{"title":"Pd Nanoparticles Immobilized on Pyridinic N-Rich Carbon Nanosheets for Promoting Suzuki Cross-Coupling Reactions.","authors":"Shihao Cui, Dejian Xu, Zhiyuan Wang, Libo Wang, Yikun Zhao, Wei Deng, Qingshan Zhao, Mingbo Wu","doi":"10.3390/nano14211690","DOIUrl":"10.3390/nano14211690","url":null,"abstract":"<p><p>Palladium (Pd) catalysts play a crucial role in facilitating Suzuki cross-coupling reactions for the synthesis of valuable organic compounds. However, conventional heterogeneous Pd catalysts often encounter challenges such as leaching and deactivation during reactions, leading to reduced catalytic efficiency. In this study, we employed an innovative intercalation templating strategy to prepare two-dimensional carbon nanosheets with high nitrogen doping derived from petroleum asphalt, which were utilized as a versatile support for immobilizing Pd nanoparticles (Pd/N-CNS) in efficient Suzuki cross-coupling reactions. The results indicate that the anchoring effect of high-pyridinic N species on the two-dimensional carbon nanosheets enhances interactions between Pd and the support, effectively improving both the dispersibility and stability of the Pd nanoparticles. Notably, the Pd/N-CNS catalyst achieved an overall turnover frequency (TOF) of 2390 h<sup>-1</sup> for the Suzuki cross-coupling reaction under mild conditions, representing approximately a nine-fold increase in activity compared to commercial Pd/C catalysts. Furthermore, this catalyst maintained an overall TOF of 2294 h<sup>-1</sup> even after five reaction cycles, demonstrating excellent stability. Theoretical calculations corroborate these observed enhancements in catalytic performance by attributing them to improved electron transfer from Pd to the support facilitated by abundant pyridinic N species. This work provides valuable insights into feasible strategies for developing efficient catalysts aimed at sustainable production of biaromatic compounds.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 21","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548024/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142605559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-22DOI: 10.3390/nano14211687
Jernej Ekar, Sabina Markelj, Miran Mozetič, Rok Zaplotnik, Janez Kovač
{"title":"Effects of Hydrogen Dissociation During Gas Flooding on Formation of Metal Hydride Cluster Ions in Secondary Ion Mass Spectrometry.","authors":"Jernej Ekar, Sabina Markelj, Miran Mozetič, Rok Zaplotnik, Janez Kovač","doi":"10.3390/nano14211687","DOIUrl":"10.3390/nano14211687","url":null,"abstract":"<p><p>The application of hydrogen flooding was recently shown to be a simple and effective approach for improved layer differentiation and interface determination during secondary ion mass spectrometry (SIMS) depth profiling of thin films, as well as an approach with potential in the field of quantitative SIMS analyses. To study the effects of hydrogen further, flooding of H<sub>2</sub> molecules was compared to reactions with atomic H on samples of pure metals and their alloys. H<sub>2</sub> was introduced into the analytical chamber via a capillary, which was heated to approximately 2200 K to achieve dissociation. Dissociation of H<sub>2</sub> up to 30% resulted in a significant increase in the intensity of the metal hydride cluster secondary ions originating from the metallic samples. Comparison of the time scales of possible processes provided insight into the mechanism of hydride cluster secondary ion formation. Cluster ions presumably form during the recombination of the atoms and molecules from the sample and atoms and molecules adsorbed from the gas. This process occurs on the surface or just above it during the sputtering process. These findings coincide with those of previous mechanistic and computational studies.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 21","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11547559/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142605128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-22DOI: 10.3390/nano14211689
Thi Quynh Xuan Le, Thanh Binh Pham, Van Chuc Nguyen, Minh Thu Nguyen, Thu Loan Nguyen, Nguyen Thuan Dao
