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Preparation and Characterization of PVA/ZrO2 Composite Membranes PVA/ZrO2复合膜的制备与表征
physica status solidi (b) Pub Date : 2023-08-01 DOI: 10.1002/pssb.202300164
Akanksha Mehto, V. R. Mehto, J. Chauhan
{"title":"Preparation and Characterization of PVA/ZrO2 Composite Membranes","authors":"Akanksha Mehto, V. R. Mehto, J. Chauhan","doi":"10.1002/pssb.202300164","DOIUrl":"https://doi.org/10.1002/pssb.202300164","url":null,"abstract":"","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76069554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nitride Semiconductors 氮化硅半导体
physica status solidi (b) Pub Date : 2023-08-01 DOI: 10.1002/pssb.202300286
M. Kneissl, J. Christen, A. Hoffmann, B. Monemar, T. Wernicke, Ulrich T. Schwarz, Å. Haglund, M. Meneghini
{"title":"Nitride Semiconductors","authors":"M. Kneissl, J. Christen, A. Hoffmann, B. Monemar, T. Wernicke, Ulrich T. Schwarz, Å. Haglund, M. Meneghini","doi":"10.1002/pssb.202300286","DOIUrl":"https://doi.org/10.1002/pssb.202300286","url":null,"abstract":"","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85372965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Demonstration of enhanced saturable absorption in upconverter integrated MoS2 heterostructure thin film using nanopulsed green laser 纳米脉冲绿色激光增强上转换器集成二硫化钼异质结构薄膜的饱和吸收
physica status solidi (b) Pub Date : 2023-08-01 DOI: 10.1002/pssb.202300216
M. Durairaj, T. Girisun
{"title":"Demonstration of enhanced saturable absorption in upconverter integrated MoS2 heterostructure thin film using nanopulsed green laser","authors":"M. Durairaj, T. Girisun","doi":"10.1002/pssb.202300216","DOIUrl":"https://doi.org/10.1002/pssb.202300216","url":null,"abstract":"Upconverter/MoS2 heterostructure thin films fabricated by hydrothermal technique are confirmed by X‐ray diffraction and Raman studies. Field‐emission scanning electron microscopy (FESEM) and high‐resolution transmission electron microscopy (HRTEM) reveal the nanobelt structured MoS2 mingled with trapezoid structure fluoride upconverters and sphere‐shaped oxide upconverters. The films exhibit green ( H 11 / 2 2   to   I 15 / 2 4 ) and red ( F 9 / 2 4   to   I 15 / 2 4 ) emission. The influence of upconverters on the nonlinear absorption of MoS2 is exploited by Z‐scan technique using nanopulsed laser. Estimated ground‐state absorption cross section is higher than the excited‐state absorption cross section of the samples and it confirms the occurrence of saturable absorption. CeO2:Yb,Er@MoS2 exhibits stronger saturable absorption due to synergetic effects like higher linear absorption coefficient at 532 nm, stronger green emission, and reduced size. Results pave way for the design of optical switches, Q‐switches, and mode lockers using upconverter integrated MoS2 thin films.","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79039503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Hydrogen Incorporation in Semiconductors 半导体中氢的掺入
physica status solidi (b) Pub Date : 2023-07-30 DOI: 10.1002/pssb.202300309
Norbert H. Nickel
{"title":"Hydrogen Incorporation in Semiconductors","authors":"Norbert H. Nickel","doi":"10.1002/pssb.202300309","DOIUrl":"https://doi.org/10.1002/pssb.202300309","url":null,"abstract":"In many materials, the presence of hydrogen influences the structural and electronic properties. An equilibrium model based on statistical mechanics is presented that describes the unintentional incorporation of hydrogen. As an example, the H concentration in four different semiconductors, namely, c‐Si, c‐Ge, ZnO, and β‐Ga2O3, is measured using H effusion. The measured H concentration ranges from 5.2×1016 to 1.1×1018  cm −3 . From the effusion data, the position of the H chemical potential and the H binding energies are derived.","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80427165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystal Structure, Magnetic, and Dielectric Properties of (x)CoFe2O4–(1−x)Ba0.8Sr0.2TiO3 Multiferroics (x)CoFe2O4 -(1−x)Ba0.8Sr0.2TiO3多铁质材料的晶体结构、磁性和介电性能
physica status solidi (b) Pub Date : 2023-07-29 DOI: 10.1002/pssb.202300215
Anant Shukla, Jyotirekha Mallick, Suman Kumari, Murli Kumar Manglam, P. Biswas, M. Kar
