Reactive & Functional Polymers最新文献

{"title":"HA/HTC-PVA coated with superphosphate to prepare slow-release phosphorus fertilizer: For hydroponic plant growth","authors":"Shuo Zhang,&nbsp;Shaoqi Ma,&nbsp;Qi Zhu","doi":"10.1016/j.reactfunctpolym.2025.106257","DOIUrl":"10.1016/j.reactfunctpolym.2025.106257","url":null,"abstract":"<div><div>In recent years, the low fertilizer utilization efficiency is prominent in the soil, and the application of fertilizer to hydroponic plants has also encountered the same problem. Due to the continuous accumulation of soluble fertilizers in the water, it is necessary to frequently change the water to ensure the appropriate nutrient concentration.To improve the utilization rate of nutrients,in this study, the core particles were prepared by bentonite and superphosphate, and the slow-release film raw materials hydrothermal carbon(<em>HTC</em>)and humic acid(<em>HA</em>)were prepared by resource utilization of agricultural waste rape stalks. Together with polyvinyl alcohol(PVA), the slow-release film was prepared by in-situ polymerization, and the slow-release particles were obtained by impregnation. The material was characterized and the results showed that hydrothermal carbon, humic acid and polyvinyl alcohol could improve the water absorption and swelling performance of the slow-release materials, and had a good slow-release effect on phosphorus(<em>P</em>)release. The initial phosphorus release rate was 10.2 % on the first day, and the nutrient release rate was 73.6 % on the 28th day, which met the slow-release standard of fertilizer. Therefore, the slow-release material has the potential to be widely used in aquatic plant cultivation.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106257"},"PeriodicalIF":4.5,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143593030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Main-chain hybrid azobenzene-1,2,3-triazoleoligo(dimethylsiloxane) liquid-crystalline photoactive copolymers","authors":"Dmitry Migulin ,&nbsp;Kseniya Bezlepkina ,&nbsp;Mikhail Buzin ,&nbsp;Artem Bakirov","doi":"10.1016/j.reactfunctpolym.2025.106256","DOIUrl":"10.1016/j.reactfunctpolym.2025.106256","url":null,"abstract":"<div><div>The development of well-designed anisotropically ordered photoactive liquid-crystalline polymers has potential in the development of a number of areas related to high-tech light-responsive materials and devices, including photonics, optical switching, image storage, soft actuators, etc.</div><div>The synthesis and characterization of a new type of photoactive linear main chain liquid-crystalline hybrid copolymers with regularly alternating molecular architectures is achieved for the first time through the use of azide-alkyne cycloaddition chemical reactions between a series of alkyne-terminated azobenzene molecules and azide-functional oligo(dimethylsiloxane) telechelics.</div><div>The present investigation encompasses an array of chemical structures and molecular morphologies, thermodynamic properties, thermotropic liquid-crystalline and photoisomerization behaviors, and the influence of the azo-copolymer molecular composition on the polymers' microstructure, morphologies, and propensity towards thermotropic self-assembly into lamellar spherulitic structures.</div><div>The kinetics of non-degradative reversible <em>E-Z</em> photoisomerization transitions and the relationship between the molecular composition of the polymers and their photoinduced isomerization behavior were investigated.</div><div>The morphology and degree of anisotropy of physically cross-linked LCPs fibers prepared by the simple melt spinning method were studied.</div><div>The results obtained provide important insights into the structure-property relationship of photoactive main chain hybrid azobenzene-siloxane LCPs, which are useful for the design of novel advanced photoactive polymers.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106256"},"PeriodicalIF":4.5,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143620388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Zwitterion polymer-modified graphene oxides enhance antibacterial activity with improved biocompatibility and osteogenesis: An in vitro study","authors":"Liying Peng ,&nbsp;Li Chang ,&nbsp;Rushui Bai ,&nbsp;Qiannan Sun ,&nbsp;Yunfan Zhang ,&nbsp;Hongliang Liu ,&nbsp;Chuao Ma ,&nbsp;Jiuxiang Lin ,&nbsp;Bing Han","doi":"10.1016/j.reactfunctpolym.2025.106229","DOIUrl":"10.1016/j.reactfunctpolym.2025.106229","url":null,"abstract":"<div><div>This study utilized surface-initiated atom transfer radical polymerization (SI-ATRP) to graft the zwitterionic polymer poly(carboxybetaine methacrylate) (PCBMA) onto graphene oxide (GO) (GO/PCBMA), enhancing its physicochemical properties and biomedical potential. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) confirmed successful grafting, while thermogravimetric analysis (TGA) indicated a PCBMA loading of 0.54 mg/mg GO. Gel permeation chromatography (GPC) showed a monomer conversion efficiency of ∼40 %, demonstrating good polymerization control. GO/PCBMA exhibited superior antibacterial performance, reducing <em>Streptococcus mutans</em> viability by 87.6 % at 80 μg/mL within 5 h, while GO required 160 μg/mL to achieve a 78.3 % reduction. Long-term antibacterial effects were further validated through three-day colony-forming unit (CFU) counts. GO/PCBMA also improved L929 fibroblast viability and promoted osteogenic differentiation in human bone marrow mesenchymal stem cells (hBMMSCs), as evidenced by increased alkaline phosphatase (ALP) activity and osteocalcin (OCN) expression. These findings highlight GO/PCBMA as a promising material for applications requiring both antibacterial activity and biocompatibility, particularly for long-term biomedical implants. This study provides insights for the development of multifunctional graphene oxide-based biomaterials.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106229"},"PeriodicalIF":4.5,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143637757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-performance thermoplastic polyimide enabled by ketone-based diamine monomer","authors":"Qi-Yuan Du ,&nbsp;Wei-Peng Chen ,&nbsp;Hao Guo ,&nbsp;Zhi Wang ,&nbsp;Xiao-Kun Qiu ,&nbsp;Wan-Yi Tan ,&nbsp;Yonggang Min ,&nbsp;Yidong Liu","doi":"10.1016/j.reactfunctpolym.2025.106230","DOIUrl":"10.1016/j.reactfunctpolym.2025.106230","url":null,"abstract":"<div><div>Thermoplastic polyimide (TPI) as adhesive can meet the requirements of flexible copper clad laminates (FCCLs) applied under extreme condition. Incorporating flexible groups, asymmetric structures and bulky side groups into the main chain, and copolymerization are common ways to achieve thermoplasticity, through reducing the rigidity of polymer chains or intermolecular interaction. However, it induces a trade-off between thermoplasticity and thermal dimensional stability as well as mechanical property. Furthermore, the adhesion strength between TPI film and copper foil is highly desirable in FCCL. Herein, we develop a ketone-based diamine 1,3-phenylenebis((3′-amino-[1,1′-biphenyl]-4-yl)methanone) (Ph-BiAmMe) to afford copolymerized TPI with 4,4′-oxydianiline (ODA) and 3,3′,4,4’-Biphenyltetracarboxylic dianhydride (BPDA). As for thermoplasticity, flexible linkages such as ether and ketone enhance the movability of polymer chains, and copolymerization weakens the intermolecular interaction between polymer chains to some extent. Furthermore, the incorporation of Ph-BiAmMe promotes denser chain packing and stronger CTC effect, thereby maintaining good thermal dimensional stability and mechanical properties. Simultaneously, ketone moieties enhance the peel strength of TPI when bonded with copper. Based on this strategy, the as-prepared TPI shows good thermoplasticity with a proper <em>T</em>_g of 274 °C. Meanwhile, it preserves a low CTE of 46.5 ppm K⁻¹, high tensile strength of 117.4 MPa, elongation at break of 27.3 % and peel strength of 1.11 N mm⁻¹.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106230"},"PeriodicalIF":4.5,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143620389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and post-polymerization functionalization of bromide-terminated polyesters via 1,1,3,3-tetramethylguanidine (TMG)-promoted polyesterification for biomedical applications","authors":"Pengfei Shan ,&nbsp;Yupeng Qiu ,&nbsp;Honglei Wang ,&nbsp;Qingyue Zhang ,&nbsp;Tingting Xiang ,&nbsp;Wenwen Lin ,&nbsp;Qiji Zhou ,&nbsp;Suyang Chen ,&nbsp;Liwen Li ,&nbsp;Zhenyu Yan ,&nbsp;Yangchun Ge ,&nbsp;Yuying Xie ,&nbsp;Zhuochao Shen ,&nbsp;Qilun Li ,&nbsp;Zhongyu Li ,&nbsp;Zhihui Li","doi":"10.1016/j.reactfunctpolym.2025.106248","DOIUrl":"10.1016/j.reactfunctpolym.2025.106248","url":null,"abstract":"<div><div>This study explores the synthesis of functionalized polyesters using 1,1,3,3-tetramethylguanidine (TMG)-promoted polyesterification between dicarboxylic acids and dibromides. Traditional polyesters face limitations due to a lack of functional groups, hindering their biomedical utility. The TMG-mediated method enables efficient polymerization under mild conditions, producing linear and hyperbranched polyesters with reactive bromide termini. These bromide-terminated polyesters serve as versatile precursors for post-polymerization modifications, allowing the introduction of diverse functionalities (e.g., stimuli-responsiveness, fluorescence, drug conjugation) and the creation of block copolymers, hydrogels, and polymer-drug conjugates. The platform demonstrates broad monomer compatibility, scalability, and tunability, making it promising for applications such as drug delivery, tissue engineering, and multifunctional biomaterials.