{"title":"A Novel Method for Rapid and High-Performance SERS Substrate Fabrication by Combination of Cold Plasma and Laser Treatment.","authors":"Thi Quynh Xuan Le, Thanh Binh Pham, Van Chuc Nguyen, Minh Thu Nguyen, Thu Loan Nguyen, Nguyen Thuan Dao","doi":"10.3390/nano14211689","DOIUrl":"10.3390/nano14211689","url":null,"abstract":"<p><p>In this paper, we report a simple yet efficient method for rapid and high-performance SERS substrate fabrication by a combination of cold plasma and laser treatment. Our analysis reveals that cold plasma pre-treatment significantly reduced surface roughness, transforming 200 nm spikes into an almost perfectly uniform surface, while enhancing the substrate's surface energy by lowering the water contact angle from 59° to 0°, all achieved within just 30 s of 0.9-mW plasma treatment, while 15-min green-laser treatment facilitated more uniform deposition of AuNPs across the entire treated area, effectively creating the SERS substrates. The combined treatments result in enhancement of the Raman intensity (11 times) and consistency over the whole area of the SERS substrates, and their reusability (up to 10 times). The fabricated SERS substrates exhibit a significant enhancement factor of approximately 3 × 10⁸ with R6G, allowing detection down to a concentration of 10<sup>-12</sup> M. We demonstrate the application of these SERS substrates by detecting amoxicillin-an antibiotic used worldwide to treat a diversity of bacterial infections-in a dynamic expanded linear range of seven orders (from 10<sup>-3</sup> to 10<sup>-9</sup> M) with high reliability (R<sup>2</sup> = 0.98), and a detection limit of 9 × 10<sup>-10</sup> M. Our approach to high-performance SERS substrate fabrication holds potential for further expansion to other metallic NPs like Ag, or magnetic NPs (Fe<sub>3</sub>O<sub>4</sub>).</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 21","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11547355/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142605064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-22DOI: 10.3390/nano14211691
Elena Rozas, Yannik Brune, Ken West, Kirk W Baldwin, Loren N Pfeiffer, Jonathan Beaumariage, Hassan Alnatah, David W Snoke, Marc Aßmann
{"title":"Targeted Polariton Flow Through Tailored Photonic Defects.","authors":"Elena Rozas, Yannik Brune, Ken West, Kirk W Baldwin, Loren N Pfeiffer, Jonathan Beaumariage, Hassan Alnatah, David W Snoke, Marc Aßmann","doi":"10.3390/nano14211691","DOIUrl":"10.3390/nano14211691","url":null,"abstract":"<p><p>In non-Hermitian open quantum systems, such as polariton condensates, the local tailoring of gains and losses opens up an interesting possibility to realize functional optical elements. Here, we demonstrate that deliberately introducing losses via a photonic defect, realized by reducing the quality factor of a DBR mirror locally within an ultrahigh-quality microcavity, may be utilized to create directed polariton currents towards the defect. We discuss the role of polariton-polariton interactions in the process and how to tailor the effective decay time of a polariton condensate by coupling it to the defect. Our results highlight the far-reaching potential of non-Hermitian physics in polaritonics.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 21","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11547211/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142605696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-22DOI: 10.3390/nano14211688
Guohai Chen, Dai-Ming Tang
{"title":"Machine Learning as a \"Catalyst\" for Advancements in Carbon Nanotube Research.","authors":"Guohai Chen, Dai-Ming Tang","doi":"10.3390/nano14211688","DOIUrl":"10.3390/nano14211688","url":null,"abstract":"<p><p>The synthesis, characterization, and application of carbon nanotubes (CNTs) have long posed significant challenges due to the inherent multiple complexity nature involved in their production, processing, and analysis. Recent advancements in machine learning (ML) have provided researchers with novel and powerful tools to address these challenges. This review explores the role of ML in the field of CNT research, focusing on how ML has enhanced CNT research by (1) revolutionizing CNT synthesis through the optimization of complex multivariable systems, enabling autonomous synthesis systems, and reducing reliance on conventional trial-and-error approaches; (2) improving the accuracy and efficiency of CNT characterizations; and (3) accelerating the development of CNT applications across several fields such as electronics, composites, and biomedical fields. This review concludes by offering perspectives on the future potential of integrating ML further into CNT research, highlighting its role in driving the field forward.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 21","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11547478/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142605535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-21DOI: 10.3390/nano14201683
