Rubber Chemistry and Technology最新文献_第9页

ENTIRE-REGION CONSTITUTIVE RELATION FOR TRELOAR'S DATA TRELOAR数据的全区域本构关系

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-10-15 DOI: 10.5254/rct.21.78993

L. Han, X. Peng, L. X. Li

引用次数: 0

ADDITIVE MANUFACTURING AND VULCANIZATION OF CARBON BLACK–FILLED NATURAL RUBBER–BASED COMPONENTS 炭黑填充天然橡胶基组件的增材制造和硫化

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-10-15 DOI: 10.5254/rct.21.79906

Sebastian Leineweber, Lion Sundermann, Lars Bindszus, L. Overmeyer, B. Klie, Heike Wittek, U. Giese

{"title":"ADDITIVE MANUFACTURING AND VULCANIZATION OF CARBON BLACK–FILLED NATURAL RUBBER–BASED COMPONENTS","authors":"Sebastian Leineweber, Lion Sundermann, Lars Bindszus, L. Overmeyer, B. Klie, Heike Wittek, U. Giese","doi":"10.5254/rct.21.79906","DOIUrl":"https://doi.org/10.5254/rct.21.79906","url":null,"abstract":"\u0000 Additive manufacturing of thermoplastics or metals is a well-approved sustainable process for obtaining rapidly precise and individual technical components. Except for crosslinked silicone rubber or thermoplastic elastomers, there is no method of additive manufacturing of elastomers. Based on the development of the additive manufacturing of elastomers (AME) process, the material group of rubber-based cured elastomers may gain first access to the process field of three-dimensional (3D) printing. Printing and crosslinking of rubber is separated into two steps. In the first step, printing is realized by extrusion of the rubber by using a twin-screw extruder, which works according to the derived fused-filament-fabrication principle. In the second step, the component is vulcanized in a high-pressure hot-air autoclave. Because of the plastic flow behavior of non–crosslinked rubber materials, a thermoplastic shell is probably needed to maintain the geometry and position of the additively manufactured rubber. In this way, one layer of thermoplastic and one layer of rubber are printed alternatingly until the component is finished. Afterward, the manufactured binary component is placed in an autoclave to obtain the elastomer after vulcanization under a hot-air and high-pressure atmosphere. Then, the thermoplastic shell is removed from the elastomer and can subsequently be recycled. As compared with conventional thermoplastics, the high viscosity of rubber during processing and its instable shape after extrusion are challenging factors in the development of the AME. This contribution will show a modified 3D printer; explain the printing process from the designed component, via shell generation, to the vulcanized component; and show first printed components.","PeriodicalId":21349,"journal":{"name":"Rubber Chemistry and Technology","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2021-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47403682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

ADVANCES IN TECHNIQUES AND APPLICATIONS OF RUBBER SURFACE GRAFTING MODIFICATION 橡胶表面接枝改性技术及应用进展

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-10-15 DOI: 10.5254/rct.21.79893

Xiaolong Lu, S. Cai, Ben Niu, Xian Li, Qin He, Xianru He

引用次数: 2

BROMINATION OF NR WITH N-BROMOSUCCINIMIDE nr与n -溴琥珀酰亚胺的溴化

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-10-01 DOI: 10.5254/rct.21.78980

N. Choothong, S. Kawahara

引用次数: 1

EFFECT OF OXYGENATED COMPOUNDS ON 1,3-BUTADIENE POLYMERIZATIONS PERFORMED WITH NEODYMIUM VERSATATE. PART I: ALCOHOLS, ALDEHYDES, KETONES, AND WATER 含氧化合物对叔酸钕催化1,3-丁二烯聚合反应的影响。第一部分：醇、醛、酮和水

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-09-27 DOI: 10.5254/rct.21.78979

