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Eu2O3-driven tailoring strategies on Al6061-Alloy for nuclear applications: A comprehensive study on structural, physical, and radiation transmission properties 核用al6061合金的eu2o3驱动裁剪策略:结构、物理和辐射传输性能的综合研究
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-16 DOI: 10.1016/j.radphyschem.2025.112949
Oykum Basgoz , Seval Hale Guler , Omer Guler , Ghada ALMisned , Duygu Sen Baykal , G. Kilic , H.O. Tekin
{"title":"Eu2O3-driven tailoring strategies on Al6061-Alloy for nuclear applications: A comprehensive study on structural, physical, and radiation transmission properties","authors":"Oykum Basgoz ,&nbsp;Seval Hale Guler ,&nbsp;Omer Guler ,&nbsp;Ghada ALMisned ,&nbsp;Duygu Sen Baykal ,&nbsp;G. Kilic ,&nbsp;H.O. Tekin","doi":"10.1016/j.radphyschem.2025.112949","DOIUrl":"10.1016/j.radphyschem.2025.112949","url":null,"abstract":"<div><div>In this study, Al6061–Eu<sub>2</sub>O<sub>3</sub> composites were fabricated via mechanical alloying and systematically characterized using X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy to evaluate structural and compositional features. The incorporation of Eu<sub>2</sub>O<sub>3</sub> in varying weight percentages (1–20 wt%) was confirmed by XRD, revealing phase retention and crystallite refinement, while SEM–EDS analyses indicated uniform elemental distribution at low doping and localized clustering at higher reinforcement levels. Radiation shielding properties were comprehensively assessed through mass and linear attenuation coefficients, half value layer, effective atomic number, fast neutron removal cross section, buildup factors, and photon transmission factors. The results demonstrated a strong correlation between increasing Eu<sub>2</sub>O<sub>3</sub> content and improved shielding performance. The E20 composite exhibited a mass attenuation coefficient of 22.33 cm<sup>2</sup>/g at 0.015 MeV, over threefold higher than the base alloy, and fast neutron removal cross section improved by 22.5 % compared to Al6061 alone. Additionally, EBF and EABF values decreased significantly, confirming reduced secondary photon build-up. These findings validate the effectiveness of Eu<sub>2</sub>O<sub>3</sub> as a reinforcement phase for tailoring Al6061 for multifunctional applications, particularly in nuclear, aerospace, and radiological environments requiring lightweight materials with superior gamma and neutron attenuation.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112949"},"PeriodicalIF":2.8,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144083799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Empirical formula for Mass attenuation coefficient of lead and bismuth nano materials 铅铋纳米材料质量衰减系数的经验公式
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-16 DOI: 10.1016/j.radphyschem.2025.112894
B.M. Chandrika , N. Sowmya , L. Seenappa , H.C. Manjunatha , K.N. Sridhar , A.J. Clement Lourduraj
{"title":"Empirical formula for Mass attenuation coefficient of lead and bismuth nano materials","authors":"B.M. Chandrika ,&nbsp;N. Sowmya ,&nbsp;L. Seenappa ,&nbsp;H.C. Manjunatha ,&nbsp;K.N. Sridhar ,&nbsp;A.J. Clement Lourduraj","doi":"10.1016/j.radphyschem.2025.112894","DOIUrl":"10.1016/j.radphyschem.2025.112894","url":null,"abstract":"<div><div>This study proposes an empirical formula for the mass attenuation coefficient (<span><math><mrow><mi>μ</mi><mo>/</mo><mi>ρ</mi></mrow></math></span>) of lead and bismuth nanoparticles, accounting for photon energy and material density through quadratic energy terms and density-dependent coefficients. This formula is applicable for the photon energy range 0.365 to 1.332 MeV. Validation against various nanoparticle-based compounds, including barium bismuth oxide borate and lead nickel copper, demonstrates the formula’s accuracy. The proposed formula is the first of its kind which produces mass attenuation coefficient for nanoparticles. The model offers a reliable framework for designing high-performance radiation shielding materials, addressing key needs in nuclear physics, medical imaging and dosimetry applications.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112894"},"PeriodicalIF":2.8,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144083795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Monte Carlo simulation surveying direct DNA damage using different biologically relevant electron energy, absorbed dose, electron tracking and base pair cutoff 蒙特卡罗模拟测量直接DNA损伤使用不同的生物相关电子能量,吸收剂量,电子跟踪和碱基对切断