Tao Chen, Hongyan Li, Jiaziyi Wang, Xilai Jia
{"title":"Flexible All-Carbon Nanoarchitecture Built from In Situ Formation of Nanoporous Graphene Within \"Skeletal-Capillary\" Carbon Nanotube Networks for Supercapacitors.","authors":"Tao Chen, Hongyan Li, Jiaziyi Wang, Xilai Jia","doi":"10.3390/nano14201683","DOIUrl":"https://doi.org/10.3390/nano14201683","url":null,"abstract":"<p><p>It is difficult for carbonaceous materials to combine a large specific surface area with flexibility. Here, a flexible all-carbon nanoarchitecture based on the in situ growth of nanoporous graphene within \"skeletal-capillary\" carbon nanotube (CNT) networks has been achieved by a chemical vapor deposition (CVD) process. Multi-path long-range conductivity is established, and the porous graphene provides a large specific surface area for charge storage. The flexibility of the films allows them to be directly used as binder-free electrodes for supercapacitors. Since the polymeric binders are saved, the supercapacitors exhibit a higher overall storage density.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 20","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11510038/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142504487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-21DOI: 10.3390/nano14201685
Jungwook Choi, Byung Hyo Kim
{"title":"Ligands of Nanoparticles and Their Influence on the Morphologies of Nanoparticle-Based Films.","authors":"Jungwook Choi, Byung Hyo Kim","doi":"10.3390/nano14201685","DOIUrl":"https://doi.org/10.3390/nano14201685","url":null,"abstract":"<p><p>Nanoparticle-based thin films are increasingly being used in various applications. One of the key factors that determines the properties and performances of these films is the type of ligands attached to the nanoparticle surfaces. While long-chain surfactants, such as oleic acid, are commonly employed to stabilize nanoparticles and ensure high monodispersity, these ligands often hinder charge transport due to their insulating nature. Although thermal annealing can remove the long-chain ligands, the removal process often introduces defects such as cracks and voids. In contrast, the use of short-chain organic or inorganic ligands can minimize interparticle distance, improving film conductivity, though challenges such as incomplete ligand exchange and residual barriers remain. Polymeric ligands, especially block copolymers, can also be employed to create films with tailored porosity. This review discusses the effects of various ligand types on the morphology and performance of nanoparticle-based films, highlighting the trade-offs between conductivity, structural integrity, and functionality.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 20","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11510505/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142504497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-21DOI: 10.3390/nano14201684
Alexander Arkhipov, Karina Trofimovich, Nikolay Arkhipov, Pavel Gabdullin
{"title":"Phonon Drag Contribution to Thermopower for a Heated Metal Nanoisland on a Semiconductor Substrate.","authors":"Alexander Arkhipov, Karina Trofimovich, Nikolay Arkhipov, Pavel Gabdullin","doi":"10.3390/nano14201684","DOIUrl":"https://doi.org/10.3390/nano14201684","url":null,"abstract":"<p><p>The possible contribution of phonon drag effect to the thermoelectrically sustained potential of a heated nanoisland on a semiconductor surface was estimated in a first principal consideration. We regarded electrons and phonons as interacting particles, and the interaction cross-section was derived from the basic theory of semiconductors. The solution of the equation of motion for average electrons under the simultaneous action of phonon drag and electric field gave the distributions of phonon flux, density of charge carriers and electric potential. Dimensional suppression of thermal conductance and electron-phonon interaction were accounted for but found to be less effective than expected. The developed model predicts the formation of a layer with a high density of charge carriers that is practically independent of the concentration of dopant ions. This layer can effectively intercept the phonon flow propagating from the heated nanoisland. The resulting thermoEMF can have sufficient magnitudes to explain the low-voltage electron emission capability of nanoisland films of metals and sp<sup>2</sup>-bonded carbon, previously studied by our group. The phenomenon predicted by the model can be used in thermoelectric converters with untypical parameters or in systems for local cooling.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 20","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11509935/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142504509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-21DOI: 10.3390/nano14201686
