Tenside Surfactants Detergents最新文献

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Preparation, characterization, and stability of lipid nanoparticles including unsaturated lipids 脂质纳米颗粒的制备、表征和稳定性,包括不饱和脂质
4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-09-20 DOI: 10.1515/tsd-2023-2544
Yeseul Park, Jin-Won Park
{"title":"Preparation, characterization, and stability of lipid nanoparticles including unsaturated lipids","authors":"Yeseul Park, Jin-Won Park","doi":"10.1515/tsd-2023-2544","DOIUrl":"https://doi.org/10.1515/tsd-2023-2544","url":null,"abstract":"Abstract Among the SARS-CoV-2 vaccines developed to date, the mRNA vaccines developed by the Pfizer/BioNTech and Moderna companies have been formulated using saturated lipids, specifically 1,2-distearoyl- sn -glycero-3-phosphocholine (DSPC), along with cholesterol. DSPC and cholesterol have the disadvantage of causing sclerosis. Therefore, in this study, lipid nanoparticles (LNPs) were prepared and characterized by replacing DSPC with 1,2-dioleoyl- sn -glycero-3-phosphocholine (DOPC) and excluding cholesterol. The results showed that the DOPC-based LNPs had a smaller diameter (75.67 nm) compared to the previous study and the polydispersity index (PI) indicated a good dispersion homogeneity, suggesting size uniformity. Additionally, the LNPs maintained their size between 57 nm and 152 nm and showed stable PI values (0.330–0.393) throughout the 25 days.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136264250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulation of adsorption at rotating disk 旋转圆盘吸附的模拟
4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-09-12 DOI: 10.1515/tsd-2023-2522
Milivoj Lovrić
{"title":"Simulation of adsorption at rotating disk","authors":"Milivoj Lovrić","doi":"10.1515/tsd-2023-2522","DOIUrl":"https://doi.org/10.1515/tsd-2023-2522","url":null,"abstract":"Abstract Diffusion-controlled adsorption at the rotating disk is calculated for Frumkin isotherm. The near equilibrium isotherms are simulated and their time components are analysed. The purpose of the work is to investigate the physical meanings of S-shaped isotherms that appear for strong attractions in the adsorbed layer. It is demonstrated that the surface coverage that is created gradually, by the diffusion process, consumes the concentration gradient of the dissolved surfactant in the diffusion layer. Once the equilibrium with the bulk of the solution is established, the driving force of diffusion-controlled adsorption vanishes and no additional adsorption is possible. The diffusion layer thickness on the rotating disk tends to the constant value and the flux depends only on the concentration of dissolved adsorbent at the disk surface. Hence, the equilibrium with the bulk of solution is established faster than at the stationary disk. This equilibrium takes an infinite amount of time to reach, but the system can approach close to the equilibrium within a definite period of time. The near equilibration time depends on the bulk concentration of surfactant. These relationships exhibit sharp maxima under the influence of attractions in the adsorbed layer.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135825608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of tetrabutylammonium bromide based ionic liquid on the aggregation behavior of dodecyltrimethylammonium bromide in the range (293.15 K–313.15 K): acoustic and volumetric investigation 四丁基溴化铵离子液体对十二烷基三甲基溴化铵在(293.15 K - 313.15 K)范围内聚集行为的影响:声学和体积学研究
IF 1 4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-09-01 DOI: 10.1515/tsd-2023-2523
H. Hooshyar, Rahmat Sadeghi
{"title":"Influence of tetrabutylammonium bromide based ionic liquid on the aggregation behavior of dodecyltrimethylammonium bromide in the range (293.15 K–313.15 K): acoustic and volumetric investigation","authors":"H. Hooshyar, Rahmat Sadeghi","doi":"10.1515/tsd-2023-2523","DOIUrl":"https://doi.org/10.1515/tsd-2023-2523","url":null,"abstract":"Abstract The effect of the ionic liquid analogue tetrabutylammonium bromide on the aggregation behaviour of the cationic surfactant dodecyltrimethylammonium bromide in aqueous medium was investigated with volumetric and compressibility measurements over a wide temperature range (293.15–313.15) K. The data obtained were used to obtain density data. Based on the density data obtained, the volumetric properties (apparent molar volumes and partial molar volumes) of the surfactant in unimeric and micellar forms were evaluated and discussed in terms of the respective ionic and dipolar interactions. The data obtained were analysed to determine the effects of (i) temperature and (ii) salt added to the surfactant. The results were also interpreted in terms of the molecular interactions occurring in the binary mixtures of the present study. The addition of tetrabutylammonium bromide has a lowering effect on the CMC values of the surfactant studied in aqueous medium.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42623516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontmatter 头版头条
4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-09-01 DOI: 10.1515/tsd-2023-frontmatter5
{"title":"Frontmatter","authors":"","doi":"10.1515/tsd-2023-frontmatter5","DOIUrl":"https://doi.org/10.1515/tsd-2023-frontmatter5","url":null,"abstract":"","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135099217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and properties of amide-based cationic gemini surfactants with semi-rigid spacer 半刚性间隔基酰胺基阳离子双子表面活性剂的合成与性能
