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Electron microscopy study of the shell geometry in bent and twisted GaAs-InP core-shell nanowires. 弯曲和扭曲GaAs-InP核壳纳米线壳几何结构的电镜研究。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-12 DOI: 10.1088/1361-6528/add26e
Spencer McDermott, Trevor R Smith, Ryan B Lewis
{"title":"Electron microscopy study of the shell geometry in bent and twisted GaAs-InP core-shell nanowires.","authors":"Spencer McDermott, Trevor R Smith, Ryan B Lewis","doi":"10.1088/1361-6528/add26e","DOIUrl":"https://doi.org/10.1088/1361-6528/add26e","url":null,"abstract":"<p><p>The spontaneous bending of core-shell nanowires through asymmetric shell deposition has implications for sensors, enabling both parallel fabrication and creating advantageous out-of-plane nanowire sensor geometries. This study investigates the impact of shell deposition geometry on the shell distribution and bending of GaAs-InP core-shell nanowires. Scanning and transmission electron microscopy methods are employed to quantify nanowire twisting and bending. A practical analytical electron tomography reconstruction technique is developed for characterizing the nanowire shell distribution, which utilizes the hexagonal nanowire shape to reconstruct two-dimensional cross-sections along the nanowire length. The study reveals that the orientation of the phosphorus beam with respect to the nanowire side facets induces significant variations in nanowire bending and twisting. The findings demonstrate the important role of crystallographic orientation during core-shell nanowire synthesis for engineering the shape of bent nanowire sensors.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 22","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143994883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improved energy storage performance of BOPP sandwich structured films by modulating the topological structure. 通过调制拓扑结构,提高了BOPP夹层结构薄膜的储能性能。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-12 DOI: 10.1088/1361-6528/add01d
Yi Gong, Xin Wei, Liangbao Liu, Haozhe Jia, Ruijiao Liu
{"title":"Improved energy storage performance of BOPP sandwich structured films by modulating the topological structure.","authors":"Yi Gong, Xin Wei, Liangbao Liu, Haozhe Jia, Ruijiao Liu","doi":"10.1088/1361-6528/add01d","DOIUrl":"https://doi.org/10.1088/1361-6528/add01d","url":null,"abstract":"<p><p>As the basis of the modern electronics industry, electronic functional materials provide powerful support for the development of science and technology. Biaxially oriented polypropylene (BOPP) dielectric films are widely used in capacitors for excellent dielectric advantages. In this paper, a topological-structured multilayer sandwich dielectric film was designed. BOPP was used as the outer layer, the blend of chlorinated polypropylene/polyvinylidene fluoride (CPP/PVDF) as the middle layer, and two-dimensional boron nitride nanosheets (BNNS) were added to the CPP/PVDF blend to enhance its breakdown strength. The sandwich-structured films had the highest discharged energy density of 5.17 J cm<sup>-3</sup>at 3 vol% addition of BNNS in the middle layer, and the charge-discharge efficiency maintained at a high level of 82.1%. The dielectric and energy storage properties of BOPP sandwich films were effectively improved by the introduction of large aspect ratio fillers.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 22","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143972034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bright quantum dot light sources using monolithic microlenses on gold back-reflectors. 明亮的量子点光源使用单片微透镜在黄金背反射器上。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-12 DOI: 10.1088/1361-6528/add350
Moritz Langer, Sai A Dhurjati, Yared G Zena, Ahmad Rahimi, Mandira Pal, Liesa Raith, Sandra Nestler, Riccardo Bassoli, Frank H P Fitzek, Oliver G Schmidt, Caspar Hopfmann
{"title":"Bright quantum dot light sources using monolithic microlenses on gold back-reflectors.","authors":"Moritz Langer, Sai A Dhurjati, Yared G Zena, Ahmad Rahimi, Mandira Pal, Liesa Raith, Sandra Nestler, Riccardo Bassoli, Frank H P Fitzek, Oliver G Schmidt, Caspar Hopfmann","doi":"10.1088/1361-6528/add350","DOIUrl":"https://doi.org/10.1088/1361-6528/add350","url":null,"abstract":"<p><p>We demonstrate a scalable method for fabricating bright GaAs quantum dot (QD) photon sources by embedding them into broadband monolithic AlGaAs microlens arrays on gold-coated GaAs substrates. Cylindrical photoresist templates (2-5 <i>µ</i>m diameter) are thermally reflowed and transferred into AlGaAs thin films using an optimized 3D reactive ion etching process. This yields large-area (2 mm × 4 mm), high-density (∼40×103 mm<sup>-2</sup>) microlens arrays of uniform shape. The brightest QD emissions are found in lenses with 2.7 <i>µ</i>m diameter and 1.35 <i>µ</i>m height. Finite-difference time-domain simulations of lens geometries reveal optimization potentials, including anti-reflection coatings. It is found that free-space and fiber-coupled extraction efficiencies can reach up to 62% and 37%, respectively. A statistical fabrication model, validated through photoluminescence spectroscopy, shows intensity enhancements up to × 200 in ca. 1 out of 200 lenses, aligning well with theoretical predictions. This approach highlights the promise of compact, efficient photon sources for future large-scale quantum network applications.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 22","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144029712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The convergence of nanomanufacturing and artificial intelligence: trends and future directions. 纳米制造与人工智能的融合:趋势与未来方向。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-12 DOI: 10.1088/1361-6528/add304