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106248"},"PeriodicalIF":4.5,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and isomeric effect of ethynyl-containing sesamol-based monobenzoxazine resins","authors":"Min Zhong ,&nbsp;Weichen Sheng ,&nbsp;Jianfeng Chen ,&nbsp;Han Zhang ,&nbsp;Hongping Li ,&nbsp;Kan Zhang","doi":"10.1016/j.reactfunctpolym.2025.106245","DOIUrl":"10.1016/j.reactfunctpolym.2025.106245","url":null,"abstract":"<div><div>The objective of this paper is to conduct a comparative analysis of sesamol-based benzoxazine monomers derived from anilines with an ethynyl substituent in a different position and to obtain some laws to guide the design of thermosets. The synthesis of bio-benzoxazine monomers (S-a, S-<em>o</em>ea, S-<em>m</em>ea, and S-<em>p</em>ea) via a one-step method from sesamol, a biomass monophenol, in the presence of polyformaldehyde by combining four different amines (aniline, <em>ortho</em>-ethynyl aniline, <em>meta</em>-ethynyl aniline, and <em>para</em>-ethynyl aniline), respectively. The structures of four new benzoxazine monomers were characterized by ¹H NMR, ¹³C NMR, 2D-HMQC, and FT IR analysis. The FT IR spectra calculated by Gaussian 16 exhibited a high degree of consistency with the experimental data. The DSC scanning results of the monomers demonstrated that the order of the maximum exothermic peak temperature of polymerization was as follows: S-<em>o</em>ea (198.3 °C) &lt; S-<em>p</em>ea (202.1 °C) &lt; S-<em>m</em>ea (216.8 °C) &lt; S-a (240.2 °C), which is in general agreement with the energy level order of HOMO-LUMO, as determined by Gaussian analysis. In addition, the reaction mechanisms of the oxazine ring and the ethynyl moiety were proposed in conjunction with an investigation of the polymerization process by in-situ FT IR. The TGA and MCC test results showed that the polymers (poly(S-<em>o</em>ea), poly(S-<em>m</em>ea), and poly(S-<em>p</em>ea)) derived from the corresponding monomers with ethynyl substituent in various site exhibit both excellent thermal stability and flame retardancy. Notably, poly(S-<em>p</em>ea) exhibited the highest carbon yield (70.2 %) at 800 °C. The incorporation of the ethynyl group not only reduces the polymerization process of benzoxazine monomers but also enhances the performance of resulting polybenzoxazines. This work offers a valuable reference for the preparation of optimal benzoxazine structures in future research.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106245"},"PeriodicalIF":4.5,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and characterization of highly flexible polyguanamines bearing di-n-octylamino groups in their side chains","authors":"Tadashi Tsukamoto ,&nbsp;Takara Goto ,&nbsp;Yuji Shibasaki","doi":"10.1016/j.reactfunctpolym.2025.106247","DOIUrl":"10.1016/j.reactfunctpolym.2025.106247","url":null,"abstract":"<div><div>In this study, polyguanamines were synthesized by polymerizing 2-amino-4,6-dichloro-<em>N</em>,<em>N</em>-dioctyl-1,3,5-triazine (<strong>DOctATC</strong>) with various <em>α</em>,<em>ω</em>-alkylene diamines, namely, 1,12-diaminododecane, 1,10-diaminodecane, and 1,8-diaminooctane. The resulting polyguanamines exhibited good solubility in typical organic solvents, particularly in non-polar ones. Films of the synthesized polyguanamines, prepared <em>via</em> casting, were soft and sticky. Under both N₂ and air flow, the polyguanamines demonstrated 5 % weight loss at temperatures of up to 380 °C. Furthermore, their glass transition temperatures (<em>T</em>_g) were approximately −20 °C. Thermomechanical analysis revealed a softening temperature above <em>T</em>_g, while dynamic mechanical analysis showed a relaxation corresponding to this softening temperature. During tensile tests, the polyguanamine films displayed large elongations ranging1 from 54 %–2034 %.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106247"},"PeriodicalIF":4.5,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143579497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Comparative studies of specific capacitance in different electrolytes of two Ru(II)-metallopolymers synthesized using positional isomeric ligands","authors":"Shubham Bawa,&nbsp;Samaresh Ghosh,&nbsp;Anil Kumar,&nbsp;Anasuya Bandyopadhyay","doi":"10.1016/j.reactfunctpolym.2025.106246","DOIUrl":"10.1016/j.reactfunctpolym.2025.106246","url":null,"abstract":"<div><div>Metallopolymers are hybrid materials made from both organic and inorganic components, with adjustable properties that make them great for advanced uses. This study focuses on the synthesis and characterization of Ru(II)-metallopolymers using positionally isomeric ditopic ligands with multiple binding sites, enabling stable metal-ligand complexes and the growth of linear polymer chains. Analytical techniques such as ATR-IR, NMR, UV–Vis, and electrochemical methods were employed to assess their structural, electronic, and redox properties. A detailed investigation of specific capacitance in various electrolytes revealed capacitance values of 131 Fg⁻¹ in 1 M H₂SO₄ for Ru(II)-L₁ Poly and 130 Fg⁻¹ in LiClO₄ for Ru(II)-L₂ Poly, with robust cyclic stability retaining 98 % of initial capacitance after 8000 cycles. These metallopolymers offer superior compatibility and flexibility with organic conjugated polymers, making them ideal for making hybrid energy storage devices. Their excellent retention and stability underscore their potential as redox additives in supercapacitors. This work not only addresses gaps in energy storage research but also highlights the adaptability of Ru(II)-metallopolymers in developing high-performance, electrochemical materials for advanced energy technologies.