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Polish Journal of Chemical Technology最新文献

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Modeling and experimental studies of carbon dioxide separation on zeolite fixed bed by cyclic pressure swing adsorption 沸石固定床循环变压吸附分离二氧化碳的模型和实验研究
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0002
Tomasz Aleksandrzak, Kamila Zabielska, Elżbieta Gabruś
{"title":"Modeling and experimental studies of carbon dioxide separation on zeolite fixed bed by cyclic pressure swing adsorption","authors":"Tomasz Aleksandrzak, Kamila Zabielska, Elżbieta Gabruś","doi":"10.2478/pjct-2024-0002","DOIUrl":"https://doi.org/10.2478/pjct-2024-0002","url":null,"abstract":"The paper presents the results of experimental and model studies of the pressure swing adsorption (PSA) process in a column with a zeolite 13X bed with a height of 0.5 m. The gas mixture consisted of CO<jats:sub>2</jats:sub> (10–20%), N<jats:sub>2</jats:sub>, and H<jats:sub>2</jats:sub>O (RH 50%) in different ratios. As a result of the column tests, concentration, and temperature evolutions were obtained for each of the adsorption and desorption stages, which were used to determine the breakthrough and bed saturation times and other parameters important for the analysis of the column operation. A mathematical model of the PSA process for the separation of CO<jats:sub>2</jats:sub> from the gas mixture was developed. The system of second-order partial differential equations was solved using Matlab software. The research focuses on adsorptive CO<jats:sub>2</jats:sub> capture and shows the influence of water vapor and operational parameters on the quality of model validation.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"48 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characteristics and applications of iron oxides reduction processes 氧化铁还原工艺的特点和应用
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0005
K.S. Abdel Halim, A.A. El-Geassy, M.I. Nasr, Mohamed Ramadan, Naglaa Fathy, Abdulaziz S. Al-ghamdi
{"title":"Characteristics and applications of iron oxides reduction processes","authors":"K.S. Abdel Halim, A.A. El-Geassy, M.I. Nasr, Mohamed Ramadan, Naglaa Fathy, Abdulaziz S. Al-ghamdi","doi":"10.2478/pjct-2024-0005","DOIUrl":"https://doi.org/10.2478/pjct-2024-0005","url":null,"abstract":"The present review handles the main characteristics of iron oxide reduction and its industrial applications. The reduction of iron oxide is the basis of all ironmaking processes, whether in a blast furnace or by direct reduction and/or direct smelting processes. The reduction characteristics of iron ores control the efficiency of any ironmaking process and the quality of the produced iron as well. Many controlling parameters should be considered when discussing the reducibility of iron ores such as equilibrium phase diagrams, reduction temperature, pressure, gas composition, and the nature of both iron ores and reducing agent. The different factors affecting the main routes of ironmaking will be highlighted in the present review to give a clear picture for each technology. Moreover, further innovations regarding the reduction of iron oxides such as reduction by green hydrogen will be discussed.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"66 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of calcination temperatures on optical and magnetic properties of FeWO4 nanoparticles 煅烧温度对 FeWO4 纳米粒子光学和磁学特性的影响
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0003
Anh Q.K. Nguyen, Thi K.N. Tran, Bich N. Hoang, Ngo T.C. Quyen, Tai T. Huynh, Nguyen P. Yen, Bich N. Nguyen
