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Recent advances in DNA nanomaterials for cancer diagnosis and treatment DNA纳米材料在癌症诊断和治疗中的最新进展
3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0135
Longjie Li, Zhen Wang, Xuehao Zhang, Yukai Deng, Yaoqin Mu, Jingrou Li, Li-mei Wang, Hong-xun Wang, Junlin Zhang, Hengyi Gao, Yajie Mao
{"title":"Recent advances in DNA nanomaterials for cancer diagnosis and treatment","authors":"Longjie Li, Zhen Wang, Xuehao Zhang, Yukai Deng, Yaoqin Mu, Jingrou Li, Li-mei Wang, Hong-xun Wang, Junlin Zhang, Hengyi Gao, Yajie Mao","doi":"10.1515/ntrev-2023-0135","DOIUrl":"https://doi.org/10.1515/ntrev-2023-0135","url":null,"abstract":"Abstract The elucidation of the structural characteristics of deoxyribonucleic acid (DNA) by Watson and Crick, the advent of polymerase chain reaction technology, and the development of primer-synthesis methods, enable DNA to be replicated and transformed in an increasingly easy manner, such that it is among the most directed and evolving nanomaterials in molecular biology. Traditional cancer diagnosis methods are somewhat limited and are unable to meet existing needs; consequently, DNA nanostructures with wide ranging properties are receiving increasingly more attention because a number of DNA materials have been shown to exhibit diagnostic properties. Some DNA materials can functionally alter the biological behavior of cells, such as cell migration, cell proliferation, cell differentiation, autophagy, and anti-inflammatory effects. Some single-stranded DNA or ribonucleic acid with secondary structure through self-pairing, called aptamer, systematic evolution of ligands by exponential enrichment (SELEX), have targeting capabilities and can be applied to tumor targeted diagnosis and therapy. Several DNA nanomaterials with three-dimensional nanostructures and stable structures are being investigated as drug carrier systems to act on a variety of antitumor drugs or gene therapy agents. This article reviews the use of functionalized DNA nanostructures in cancer diagnosis and treatment applications. Various biosensors and carriers based on DNA nanostructures are introduced and chemical reactions related to the preparation of the carrier and the signal transduction mechanism of the sensor are discussed. Efficient carrier/biosensor platforms based on various structural developments and current DNA nanomaterial developments are also presented.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135009503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced visible-light-driven photocatalytic degradation of azo dyes by heteroatom-doped nickel tungstate nanoparticles 杂原子掺杂钨酸镍纳米颗粒增强可见光驱动光催化降解偶氮染料
3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0143
Fahad A. Alharthi, Mohammed Abdullah Albaeejan, Alanoud Abdullah Alshayiqi, Hend Khalid Aldubeikl, Imran Hasan
{"title":"Enhanced visible-light-driven photocatalytic degradation of azo dyes by heteroatom-doped nickel tungstate nanoparticles","authors":"Fahad A. Alharthi, Mohammed Abdullah Albaeejan, Alanoud Abdullah Alshayiqi, Hend Khalid Aldubeikl, Imran Hasan","doi":"10.1515/ntrev-2023-0143","DOIUrl":"https://doi.org/10.1515/ntrev-2023-0143","url":null,"abstract":"Abstract In this study, we conducted the hydrothermal synthesis of cobalt (Co)–doped NiWO 4 , resulting in the formation of Co–NiWO 4 nanoparticles (NPs), followed by calcination at 550℃ for 12 h. Comprehensive analyses were performed to characterize the composition, structure, and morphology of the synthesized material. X-ray diffraction results confirmed the successful inclusion of Co in the NiWO 4 lattice, with the presence of characteristic peaks of CoWO 4 . The crystallite size, determined using the Scherrer equation, was measured to be 22 nm. Using UV-Vis spectroscopy and Tauc’s equation, we calculated the band gap energy ( E g ) to be 3.75 eV for NiWO 4 and 1.75 eV for Co–NiWO 4 . The potential application of the synthesized material as a photocatalyst was investigated for the degradation of the diazo dye Congo red (CR). Under optimized reaction conditions, Co–NiWO 4 NPs demonstrated outstanding efficiency, degrading a total of 95% of CR. The degradation kinetics were well-described by the Langmuir–Hinshelwood (L–H) kinetic model, indicating that photoabsorption played a crucial role in the rate-controlling step. These encouraging results suggest that Co–NiWO 4 NPs hold promise as a viable option for addressing other pollutants in various applications.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":"41 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135101826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanocoatings for ballistic applications: A review 用于弹道的纳米涂层:综述
3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0574
Anand Biradar, S. Arulvel, Jayakrishna Kandasamy, Mohamed Thariq Hameed Sultan, Farah Syazwani Shahar, Muhammad Imran Najeeb, Milan Gaff, David Hui
