p型导电聚合物/三聚铁(Fe-BTC)金属有机骨架的纳米复合材料:合成、表征及赝电容性能

IF 2.1 4区材料科学 Q3 MATERIALS SCIENCE, COMPOSITES

Plastics, Rubber and Composites Pub Date : 2021-08-17 DOI:10.1080/14658011.2021.1966247

H. Mostaanzadeh, M. Shahmohammadi, A. Ehsani, Mojtaba Moharramnejad, M. Babazadeh

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引用次数: 12

摘要

摘要本研究通过化学方法合成Fe(II)基MOF (Fe-BTC, BTC = 1,3,5-苯三甲酸酯)，然后在Fe-BTC存在下，通过POAP的电聚合合成聚氨基酚(POAP)/Fe-BTC杂化膜，作为电化学存储装置的活性电极。通过表面分析和电化学分析研究了Fe-BTC和POAP/ Fe-BTC复合膜的性能。得益于结构/组成优点的内在协同贡献，该电极在0.005 mA时提供了令人印象深刻的625 F g−1容量。本文介绍了一种合成简单、活性表面积高、在水溶液中稳定性好的新型电化学假电容器纳米复合材料。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Nanocomposite of p-type conductive polymer/iron (III) trimesic (Fe-BTC) metal–organic frameworks: synthesis, characterisation and pseudocapacitance performance

ABSTRACT In the present study, Fe(II)-based MOF (Fe-BTC, BTC = 1,3,5-benzentricarboxylate) was synthesised via a chemical method and then synthesised hybrid polyorthoaminophenol (POAP)/Fe-BTC films by electropolymerisation of POAP in the presence of Fe-BTC to serve as the active electrode for the electrochemical storage device. The characterisation of Fe-BTC and POAP/ Fe-BTC composite film has been investigated by surface and electrochemical analysis. Benefitting from the intrinsic synergetic contributions from structural/compositional merits, the electrode delivers an impressive capacity of 625 F g−1 at 0.005 mA. This article introduces new nanocomposite materials for electrochemical pseudocapacitor by taking advantage of simple synthesis, high active surface area and stability in an aqueous electrolyte.

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来源期刊

Plastics, Rubber and Composites 工程技术-材料科学：复合

CiteScore

4.10

自引率

0.00%

发文量

审稿时长

4 months

期刊介绍： Plastics, Rubber and Composites: Macromolecular Engineering provides an international forum for the publication of original, peer-reviewed research on the macromolecular engineering of polymeric and related materials and polymer matrix composites. Modern polymer processing is increasingly focused on macromolecular engineering: the manipulation of structure at the molecular scale to control properties and fitness for purpose of the final component. Intimately linked to this are the objectives of predicting properties in the context of an optimised design and of establishing robust processing routes and process control systems allowing the desired properties to be achieved reliably.