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-14 DOI: 10.1016/j.radphyschem.2025.112940
Mariam M. Ahmed , M. Ali , Mona Moustafa , Magdy M. Khalil
{"title":"A Monte Carlo simulation surveying direct DNA damage using different biologically relevant electron energy, absorbed dose, electron tracking and base pair cutoff","authors":"Mariam M. Ahmed ,&nbsp;M. Ali ,&nbsp;Mona Moustafa ,&nbsp;Magdy M. Khalil","doi":"10.1016/j.radphyschem.2025.112940","DOIUrl":"10.1016/j.radphyschem.2025.112940","url":null,"abstract":"<div><div>X-ray or heavy ion beams are used in radiotherapy to target cancers and damage DNA. The primary cause of this damage is secondary low energy electrons. This work presents the analysis of DNA molecular damage including single (SSB) and double breaks (DSB) using an atomistic DNA model and track structure physics models. Considerations have been made on the influence of electron energy, electron dose, tracking cutoff as well as base pair cutoff. We simulated a model of atomistic DNA in vacuum, simulating 3 base pairs for each energy which is ranging from 0.04 to 5 keV. The current work showed a significant energy range in the direct interaction between low energy electrons and DNA. By incorporating information about indirect effects, the combination of data allows for the creation of a comprehensive global understanding of the impact of electrons on the biological target. The electron energy range of 100–600 eV has various advantages when used to irradiate cancer cells. This is because energy deposition occurs in dimensions that are like those of DNA strands and nucleosomes, showing that the highest yields of SSB and DSB occurred within the 300–600 eV range, peaking at 400 eV and 500 eV. The most common energy range for SSBs and DSBs was found between 300 and 600 eV. Lower energy and base pair cut-offs lead to greater damage but raising the energy cut-off from 10 to 20 eV greatly lowers the quantity of SSBs and DSBs per electron.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112940"},"PeriodicalIF":2.8,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144083800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effects of Zn and Sr Co-doping on local structure, dielectric properties, and bioactivity of hydroxyapatite porous materials Zn和Sr共掺杂对羟基磷灰石多孔材料局部结构、介电性能和生物活性的影响
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-12 DOI: 10.1016/j.radphyschem.2025.112928
Arthit Ruttakorn , Siriwan Tocho , Rattikorn Yimnirun , Thanit Saisopa , Tanachat Eknapakul , Prae Chirawatkul , Russameeruk Noonurak , Atipong Bootchanont
{"title":"The effects of Zn and Sr Co-doping on local structure, dielectric properties, and bioactivity of hydroxyapatite porous materials","authors":"Arthit Ruttakorn ,&nbsp;Siriwan Tocho ,&nbsp;Rattikorn Yimnirun ,&nbsp;Thanit Saisopa ,&nbsp;Tanachat Eknapakul ,&nbsp;Prae Chirawatkul ,&nbsp;Russameeruk Noonurak ,&nbsp;Atipong Bootchanont","doi":"10.1016/j.radphyschem.2025.112928","DOIUrl":"10.1016/j.radphyschem.2025.112928","url":null,"abstract":"<div><div>Hydroxyapatite (HA) is a vital biomaterial widely used in bone implants and orthodontics due to its excellent biocompatibility. In this study, Sr and Zn co-doped HA was synthesized using the sol-gel combustion method and cast into porous materials. Samples containing 5 mol% Sr and varying Zn concentrations (0, 1, 3, and 5 mol%) were labeled as 0ZnSr-HA, 1ZnSr-HA, 3ZnSr-HA, and 5ZnSr-HA, respectively. The crystal and local structures were analyzed using X-ray diffraction (XRD) and X-ray absorption near-edge structure (XANES), revealing that Zn<sup>2+</sup> and Sr<sup>2+</sup> ions substitute at the Ca1 and Ca2 sites within the hydroxyapatite lattice. The dielectric properties were investigated over a frequency range of 20–10<sup>3</sup> Hz, where 3ZnSr-HA exhibited the highest dielectric constant of 39.74, suggesting its potential to support bone growth during simulated body fluid (SBF) testing. The microstructure and elemental composition of the samples were examined using scanning electron microscopy (SEM) and energy-dispersive X-ray analysis (EDX). After 2 weeks of immersion in SBF, 3ZnSr-HA demonstrated significant apatite growth, highlighting the ability of Zn and Sr co-substitution to enhance the HA structure and improve bone regeneration efficiency. This study confirms the potential of Sr- and Zn-doped HA as a promising material for biomedical applications.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112928"},"PeriodicalIF":2.8,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144083696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A statistical evaluation of material discrimination approaches in cargo inspection systems 货物检验系统中材料鉴别方法的统计评价