{"title":"Nanocoatings for ballistic applications: A review","authors":"Anand Biradar, S. Arulvel, Jayakrishna Kandasamy, Mohamed Thariq Hameed Sultan, Farah Syazwani Shahar, Muhammad Imran Najeeb, Milan Gaff, David Hui","doi":"10.1515/ntrev-2023-0574","DOIUrl":"https://doi.org/10.1515/ntrev-2023-0574","url":null,"abstract":"Abstract The manufacturing of ballistic impact-resistant (BIR) body armours has evolved over the years with the aim of reducing their weight and enhancing their energy-absorbing capacity upon ballistic impacts. The incorporation of nanoparticles into advanced BIR body armour systems is considered one of the promising techniques. The methods employed in incorporating various nanoparticles in the manufacturing of textile-based body armour systems face a research gap in the optimisation of the associated parameters. This article discusses the mechanism involved in the energy absorption of composites and nanocomposites upon ballistic impact. The current review article highlights the chemical, physical, and mechanical properties of various nanoparticles incorporated into BIR body armour systems. BIR nanocomposites consisting of carbon nanotubes, graphene nanoplatelets, nano-silica, nanoclays, nano-alumina, etc ., have been discussed herein. In addition, the significance of various techniques for the dispersion of these nanoparticles was also highlighted. Various methods, such as sol–gel, PVD, CVD, thermal spray, and electroless methods for coating the nanoparticles on the surface of the fibre/fabric were also discussed.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":"8 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136048769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploration of generalized two-phase free convection magnetohydrodynamic flow of dusty tetra-hybrid Casson nanofluid between parallel microplates 含尘四杂卡森纳米流体在平行微板间广义两相自由对流磁流体力学流动的探索
3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0102
Dolat Khan, Mostafa A. Hussien, Awatif M. A. Elsiddieg, Showkat Ahmad Lone, Ahmed M. Hassan
{"title":"Exploration of generalized two-phase free convection magnetohydrodynamic flow of dusty tetra-hybrid Casson nanofluid between parallel microplates","authors":"Dolat Khan, Mostafa A. Hussien, Awatif M. A. Elsiddieg, Showkat Ahmad Lone, Ahmed M. Hassan","doi":"10.1515/ntrev-2023-0102","DOIUrl":"https://doi.org/10.1515/ntrev-2023-0102","url":null,"abstract":"Abstract Dusty Casson fluids and tetra-hybrid nanofluids are complex phenomena that find their extensive uses in engineering and industrial applications. For instance, dusty fluids are used in gas-freezing systems and nuclear power reactors. The main objective of this article is to focus on the characterization of generalized two-phase free convection magnetohydrodynamic flow of dusty tetra-hybrid Casson nanofluid among parallel microplates: dusty Casson fluid and tetra-hybrid nanofluid exhibit free movement and electrical conductivity. The Caputo–Fabrizio fractional derivative recently discovered generalizes the partial differential equations governing the flow. Highly accurate temperature and velocity distributions can be obtained using finite sine Fourier and Laplace transform together. This study examines the relationships between temperature, dust particle velocity, and Casson fluid velocity, along with the effects of magnetic parameter, Grashof number, dusty fluid parameter, Peclet number, Reynold number, and particle mass parameter. The Mathcad-15 software provides Casson, dusty, and temperature profiles graphically. The Nusselt number and skin friction are also examined for the tetra-hybrid nanofluid. The fractional Casson fluid model is more accurate than the classical model in terms of velocity, temperature, heat transfer, and skin friction. Graphical results conclude that the fractional Casson fluid model describes a more realistic aspect of both (fluid and dust particle) velocities and temperature profiles, heat transfer rate, and skin friction than the classical Casson fluid model. Furthermore, the heat transfer rate enhanced from 0 to 39.3111% of the tetra-hybrid nanofluid.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":"66 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135494832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research progress on preparation, modification, and application of phenolic aerogel 酚醛气凝胶的制备、改性及应用研究进展
IF 7.4 3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0109
Chengfang Yuan, Degang Wang, Yijun Zhang, Kai Li, Jie Ding