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106246"},"PeriodicalIF":4.5,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143562029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"ZnTi layered double hydroxide/dealkaline lignin 2D/2D nanosheets for ultraviolet shielding poly(ethylene terephthalate) nanocomposites","authors":"Yan Gao ,&nbsp;Haoguan Gui ,&nbsp;Jiale Xu ,&nbsp;Ruiqi Shen ,&nbsp;Leyan Wei ,&nbsp;Xi Zhao ,&nbsp;Shixiang Zuo ,&nbsp;Jie Xu ,&nbsp;Xiazhang Li ,&nbsp;Chao Yao","doi":"10.1016/j.reactfunctpolym.2025.106249","DOIUrl":"10.1016/j.reactfunctpolym.2025.106249","url":null,"abstract":"<div><div>Ultraviolet (UV) protection is crucial for enhancing the durability, reliability, and safety of polymeric products. To address this need, a two-dimensional (2D) UV nano-filter was developed by integrating ZnTi layered double hydroxide (ZnTi-LDH) with dealkaline lignin (DL). The ZnTi-LDH/DL nanosheets were then incorporated into a poly(ethylene terephthalate) (PET) matrix using an in-situ polymerization technique. To evaluate its UV shielding performance, the microstructures of the ZnTi-LDH/DL nanosheets and the physicochemical properties of the resulting PET nanocomposites were investigated. The ZnTi-LDH/DL nanosheets retained the intrinsic crystalline structure and 2D morphology of pristine ZnTi-LDH while exhibiting significantly enhanced UV absorption over a broader wavelength range. Incorporating these nanosheets heightened the thermal stability, crystallization behavior, mechanical properties, and UV shielding performance of PET nanocomposites. At a mass fraction of 0.5 % nanosheets, the PET nanocomposite achieved optimal overall performance, exhibiting a Young's modulus of 436.8 MPa, an elongation at break of approximately 580 % and over 90 % blocking efficiency for UVA radiation (400–315 nm). These results indicate the potential of these PET nanocomposites for UV protection applications, particularly in UVA blocking.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106249"},"PeriodicalIF":4.5,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143579494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dialdehyde carboxylated cellulose green crosslinked soybean protein isolate based on Schiff base reaction to improve the emulsification performance and stability of emulsion","authors":"Yanling Jiang ,&nbsp;Jianshuo Miao ,&nbsp;Qiong Jiang ,&nbsp;Yidan Zhang ,&nbsp;Liuting Mo ,&nbsp;Wei Gao ,&nbsp;Zhiyong Qin","doi":"10.1016/j.reactfunctpolym.2025.106244","DOIUrl":"10.1016/j.reactfunctpolym.2025.106244","url":null,"abstract":"<div><div>To enhance the stabilization emulsion of soybean protein isolate (SPI), many strategies have been developed, such as modifying the properties of plant protein, using plant protein-polysaccharide complex, forming emulsion and so on. The purpose of this study was to investigate the response of SPI and dialdehyde carboxylated cellulose nanofibers (DCNFs) with Schiff base at different concentrations and its effect on the emulsification property of SPI were investigated. The results indicated that the α-helix and β-turn contents of the protein in the SPI/DCNFs conjugates decreased by 35.9 % and 2 %, respectively. The fluorescence intensity reduced as the addition of DCNFs, indicating that there was a static quenching between DCNFs and SPI. SPI was caused by DCNFs to reduce the surface hydrophobicity, expand the molecular structure of protein, and form the new covalent bonds (C=N). In addition, The average diameter of the SPI/DCNFs emulsion was reduced to 117 nm, the zeta potential was enhanced to −35.6 mV, and the emulsification performance and stability were increased by 40.9 % and 40.8 %, respectively. The results suggested that the Schiff base reaction generated the conformational change of protein and improved the emulsification function, which offered a possible way to control glycosylation and improve the emulsifying property of SPI.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"212 ","pages":"Article 106244"},"PeriodicalIF":4.5,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143549294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}