%. PEG enhancement: Incorporating 0.5 wt.% PEG as a pore-forming agent further improved the membrane's pure water flux to 4.97 L·m<sup>-2</sup>·h<sup>-1</sup>·bar<sup>-1</sup>, without compromising Ni rejection. Exceptional flexibility: The adopted strategy yielded membranes with exceptional flexibility, making them suitable for scale-ups and other applications.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11126"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142296668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Treatment of pulp and paper mill effluent through combined aerobic and anaerobic suspended fixed-bed bioreactor. 通过组合式好氧和厌氧悬浮固定床生物反应器处理纸浆和造纸厂污水。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11133
Apourv Pant, Anuj Kumar Dwivedi, Surajit Murasingh, Deepak Singh, Muskan Mayank, Chandra Shekhar Prasad Ojha
{"title":"Treatment of pulp and paper mill effluent through combined aerobic and anaerobic suspended fixed-bed bioreactor.","authors":"Apourv Pant, Anuj Kumar Dwivedi, Surajit Murasingh, Deepak Singh, Muskan Mayank, Chandra Shekhar Prasad Ojha","doi":"10.1002/wer.11133","DOIUrl":"https://doi.org/10.1002/wer.11133","url":null,"abstract":"<p><p>This study explored using ultrafiltration (UF) membranes to treat pulp and paper mill wastewater, implementing a novel Taguchi experimental design to optimize operating conditions for pollutant removal and minimal membrane fouling. Researchers examined four factors: pH, temperature, transmembrane pressure, and volume reduction factor (VRF), each at three levels. Optimal conditions (pH 10, 25°C, 6 bar, VRF 3) led to a 35% reduction in flux due to fouling and high pollutant rejections: total hardness (83%), sulfate (97%), spectral absorption coefficient (SAC254) (95%), and chemical oxygen demand (COD) (89%). Conductivity had a lower rejection rate of 50%. Advanced imaging techniques like atomic force microscopy (AFM) and scanning electron microscopy (SEM) revealed reduced membrane fouling under these conditions. The Taguchi method effectively identified optimal conditions, significantly improving wastewater treatment efficiency and promoting environmental sustainability in the pulp and paper industry. PRACTITIONER POINTS: This study optimized UF membrane conditions for pulp and paper mill wastewater, reducing fouling and enhancing pollutant removal, offering practical strategies for industrial treatment. AFM and SEM provided key insights into membrane fouling and mitigation, promoting real-time diagnosis and optimization for enhanced treatment efficiency. Prioritizing anaerobic fixed-bed systems in wastewater treatment is beneficial for achieving high COD removal efficiency. Optimizing hydraulic retention time (HRT) in these systems can further improve their overall effectiveness and sustainability.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11133"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142296671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis and calculation of scour critical velocity of suspended particles in a storm sewer. 分析和计算雨水管道中悬浮颗粒的冲刷临界速度。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11135
Haodong Wei, Yuling Xie, Changfeng Zhou, Yang Tao, Jingqin Zhou, Cuiyun Liu
{"title":"Analysis and calculation of scour critical velocity of suspended particles in a storm sewer.","authors":"Haodong Wei, Yuling Xie, Changfeng Zhou, Yang Tao, Jingqin Zhou, Cuiyun Liu","doi":"10.1002/wer.11135","DOIUrl":"https://doi.org/10.1002/wer.11135","url":null,"abstract":"<p><p>The suspended particles in storm sewer can be easily washed away and migrated. However, few studies analyzed the scouring state of suspended particles in pipelines, and also, there was a lack of quantitative calculation. This study simulated the scouring process of suspended particles in a storm sewer with different pipe materials, and mathematical models were built for the scour critical velocity. The results showed that with the increase of particle size, density and the roughness of the pipe wall, the scour resistance of suspended particles increased, and the scouring rate decreased; therefore, the corresponding scour critical velocity increased. In accordance with the scouring rates of quartz sand and zeolite at different flow velocities in the storm sewer, the scouring state of the suspended particles could be divided into three types: no scouring, minor scouring, and massive scouring. The scour critical velocity ranges of quartz sand and zeolite with two densities in four kinds of pipes were determined, and mathematical models for the scour critical velocity of suspended particles were established. After verification, the difference rate between the calculated values and measured values was in the range of -10.56% to 6.63%, and the two values had good consistency. PRACTITIONER POINTS: Scour resistance of suspended particles increases with particle size or density. The smaller the roughness of the pipe wall, the higher the scouring rate. Higher flow velocity leads to a higher scouring rate. As scouring rate rises, no scouring, minor or massive scouring occur in sequence. Difference between the calculated and measured values is from -10.56% to 6.63%.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11135"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142296646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrochemical processes and inorganic nitrogen sources of shallow groundwater in the Sanjiang Plain, northeast China. 中国东北三江平原浅层地下水的水化学过程和无机氮源。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11121