{"title":"Crystal Structure, Magnetic, and Dielectric Properties of (x)CoFe2O4–(1−x)Ba0.8Sr0.2TiO3 Multiferroics","authors":"Anant Shukla, Jyotirekha Mallick, Suman Kumari, Murli Kumar Manglam, P. Biswas, M. Kar","doi":"10.1002/pssb.202300215","DOIUrl":"https://doi.org/10.1002/pssb.202300215","url":null,"abstract":"The composites (x)CoFe2O4–(1−x)Ba0.8Sr0.2TiO3 are prepared by solid‐state reaction method using microwave double‐step sintering. Ba0.8Sr0.2TiO3 crystallizes to tetragonal crystal symmetry with P4mm space group and CoFe2O4 crystallizes to cubic crystal symmetry with Fd3¯m space group. Electron microscopy techniques are used to understand the microstructure, elemental composition, and morphology of the composites. The dielectric properties are measured in the 1 Hz–1 MHz frequency range and 40–400 °C temperature range. Composite with x = 0.1 (ε′ ≈ 170, tan δ = 0.08 at 1 kHz) and 0.2 (ε′ ≈ 390, tan δ = 0.07 at 1 kHz) has better dielectric properties than the parent Ba0.8Sr0.2TiO3 ferroelectric (ε′ ≈ 125, tan δ = 0.16 at 1 kHz) and CoFe2O4 ferrimagnetic phases (ε′ ≈ 375, tan δ = 0.72 at 1 kHz), respectively. Composite with 10% cobalt ferrite has the highest saturation polarization (2.1 μC cm−2), the highest remanent polarization (0.9 μC cm−2), and coercive field (23.9 kV cm−1) compared to ferroelectric phase followed by x = 0.2 composite (PS = 1.6 μC cm−2, Pr = 0.8 μC cm−2, and EC = 19.2 kV cm−1). Composite with x = 0.2 shows the highest magnetic coercive field of 1.96 kOe. Hence, this article advocates that 20% ferrite in the composites is the optimized composition for multiferroic applications. The present study will help to explore piezoelectric, magnetostrictive, and magnetoelectric properties of (x)CoFe2O4–(1−x)Ba0.8Sr0.2TiO3 for the technological application.","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76970671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First‐Principles Study of the Effects of La2+/3+ Doping and Oxygen Vacancies on TiO2 Magnetism, Carrier Lifetime, Activity, and Absorption Spectra La2+/3+掺杂和氧空位对TiO2磁性、载流子寿命、活性和吸收光谱影响的第一线原理研究
physica status solidi (b) Pub Date : 2023-07-28 DOI: 10.1002/pssb.202300276
Q. Hou, Mude Qi, Fang Wang, Riguleng Si
{"title":"First‐Principles Study of the Effects of La2+/3+ Doping and Oxygen Vacancies on TiO2 Magnetism, Carrier Lifetime, Activity, and Absorption Spectra","authors":"Q. Hou, Mude Qi, Fang Wang, Riguleng Si","doi":"10.1002/pssb.202300276","DOIUrl":"https://doi.org/10.1002/pssb.202300276","url":null,"abstract":"The effects of photocatalytic performance and magnetism between La doping and oxygen vacancy on rutile and anatase TiO2 systems are rarely compared. Oxygen vacancies in rutile and anatase TiO2 are also experimentally challenging to control accurately. Herein, the first‐principles generalized gradient approximation (GGA + U) method is used to investigate the effects of La2+/La3+doping and oxygen vacancy on TiO2 magnetism and photocatalytic performance. Results of magnetic calculation show that La2+ doping and oxygen vacancies are magnetic to TiO2, whether rutile or anatase, and that the bound magnetic polaron is the source of ferromagnetism in the anatase Ti15La2+O31 system. The anatase Ti30La22+O62 system can achieve room‐temperature ferromagnetism at Curie temperature. The calculation results of photocatalytic performance show that the anatase‐type Ti15La3+O31 system has minimum formation energy, the highest stability, maximum electric dipole moment, the strongest carrier activity, the strongest polarization ability, the slowest electron–hole recombination, the longest lifetime, and remarkable absorption spectrum redshift among the tested systems.","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72811811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystal Growth and Physical Properties Evolution in Co‐Doped NiTe2 System Co掺杂NiTe2体系的晶体生长和物理性质演变
physica status solidi (b) Pub Date : 2023-07-26 DOI: 10.1002/pssb.202300272
Wei-Bin Wu, Yuan-Qiao Chen, Li-Xin Gao, Luo-Zhao Zhang, Qiling Xiao, Junyi Ge
{"title":"Crystal Growth and Physical Properties Evolution in Co‐Doped NiTe2 System","authors":"Wei-Bin Wu, Yuan-Qiao Chen, Li-Xin Gao, Luo-Zhao Zhang, Qiling Xiao, Junyi Ge","doi":"10.1002/pssb.202300272","DOIUrl":"https://doi.org/10.1002/pssb.202300272","url":null,"abstract":"Transition metal tellurides have been widely studied for their diverse crystal structures and exotic physical properties such as large magnetoresistance, charge density waves, superconductivity, ferromagnetic and topological properties. NiTe2 has recently been found to be a Dirac semimetal, allowing it to achieve exotic properties by pressure and doping. A series of Ni1−xCoxTe2−δ single crystals are synthesized by the standard solid‐state reaction method. The energy‐dispersive X‐ray spectroscopy and X‐ray diffraction tests confirm Co is successfully doped into the crystal structure. The electrical transport measurements show typical metallic behaviors for all the samples. Magnetization measurements reveal that, in the doping range of x = 0.12–0.62, the samples exhibit a coexistence of antiferromagnetic and paramagnetic phases above the characteristic temperature Tt. By using the combined Curie–Weiss and spin‐wave model, the antiferromagnetic to ferromagnetic transition is found to occur as the temperature drops below Tt. The magnetic transition is attributed to the Te vacancies, which can be explained using the bound magnetic polaritons model. A magnetic phase diagram for Ni1−xCoxTe2−δ system is constructed.","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82480252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optoelectronic characterization of 2D graphene based heterostructures. Gr/MoS2 and Gr/WS2 二维石墨烯异质结构的光电特性。Gr/MoS2和Gr/WS2