IF 1 4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-09-01 DOI: 10.1515/tsd-2022-2463
Yue Zhou, Haiyan Gao, Hujun Xu, Ying Li, Hongqiang Zhang, Zirui Lu
{"title":"Synthesis and properties of amide-based cationic gemini surfactants with semi-rigid spacer","authors":"Yue Zhou, Haiyan Gao, Hujun Xu, Ying Li, Hongqiang Zhang, Zirui Lu","doi":"10.1515/tsd-2022-2463","DOIUrl":"https://doi.org/10.1515/tsd-2022-2463","url":null,"abstract":"Abstract A series of novel gemini surfactants (m-E2Ph-m) with ester groups and a benzene ring as rigid spacer were synthesized and characterized by IR, 1H NMR and Mass spectrometry. The effect of hydrophobic chain length on the surface properties and aggregation behavior of the gemini surfactants were investigated by the measurements of surface tension, electrical conductivity, fluorescence. The critical micelle concentration (CMC) of these surfactants decreases with increasing alkyl chain length. The thermodynamic parameters exhibited that the micellization was a spontaneous and exothermic process in environment. The micellization process became more beneficial with the increase of alkyl chain length and the decrease of temperature.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42890520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Facile synthesis of novel interpenetrating polymeric network (IPN) from semi-IPN: comparative analysis of biodegradation studies for environmental remediation 由半互穿网络合成新型互穿聚合物网络:环境修复生物降解研究的比较分析
IF 1 4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-08-15 DOI: 10.1515/tsd-2023-2514
Anjali Singh, B. Kaith, D. Sud
{"title":"Facile synthesis of novel interpenetrating polymeric network (IPN) from semi-IPN: comparative analysis of biodegradation studies for environmental remediation","authors":"Anjali Singh, B. Kaith, D. Sud","doi":"10.1515/tsd-2023-2514","DOIUrl":"https://doi.org/10.1515/tsd-2023-2514","url":null,"abstract":"Abstract This paper reports the novel synthesis of an interpenetrating polymer network (IPN) from semi-IPN. This semi-IPN is based on naturally occurring Colocasia esculenta corn starch. The toxicity levels were compared through various biodegradation methods. The polymer network was synthesised from the corresponding semi-IPN via a green pathway by using green solvent (water) and polyvinyl alcohol (PVA) as secondary monomer. The biodegradability of synthesized IPN was tested by vermi-composting, composting and soil burial methods. The study was divided into three stages that lasted up to 70 days. The synthesised IPN degraded 78.94 %, 69.23 % and 67.24 % within 70 days by vermi-composting, composting and burying in the soil, respectively. This was confirmed by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy with electron dispersion analysis (SEM-EDX) for each stage. Therefore, the system could be considered for agrochemical release without affecting soil fertility.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2023-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44150836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of process variable effects on palm kernelamidopropyl betaine production 工艺变量对棕榈仁酰胺丙基甜菜碱生产影响的研究
IF 1 4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-08-03 DOI: 10.1515/tsd-2023-2505
Amanda Nazwa Nur Fatihah, M. Pratiwi, A. N. Istyami, R. Purwadi, D. Lestari
{"title":"Investigation of process variable effects on palm kernelamidopropyl betaine production","authors":"Amanda Nazwa Nur Fatihah, M. Pratiwi, A. N. Istyami, R. Purwadi, D. Lestari","doi":"10.1515/tsd-2023-2505","DOIUrl":"https://doi.org/10.1515/tsd-2023-2505","url":null,"abstract":"Abstract Cocamidopropyl betaine is a coconut oil-based surfactant that is widely used in cosmetics and personal care products due to its milder and less irritating properties compared to conventional petroleum-based surfactants. Palm kernel oil can be used for the synthesis of betaine (palm kernel amidopropyl betaine), following the same route as for the synthesis with coconut oil via two reaction steps. However, there was little information on the optimal operating conditions for each process. The method for the production of betaine and its operating conditions were studied in order to obtain a compatible betaine product with better properties than those of the commercial product. The studied method and operating conditions allowed the production of low viscosity betaine with a higher surfactant content (31.55 wt%) than that of the commercial betaine products (25.10 wt%). In addition, other feedstocks such as coconut oil, split palm kernel oil and coconut oil-based fatty acid methyl ester were used in this study to produce betaine from low-cost production.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2023-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44756660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption of Ni2+ by functionalized hydroxyapatite-chitosan composite 功能化羟基磷灰石-壳聚糖复合材料对Ni2+的吸附
IF 1 4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-07-31 DOI: 10.1515/tsd-2022-2479
Ya Xu, Zheng Ji, Yansong Zhang, M. Sha, Chuanrun Li, Huchuan Wang