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-12 DOI: 10.1016/j.radphyschem.2025.112873
Hossein Barati , Seyed AmirHossein Feghhi , Rouhollah Azimirad
{"title":"A statistical evaluation of material discrimination approaches in cargo inspection systems","authors":"Hossein Barati ,&nbsp;Seyed AmirHossein Feghhi ,&nbsp;Rouhollah Azimirad","doi":"10.1016/j.radphyschem.2025.112873","DOIUrl":"10.1016/j.radphyschem.2025.112873","url":null,"abstract":"<div><div>In X-ray inspection systems employing dual-energy capabilities, material discrimination primarily centers on three methodologies based on curves: the <span><math><mi>α</mi></math></span> curve, the <span><math><mi>R</mi></math></span> curve, and the <span><math><mrow><mi>H</mi><mo>−</mo><mi>L</mi></mrow></math></span> curve. Despite extensive research in this field, there remains ambiguity regarding the comparative effectiveness of these methods under different conditions. This study aims to evaluate the accuracy of material discrimination using a standard cargo inspection system for four wedge-shaped materials. Multiple experiments were conducted, where experimental data were mapped onto the coordinate system for all three discrimination methods, and discrimination curves were generated using cubic interpolation. Regular residual analysis and statistical tests, including ANOVA and Tukey HSD, were performed to evaluate the effectiveness of the <span><math><mi>R</mi></math></span>, <span><math><mi>α</mi></math></span>, and <span><math><mrow><mi>H</mi><mo>−</mo><mi>L</mi></mrow></math></span> methods. No statistically significant differences in the performance of these methods were found. Unlike some previous studies where one method was favored over another, no inherent superiority of any particular method was observed in this research. Additionally, combining these methods yields no significant gains in accuracy or efficiency, and their simultaneous use is not recommended due to increased computational costs. The analysis of sample thickness effects revealed higher success rates for thicker samples, though no method outperformed the others across thickness ranges. These findings suggest that the choice of method should be guided by practical considerations rather than assumptions of inherent superiority.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112873"},"PeriodicalIF":2.8,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143946636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dosimetric evaluation of 6 MV photon beams in small fields using PRIMO-penEasy Monte Carlo 基于PRIMO-penEasy蒙特卡罗的6毫伏光子束小场剂量学评价
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-12 DOI: 10.1016/j.radphyschem.2025.112904
Nataly Díaz , Amaia Villa Abaunza , Jorge Muñoz , José Manuel Udías , Paula Ibáñez
{"title":"Dosimetric evaluation of 6 MV photon beams in small fields using PRIMO-penEasy Monte Carlo","authors":"Nataly Díaz ,&nbsp;Amaia Villa Abaunza ,&nbsp;Jorge Muñoz ,&nbsp;José Manuel Udías ,&nbsp;Paula Ibáñez","doi":"10.1016/j.radphyschem.2025.112904","DOIUrl":"10.1016/j.radphyschem.2025.112904","url":null,"abstract":"<div><div>Dosimetric validation of clinical radiotherapy plans for small fields requires high-precision instrumentation to ensure accuracy and spatial resolution. This study proposes a combination of PRIMO and penEasy Monte Carlo simulators to address scenarios where direct measurements are impractical, challenging, or yield inconsistent results due to detector limitations.</div><div>We compared three dosimetric tools: A Semiflex ionization chamber PTW (model 31010) within a water-filled acrylic tank; EBT3 radiochromic films positioned between solid water layers; and PRIMO-PenEasy simulations. Experiments were performed at San Ignacio University Hospital in Bogota, Colombia, with dose measurements in two small fields and one conventional field for an Axesse-type linear accelerator.