L. Dutra, M. Vasconcelos, Anderson Cazumbá, Maria Clara Leite Scaldaferri, Márcio Henrique Dos Santos Andrade, J. Pinto

{"title":"EFFECT OF OXYGENATED COMPOUNDS ON 1,3-BUTADIENE POLYMERIZATIONS PERFORMED WITH NEODYMIUM VERSATATE. PART I: ALCOHOLS, ALDEHYDES, KETONES, AND WATER","authors":"L. Dutra, M. Vasconcelos, Anderson Cazumbá, Maria Clara Leite Scaldaferri, Márcio Henrique Dos Santos Andrade, J. Pinto","doi":"10.5254/rct.21.78979","DOIUrl":"https://doi.org/10.5254/rct.21.78979","url":null,"abstract":"\u0000 1,3-butadiene (1,3-BD) is a building block produced mainly as a byproduct of the ethylene steam cracking process. However, due to the growing interest in sustainable technologies, there is also growing interest in manufacturing 1,3-BD from ethanol. For this reason, taking into account that the ethanol-derived 1,3-BD can contain oxygenated contaminants that are difficult to remove, the present manuscript investigates for the first time how the presence of low concentrations of some oxygenates (acetaldehyde, crotonaldehyde, 3-hydroxybutyraldehyde, acetone, water, ethanol, 1,3-butanodiol, 3-buten2-ol, crotyl alcohol, and 1-butanol) in the 1,3-BD monomer can affect polymerization reactions performed with the neodymium versatate catalyst and modify the characteristics of the obtained polybutadiene products. It is shown that the presence of oxygenated compounds can cause inhibitory effects on the course of the polymerization and modify the molar mass distributions and flow properties of the final products, although all analyzed samples presented the characteristic high-cis character of polybutadienes produced with the neodymium versatate catalyst.","PeriodicalId":21349,"journal":{"name":"Rubber Chemistry and Technology","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2021-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42179516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

EFFECT OF CELLULOSE FIBER SURFACE TREATMENT TO REPLACE CARBON BLACK IN NATURAL RUBBER HYBRID COMPOSITES 纤维素纤维表面处理在天然橡胶混杂复合材料中取代炭黑的效果

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-09-07 DOI: 10.5254/rct.21.78988

H. Kazemi, F. Mighri, Keun-Wan Park, Slim Frikha, D. Rodrigue

{"title":"EFFECT OF CELLULOSE FIBER SURFACE TREATMENT TO REPLACE CARBON BLACK IN NATURAL RUBBER HYBRID COMPOSITES","authors":"H. Kazemi, F. Mighri, Keun-Wan Park, Slim Frikha, D. Rodrigue","doi":"10.5254/rct.21.78988","DOIUrl":"https://doi.org/10.5254/rct.21.78988","url":null,"abstract":"\u0000 In recent years, cellulose fibers have attracted considerable attention as biofillers for natural rubber (NR) composites. However, neat cellulose cannot be used as a substitute for conventional fillers due to its poor compatibility with NR. Therefore, a new surface treatment via maleic anhydride grafted to polyisoprene (MAPI) in solution was developed to improve the filler–matrix interaction. Different contents of carbon black (CB) and cellulose fibers (before and after modification) were used as a hybrid filler system to investigate the possibility of CB substitution in NR composites. First, contact angle, Fourier transformed infrared spectrometry (FTIR), and scanning electron microscopy (SEM) techniques were used to confirm the successful cellulose surface treatment. Second, morphological analysis, Payne effect, and swelling behavior of the rubber compounds in toluene confirmed the effect of cellulose treatment on improving the interfacial filler–matrix adhesion. Finally, the results showed that the composite filled with 20 phr modified cellulose and 20 phr CB (50% replacement of CB) exhibited even better results than the composite filled with 40 phr of CB, since the tensile strength was only 7% lower, but the elongation at break, tensile modulus at 100%, and storage modulus at 25 °C were respectively 35%, 24%, and 22% higher.","PeriodicalId":21349,"journal":{"name":"Rubber Chemistry and Technology","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2021-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46272158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 6

ESTIMATION OF MECHANICAL LOAD ON RUBBER MIXING ROTORS BY USING A PARTIALLY FILLED FLOW SIMULATION IN CHAMBER 用室内部分填充流模拟计算混炼胶转子的机械负荷

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-09-03 DOI: 10.5254/rct.21.79951

