Supramolecular Science最新文献_第2页

Surface plasmon resonance on the LB monolayer of solvent-soluble silicon phthalocyanine 溶剂溶性酞菁硅LB单层表面等离子体共振

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00091-1

Qing Zhang , Bin He , Qing Dai , Jian-hua Gu , Ning Gu , Deyin Huang

{"title":"Surface plasmon resonance on the LB monolayer of solvent-soluble silicon phthalocyanine","authors":"Qing Zhang , Bin He , Qing Dai , Jian-hua Gu , Ning Gu , Deyin Huang","doi":"10.1016/S0968-5677(98)00091-1","DOIUrl":"10.1016/S0968-5677(98)00091-1","url":null,"abstract":"<div>Thin films of bis-(p-chlorophenoxy) (tetra-4-nitrophthalocyaninato)silicon, TNPcSi(OPhCl-p)2, were prepared by using Langmir-Blodgett techniques and the morphology of the film was investigated by AFM (atomic force microscope) analysis. It has been found that the LB films were successfully transferred onto substrates like mica, gold deposited glass, and pure glass with domains aggregated on the substrates. Surface plasmon resonance has been used to investigate the interaction between sulfur dioxide and a monolayer of TNPcSi(OPhCl-p)2 LB film. It has been found that the monolayer of LB film transferred onto gold deposited glass gave a 0.55° shift of resonant angle and an additional 0.45° shift of resonant angle after exposion in sulfur dioxideatomospheric ambient for twenty minute. The UV–visible absorption spectrum of the LB films of TNPcSi(OPhCl-p)2 showed that there is chemical changes in the film after the exposure to the sulfur dioxide ambient. This work has shown a promising application as an optical gas sensor.</div>","PeriodicalId":22050,"journal":{"name":"Supramolecular Science","volume":"5 5","pages":"Pages 631-634"},"PeriodicalIF":0.0,"publicationDate":"1998-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0968-5677(98)00091-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82351536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 8

Optimal fabrication condition of bacteriorhodopsin films by electrophoretic sedimentation technique 电泳沉淀法制备细菌紫质膜的最佳工艺条件

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00103-5

Junhong Min , Hyun-Goo Choi , Jeong-Woo Choi , Won Hong Lee , Rak Kim

引用次数: 10

Photocatalytic TiO2 nanoparticles damage to cellular membranes and genetic supramolecules 光催化TiO2纳米粒子对细胞膜和遗传超分子的损伤

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00063-7

Minhua Xu, Jianmin Ma, Jianhua Gu, Zuhong Lu

引用次数: 15

All solid-state electrochromic smart window of electrodeposited WO3 and prussian blue film with PVC gel electrolyte 全固态电致变色智能窗是用PVC凝胶电解质电沉积WO3和普鲁士蓝薄膜

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00096-0

Lianyong Su, Hong Wang, Zuhong Lu

引用次数: 15

Neural network devices based on reaction–duffusion media: an approach to artificial retina 基于反应扩散介质的神经网络装置:一种人工视网膜的方法

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00121-7

Nicholas G. Rambidi

引用次数: 19

Preparation of asymmetric bilayer-vesicles with inner and outer monolayers composed of different amphiphilic molecules 由不同两亲性分子组成的内外单分子不对称双层囊泡的制备

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00088-1

Zhongdang Xiao, Minhua Xu, Ming Li, Zuhong Lu, Yu Wei

引用次数: 11

Site–specific immobilization of Fab’ fragments of goat antihuman IgG on quartz surfaces 山羊抗人IgG Fab片段在石英表面的定点固定

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00107-2

Qian Weiping, Yu Fang, Song Zhendong, Liang Bingjie, Wei Yu

引用次数: 4

The CdS nanoparticle with capped surface and its nonlinear optical properties studied by hyper-Rayleigh scattering 利用超瑞利散射研究了具有帽状表面的CdS纳米粒子及其非线性光学性质

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00058-3

De-gang Fu , Ming Li , Xin Wang , Ji-qi Cheng , Yu Zhang , Zu-hong Lu , Ju-zheng Liu , Yi-ping Cui

引用次数: 13

Langmuir–Blodgett films of dichroic dyes oriented by liquid crystal 液晶定向二向色染料的Langmuir-Blodgett薄膜

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00094-7

Tomasz Martynski, Jun Miyake

{"title":"Langmuir–Blodgett films of dichroic dyes oriented by liquid crystal","authors":"Tomasz Martynski, Jun Miyake","doi":"10.1016/S0968-5677(98)00094-7","DOIUrl":"10.1016/S0968-5677(98)00094-7","url":null,"abstract":"<div>A cyanobiphenyl molecular film mixed with nonamphiphilic azobenzene and benzimidazole derivative dichroic dyes was transferred from an air–water interface onto a hydrophilic quartz plate. 4-cyano-4-octylbiphenyl is a liquid crystal material which played the role of a host in the mixed films. The mole fraction of dye to cyanobiphenyl molecules was varied from 0.5 to 0.02. One layer was successfully deposited onto a quartz plate with the transfer ratio slightly higher than one. The films were deposited at a surface pressure π between 1 and 15mN/m. The structure of the film at the air–water interface was observed by using a Brewster angle microscope. The orientation of cyanobiphenyl as well as dye molecules were estimated by polarized absorption spectra. The angle of the cyanobiphenyl <math><mtext>(β</mtext><msub><mi></mi><mn><mtext>H</mtext></mn></msub><mtext>)</mtext></math> molecules between the long molecular axis and normal to the quartz surface in pure and mixed monolayers was found to be between 64° and 54°. These values depend on the surface pressure during deposition. The smaller angles were observed for mixed layers and for high surface pressure. Analyzing polarized spectra of dyes incorporated in the monolayer made similar observations. The dyes show a sharper angle <math><mtext>β</mtext><msub><mi></mi><mn><mtext>G</mtext></mn></msub><mtext>=(60°–38°)</mtext></math> than host molecules <math><mtext>(β</mtext><msub><mi></mi><mn><mtext>H</mtext></mn></msub><mtext>=(64°–54°)</mtext></math>. The dye absorption spectra at the high dye concentration and surface pressure differ from those for the films deposited at low concentration or low surface pressure.</div>","PeriodicalId":22050,"journal":{"name":"Supramolecular Science","volume":"5 5","pages":"Pages 643-647"},"PeriodicalIF":0.0,"publicationDate":"1998-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0968-5677(98)00094-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81370723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 11

The very strong photoluminescent (PL) effect of mesoporous molecular sieve materials 介孔分子筛材料的强光致发光效应

Supramolecular Science Pub Date : 1998-10-01 Epub Date: 1999-02-16 DOI: 10.1016/S0968-5677(98)00066-2

Nongyue He , Chunwei Yuan , Zuhong Lu , Chun Yang , Liangsheng Liao , Shulin Bao , Qinhua Xu

引用次数: 21