</div><div>Results indicate that EBT3 radiochromic film show better agreement with MC simulation than the Semiflex ionization chamber, likely due to the chamber dose averaging effect across its detection volume. Additionally, variations in off-axis ratios were noted in both crossplane and inplane directions with more pronounced discrepancies observed in small fields compared to the conventional field. Overall, PRIMO-PenEasy MC simulations demonstrated accurate dose distributions and can be used as a viable for dosimetric validation in small photon fields.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112904"},"PeriodicalIF":2.8,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144066392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal-organic frameworks with high photoluminescence quantum yield for X-ray scintillators 用于x射线闪烁体的高光致发光量子产率金属有机骨架
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-11 DOI: 10.1016/j.radphyschem.2025.112916
Siqi Yan , Qian Yang , Shuya Zhang , Jiayi Zhang , Tianping Wang , Jia Li , Yanlong Wang , Aiping Jin , Xiaohong Xiong , Xiaoping Ouyang , Hanzhou Liu , Shuao Wang
{"title":"Metal-organic frameworks with high photoluminescence quantum yield for X-ray scintillators","authors":"Siqi Yan ,&nbsp;Qian Yang ,&nbsp;Shuya Zhang ,&nbsp;Jiayi Zhang ,&nbsp;Tianping Wang ,&nbsp;Jia Li ,&nbsp;Yanlong Wang ,&nbsp;Aiping Jin ,&nbsp;Xiaohong Xiong ,&nbsp;Xiaoping Ouyang ,&nbsp;Hanzhou Liu ,&nbsp;Shuao Wang","doi":"10.1016/j.radphyschem.2025.112916","DOIUrl":"10.1016/j.radphyschem.2025.112916","url":null,"abstract":"<div><div>Here, we report a Pb-based metal-organic framework, Pb((TPA)DMF)<sub>2</sub>·H<sub>2</sub>O (denoted as <strong>Pb-TPA</strong>, where TPA stands for terephthalic acid and DMF for N, N-dimethylformamide), synthesized under mild synthesis conditions (353 K, 3 days), as an X-ray scintillator. <strong>Pb-TPA</strong> features persistent luminescent centers and an impressive photoluminescence quantum yield of 86.7 %. Over a wide dose rate range 0.97–26.50 Gy min<sup>−1</sup> (dose to air), <strong>Pb-TPA</strong> demonstrates a robust linear response to X-ray radiation with a detection limit of 0.531 μGy s<sup>−1</sup>. In addition, <strong>Pb-TPA</strong> exhibits a 60-fold enhancement in detection sensitivity compared to commercial PbWO<sub>4</sub> (PWO) crystals.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112916"},"PeriodicalIF":2.8,"publicationDate":"2025-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144066397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential application of slice heavy ion beam radiography by energy difference method for future theranostic of carbon ions therapy 能量差法层重离子束放射成像在未来碳离子治疗中的潜在应用
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-10 DOI: 10.1016/j.radphyschem.2025.112921
Zexian Zhou , Rui Cheng , Jiangtao Zhao , Yuyu Wang , Yu Lei , Guodong Wang , Lulin Shi , Zhao Wang , Jingfu Zhang , Xuejian Jin , Yanhong Chen , Xiaoxia Wu , Yanshi Zhang , Liangwen Chen , Yongtao Zhao , Jie Yang , Maogen Su , Guoqing Xiao
{"title":"Potential application of slice heavy ion beam radiography by energy difference method for future theranostic of carbon ions therapy","authors":"Zexian Zhou ,&nbsp;Rui Cheng ,&nbsp;Jiangtao Zhao ,&nbsp;Yuyu Wang ,&nbsp;Yu Lei ,&nbsp;Guodong Wang ,&nbsp;Lulin Shi ,&nbsp;Zhao Wang ,&nbsp;Jingfu Zhang ,&nbsp;Xuejian Jin ,&nbsp;Yanhong Chen ,&nbsp;Xiaoxia Wu ,&nbsp;Yanshi Zhang ,&nbsp;Liangwen Chen ,&nbsp;Yongtao Zhao ,&nbsp;Jie Yang ,&nbsp;Maogen Su ,&nbsp;Guoqing Xiao","doi":"10.1016/j.radphyschem.2025.112921","DOIUrl":"10.1016/j.radphyschem.2025.112921","url":null,"abstract":"<div><div>Carbon ions therapy has become a globally prevalent treatment due to its highly efficiency in tumor eradication by including DNA double-strand breaks within the Bragg peak region, while avoiding the need for invasive surgery. A pre-treatment assessment using X-ray technology is necessary to draw the tumor morphology for carbon ions impinging. However, metal implants adjacent to tumor area often generate heavy artifacts during CT scans, compromising accurate tumor evaluation. We propose a radiography method utilizing high-energy carbon ion beams, which exhibit stronger penetration and density sensitivity compared to X-ray. In this study, we investigate the important physical properties of marginal range (where Bragg peaks location) radiography by using high energy carbon ions beams incidence different morphology targets at the Heavy Ion Research