So-Won Kim, Jae-Hoon Yoo, Won-Ji Park, Chan-Hee Lee, Joung-Ho Lee, Jong-Hwan Kim, Sae-Hoon Uhm, Hee-Chul Lee
{"title":"Enhancing Charge Trapping Performance of Hafnia Thin Films Using Sequential Plasma Atomic Layer Deposition.","authors":"So-Won Kim, Jae-Hoon Yoo, Won-Ji Park, Chan-Hee Lee, Joung-Ho Lee, Jong-Hwan Kim, Sae-Hoon Uhm, Hee-Chul Lee","doi":"10.3390/nano14201686","DOIUrl":"https://doi.org/10.3390/nano14201686","url":null,"abstract":"<p><p>We aimed to fabricate reliable memory devices using HfO<sub>2</sub>, which is gaining attention as a charge-trapping layer material for next-generation NAND flash memory. To this end, a new atomic layer deposition process using sequential remote plasma (RP) and direct plasma (DP) was designed to create charge-trapping memory devices. Subsequently, the operational characteristics of the devices were analyzed based on the thickness ratio of thin films deposited using the sequential RP and DP processes. As the thickness of the initially RP-deposited thin film increased, the memory window and retention also increased, while the interface defect density and leakage current decreased. When the thickness of the RP-deposited thin film was 7 nm, a maximum memory window of 10.1 V was achieved at an operating voltage of ±10 V, and the interface trap density (D<sub>it</sub>) reached a minimum value of 1.0 × 10<sup>12</sup> eV<sup>-1</sup>cm<sup>-2</sup>. Once the RP-deposited thin film reaches a certain thickness, the ion bombardment effect from DP on the substrate is expected to decrease, improving the Si/SiO<sub>2</sub>/HfO<sub>2</sub> interface and thereby enhancing device endurance and reliability. This study confirmed that the proposed sequential RP and DP deposition processes could resolve issues related to unstable interface layers, improve device performance, and enhance process throughput.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 20","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11509989/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142504484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
NanomaterialsPub Date : 2024-10-20DOI: 10.3390/nano14201682
Zain Ul Abedin, Ajaz Ul Haq, Rizwan Ahmed, Tahani A Alrebdi, Ali M Alshehri, Muhammad Irfan, Haroon Asghar
{"title":"On the Synthesis of Graphene Oxide/Titanium Dioxide (GO/TiO<sub>2</sub>) Nanorods and Their Application as Saturable Absorbers for Passive Q-Switched Fiber Lasers.","authors":"Zain Ul Abedin, Ajaz Ul Haq, Rizwan Ahmed, Tahani A Alrebdi, Ali M Alshehri, Muhammad Irfan, Haroon Asghar","doi":"10.3390/nano14201682","DOIUrl":"https://doi.org/10.3390/nano14201682","url":null,"abstract":"<p><p>We report passively Q-switched pulse operation through an erbium-doped fiber laser (EDFL) utilizing graphene oxide/titania (GO/TiO<sub>2</sub>) nanorods as a saturable absorber. The GO/TiO<sub>2</sub> nanorods were fabricated using a Sol-gel-assisted hydrothermal method. The optical and physical characterization of the GO/TiO<sub>2</sub> was then characterized using a field-emission-scanning electron microscope (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), and diffuses reflectance spectroscopy (DRS). To investigate the performance of the Q-switched EDFL based on the GO/TiO<sub>2</sub> SA, the prepared nanorods were mechanically deposited on the fiber ferrule employing adhesion effects of in-dex-matching gel. This integration of the nanorod SA resulted in a self-starting Q-switching opera-tion initiated at a pump power of 17.5 mW and sustained up to 306.9 mW. When the pump range was tuned from 17.5 to 306.9 mW, the emission wavelength varied from 1564.2 to 1562.9 nm, pulse repetition rates increased from 13.87 kHz to 83.33 kHz, and pulse width decreased from 30.27 µs to 3.75 µs. Moreover, at the maximum pump power of 306.9 mW, the laser exhibited an average output power of 0.74 mW, a peak power of 1.54 mW, and a pulse energy of 8.88 nJ. Furthermore, this study investigates the GO/TiO<sub>2</sub> damage threshold and prolonged stability of the proposed EDFL system.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"14 20","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11510206/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142504505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}