Plastics, Rubber and Composites最新文献_第8页

Synthesis and characterisation of polyaniline/polyvinyl alcohol composites as supercapacitor electrode materials 聚苯胺/聚乙烯醇复合材料超级电容器电极材料的合成与表征

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-09-23 DOI: 10.1080/14658011.2021.1981090

Roopasri Rajamany, Sivakrishna Prakash, Y. Ismail

{"title":"Synthesis and characterisation of polyaniline/polyvinyl alcohol composites as supercapacitor electrode materials","authors":"Roopasri Rajamany, Sivakrishna Prakash, Y. Ismail","doi":"10.1080/14658011.2021.1981090","DOIUrl":"https://doi.org/10.1080/14658011.2021.1981090","url":null,"abstract":"ABSTRACT Composites of polyaniline and polyvinyl alcohol were prepared through an in-situ polymerisation of aniline using ethanol as a coagulating agent and characterised for their applicability as supercapacitor electrode material. The thermally stable composites afford moderately high electrical conductivity. Composite with 0.03 mol aniline exhibited a high electrical conductivity of 0.371 × 10−2 S/cm. The variation in electrical conductivity with an increase in aniline content is consistent with the band gap energies estimated from electronic spectra and IR drop. SEM analysis confirms coral-like nanowires of polyaniline (PANI) grown within the polyvinyl alcohol matrix. Cyclic voltametric studies revealed that the composites are highly electroactive as they allow easy diffusion of ions through the nanowires of PANI for efficient electrochemical reaction. The composite with 0.03 mol aniline has a superior specific capacitance of 302 Fg−1 at a scan rate of 5 mV/s. The composite exhibited a maximum energy density of 41.94 Whkg−1 and excellent stability even after storage of 18 months in ambient condition with 83.3% capacitance retention.","PeriodicalId":20245,"journal":{"name":"Plastics, Rubber and Composites","volume":"18 1","pages":"240 - 249"},"PeriodicalIF":2.0,"publicationDate":"2021-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85208579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 4

The effect of different compatibilisers on the morphology and rheological properties of PP/PET polymer blends 不同增容剂对PP/PET共混物形态和流变性能的影响

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-09-23 DOI: 10.1080/14658011.2021.1981525

S. Kordjazi, Z. Kordjazi, N. Golshan Ebrahimi

{"title":"The effect of different compatibilisers on the morphology and rheological properties of PP/PET polymer blends","authors":"S. Kordjazi, Z. Kordjazi, N. Golshan Ebrahimi","doi":"10.1080/14658011.2021.1981525","DOIUrl":"https://doi.org/10.1080/14658011.2021.1981525","url":null,"abstract":"ABSTRACT In the present study, the compatibilisation of polypropylene/polyethylene terephthalate (PP/PET) blends with different types of compatibilisers including maleic anhydride-grafted polypropylene (PP-g-MA), glycidyl methacrylate-grafted polypropylene (PP-g-GMA) and ethylene propylene diene monomer (EPDM) rubber in different concentrations was examined. Samples were evaluated in terms of morphology, thermal and rheological properties. Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimeter (DSC) were used. According to the results, all samples had a matrix-droplet morphology. Moreover, with increasing the compatibiliser and its concentration, the droplet sizes in dispersed phase decreased. In other words, compatibilised PP/PET showed a greater dispersed phase size reduction, lower crystallinity percentage and larger storage modulus at low frequencies in comparison with non-compatibilised PP/PET blend. Among different samples, polymer blend compatibilised with PP-g-MA (5 phr) indicated the lowest particle size and significantly improved the compatibilisation of the PP/PET blend.","PeriodicalId":20245,"journal":{"name":"Plastics, Rubber and Composites","volume":"19 1","pages":"250 - 258"},"PeriodicalIF":2.0,"publicationDate":"2021-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75230534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 5

Simulating the electric field distribution in medium-voltage cables of cross-linked polyethylene/Cu nanocomposites irradiated by E-beam with reference to the XLPE market 模拟电子束辐照下交联聚乙烯/铜纳米复合材料中压电缆的电场分布，参考交联聚乙烯市场

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-09-07 DOI: 10.1080/14658011.2021.1975445

A. I. Sharshir, S. Fayek, Amal. F. Abd El-Gawad, M. Farahat, M. Ismail, M. Ghobashy

{"title":"Simulating the electric field distribution in medium-voltage cables of cross-linked polyethylene/Cu nanocomposites irradiated by E-beam with reference to the XLPE market","authors":"A. I. Sharshir, S. Fayek, Amal. F. Abd El-Gawad, M. Farahat, M. Ismail, M. Ghobashy","doi":"10.1080/14658011.2021.1975445","DOIUrl":"https://doi.org/10.1080/14658011.2021.1975445","url":null,"abstract":"ABSTRACT In this paper, the distribution of the electric field of medium voltage (MV) underground cable insulation made of polyethylene/copper nanoparticles (XLPE/Cu) is investigated. Three methods were established for copper nanoparticles (CuNPs) synthesis such as the alkaline reduction process, electrolysis process and metal displacement reaction. Ultraviolet–visible spectra, X-ray diffraction, and transmission electron microscopy (TEM) were used to classify the obtained CuNPs. The XLPE/Cu films with different CuNP weight content (0%, 1%, 3% and 5%) were subjected to a 3 MeV electron beam (EB) with different doses (0, 15, 20 and 25 kGy). The optimum AC/DC conductivity (AC 2 × 10−3 S m−1, DC 4.63 × 10−2 S m−1) in minimum relative permittivity (2.05) achieved for (XLPE/5-Cu) 25 kGy that is has a CuNP content of 5 wt-% and irradiated at 25 kGy. The electric field distribution in the middle of the (XLPE/5-Cu) 25 kGy sample is maximum uniform than at the top or bottom.","PeriodicalId":20245,"journal":{"name":"Plastics, Rubber and Composites","volume":"41 1","pages":"281 - 292"},"PeriodicalIF":2.0,"publicationDate":"2021-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77196917","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