{"title":"Effect of calcination temperatures on optical and magnetic properties of FeWO4 nanoparticles","authors":"Anh Q.K. Nguyen, Thi K.N. Tran, Bich N. Hoang, Ngo T.C. Quyen, Tai T. Huynh, Nguyen P. Yen, Bich N. Nguyen","doi":"10.2478/pjct-2024-0003","DOIUrl":"https://doi.org/10.2478/pjct-2024-0003","url":null,"abstract":"Calcination temperature is a crucial parameter that can be easily controlled to induce a change in material properties. Herein, iron tungstate (FeWO<jats:sub>4</jats:sub>) was synthesized via a hydrothermal method using iron(II) sulfate heptahydrate and sodium tungstate dihydrate as precursors and calcined at the temperature between 300 <jats:sup>o</jats:sup>C and 700 <jats:sup>o</jats:sup>C. With increasing calcination temperature, the saturation magnetization of FeWO<jats:sub>4</jats:sub> nanoparticles decreased from 6.6 emu/g for FeWO<jats:sub>4</jats:sub> to 0.4 emu/g for FeWO4_700, whereas their band gaps increased from 1.95 eV for FeWO<jats:sub>4</jats:sub> to 2.20 eV for FeWO4_700. More crystallinity and crystal defects, and morphological changes at higher calcination temperatures contributed to varying magneto-optical properties of FeWO<jats:sub>4</jats:sub> nanoparticles.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"51 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, structural, thermal, and morphological characterization of Ru(III) complex with gatifloxacin and its utility to obtain RuO2 nanostructures Ru(III)与加替沙星配合物的合成、结构、热和形态特征及其在获得 RuO2 纳米结构中的应用
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0008
Khaled Althubeiti
{"title":"Synthesis, structural, thermal, and morphological characterization of Ru(III) complex with gatifloxacin and its utility to obtain RuO2 nanostructures","authors":"Khaled Althubeiti","doi":"10.2478/pjct-2024-0008","DOIUrl":"https://doi.org/10.2478/pjct-2024-0008","url":null,"abstract":"In this work, the reaction between the drug gatifloxacin (as a ligand) with Ru(III) ions was investigated and the resulting complex was structurally and morphologically characterized. The structural properties of the complex were assessed using elemental analyses, molar conductance, thermogravimetry, UV-Vis, and IR spectroscopies, where the morphological characteristics were evaluated using SEM-EDX and XRD methods. The analyses suggested that two ligand molecules were coordinated to the Ru(III) ion via the nitrogen atoms of piperazine rings. The complex was formulated as [Ru(L)<jats:sub>2</jats:sub>(Cl)<jats:sub>2</jats:sub>]Cl, where the Ru(III) ion has a six-coordinate mode, and the coordination sphere is complemented by chlorine atoms. The interaction of the ligand with the Ru(III) ions leads to the product having an organized smooth plate-like structure with a main diameter of 39.42 nm. The RuO<jats:sub>2</jats:sub> oxide in the nanoscale range was generated by the thermal decomposition of the [Ru(L)<jats:sub>2</jats:sub>(Cl)<jats:sub>2</jats:sub>]Cl complex at 600 <jats:sup>o</jats:sup>C for 3 hours. SEM micrographs indicated that the RuO<jats:sub>2</jats:sub> material possesses uniform and organized microstructures with many internal cavities enabling it to be used as a catalyst for the heterogeneous degradation of dyes and organic pollutants.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"31 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterization, and molecular modeling of novel 1,3,4-oxadiazole derivatives of mefenamic acid 新型甲灭酸 1,3,4-恶二唑衍生物的合成、表征和分子建模
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0016
Mashooq A. Bhat, Ahmed M. Naglah, Ahmed Hassan Bakheit, Mohamad A. Al-Omar
{"title":"Synthesis, characterization, and molecular modeling of novel 1,3,4-oxadiazole derivatives of mefenamic acid","authors":"Mashooq A. Bhat, Ahmed M. Naglah, Ahmed Hassan Bakheit, Mohamad A. Al-Omar","doi":"10.2478/pjct-2024-0016","DOIUrl":"https://doi.org/10.2478/pjct-2024-0016","url":null,"abstract":"A novel series of 1,3,4-oxadiazole derivatives of mefenamic acid was obtained by reacting hydrazones of mefenamic acid with anhydrous acetic anhydride. The mefenamic hydrazones were obtained by reacting different substituted aldehydes with mefenamic acid hydrazide. All the compounds were characterized by spectral data and elemental analysis. Molecular docking studies of all the compounds were performed against COX-1/COX-2 enzymes. Compound 4 and compound 10 were found to have the highest potential to bind with COX-1 while compound 3, compound 6, and compound 10 were found to have the highest potential to bind with COX-2 enzyme.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"262 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Liquid-liquid two phase-system stabilized by tween 40 and 80 surfactants: multiparametric study 由吐温 40 和 80 表面活性剂稳定的液液两相系统：多参数研究