physica status solidi (b) Pub Date : 2023-07-26 DOI: 10.1002/pssb.202300202
D. Arcos, Daniel Nuño, Muhammad Farooq Khan, J. Eom, L. Ametller, N. Ferrer‐Anglada
{"title":"Optoelectronic characterization of 2D graphene based heterostructures. Gr/MoS2 and Gr/WS2","authors":"D. Arcos, Daniel Nuño, Muhammad Farooq Khan, J. Eom, L. Ametller, N. Ferrer‐Anglada","doi":"10.1002/pssb.202300202","DOIUrl":"https://doi.org/10.1002/pssb.202300202","url":null,"abstract":"","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72949963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of Optical, Electrical, Magnetic, and Thermopower Properties of LaMnO3 by Potassium‐Doping 钾掺杂增强LaMnO3的光、电、磁和热电性能
physica status solidi (b) Pub Date : 2023-07-25 DOI: 10.1002/pssb.202300175
Hany F. Mohamed, Ahmed M. Ahmed, M. R. Ahmed, J A Paixão, S. A. Mohamed
{"title":"Enhancement of Optical, Electrical, Magnetic, and Thermopower Properties of LaMnO3 by Potassium‐Doping","authors":"Hany F. Mohamed, Ahmed M. Ahmed, M. R. Ahmed, J A Paixão, S. A. Mohamed","doi":"10.1002/pssb.202300175","DOIUrl":"https://doi.org/10.1002/pssb.202300175","url":null,"abstract":"Optical, magnetoresistance, and thermoelectric properties of La1−xKxMnO3 (x = 0.05, 0.15, and 0.25) compounds have been investigated. The crystallography demonstrates that the samples x = 0.05 and 0.15 are a single‐phase rhombohedral ( R3¯C$R overset{cdot}{3} C$ ) structure, while x = 0.25 is near to a single rhombohedral phase with a minor amount of Mn3O4 (with a ratio of ≈2%). The optical properties manifest that the reflectivity decreases slightly with increasing x‐doping, where the sample of x = 0.05 has the lowest reflection value, making it a promising material for photovoltaic applications. Electrical resistivity measurements show that the samples have a metal–semiconductor transition, and the transition temperature Tms decreases with the K content. The thermoelectric data show a remarkable coincidence behavior of the ρ–T relationship, which has a peak at a transition temperature (TS). Magnetic susceptibility data show that the samples undergo ferro‐paramagnetic transition at a certain temperature (Curie temperature).","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79334640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Visible Light Absorption Mechanism for Cubic Zirconia by Cobalt‐Ion Implantation 钴离子注入对立方氧化锆可见光吸收机理的研究
physica status solidi (b) Pub Date : 2023-07-21 DOI: 10.1002/pssb.202300227
Dongyu Cao, Xiaoqing Zhao, Miao Tang, W. Lu, Jingyan Weng, Xier Yu, Jie Yu
{"title":"The Visible Light Absorption Mechanism for Cubic Zirconia by Cobalt‐Ion Implantation","authors":"Dongyu Cao, Xiaoqing Zhao, Miao Tang, W. Lu, Jingyan Weng, Xier Yu, Jie Yu","doi":"10.1002/pssb.202300227","DOIUrl":"https://doi.org/10.1002/pssb.202300227","url":null,"abstract":"To investigate the effect of Co ions on the visible light absorption mechanism of cubic zirconia, Co ions are doped into colorless cubic zirconia with an ion implantation method and related heat treatment is performed. The elemental content, the role of Co, and the types of O elements in cubic ZrO2 are also analyzed utilizing the data from UV–visible spectroscopy, X‐ray diffraction, X‐ray photoelectron spectroscopy, and electron paramagnetic resonance spectroscopy. Based on the experimental results, the contribution of Co implantation on the visible light absorption of cubic zirconia is calculated from the electronic structure and related optical properties according to the density functional theory. The study results show that the colorless cubic ZrO2 is blue in color after ion implantation and then fades after 1400 °C heat treatment. Thus, the visible light absorption and the spectroscopic characteristics are related to the oxygen vacancy and the d‐orbital transition of Co ions.","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79422684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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