Nature reviews. Chemistry最新文献_第4页

The man of MOFs and more MOFs和更多的人

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-09 DOI: 10.1038/s41570-025-00691-w

Stephanie Greed, Omar M. Yaghi

引用次数: 0

Free water releases hydrogen 游离水释放氢

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-02-05 DOI: 10.1038/s41570-025-00693-8

Eleanor Stewart-Jones, James Sappington

引用次数: 0

Taking dynamic covalent chemistry out of the lab and into reprocessable industrial thermosets 将动态共价化学带出实验室，进入可再处理的工业热固性

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-31 DOI: 10.1038/s41570-025-00686-7

Stephan Maes, Nezha Badi, Johan M. Winne, Filip E. Du Prez

{"title":"Taking dynamic covalent chemistry out of the lab and into reprocessable industrial thermosets","authors":"Stephan Maes, Nezha Badi, Johan M. Winne, Filip E. Du Prez","doi":"10.1038/s41570-025-00686-7","DOIUrl":"10.1038/s41570-025-00686-7","url":null,"abstract":"Dynamic covalent chemistry (DCC) allows the development of thermally (re)processable and recyclable polymer networks, which is a highly attractive feature for new generations of thermoset materials. However, despite a surge in academic interest wherein soon almost any imaginable DCC platform may have been applied in a thermoset formulation, dynamic or reversible covalent polymer networks have so far found only few industrial applications. This Review provides a perspective on the main strategies for the application of DCC in the design and development of bulk thermoset materials, and it presents some of the key hurdles for their industrial implementation. The polymer design strategies and associated chemistries are viewed from the perspective of how ‘close to market’ their development pathway is, thus providing a roadmap to achieve high-volume breakthrough applications. Ever-increasing society needs have made thermosets crucial, but their recycling poses considerable challenges. Dynamic covalent chemistry (DCC) offers a solution, and industry is ready for its implementation. On the basis of market proximity, three DCC-based strategies are proposed for stimulating industrial uptake of DCC-thermosets.","PeriodicalId":18849,"journal":{"name":"Nature reviews. Chemistry","volume":"9 3","pages":"144-158"},"PeriodicalIF":38.1,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143072909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Return to Flatland 回到平地。

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-31 DOI: 10.1038/s41570-025-00688-5

Ian Churcher, Stuart Newbold, Christopher W. Murray

引用次数: 0

Publisher Correction: Performance metrics and mechanistic considerations for the development of 3D batteries 发行商更正：3D电池开发的性能指标和机制考虑。

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-20 DOI: 10.1038/s41570-025-00689-4

Kelly Nieto, Daniel S. Windsor, Bairav S. Vishnugopi, Partha P. Mukherjee, Amy L. Prieto

引用次数: 0

Catechol redox maintenance in mussel adhesion 贻贝粘附过程中的儿茶酚氧化还原维持作用

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-15 DOI: 10.1038/s41570-024-00673-4

Stephanie X. Wang, J. Herbert Waite

{"title":"Catechol redox maintenance in mussel adhesion","authors":"Stephanie X. Wang, J. Herbert Waite","doi":"10.1038/s41570-024-00673-4","DOIUrl":"10.1038/s41570-024-00673-4","url":null,"abstract":"Catechol-functionalized proteins in mussel holdfasts are essential for underwater adhesion and cohesion and have inspired countless synthetic polymeric materials and devices. However, as catechols are prone to oxidation, long-term performance and stability of these inventions awaits effective antioxidation strategies. In mussels, catechol-mediated interactions are stabilized by ‘built-in’ homeostatic redox reservoirs that restore catechols oxidized to quinones. Mussel byssus has a typical ‘core-shell’ architecture in which the core is a degradable fibrous block copolymer consisting of collagen and fibroin coated by robust protein networks stabilized by bis-catecholato-metal and tris-catecholato-metal ion complexes. The coating is well-adapted to protect the core against abrasion, hydrolysis and microbial attack, but it is not impervious to oxidative damage, which, during function, is promptly repaired by redox poise via coacervated catechol-rich and thiol-rich reducing interlayers and inclusions. However, when the e− and H+ equivalents from these reducing reservoirs are depleted, coating damage accumulates, leading to exposure of the vulnerable core to environmental attack. Heeding and translating these strategies is essential for deploying catechols with longer service lifetimes and designing more sustainable next-generation polymeric adhesives. Mussel reliance on catechol-functionalized proteins for adhesion in wet environments comes with advantages and risks. Catechol interactive versatility is an obvious benefit; the greatest risk is catechol oxidation, which is mitigated by an intrinsic redox homeostasis that repairs oxidative damage.","PeriodicalId":18849,"journal":{"name":"Nature reviews. Chemistry","volume":"9 3","pages":"159-172"},"PeriodicalIF":38.1,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142984275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Reflections on the pigments of life 对生活色彩的反思。

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-15 DOI: 10.1038/s41570-025-00684-9

Alexander Rosu-Finsen, David Dolphin

引用次数: 0

Practical access to piperidines 实际使用哌啶

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-14 DOI: 10.1038/s41570-025-00685-8

Lucy A. Harwood, Victoria Barros Metlova

引用次数: 0

Biological and environmental degradation of two-dimensional materials 二维材料的生物和环境降解

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-10 DOI: 10.1038/s41570-024-00680-5

Sandra Vranic, Rajendra Kurapati, Kostas Kostarelos, Alberto Bianco

{"title":"Biological and environmental degradation of two-dimensional materials","authors":"Sandra Vranic, Rajendra Kurapati, Kostas Kostarelos, Alberto Bianco","doi":"10.1038/s41570-024-00680-5","DOIUrl":"10.1038/s41570-024-00680-5","url":null,"abstract":"As the use of two-dimensional materials continues to grow, so too does the need to understand the environmental and biological impact of such materials. Degradation is a critical step in the life cycle of any material, but the majority of such knowledge is obtained from test tube and in vitro studies. Therefore, there remains a gap in understanding the degradability of two-dimensional materials in complex systems (in vivo) and in different ambient environments. In this Review, we highlight the need for more data-driven studies on the degradation of two-dimensional materials, including their kinetics, by-products, stability and possible downstream effects. Although challenging, building an understanding of the degradation profiles of different advanced materials in various environments at the chemical and molecular level is essential. As their applications grow, it is vital to understand how 2D materials degrade in the environment and biological systems. Current knowledge remains limited, and the available methodologies are specific and challenging to carry out. This article aims to identify opportunities for us to better understand the end-of-life characteristics of advanced materials. ","PeriodicalId":18849,"journal":{"name":"Nature reviews. Chemistry","volume":"9 3","pages":"173-184"},"PeriodicalIF":38.1,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142939522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Giving actinide chemistry a new start 给锕系化学一个新的开始

IF 38.1 1区化学

Nature reviews. Chemistry Pub Date : 2025-01-09 DOI: 10.1038/s41570-024-00682-3

Leslie G. Castro, Nolwenn Mahieu

引用次数: 0