{"title":"Adsorption of Ni2+ by functionalized hydroxyapatite-chitosan composite","authors":"Ya Xu, Zheng Ji, Yansong Zhang, M. Sha, Chuanrun Li, Huchuan Wang","doi":"10.1515/tsd-2022-2479","DOIUrl":"https://doi.org/10.1515/tsd-2022-2479","url":null,"abstract":"Abstract Chitosan and hydroxyapatite are commonly used materials for adsorption. In this work, chitosan was modified by polyethylene glycol and maleic anhydride. Subsequently, a hydroxyapatite-chitosan composite was synthesised by precipitation. The composite was characterised and analysed by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS). Adsorption experiments were used to investigate the effects of external factors such as different pH values, adsorbent dosage, adsorption time and initial nickel ion concentration on the adsorption capacity of Ni2+ and to discuss the mechanism of Ni2+ removal by composites. The results show that the hydroxyapatite-chitosan composite has significant adsorption of Ni2+. The adsorption capacity of the hydroxyapatite-chitosan composite for Ni2+ reaches 63.8 mg g−1. The adsorption process is consistent with the pseudo-second-order kinetic model and the Langmuir isothermal model.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48059761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Green removal of low and high levels of Cu(II) and Cr(III) cations from concentrated saline chloride medium achieved by a mixture of N,N′-bis(salicylidene)-thiocarbohydrazide-TritonX-100 micellar system via cloud point extraction process N,N′-双(亚水杨基)-硫代羧酰肼-TritonX-100胶束体系浊点萃取法从浓氯化盐水介质中绿色去除低和高水平的Cu(II)和Cr(III)阳离子
IF 1 4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-07-31 DOI: 10.1515/tsd-2023-2508
Meriem Khiat, H. Reffas, M. Hadj Youcef, T. Benabdallah
{"title":"Green removal of low and high levels of Cu(II) and Cr(III) cations from concentrated saline chloride medium achieved by a mixture of N,N′-bis(salicylidene)-thiocarbohydrazide-TritonX-100 micellar system via cloud point extraction process","authors":"Meriem Khiat, H. Reffas, M. Hadj Youcef, T. Benabdallah","doi":"10.1515/tsd-2023-2508","DOIUrl":"https://doi.org/10.1515/tsd-2023-2508","url":null,"abstract":"Abstract In this work, we performed the cloud point extraction with low and high concentrations of Cu(II) and Cr(III), two particularly toxic metallic pollutants, that have been shown to have adverse effects on human health and the environment. Removal of the metal ions was achieved in the presence of Triton X-100 as a non-ionic surfactant and N,N′-bis(salicylidene)-thiocarbohydrazide as a chelating ligand in concentrated chloride medium. The behavior of the Schiff base was initially investigated in homogeneous DMSO-water and micellar Triton X-100-water media. The obtained values of the acid constants show that the extractant is more acidic in micellar media than in pure aqueous medium. The recorded cloud point temperatures of Triton X-100 are significantly impacted by the sodium chloride concentration, the surfactant concentration, and the Schiff base ligand. Under the optimised experimental conditions, a quantitative extraction of Cu(II) and a maximum extraction rate of 74 % of Cr(III) were obtained. The reduction of the metal concentration from 10−3 mol L−1 to 10−6 mol L−1 resulted in a reduction of the temperature by 10 °C and a reduction of the contact time from 10 h to 3 h.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43635385","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Change in gastric-lipase adsorption on lipid layer by stigmasterols 豆甾醇对脂质层胃脂肪酶吸附的变化
IF 1 4区 工程技术
Tenside Surfactants Detergents Pub Date : 2023-07-28 DOI: 10.1515/tsd-2023-2519
Gounhanul Shin, Kunn Hadinoto, Jin-Won Park
{"title":"Change in gastric-lipase adsorption on lipid layer by stigmasterols","authors":"Gounhanul Shin, Kunn Hadinoto, Jin-Won Park","doi":"10.1515/tsd-2023-2519","DOIUrl":"https://doi.org/10.1515/tsd-2023-2519","url":null,"abstract":"Abstract Gastric-lipase (GL) binding to a lipid layer was investigated for the phase of the layer adjusted with the ratio of stigmasterol to the lipid using surface plasmon resonance. While the layer was formed on the hydrophobic surface, more stigmasterol led to lower surface density only in the dipalmitoylphosphatidylcholine (DPPC) layer. The addition of stigmasterol was believed to transform the phase (condensed liquid-phase) of DPPC layer closer to the phase (expanded liquid-phase) of dioleoylphosphatidylcholine (DOPC) layer. At a ratio greater than 15:85, the effect of the stigmasterol on the DPPC was saturated. The adsorption behavior of GL showed the similar trend with the lipid formation. The adsorption increased with the increase in the ratio of stigmasterol to lipid up to 15:85. On the DOPC layer of the expanded liquid-phase, the most adsorption seemed to occur and was indistinguishable from that in the DPPC layer of 15:85. The surface density of the adsorbed GL was interpreted into the fraction of the stigmasterol-dependent DPPC, 0.33, 0.67, and 1.00 for 10:90, 5:95, and 0:100 of DPPC. Furthermore, the equilibrium constant was between 1 × 1013 M−1 and 2 × 1013 M−1 and the kinetics of the adsorption showed an increase in the adsorption rate constant with the increase of the ratio up to 15:85.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2023-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48063268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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