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0006
Halina Murasiewicz, Khrystyna Illienko
{"title":"Liquid-liquid two phase-system stabilized by tween 40 and 80 surfactants: multiparametric study","authors":"Halina Murasiewicz, Khrystyna Illienko","doi":"10.2478/pjct-2024-0006","DOIUrl":"https://doi.org/10.2478/pjct-2024-0006","url":null,"abstract":"The purpose of this study was to investigate the impact of process parameters such as interfacial tension, type of surfactants, and their concentration on simple oil-in-water dispersion. Explored systems were prepared with 5% liquid paraffin oil and aqueous phase with emulsifiers Tween 40 of concentrations from 0.008325 mM to 0.025 mM and Tween 80 with concentrations ranging from 0.00375 mM to 0.011 mM. All systems were characterized in terms of their density and interfacial tension. In the next step analysis of droplet size distributions and mean droplet diameter was performed. The results showed that the size of paraffin droplets decreased as the concentration of surfactants grew. This trend is accompanied by decrease in the interfacial tension between phases. The correlation between mean drop size and the energy input and physical properties of both liquids was developed. The last step provides scientific evidence for the formulation of stable droplets of liquid paraffin.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"42 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of drops dimensions and rheological properties in production of multiple emulsion in a vessel 评估在容器中生产多重乳液时的液滴尺寸和流变特性
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0009
Marta Major-Godlewska
{"title":"Evaluation of drops dimensions and rheological properties in production of multiple emulsion in a vessel","authors":"Marta Major-Godlewska","doi":"10.2478/pjct-2024-0009","DOIUrl":"https://doi.org/10.2478/pjct-2024-0009","url":null,"abstract":"The structure and size of droplets of the inner phase of a multiple emulsion and rheological properties of the produced multiple emulsion are presented in this paper. The multiple emulsion was produced in a stirred vessel equipped with four baffles. In the study, two different stirrers: turbine impeller and Rushton turbine impeller were used. The liquids used in the produced multiple emulsion were: distilled water and refined sunflower oil. 8 g and 16 g lecithin from soya beans were used as an emulsifier. The preparation time was respectively 15 min. and 45 min. The structure of the obtained emulsions is presented in the form of photos taken with the diagnostic inverted microscope. The results size of droplets were presented in the form of graphics as a distribution of drops. The rheological properties of the multiple emulsion were presented graphically and it was described using the rheological model.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"121 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140577429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of (2E)-3,7-dimethyl-2,6-octadien-l-ol (geraniol) transformation process parameters using Response Surface Method (RSM) 利用响应面法 (RSM) 优化 (2E)-3,7-二甲基-2,6-辛二烯-l-醇（香叶醇）转化工艺参数
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0004
Anna Fajdek-Bieda, Agnieszka Wróblewska
{"title":"Optimization of (2E)-3,7-dimethyl-2,6-octadien-l-ol (geraniol) transformation process parameters using Response Surface Method (RSM)","authors":"Anna Fajdek-Bieda, Agnieszka Wróblewska","doi":"10.2478/pjct-2024-0004","DOIUrl":"https://doi.org/10.2478/pjct-2024-0004","url":null,"abstract":"This paper presents the results of studies on the transformation of geraniol (GA) in the presence of the natural mineral bentonite. The paper determines the influence of temperature, catalyst content, and reaction time on the course of the process. In order to determine the most favorable process conditions, the catalytic tests were carried out without solvent and under atmospheric pressure. Three functions were chosen to determine the most favorable process conditions: GA conversion and the selectivities of the main products: linalool – LO and beta-pinene – BP. In addition, the paper optimize GA transformation process based on response surface methodology (RSM). The impact of the most relevant process indicators was presented. For all factors of the method, their effects on all primary parameters were determined in the form of second-degree polynomials, and such process conditions were determined to achieve their maximum.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"66 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of the corrosion resistance for stainless steel 316 by applying laser shock peening 通过激光冲击强化提高 316 不锈钢的耐腐蚀性能