K. Fukutani, Kousuke Higashi, Hodaka Miura, Yasuaki Yamane

{"title":"ESTIMATION OF MECHANICAL LOAD ON RUBBER MIXING ROTORS BY USING A PARTIALLY FILLED FLOW SIMULATION IN CHAMBER","authors":"K. Fukutani, Kousuke Higashi, Hodaka Miura, Yasuaki Yamane","doi":"10.5254/rct.21.79951","DOIUrl":"https://doi.org/10.5254/rct.21.79951","url":null,"abstract":"\u0000 Mixing characteristics and mechanical loads of rubber-mixing rotors are considered to be the two most important factors in actual rotor design. For the design of highly reliable production mixers, there is a great need for a proper estimation method of mechanical load, such as radial force or rotation torque of the rotors. The mechanical load of tangential mixing rotors and surrounding flow are mainly discussed by using partially filled numerical flow simulation. Operational parameters of the mixing condition were set to be fill factor and rotor phase angle of two rotors rotating at an even speed. The Carreau model was applied to the shear rate dependence of viscosity. The volume-of-fluid method was used for free surface simulation. Both two-dimensional and three-dimensional simulations were carried out to discuss mechanical load and its fluctuation mechanisms. For the numerical results, radial force on rotors, pressure, and the velocity distribution around the rotors and their fluctuations are presented and discussed. It was found that the radial force of the rotors could be estimated using this kind of flow simulation, and the fluctuation phenomena could be explained by the movement of a high-pressure region between the front of the rotor wings and the chamber wall.","PeriodicalId":21349,"journal":{"name":"Rubber Chemistry and Technology","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2021-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46999870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

PREPARATION AND CHARACTERIZATION OF SPECIALTY NATURAL RUBBER LATEX CONCENTRATE 特种天然胶乳浓缩物的制备与表征

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-07-29 DOI: 10.5254/rct.21.79945

Roslim Ramli, C. Bao, Ho Jee Hou, S. Kamaruddin, F. Rasdi, D. S. D. De Focatiis

{"title":"PREPARATION AND CHARACTERIZATION OF SPECIALTY NATURAL RUBBER LATEX CONCENTRATE","authors":"Roslim Ramli, C. Bao, Ho Jee Hou, S. Kamaruddin, F. Rasdi, D. S. D. De Focatiis","doi":"10.5254/rct.21.79945","DOIUrl":"https://doi.org/10.5254/rct.21.79945","url":null,"abstract":"\u0000 Conventionally, specialty natural rubber (SpNR) latex, namely, deproteinized natural rubber (DPNR) latex and epoxidized natural rubber (ENR) latex, are prepared from low ammonia latex (LATZ) causing high material cost. To address this issue, the objective of this study is to prepare SpNR latex directly from freshly tapped NR latex. In this work, DPNR latex is prepared via a heat enzymatic hydrolysis process, while ENR latex is prepared via in situ epoxidation chemical modification process. In addition, both DPNR and ENR latex were concentrated to 60% total solid content via ultrafiltration process using membrane separation technology. Physiochemical properties of DPNR, ENR, and LATZ latex were compared. Results show that the total solid content, dry rubber content, and alkalinity level of the latexes achieved the targeted value. This study also found that nitrogen content of DPNR latex, LATZ latex, and ENR latex were at 0.11%, 0.29%, and 0.25%, respectively, indicating successful deproteinization of the DPNR latex. On the other hand, the epoxidation level of ENR latex produced in this study was at 46.3%, which is slightly lower than the targeted level of 50%. Rheological studies found that ENR latex exhibits the highest viscosity, followed by DPNR and LATZ, but all show characteristic shear-thinning behavior. This study also found that LATZ and DPNR latex are more liquid-like in nature, while ENR latex behaves more like an elastic solid. Non-ionic surfactants play a major role in influencing flow and deformation behavior of the ENR and DPNR latex.","PeriodicalId":21349,"journal":{"name":"Rubber Chemistry and Technology","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2021-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47866075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 5

LIQUID POLYBUTADIENE EXTENDED ESBR/SILICA WET-MASTERBATCH COMPOSITES FOR IMPROVING ABRASION RESISTANCE AND DYNAMIC PROPERTIES OF TIRE TREAD COMPOUNDS 用于改善轮胎胎面化合物耐磨性和动态性能的液态聚丁二烯扩展esbr /二氧化硅湿母粒复合材料

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-07-29 DOI: 10.5254/rct.21.79881

