Tenside Surfactants Detergents最新文献_第10页

Dilute hydrochloric acid induced switching from antagonism to synergism in the binary mixed systems of cocamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) 稀盐酸诱导椰油酰胺丙基甜菜碱(CAPB)和十二烷基苯磺酸钠(SDBS)二元混合体系由拮抗转向协同作用

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-27 DOI: 10.1515/tsd-2022-2500

R. Abdel-Rahem

{"title":"Dilute hydrochloric acid induced switching from antagonism to synergism in the binary mixed systems of cocamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS)","authors":"R. Abdel-Rahem","doi":"10.1515/tsd-2022-2500","DOIUrl":"https://doi.org/10.1515/tsd-2022-2500","url":null,"abstract":"Abstract A synergism is reported in the binary mixtures of cocamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) at mole fractions of 0.25, 0.50, and 0.75, in dilute hydrochloric acid solutions (∼0.05 M) HCl, at 25 °C. Such synergism is confirmed by surface tension values, critical micelle concentration (CMC), and interaction parameter values according to Holland and Rubingh’s model and the satisfaction of Hua and Rosen conditions. Surface excess (Γ) at air/water interface and the minimum area occupied by surfactant molecule (A min) also indicated a reduction in the A min of mixed CAPB/SDBS compared to single surfactants that is due to the strong electrostatic interaction between surfactants heads. The composition of CAPB/SDBS mixed micelles, the interaction parameter (β) and the micellar activity coefficients (f 1 and f 2) were evaluated from the regular solution model for these binary amphoteric/anionic mixed systems. It is clear the CAPB surfactants are converted to the cationic form by charging in the presence of HCl, which enhances the interaction between the oppositely charged CAPB and SDBS heads and overcomes the unfavourable packing between the tails predicted in pure water. Such strong interaction was also reflected on the phase behavior of CAPB/SDBS binary mixed system. Accordingly, a switching from antagonism to synergism is reported for CAPB/SDBS binary mixed system in the presence of dilute hydrochloric acid.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":"60 1","pages":"223 - 230"},"PeriodicalIF":1.0,"publicationDate":"2023-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43795223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Synthesis and properties of alkyl glyceryl ether sulfonate 烷基甘油醚磺酸盐的合成及性能研究

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-21 DOI: 10.1515/tsd-2022-2457

Jixiang Guo, Hujun Xu, Jingguo Yang, Liang‐Chang Lin

引用次数: 0

Stain removal performance of moisture-wicking fabric during home laundry 吸湿排汗织物在家庭洗衣中的去污性能

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-17 DOI: 10.1515/tsd-2022-2436

Wenhua Shi, Liujun Pei, X. Gu, Jiping Wang

{"title":"Stain removal performance of moisture-wicking fabric during home laundry","authors":"Wenhua Shi, Liujun Pei, X. Gu, Jiping Wang","doi":"10.1515/tsd-2022-2436","DOIUrl":"https://doi.org/10.1515/tsd-2022-2436","url":null,"abstract":"Abstract Moisture-wicking clothes are widely used in various sports or athletic activities due to their function of moisture absorption and perspiration. In this study, the washing and decontamination of moisture-wicking fabrics, especially the performance and decontamination effect of moisture-wicking fabrics after washing were investigated. The results showed that the physical morphology of moisture-wicking fabric is very different from that of an ordinary polyester fabric. The cross-section of the moisture-wicking fabric is hexagonal, and this fabric has good hydrophilicity. After the degreasing & thermosetting process, the air permeability of the moisture-wicking fabric is increased from 1013 mm/s to 2911 mm/s. However, the air permeability is decreased after one washing, but it has little effect during the subsequent washing cycles. Moreover, the degreasing & thermosetting process also improve the stains removal index. If the moisture-wicking fabric was washed before the preparation of stained fabric, the stain removal index of carbon black soil and sebum stains is increased. Although most of the aggregated particles on the surface of the fibers are removed after washing, a small amount of sebum still remains in the spaces between the fibers. These results indicate that most of the carbon black in the stained area is removed after washing, while oil components are hardly removed from the moisture-wicking fabric during home laundry. Compared to other surfactants, C18 fatty acid methyl ester ethoxylates and nonionic surfactants with long carbon chains can effectively reduce the surface tension of water and improve the wettability of moisture-wicking fabric, so that water molecules can diffuse well between fibers and stains, the binding force between stains and fabric is weakened, and the decontamination of the fabric is improved.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":"60 1","pages":"203 - 213"},"PeriodicalIF":1.0,"publicationDate":"2023-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46835773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

How many resources can be saved by changing consumers’ automatic dishwashing behaviour? 通过改变消费者的自动洗碗行为，可以节省多少资源?