Facility in Lanzhou (HIRFL). By modulating the beam energy, the detailed interior structures of targets are visualized slice-by-layer. The results demonstrated that the marked copper plate and the CPU targets achieved density resolution of about 1.6 % at 10.9 g/cm<sup>2</sup> and spatial resolution of 500 <span><math><mrow><mi>μ</mi></mrow></math></span> m. For the ball-point pen, the sequence radiographs of different depth features are presented. An agreement is found between the Geant4 simulation and the experimental results. Both low-Z and high-Z material components in the ball-point pen are distinctly differentiated, and a three-dimensional visual target is reconstructed. Through in vitro experiment, we validate the important physical properties of marginal range radiography and extending its application to tumor cases with high Z metal implants. The excellent resolution power is expected to solve the tumor morphology caused by metal artifacts in CIRT treatment. Such combination of marginal range radiography with Bragg peak cancer therapy provides a unique solution for the future development of carbon ion theranostic.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112921"},"PeriodicalIF":2.8,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143936265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Degradation of target pollutants under simultaneous competition from coexisting compounds: Electron-beam treatment of a real hair dye wastewater 共存化合物同时竞争下目标污染物的降解:电子束处理真实染发剂废水
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-10 DOI: 10.1016/j.radphyschem.2025.112929
Qiburi Bao , Boming Yu , Wangrui Li , Miao Yang , Zhen Dong , Long Zhao
{"title":"Degradation of target pollutants under simultaneous competition from coexisting compounds: Electron-beam treatment of a real hair dye wastewater","authors":"Qiburi Bao ,&nbsp;Boming Yu ,&nbsp;Wangrui Li ,&nbsp;Miao Yang ,&nbsp;Zhen Dong ,&nbsp;Long Zhao","doi":"10.1016/j.radphyschem.2025.112929","DOIUrl":"10.1016/j.radphyschem.2025.112929","url":null,"abstract":"<div><div>Water pollution resulting from the extensive production and consumption of hair dyes has been threatening human health and aquatic ecosystems globally. Gaining knowledge on the presence of compounds in real hair dye wastewater and developing efficient treatment are emerging issues. This paper studies the electron beam irradiation of a real hair dye industrial wastewater. The COD<sub>Cr</sub> of the industrial wastewater was reduced by 35 % through EB irradiation at 9 kGy. Four dyestuff intermediates (phenol, 5-amino-<em>o</em>-cresol, 5-amino-4-chloro-<em>o</em>-cresol and 5-amino-6-chloro-<em>o</em>-cresol) were identified as the target pollutants through compositional analysis of the wastewater. The removals of target pollutants in single-component solutions reached 75.7 %–89.7 % at 9 kGy The influence of coexisting background components on the degradation of targets was investigated and the interaction between different targets was evaluated during the irradiation treatment. Compared with pure single solutions, the required doses for 50 % removal of the targets in the wastewater increased by 0.1–5.8 times. Quantitative assessment of the competing effects of non-target components and the selectivity of reactive species is performed. <sup><img></sup>OH and <sup><img></sup>O<sub>2</sub><sup>−</sup> show much lower selectivity toward the targets than reducing radicals (e<sub>aq</sub><sup>−</sup> and <sup><img></sup>H). Among them, <sup><img></sup>O<sub>2</sub><sup>−</sup> exhibits the lowest selectivity toward phenol with a log<em>f</em> value of −0.51. The main breakdown products of the target pollutants are quinones, diphenols and carboxylic acids.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"236 ","pages":"Article 112929"},"PeriodicalIF":2.8,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144066398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Degradation mechanism of Cascode GaN high electron mobility transistors device with high energy protons and heavy ions synergistic irradiations 高能质子和重离子协同辐照下Cascode GaN高电子迁移率晶体管器件的降解机理
IF 2.8 3区 物理与天体物理
Radiation Physics and Chemistry Pub Date : 2025-05-10 DOI: 10.1016/j.radphyschem.2025.112933
Yuxin Lu , Dongping Yang , Yuanyuan Xue , Rongxing Cao , Chengan Wan , Xuelin Yang , Dan Han , Xianghua Zeng , Yuxiong Xue
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