Vamsi K Yadavalli
{"title":"The convergence of nanomanufacturing and artificial intelligence: trends and future directions.","authors":"Vamsi K Yadavalli","doi":"10.1088/1361-6528/add304","DOIUrl":"https://doi.org/10.1088/1361-6528/add304","url":null,"abstract":"<p><p>The integration of nanoscale production processes with Artificial intelligence (AI) algorithms has the potential to open new frontiers in nanomanufacturing by accelerating development timelines, optimizing production, reducing costs, enhancing quality control, and improving sustainability. Such changes are already underway with digital and cyber-physical technologies becoming increasingly intertwined with 'smart' manufacturing and industrial processes today. With the nanomanufacturing sector focused on the scalable production of complex (nano)materials, (nano)devices, and biologics, AI and its sub-fields, including machine learning (ML), are positioned to be key enablers of efficiency and innovation. In this topical review, we briefly explore the current state-of-the-art of how AI and ML techniques can be employed within nanomanufacturing. We discuss from a birds-eye perspective, the impact of AI/ML on various stages of the production lifecycle, and examine future opportunities and challenges. Key areas include computational design and discovery, process optimization, predictive maintenance, and quality assurance/defect detection. Further, challenges in implementation, process complexity, and ethical and regulatory considerations are explored in light of the increasing reliance on data-driven approaches for manufacturing.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 22","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144004682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulation study of biosensor based on germanium-based dual-source dopingless line-tunneling FET. 基于锗基双源无掺杂线隧穿场效应晶体管的生物传感器仿真研究。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-12 DOI: 10.1088/1361-6528/add303
Junjie Huang, Hongxia Liu, Shupeng Chen, Shulong Wang, Chen Chong, Zhanpeng Yan, Xilong Zhou, Chang Liu
{"title":"Simulation study of biosensor based on germanium-based dual-source dopingless line-tunneling FET.","authors":"Junjie Huang, Hongxia Liu, Shupeng Chen, Shulong Wang, Chen Chong, Zhanpeng Yan, Xilong Zhou, Chang Liu","doi":"10.1088/1361-6528/add303","DOIUrl":"https://doi.org/10.1088/1361-6528/add303","url":null,"abstract":"<p><p>In this paper, we propose and investigate a biosensor based on germanium-based dual-source dopingless line-tunneling FET, which uses dielectric modulation to detect biomolecules. Dual source and line-tunneling structure improves open state current of the biosensor. The trench gate structure facilitates biomolecules filling and cavity etching while enhancing the tunneling area. The dopingless structure prevents the formation of mutant junctions and minimizes the effects of random dopant fluctuations. Simulation results show that the proposed biosensor demonstrates excellent performance, with a high switching ratio of 5.9 × 10<sup>11</sup>, a maximum threshold voltage sensitivity of 3.1 V, a maximum open state current sensitivity of 2.8 × 10<sup>6</sup>, a maximum average subthreshold swing (SS) sensitivity of 0.86, and the minimum average SS is 36.8 mv/decade. The proposed biosensor, exhibiting high sensitivity and low power consumption, holds significant application potential.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 22","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144010901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Composition-dependent properties of ultra-thin MoSixbased extreme ultraviolet pellicle. 超薄钼基极紫外光膜的成分依赖性质。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-09 DOI: 10.1088/1361-6528/add305
Munsu Choi, Juhee Hong