Tingwen Wu, Zhihong Li, Huqun Cui, Weipo Liu, Jiangtao Liu, Xuxue Cheng, Mingzhu Liu
{"title":"Hydrochemical processes and inorganic nitrogen sources of shallow groundwater in the Sanjiang Plain, northeast China.","authors":"Tingwen Wu, Zhihong Li, Huqun Cui, Weipo Liu, Jiangtao Liu, Xuxue Cheng, Mingzhu Liu","doi":"10.1002/wer.11121","DOIUrl":"https://doi.org/10.1002/wer.11121","url":null,"abstract":"<p><p>This study investigates the chemical characteristics, formation, and sources of inorganic nitrogen (IN) of shallow groundwater across the Sanjiang Plain, aiming to enhance drinking water safety management and pollution control. A total of 167 groundwater and 27 surface water samples were collected for constituents and isotopes (H<sup>2</sup> and O<sup>18</sup>). The hydrogeochemical characteristics showed that the major type is HCO<sub>3</sub>- Ca·Mg, with low total dissolved solids and a neutral to weak alkaline nature. Rock weathering processes govern the hydrochemical composition of groundwater. Hydrogen and oxygen stable isotopes analyses revealed that precipitation serves as the main water source. In alluvial areas, oxidative conditions lead to the enrichment of NO<sub>3</sub>-N concentrations, with sewage, manure, and fertilizers being the primary IN sources. In lacustrine areas, intensive rice cultivation results in reductive conditions and strong denitrification processes, causing the loss of NO<sub>3</sub>-N and leaving NH<sub>4</sub>-N as the dominant IN form. Organic matter mineralization is likely a more significant contributor to NH<sub>4</sub>-N concentrations than ammonium fertilizers. These findings provide valuable information for further research on natural sources and groundwater pollution in areas with similar hydrogeological conditions. PRACTITIONER POINTS: Rock weathering processes govern the hydrochemical composition of groundwater, and precipitation serves as the main water source. In alluvial areas, oxidative conditions lead to the enrichment of NO<sub>3</sub>-N. In lacustrine areas, intensive rice cultivation results in reductive conditions and strong denitrification processes. Organic matter mineralization is likely a more significant contributor to NH<sub>4</sub>-N concentrations than ammonium fertilizers. These findings provide references for water management and information for further research on natural sources and groundwater pollution in areas with similar hydrogeological conditions.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11121"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142296651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on soil deformation caused by overexploitation of groundwater. 过度开采地下水导致土壤变形的实验研究。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11111
Lin Sun, Xiuyan Wang, Shuaiwei Wang, Weichao Sun, Jingjing Wang, He Di
{"title":"Experimental study on soil deformation caused by overexploitation of groundwater.","authors":"Lin Sun, Xiuyan Wang, Shuaiwei Wang, Weichao Sun, Jingjing Wang, He Di","doi":"10.1002/wer.11111","DOIUrl":"https://doi.org/10.1002/wer.11111","url":null,"abstract":"<p><p>Due to the overexploitation of deep groundwater, the largest cone of depression in the world has formed in the North China Plain. This led to severe geological hazards, including land subsidence and ground fissures, and also caused economic losses. The prevention and treatment of subsidence needs to rely on the accurate prediction of subsidence amount. According to the one-dimensional consolidation theory and effective stress principle, combined with stratum structure, groundwater flow, stress distribution, and so forth, the high-pressure consolidation test results of 569.6 m deep borehole soil samples are adopted; with a specific focus on stress and deformation parameters under exploitation of groundwater condition, the soil-water coupling prediction model of groundwater level lowering depth and land subsidence has been established. Verification with measured subsidence data near the study sites demonstrated that the predicted curve is consistent with the measured one and the differences between them are acceptable. The model can be applied in different areas after making adjustment based on different regional stratigraphic structures. Its key advantage lies in the ability to provide land subsidence prediction for areas lacking monitoring data, making it highly valuable for widespread application. PRACTITIONER POINTS: There is a compressible stratum structure; it is the internal factors of land subsidence. The groundwater level decline causes the soil body stress to change. It is land subsidence of the external factors. Based on the one-dimensional consolidation theory and by combining stratigraphic structures, groundwater flow, and stress distribution, a ground settlement prediction model was established.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11111"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142126836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toward a better understanding of polymeric aluminum-modified attapulgite for the efficient removal of low phosphorus concentration. 更好地了解聚合铝改性阿塔蓬石如何高效去除低浓度磷。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11122
Xiaoben Yang, Junming Chen, Xuewen Wu, Guocheng Zhu