Double-layered radar absorbing structures of MnZn ferrite/Pani-coated MWCNT filled nanocomposites for X-band frequencies x波段MnZn铁氧体/聚苯胺包覆MWCNT填充纳米复合材料双层雷达吸波结构

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-08-26 DOI: 10.1080/14658011.2021.1971361

T. Haritha, K. Ramji

引用次数: 4

Nanocomposite of p-type conductive polymer/iron (III) trimesic (Fe-BTC) metal–organic frameworks: synthesis, characterisation and pseudocapacitance performance p型导电聚合物/三聚铁(Fe-BTC)金属有机骨架的纳米复合材料:合成、表征及赝电容性能

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-08-17 DOI: 10.1080/14658011.2021.1966247

H. Mostaanzadeh, M. Shahmohammadi, A. Ehsani, Mojtaba Moharramnejad, M. Babazadeh

引用次数: 12

Surface modified iron oxide (Fe3O4) nanosheets reinforced PVDF nanocomposites: influence on morphology, thermal and magnetic properties 表面改性氧化铁(Fe3O4)纳米片增强PVDF纳米复合材料:对形貌、热性能和磁性能的影响

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-08-12 DOI: 10.1080/14658011.2021.1966248

N. Lakshmi, P. Tambe, B. Panda

{"title":"Surface modified iron oxide (Fe3O4) nanosheets reinforced PVDF nanocomposites: influence on morphology, thermal and magnetic properties","authors":"N. Lakshmi, P. Tambe, B. Panda","doi":"10.1080/14658011.2021.1966248","DOIUrl":"https://doi.org/10.1080/14658011.2021.1966248","url":null,"abstract":"ABSTRACT In this work, iron oxide (Fe3O4) nanosheets are synthesised using the solvothermal method. Transmission electron microscope (TEM) observation confirms the nanosheets-like morphology of Fe3O4. While X-ray diffraction (XRD) studies of Fe3O4 nanosheets reveal the Fe3O4 nanosheets synthesised are crystalline in nature. Vibration sample magnetometry studies of Fe3O4 nanosheets have shown superparamagnetic behaviour with saturation magnetisation (M s) value of 29.6 emu/g. The synthesised Fe3O4 nanosheets are dispersed in poly(vinylidene fluoride) PVDF matrix using the solution casting method with slow evaporation of solvent at 60 °C which facilitates the formation of β-form of PVDF crystals. The PVP modified Fe3O4 nanosheets incorporation in the PVDF matrix influences the thermal stability and crystalline behaviour. Scanning electron microscope observation shows the improved dispersion of Fe3O4 nanosheets in the PVDF matrix by modifying Fe3O4 nanosheets with PVP. The M s value is increased by ∼122% for PVP modified Fe3O4 nanosheets reinforced PVDF nanocomposites as compared to Fe3O4 nanosheets reinforced PVDF nanocomposites.","PeriodicalId":20245,"journal":{"name":"Plastics, Rubber and Composites","volume":"36 1","pages":"205 - 216"},"PeriodicalIF":2.0,"publicationDate":"2021-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78702465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 6

Flame behaviour of magnesium and aluminium hydroxide-filled polymer composites used in power and telecom cables 电力和电信电缆用镁和氢氧化铝填充聚合物复合材料的燃烧性能

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-08-04 DOI: 10.1080/14658011.2021.1962617

Elena Roda, Franco Galletti, A. Truscello, C. Gambarotti

引用次数: 2

Effects of high functionality polyol on the structure and properties of rigid polyurethane foam 高官能团多元醇对硬质聚氨酯泡沫塑料结构和性能的影响

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-07-28 DOI: 10.1080/14658011.2021.1959132

Yumei Luo, Z. Ye, Jingcun Yan

引用次数: 2

Hybrid carbon filled thermoplastic composites: synergistic effect of synthetic graphite and graphene nanoplatelets on thermal and mechanical properties of polyamide 4.6 杂化碳填充热塑性复合材料:合成石墨和石墨烯纳米片对聚酰胺热力学性能的协同效应

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-07-26 DOI: 10.1080/14658011.2021.1955200

L. Altay, Elif Kizilkan, Y. Seki, A. Isbilir, M. Sarıkanat

引用次数: 0

Decomposition mechanism of boron phenolic resin composites under temperature gradient 温度梯度下硼酚醛树脂复合材料的分解机理

IF 2 4区材料科学

Plastics, Rubber and Composites Pub Date : 2021-07-21 DOI: 10.1080/14658011.2021.1955199

Ren Yilin, Zhixiong Huang, M. Shi, Z. Deng, Chuang Dong

引用次数: 5