{"title":"Composition-dependent properties of ultra-thin MoSi<i><sub>x</sub></i>based extreme ultraviolet pellicle.","authors":"Munsu Choi, Juhee Hong","doi":"10.1088/1361-6528/add305","DOIUrl":"https://doi.org/10.1088/1361-6528/add305","url":null,"abstract":"<p><p>Extreme ultraviolet (EUV) pellicle is essential for protecting photomask from external contamination in EUV lithography (EUVL), a critical technology for nanometer-scale photolithography. However, achieving high optical transmittance, thermal stability, and mechanical robustness in pellicle for high-power EUVL processes remains challenging. This study fabricated EUV pellicles using multilayer MoSi<i><sub>x</sub></i>thin films with varying Mo-to-Si ratios and protective capping layers. As Mo content increased, mechanical and thermal properties improved, while optical transmittance decreased. MoSi<sub>2</sub>(<i>x</i>= 2) exhibited the highest tensile strength and >90% fabrication yield. In contrast, MoSi<sub>3</sub>.<sub>4</sub>(<i>x</i>= 3.4) showed enhanced optical properties, and MoSi<sub>2</sub>.<sub>3</sub>(<i>x</i>= 2.3) offered superior thermal performance. These results highlight the composition-dependent trade-offs in optimizing pellicle performance for EUVL applications. In contrast to previous studies, which investigated a single MoSi<sub>2</sub>composition, this study systematically explores a broad compositional range of MoSi<i><sub>x</sub></i>(<i>x</i>= 1.6-3.4). A distinct contribution of this work is the quantitative linkage established between mechanical performance, particularly ultimate tensile strength, and fabrication yield. The results reveal that no single composition optimizes all critical properties simultaneously, highlighting the necessity of trade-off-based material selection for application-specific requirements in EUVL. This study offers a guideline for optimizing EUV pellicle design, contributing to higher wafer throughput, improved equipment utilization, and reduced operational costs in high-volume lithography.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 22","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143972683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electronic mechanism behind the influence of intercalated heteroatom Sn on the slip energy barrier in layered WS2. 杂原子Sn对层状WS2中滑移能垒影响的电子机制。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-08 DOI: 10.1088/1361-6528/add166
Dulin Huang, Gonglei Shao, Xu Zhang, Zhen Zhou
{"title":"Electronic mechanism behind the influence of intercalated heteroatom Sn on the slip energy barrier in layered WS<sub>2</sub>.","authors":"Dulin Huang, Gonglei Shao, Xu Zhang, Zhen Zhou","doi":"10.1088/1361-6528/add166","DOIUrl":"https://doi.org/10.1088/1361-6528/add166","url":null,"abstract":"<p><p>Frictional losses often result in substantial economic costs, and the application of lubricants can markedly mitigate these losses. Recently, layered materials have garnered extensive research interest due to their exceptional lubricating properties. However, the exploration of sliding mechanisms associated with intercalated heteroatoms in layered materials remains a subject of considerable uncertainty. In this work, we employ density functional theory to unravel the friction modulation mechanism of Sn atoms intercalated in layered WS<sub>2</sub>. Our findings demonstrate that Sn intercalation significantly reduces the sliding energy barrier (down to 0.96 meV atom<sup>-1</sup>), while the friction force and shear strength are minimized to 0.0011 nN atom<sup>-1</sup>and 0.0008 GPa, respectively, outperforming conventional two-dimensional materials such as MoS<sub>2</sub>and graphene. Furthermore, Sn intercalation enhances interlayer electrostatic repulsion and suppresses dynamic charge density fluctuations. To quantitatively elucidate the energy barrier variation, we propose a novel metric-total charge density difference evolution (Δ<i>ρ</i><sub>2</sub>). This discovery provides theoretical guidance for designing ultra-low-friction lubricants and is expected to advance energy efficiency in industrial machinery.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 22","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144037199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CVD-grown SnS2active layers on AlGaN/GaN HEMT for arsenic (III) ions detection. cvd生长的sns2活性层在AlGaN/GaN HEMT上检测砷(III)离子。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-06 DOI: 10.1088/1361-6528/adcc37
Nipun Sharma, Adarsh Nigam, Jai Mishra, Ashok Kumar, Srinjoy Mitra, Ankur Gupta, Sudhiranjan Tripathy, Mahesh Kumar
{"title":"CVD-grown SnS<sub>2</sub>active layers on AlGaN/GaN HEMT for arsenic (III) ions detection.","authors":"Nipun Sharma, Adarsh Nigam, Jai Mishra, Ashok Kumar, Srinjoy Mitra, Ankur Gupta, Sudhiranjan Tripathy, Mahesh Kumar","doi":"10.1088/1361-6528/adcc37","DOIUrl":"https://doi.org/10.1088/1361-6528/adcc37","url":null,"abstract":"<p><p>The pervasive contamination of water sources by the toxic heavy metal arsenic presents a serious threat to human health and ecological systems. This raises the critical need for innovative detection platforms that can detect such contamination at low cost and as part of an onsite, distributed sensor network. In this context, we report an Arsenic (As<sup>3+</sup>) ion detection system that was fabricated using 2D SnS<sub>2</sub>functionalized AlGaN/GaN high electron mobility transistor (HEMT). SnS<sub>2</sub>layers were grown on the HEMT surface by chemical vapor deposition (CVD) which depicts hexagonal oriented nanosheets with crystal edges. The source and drain tri-metal contacts of Au/Cr/Al were fabricated by thermal evaporation using shadow mask. The sensor response was analyzed by measuring the variation in drain