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-15 DOI: 10.1515/tsd-2022-2489

Thomas Alt, Dorothée Boivin, M. Altan, A. Kessler, Angelika Schmitz, R. Stamminger

引用次数: 2

Frontmatter 头版头条

4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-01 DOI: 10.1515/tsd-2023-frontmatter2

引用次数: 0

Formulation and characterisation of lacidipine niosomal gel for transdermal delivery 拉西地平niosomal凝胶经皮给药的处方与表征

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-01 DOI: 10.1515/tsd-2022-2439

Salika Santosh Mapari, Cleona Elizabeth Mary DCruz, L R Amruth Kumar, P. Bhide, R. Shirodkar

{"title":"Formulation and characterisation of lacidipine niosomal gel for transdermal delivery","authors":"Salika Santosh Mapari, Cleona Elizabeth Mary DCruz, L R Amruth Kumar, P. Bhide, R. Shirodkar","doi":"10.1515/tsd-2022-2439","DOIUrl":"https://doi.org/10.1515/tsd-2022-2439","url":null,"abstract":"Abstract The present study aimed to enhance the transdermal delivery of lacidipine by niosomal vesicles. Lacidipine niosomes were generated using the ultrasonic method, and Span 60 was used as a nonionic surfactant. Formulations were prepared containing Span 60 and cholesterol in 1:1 and 2:1 ratios, respectively, with essential oils added at increasing concentrations. The formulated niosomes had nano-vesicles with entrapment efficiency ranging from 75.81% to 91.25% and in-vitro drug release ranging from 80.61% to 89.81%. The optimal formulation was selected based on particle size, entrapment efficiency and in-vitro drug release. Optical microscopy and high-resolution transmission electron microscopy studies revealed a spherical shape of the niosomal vesicles. Fourier transform infrared spectroscopy, differential scanning calorimetry and X-ray diffraction studies confirmed complete encapsulation of the drug in the niosomal vesicles. The optimized formulation was also incorporated into a gel base, which was then evaluated for appearance, pH, viscosity, spreadability, in vitro drug release and stability. Overall, the results indicated that the developed niosomal lacidipine vesicles may provide an alternative to existing delivery systems for this drug.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":"60 1","pages":"124 - 139"},"PeriodicalIF":1.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46505655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Novel cationic surfactants: synthesis, surface, antimicrobial studies and applicability as an extracting agent for interested element from monazite mineral concentrate 新型阳离子表面活性剂:合成、表面、抗菌研究及从独居石矿物精矿中提取感兴趣元素的适用性

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-01 DOI: 10.1515/tsd-2022-2447

F. Abdel-salam, W. Abdellah, F. Taher, E. El-Sheikh, M. A. Hassanin, Doaa M. E. Elamary

{"title":"Novel cationic surfactants: synthesis, surface, antimicrobial studies and applicability as an extracting agent for interested element from monazite mineral concentrate","authors":"F. Abdel-salam, W. Abdellah, F. Taher, E. El-Sheikh, M. A. Hassanin, Doaa M. E. Elamary","doi":"10.1515/tsd-2022-2447","DOIUrl":"https://doi.org/10.1515/tsd-2022-2447","url":null,"abstract":"Abstract Two novel cationic surfactants based on palmitic acid were prepared to extract uranium from its fluids. The chemical structures of the surfactants prepared were confirmed spectroscopically. The surface activity of these surfactants was evaluated by measuring their surface tension. The cationic surfactants prepared were also tested for their biological activity against Gram-positive and Gram-negative bacteria and fungi. Subsequently, an attempt was made to use these surfactants to remove uranium from the hydrous oxide cake produced after the alkaline degradation of monazite mineral concentrate. To achieve this goal, several experiments were conducted to determine the optimal conditions for uranium extraction and stripping. Under these optimal conditions, the experimental capacity fitted the pseudo-second order kinetic model. Under the investigated optimal stripping factors of 1 M NaCl, acidified with 0.2 M conc. H2SO4, an A:O ratio of 1:1 and a contact time of 15 min, an uranium stripping efficiency of 83% was obtained for the case study. After the complete stripping process, the marketable uranium concentrate was percipitated using hydrogen peroxide as UO4 H2O with an uranium content of approximately 76%, which was chemically determined and confirmed by EDAX analysis.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":"60 1","pages":"140 - 159"},"PeriodicalIF":1.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46475975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Exploring consumer behaviour in automatic dishwashing: a quantitative investigation of appliance usage in six European countries 探索消费者在自动洗碗中的行为：对六个欧洲国家电器使用情况的定量调查

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-01 DOI: 10.1515/tsd-2022-2488

Thomas Alt, Dorothée Boivin, M. Altan, A. Kessler, Angelika Schmitz, R. Stamminger