Woong Kim, Iz Muhammet, Donghyuk Kim, I. Kim, Jong-Yeop Lee, Wonho Kim

{"title":"LIQUID POLYBUTADIENE EXTENDED ESBR/SILICA WET-MASTERBATCH COMPOSITES FOR IMPROVING ABRASION RESISTANCE AND DYNAMIC PROPERTIES OF TIRE TREAD COMPOUNDS","authors":"Woong Kim, Iz Muhammet, Donghyuk Kim, I. Kim, Jong-Yeop Lee, Wonho Kim","doi":"10.5254/rct.21.79881","DOIUrl":"https://doi.org/10.5254/rct.21.79881","url":null,"abstract":"\u0000 Silica wet-masterbatch (WMB) is a well-known technique for manufacturing high-content, highly dispersed silica-filled compounds. Emulsion styrene–butadiene rubber (ESBR)/silica WMB offers several advantages, including excellent silica dispersion and reduced hysteresis, as compared with conventional dry masterbatch (DMB) compound. However, because of the residual emulsifiers in ESBR latex, it can exhibit a decrease in the crosslink density and reductions in its mechanical properties. Moreover, the abrasion resistance cannot be significantly enhanced because of the tradeoff between the improvement in silica dispersion and decrease in crosslink density. Accordingly, the objective of this study was to improve the silica dispersion and abrasion resistance of ESBR/silica WMB compounds by using liquid polybutadiene rubber (LqBR) extended WMB. In detail, three types of LqBR were emulsified to LqBR emulsions, and three types of LqBR extended WMBs were produced by co-coagulating ESBR latex, silane-modified silica, and the LqBR emulsion. A thorough characterization was conducted with emphasis on the silica content, cure characteristics, mechanical properties, abrasion resistance, and dynamic viscoelastic properties. Based on the results, silane-terminated LqBR extended WMB vulcanizate showed a 58% improvement in the 300% modulus, 48% reduced DIN abrasion loss, and a 23% improvement in dynamic properties.","PeriodicalId":21349,"journal":{"name":"Rubber Chemistry and Technology","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2021-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42812023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

EFFECT OF EMULSION SBR PREPARED BY ASYMMETRIC REVERSIBLE ADDITION-FRAGMENTATION TRANSFER AGENT ON PROPERTIES OF SILICA-FILLED COMPOUNDS 不对称可逆加成-裂解转移剂制备乳液SBR对含硅化合物性能的影响

IF 1.5 4区工程技术

Rubber Chemistry and Technology Pub Date : 2021-07-21 DOI: 10.5254/rct.21.79904

Kiwon Hwang, Sanghoon Song, Yuu Kang, JaeKon Suh, H. Jeon, G. Kwag, H. Paik, Wonho Kim

{"title":"EFFECT OF EMULSION SBR PREPARED BY ASYMMETRIC REVERSIBLE ADDITION-FRAGMENTATION TRANSFER AGENT ON PROPERTIES OF SILICA-FILLED COMPOUNDS","authors":"Kiwon Hwang, Sanghoon Song, Yuu Kang, JaeKon Suh, H. Jeon, G. Kwag, H. Paik, Wonho Kim","doi":"10.5254/rct.21.79904","DOIUrl":"https://doi.org/10.5254/rct.21.79904","url":null,"abstract":"\u0000 The development of ultra-high-performance tires that satisfy fuel efficiency, traction, handling performance, and abrasion resistance has gained significant importance in the tire industry. Solution SBR has been used as a raw material, owing to its useful characteristics (e.g., narrow dispersity controllable microstructure and chain-end functionalization). In a recent improvement, emulsion SBR (ESBR), a high-molecular-weight compound with narrow dispersity, has been reported for application in the tire tread compounds. In particular, S,S-dibenzyl trithiocarbonate (DBTC) reversible addition-fragmentation transfer (RAFT) ESBR has exhibited excellent abrasion resistance and fuel efficiency in unfilled and carbon black–filled vulcanizates. However, owing to the symmetrical structure of DBTC RAFT ESBR, the polymer chain was shortened by the reaction of a silane coupling agent with trithiocarbonate, leading to poor abrasion resistance and fuel efficiency in the case of silica-filled vulcanizates. In this study, benzyl (4-methoxyphenyl) trithiocarbonate (BMPTC), an asymmetric RAFT agent that promotes unilateral polymer growth, was synthesized and used in the polymerization of BMPTC RAFT ESBR. Chain cleavage was not observed. Upon application to silica-filled vulcanizates, BMPTC RAFT ESBR exhibited improved abrasion resistance (by 9%), improved fuel efficiency (by 20%), and improved wet traction performance (by 10%) compared with the DBTC RAFT ESBR.","PeriodicalId":21349,"journal":{"name":"Rubber Chemistry and Technology","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2021-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49354325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1