to source current of the device after introducing varied concentrations of As<sup>3+</sup>ions, ranging from 1 ppb to 10 ppm. The observed sensitivity of the device is 0.42<i>μ</i>A ppb<sup>-1</sup>, with a detection limit of 0.90 ppb, and a response time of 3.2 s. Further, real-time data analysis was performed by the integration of the developed sensor with a customized printed circuit board connected with an Arduino Nano 33 Bluetooth Low Energy (BLE) module for data transmission. The concept of growing the SnS<sub>2</sub>layer as a functionalizing layer by CVD results in quick response, good repeatability, and selectivity thereby eliminating the need for any additional reference electrode. Integration of the developed AlGaN/GaN HEMT sensor with Arduino Nano 33 BLE makes it an ideal candidate for portable heavy metal ion sensing device for onsite detection.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 20","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144019343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical synthesis and supercapacitor performance of manganese and cerium oxide-doped polyaniline composites. 锰铈掺杂聚苯胺复合材料的电化学合成及其超级电容器性能。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-05-06 DOI: 10.1088/1361-6528/add01e
Hilal Yildirim Kalyon, Yakup Fatih Karasan, Metin Gencten
{"title":"Electrochemical synthesis and supercapacitor performance of manganese and cerium oxide-doped polyaniline composites.","authors":"Hilal Yildirim Kalyon, Yakup Fatih Karasan, Metin Gencten","doi":"10.1088/1361-6528/add01e","DOIUrl":"https://doi.org/10.1088/1361-6528/add01e","url":null,"abstract":"<p><p>In this study, polyaniline-based conductive polymers doped with manganese oxide and cerium oxide were electrochemically synthesized for the first time. Unlike previous studies, manganese oxide and cerium oxide doped polyaniline synthesis was carried out in perchloric acid. The resulting composite materials were characterized using spectroscopic and microscopic techniques. The doped polyaniline composites were employed as electrode components in supercapacitors and analyzed using cyclic voltammetry and electrochemical impedance spectroscopy. Changes in capacitive behavior over cycling were examined via galvanostatic charge-discharge measurements. The areal capacitance of the cerium oxide and manganese oxide doped polyaniline electrodes, synthesized under optimal conditions, were measured as 950 mF cm<sup>-2</sup>and 660 mF cm<sup>-2</sup>, respectively, at a charge-discharge current of 10 mA cm<sup>-2</sup>.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 21","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144014050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bulk synthesis of mixed transition metal dichalcogenide and performance as working electrode in Li, Na, and K-ion half cells. 混合过渡金属二硫化物的体合成及其在Li, Na和k离子半电池中作为工作电极的性能。
IF 2.9 4区 材料科学
Nanotechnology Pub Date : 2025-04-30 DOI: 10.1088/1361-6528/adcf30
Arijit Roy, Gurpreet Singh
{"title":"Bulk synthesis of mixed transition metal dichalcogenide and performance as working electrode in Li, Na, and K-ion half cells.","authors":"Arijit Roy, Gurpreet Singh","doi":"10.1088/1361-6528/adcf30","DOIUrl":"https://doi.org/10.1088/1361-6528/adcf30","url":null,"abstract":"<p><p>Nanosheets of mixed or cation-substituted Transition metal dichalcogenide (TMD) are promising materials for a range of applications, including electrodes for electrochemical energy storage devices. Yet such materials are expensive to produce in large quantities (gram levels or higher). Here, we report on a two-step process, which involves precursor pyrolysis and sulfur annealing for the preparation of bulk powders of Mo<i><sub>x</sub></i>W<sub>1-<i>x</i></sub>S<sub>2</sub>. The structural and morphological properties of the synthesized cation-substituted TMD alloy are compared with high-purity commercially sourced MoWS<sub>2</sub>and MoS<sub>2</sub>/WS<sub>2</sub>hybrid specimens. Notably, the electrochemical characteristics of synthesized Mo<i><sub>x</sub></i>W<sub>1-<i>x</i></sub>S<sub>2</sub>exhibit exceptional first-cycle specific charge capacities for lithium-ion (638 mAh g<sup>-1</sup>), sodium-ion (423 mAh g<sup>-1</sup>), and potassium-ion (328 mAh g<sup>-1</sup>) half-cells. All the cells showed capacity decay in longer-term cycling tests, arising from volume changes in TMD conversion-type electrodes. To mitigate the capacity decay, a voltage cut-off method is implemented, which minimizes irreversibility and structural distortion of TMD during cycling, even at higher cycling currents with nearly 100% average cycling efficiency. The findings of this study demonstrate a proficient and scalable synthesis methodology poised to be utilized across an array of layered TMD materials, with benefits to both industry and fundamental research into alkali-metal-ion energy storage.</p>","PeriodicalId":19035,"journal":{"name":"Nanotechnology","volume":"36 21","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144003343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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