{"title":"Optimization of (2E)-3,7-dimethyl-2,6-octadien-l-ol (geraniol) transformation process parameters using Response Surface Method (RSM)","authors":"Anna Fajdek-Bieda, Agnieszka Wróblewska","doi":"10.2478/pjct-2024-0004","DOIUrl":null,"url":null,"abstract":"This paper presents the results of studies on the transformation of geraniol (GA) in the presence of the natural mineral bentonite. The paper determines the influence of temperature, catalyst content, and reaction time on the course of the process. In order to determine the most favorable process conditions, the catalytic tests were carried out without solvent and under atmospheric pressure. Three functions were chosen to determine the most favorable process conditions: GA conversion and the selectivities of the main products: linalool – LO and beta-pinene – BP. In addition, the paper optimize GA transformation process based on response surface methodology (RSM). The impact of the most relevant process indicators was presented. For all factors of the method, their effects on all primary parameters were determined in the form of second-degree polynomials, and such process conditions were determined to achieve their maximum.","PeriodicalId":20324,"journal":{"name":"Polish Journal of Chemical Technology","volume":"66 1","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polish Journal of Chemical Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.2478/pjct-2024-0004","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
This paper presents the results of studies on the transformation of geraniol (GA) in the presence of the natural mineral bentonite. The paper determines the influence of temperature, catalyst content, and reaction time on the course of the process. In order to determine the most favorable process conditions, the catalytic tests were carried out without solvent and under atmospheric pressure. Three functions were chosen to determine the most favorable process conditions: GA conversion and the selectivities of the main products: linalool – LO and beta-pinene – BP. In addition, the paper optimize GA transformation process based on response surface methodology (RSM). The impact of the most relevant process indicators was presented. For all factors of the method, their effects on all primary parameters were determined in the form of second-degree polynomials, and such process conditions were determined to achieve their maximum.
本文介绍了在天然矿物膨润土存在下转化香叶醇(GA)的研究结果。本文确定了温度、催化剂含量和反应时间对工艺过程的影响。为了确定最有利的工艺条件,催化试验在无溶剂和常压下进行。选择了三种功能来确定最有利的工艺条件:GA 转化率和主要产物的选择性:芳樟醇 - LO 和 beta-蒎烯 - BP。此外,论文还基于响应面方法(RSM)对 GA 转化工艺进行了优化。文中介绍了最相关工艺指标的影响。对于该方法的所有因素,其对所有主要参数的影响均以二级多项式的形式确定,并确定了达到最大值的工艺条件。
期刊介绍:
Polish Journal of Chemical Technology is a peer-reviewed, international journal devoted to fundamental and applied chemistry, as well as chemical engineering and biotechnology research. It has a very broad scope but favors interdisciplinary research that bring chemical technology together with other disciplines. All authors receive very fast and comprehensive peer-review. Additionally, every published article is promoted to researchers working in the same field.