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-04-03 DOI: 10.2478/pjct-2024-0001
Sarah A. Jasim, Ammar Ayesh, A. Kadhim, Oday I. Abdullah
{"title":"Enhancement of the corrosion resistance for stainless steel 316 by applying laser shock peening","authors":"Sarah A. Jasim, Ammar Ayesh, A. Kadhim, Oday I. Abdullah","doi":"10.2478/pjct-2024-0001","DOIUrl":"https://doi.org/10.2478/pjct-2024-0001","url":null,"abstract":"This research paper focuses on enhancing the surface characteristics of the 316 stainless steel (SS316) alloy, including roughness, microhardness, and corrosion resistance. Where the application of ND-YAG laser technology, a highly relevant and timely area, was investigated deeply. The Q-switching Nd: YAG Laser was used with varying laser energy levels within the context of the laser shock peening (LSP) technique. The corrosion resistance of the 316 ss alloy is evaluated in a corrosive environment of 500 mL of saliva (with a pH of 5.6) through electrochemical corrosion testing. Corrosion rate was determined based on the analysis of polarization curves. The outcomes of this research reveal that as the laser energy was increased, there was a noticeable enhancement in the mechanical properties of the 316 ss alloy’s surface. Importantly, the corrosion rate experiences a significant reduction, decreasing from 4.94 mm/yr to 3.59 mm/yr following laser shock peening (LSP) application.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"66 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Isolation of citronellal and geraniol from citronella (Cymbopogon winterianus) oil by vacuum fractional distillation: Effect of operating conditions on the separation 通过真空分馏从香茅（Cymbopogon winterianus）油中分离香茅醛和香叶醇：操作条件对分离的影响
IF 1 4区 工程技术
Polish Journal of Chemical Technology Pub Date : 2024-01-11 DOI: 10.2478/pjct-2023-0040
Minh-Trung Le, Duc-Phuong Vu, Thanh Ngoc Nguyen, Xuan-Tien Le
{"title":"Isolation of citronellal and geraniol from citronella (Cymbopogon winterianus) oil by vacuum fractional distillation: Effect of operating conditions on the separation","authors":"Minh-Trung Le, Duc-Phuong Vu, Thanh Ngoc Nguyen, Xuan-Tien Le","doi":"10.2478/pjct-2023-0040","DOIUrl":"https://doi.org/10.2478/pjct-2023-0040","url":null,"abstract":"This study used fractional distillation to separate citronellal and geraniol from citronella (<jats:italic>Cymbopogon winterianus</jats:italic>) essential oil to improve their market value. The one-factor-at-a-time methodology investigated operating parameters’ optimum conditions and effects, including system pressure, packing types, and column height. All investigations were evaluated based on their main fraction’s citronellal and geraniol content and recovery. Regarding the effect of the variables, a higher system pressure improved the separation while increasing the temperature range of each fraction and distillation time. The packing types would also improve the separation by providing a large surface area. Finally, the column height also positively impacted the separation. In the optimum citronella oil fractionation, citronellal content experienced a 2.5-fold increase, from 37.68% to 94.33%. Geraniol purity reached 40.61% from an initial content of 17.33% in the raw CW oil. The distillation could recover up to 90.00% of citronellal and 68.18% of geraniol.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"21 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2024-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139459713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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