{"title":"Toward a better understanding of polymeric aluminum-modified attapulgite for the efficient removal of low phosphorus concentration.","authors":"Xiaoben Yang, Junming Chen, Xuewen Wu, Guocheng Zhu","doi":"10.1002/wer.11122","DOIUrl":"https://doi.org/10.1002/wer.11122","url":null,"abstract":"<p><p>Attapulgite (ATP) is a biocompatible clay mineral that efficiently absorbs water. It is widely used in water treatment due to its environmental friendliness and cost-effectiveness. This study aimed to develop a volume-expansion structure-based attapulgite flocculant (VES-ATP) using aluminum salt and attapulgite (ATP) under alkaline conditions, specifically for the treatment of water containing low levels of phosphorus. The VES-ATP was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The removal of phosphorus by the VES-ATP was conducted by varying the mass ratio of Al to attapulgite (denoted as R<sub>mAl/mATP</sub>), ATP dosage, and pH. The results showed that the VES-ATP had a good expansion and dispersibility in the presence of alkalized aluminum species. The basicity as the molar ratio of OH to Al (0.8 or 1.6) determined the expansion feasibility, and the coverage degree of Al onto ATP, as indicated by the mass ratio of Al to attapulgite (denoted as R<sub>mAl/mATP</sub>), determined Al flocculation efficiency. Higher values such as R<sub>mAl/mATP</sub> = 4:1 and 2:1 may result in a better flocculation. Low phosphorus treatment was successfully achieved through Al flocculation and ATP adsorption, including complexation, hydrogen bonding, and electrostatic attraction. As expected, the VES-ATP generated larger size flocs with a bigger fractal dimension than that with the sole Al flocculation. As a result, the total phosphorus could be reduced to the level below 5 μg/L. It is more efficient in the pH range of 5-9. Overall, the coupling of aluminum and attapulgite has significantly enhanced both purification capabilities of phosphorus. PRACTITIONER POINTS: Polymeric aluminum-modified attapulgite was efficient for removal of low phosphorus concentration. Phosphorus concentrations can be reduced to below 5 μg/L. Polymeric aluminum and attapulgite are both safe, and this technology is suitable for water treatment.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11122"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142141244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gravity-driven packed bed filter, with copper-impregnated activated carbon, for continuous water disinfection in absence of electricity. 重力驱动填料床过滤器,配有铜浸渍活性炭,用于在无电情况下对水进行持续消毒。
IF 2.5 4区 环境科学与生态学
Water Environment Research Pub Date : 2024-09-01 DOI: 10.1002/wer.11114
Mohana Mukherjee, Shankar Ramachandran, Rajdip Bandyopadhyaya
{"title":"Gravity-driven packed bed filter, with copper-impregnated activated carbon, for continuous water disinfection in absence of electricity.","authors":"Mohana Mukherjee, Shankar Ramachandran, Rajdip Bandyopadhyaya","doi":"10.1002/wer.11114","DOIUrl":"https://doi.org/10.1002/wer.11114","url":null,"abstract":"<p><p>Availability of safe drinking water is a major concern in many parts of the world. While many filtration units operating on various principles are available to combat this, most require electricity, which may not be consistently available in such areas. In the present study, we have designed and demonstrated a water disinfection system that can operate purely on gravity, without any electricity. For this, a potassium hydroxide modified copper-impregnated activated carbon (KOH-Cu-AC) hybrid was used as a filter medium for disinfection, because it is less expensive, with performance comparable to previously reported hybrids containing silver. To maintain a constant water flow rate under gravity, during disinfection, a Mariotte bottle was used as the reservoir of the contaminated water. Using this and a constant head between the bottle and the treated water exit point, the required water-filter contact time of 25 min (for decontamination) is maintained in the filter column, regardless of tank-fill level. The demonstrated lab-scale system can perform disinfection of simulated contaminated water (with an initial concentration of 10<sup>4</sup> CFU mL<sup>-1</sup> Escherichia coli), for at least 6 h, with a flow rate of 150 mL h<sup>-1</sup>. The disinfection performance from the gravity-based filter was further validated with the conventional pump-driven filter, used for continuous disinfection of drinking water. Equivalence of results between pump- and gravity-driven operations helps us to eliminate the need for power, without any compromise in disinfection efficacy. Finally, copper concentration from treated water (106 ppb at steady state) remains very well within the safe limit (1000 ppb as per USEPA guideline). Hence, the lab-scale design of gravity-based packed bed filter will be useful for domestic and community-based supply of safe drinking water in resource-constrained areas, because it eliminated electricity requirement of conventional power-driven systems. PRACTITIONER POINTS: Cost-effective KOH-Cu-AC hybrid is developed as a disinfection material. Mariotte bottle used for maintaining constant disinfected water flow rate works without any electrical power supply. This system can be used for getting on-spot, continuous disinfected water supply. The concentration of copper in the treated water is well within the safety limit. It can be applicable in rural and remote areas (no electric power source) as well as natural calamity-affected areas.</p>","PeriodicalId":23621,"journal":{"name":"Water Environment Research","volume":"96 9","pages":"e11114"},"PeriodicalIF":2.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142296650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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