{"title":"Exploring consumer behaviour in automatic dishwashing: a quantitative investigation of appliance usage in six European countries","authors":"Thomas Alt, Dorothée Boivin, M. Altan, A. Kessler, Angelika Schmitz, R. Stamminger","doi":"10.1515/tsd-2022-2488","DOIUrl":"https://doi.org/10.1515/tsd-2022-2488","url":null,"abstract":"Abstract Automatic dishwashing has been optimised in manifold ways during the last decades: new dishwashing devices (e.g. optimised for best class in energy labelling) and innovative dishwashing detergents (e.g. with advanced enzyme technologies). However, the usage of the automatic dishwasher in consumers’ home may not be adequate to gain all the benefits from these developments. Little is known about the actual consumer behaviour with automatic dishwashing. This was tried to solve by performing a survey on the consumer behaviour on automatic dishwashing in Germany, Italy, Spain, Poland, Hungary and Turkey covering large parts of Europe. The results show that the ‘eco’-programme is getting more importance in programme selection. However, feedback on the soil level of the dish items put into this programme and the observed duration of the programme show that the potential of the ‘eco’-programme is not fully utilised by consumers. Besides this, the survey delivers relevant details on differences which may help to understand the needs and wishes of consumers in those countries.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":"60 1","pages":"106 - 116"},"PeriodicalIF":1.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48061819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

Preparation and the foaming activity of hydroxymethyl octadecyltrimethyl ammonium chloride 羟甲基十八烷基三甲基氯化铵的制备及其发泡活性

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-03-01 DOI: 10.1515/tsd-2020-2259

Shiyi Lv, Qiaona Liu, Sanbao Dong, Jinling Li, Jie Zhang, Manxue Wang, Gang Chen

{"title":"Preparation and the foaming activity of hydroxymethyl octadecyltrimethyl ammonium chloride","authors":"Shiyi Lv, Qiaona Liu, Sanbao Dong, Jinling Li, Jie Zhang, Manxue Wang, Gang Chen","doi":"10.1515/tsd-2020-2259","DOIUrl":"https://doi.org/10.1515/tsd-2020-2259","url":null,"abstract":"Abstract In this work, hydroxymethyl octadecyltrimethyl ammonium chloride (HM-OTAC) was obtained from the reaction between octadecyltrimethyl ammonium chloride (OTAC) and formaldehyde in different molar ratios. The effects of the reaction conditions (different molar ratios) on the properties of the product (surface tension, foaming, high temperature resistance, methanol resistance and salt resistance) were investigated. The results showed that the HM-OTAC produced under different molar ratios could lower the surface tension of water solutions more than the surfactant OTAC. The HM-OTAC (1:2) reduced the surface tension to 28.29 mN m−1. The HM-OTAC produced under other molar ratios gave higher interfacial tensions than HM-OTAC (1:2). With increasing surfactant concentration, the foam volume first increased and then gradually decreased. At a concentration of 0.3 wt.%, the highest foam volume (460 mL) was produced with HM-OTAC (1:3). Compared to OTAC, the foams produced by each HM-OTAC surfactant exhibited higher temperature stability. In the presence of 30 mL methanol, the initial foam volume of all HM-OTAC surfactants (0.3 wt.%) was generally higher than that of OTAC. With 300 mL HM-OTAC (1:4) solution, the highest foam volume of 20.2 mL could be produced. HM-OTAC (1:3) showed the highest salt resistance.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":"60 1","pages":"182 - 189"},"PeriodicalIF":1.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47558945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Synthesis and physicochemical properties of sodium oleyl sulfate 油基硫酸钠的合成及其理化性质

IF 1 4区工程技术

Tenside Surfactants Detergents Pub Date : 2023-02-16 DOI: 10.1515/tsd-2022-2491

Xiaodan Ren, Ping Li, Xiaoyi Yang, Chaohua Guo, Jianbo Li

{"title":"Synthesis and physicochemical properties of sodium oleyl sulfate","authors":"Xiaodan Ren, Ping Li, Xiaoyi Yang, Chaohua Guo, Jianbo Li","doi":"10.1515/tsd-2022-2491","DOIUrl":"https://doi.org/10.1515/tsd-2022-2491","url":null,"abstract":"Abstract In this paper, sodium oleyl sulphate (SOS) was successfully synthesised by reacting octyl alcohol (OA) with gaseous sulphur trioxide (SO3) as a sulphating reagent in a falling film reactor. The structure was determined by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (1HNMR) spectroscopy. The dynamic adsorption and aggregation behaviour of SOS was systematically investigated to reveal the relationship between the structure and properties of SOS. The physicochemical properties of SOS were determined by measuring the equilibrium surface tension, dynamic surface tension and dynamic contact angle, respectively. A laser particle size analyser and a transmission electron microscope (TEM) were used to analyse the aggregation behaviour of SOS. Compared to sodium dodecyl sulphate (SDS) and sodium n-octadecyl sulphate (C18H37OSO3Na), which have a similar structure to SOS, the increase in hydrophobic chain size and tighter molecular packing enabled by the polar head conformation caused a decrease in CMC and an increase in surface activity. The efficiency of the surface activity was controlled by a mixed diffusion kinetic adsorption mechanism. Moreover, SOS in aqueous solution showed efficient wettability on the surface of the low-energy paraffin film at concentration above the CMC. In addition, SOS molecules can spontaneously form spheroidal aggregates with increasing concentration, and the size of the aggregates increased with the concentration.","PeriodicalId":22258,"journal":{"name":"Tenside Surfactants Detergents","volume":"60 1","pages":"170 - 181"},"PeriodicalIF":1.0,"publicationDate":"2023-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43533242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0