{"title":"Research progress on preparation, modification, and application of phenolic aerogel","authors":"Chengfang Yuan, Degang Wang, Yijun Zhang, Kai Li, Jie Ding","doi":"10.1515/ntrev-2023-0109","DOIUrl":"https://doi.org/10.1515/ntrev-2023-0109","url":null,"abstract":"Abstract Phenolic aerogel is a type of nanoporous resin-based material with low density, high specific surface area, excellent thermal insulation performance, and a high carbon residue rate which has been widely used in the field of thermal protection. However, the development of phenolic aerogel is limited by the complex and expensive preparation technique, inadequate oxidation/ablation resistance, and excessive brittleness. As a result, academic research is constantly concentrated on low-cost preparation methods and efficient modification of phenolic aerogel. This review gives a description of the preparation technology, modification techniques, and application fields of phenolic aerogel and summarizes the limitations. Now, phenolic aerogel is not applied widely due to its complex and expensive preparation technique. Moreover, phenolic aerogel shows greater brittleness and insufficient mechanical property. The prospective future developments of the materials were prospected, and the phenolic aerogel with environmental protection, efficient thermal protection, and low cost will be the mainstream research direction.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":" ","pages":""},"PeriodicalIF":7.4,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41873373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Structural properties of alumina surfaces and their roles in the synthesis of environmentally persistent free radicals (EPFRs) 氧化铝表面结构特性及其在环境持久性自由基合成中的作用
IF 7.4 3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0536
M. Altarawneh, Niveen W. Assaf, Hamed M. Hussain, B. Dlugogorski
{"title":"Structural properties of alumina surfaces and their roles in the synthesis of environmentally persistent free radicals (EPFRs)","authors":"M. Altarawneh, Niveen W. Assaf, Hamed M. Hussain, B. Dlugogorski","doi":"10.1515/ntrev-2022-0536","DOIUrl":"https://doi.org/10.1515/ntrev-2022-0536","url":null,"abstract":"Abstract Alumina oxides have been widely utilised as independent catalysts or as support materials for other catalysts. From an environmental perspective, alumina nanoclusters dispersed on surfaces of particulate matter PM12, generated from various combustion processes, play a critical role in the synthesis of environmentally persistent free radicals (EPFRs). Of particular importance are phenoxy-type EPFRs that often act as building blocks for the formation of notorious pollutants. Herein, we present a systematic review of the literature pertinent to structural features of alumina surfaces at the nano-scale and their well-established role in the synthesis of EPFRs. Central to the capacity of alumina surfaces in mediating the formation of EPFRs are their active Lewis acid–base sites. The nature of these sites is very sensitive to hydration scenarios. As evident in electroparamagnetic resonance measurements, more than one category of EPFR forms on alumina surfaces. This generally entails the co-existence of various surface terminations, varying degrees of hydrations, and distinct underlying reaction pathways. The mechanisms for the formation of EPFRs over alumina surfaces involve interactions with terminal OH groups followed by creating genuine chemical bonds with Al3+ sites. Higher concentrations of EPFRs were often detected on alumina surfaces, in reference to other transition metal oxides. We envisage that future studies may focus on the generation of EPFRs from potential precursors other than phenols and catechol, such as brominated species and substituted thiophenols.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":" ","pages":""},"PeriodicalIF":7.4,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46087108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research progress of biopolymers combined with stem cells in the repair of intrauterine adhesions 生物聚合物与干细胞联合修复宫内粘连的研究进展
IF 7.4 3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0529
Zhujie Wang, Juanjuan Jiang, Xingmiao Li, Mo Chen, Mengjia Yu, Meijun Guo, Ning Wang, Yangyang Li, Xiuxiu Jiang
{"title":"Research progress of biopolymers combined with stem cells in the repair of intrauterine adhesions","authors":"Zhujie Wang, Juanjuan Jiang, Xingmiao Li, Mo Chen, Mengjia Yu, Meijun Guo, Ning Wang, Yangyang Li, Xiuxiu Jiang","doi":"10.1515/ntrev-2022-0529","DOIUrl":"https://doi.org/10.1515/ntrev-2022-0529","url":null,"abstract":"Abstract Asherman syndrome (AS) refers to the loss of endometrial stem cells and matrix hyperplasia caused by endometrial basal layer injury. Its common clinical manifestations include narrowing of the uterine cavity, reduction in menstrual volume, abdominal pain, amenorrhea, and infertility. According to the cause of AS, treatment includes a mechanical barrier and functional recovery. Because the functional recovery of the endometrium depends on the regeneration of endometrial epithelial cells, in the absence of cell involvement, the effect of repair by mechanical removal of adhesions is limited. Recently, tissue engineering and stem cell therapy have achieved promising progress in the recovery of organ function. Biological scaffolds have been applied to encapsulated stem cells as a therapeutic strategy for repairing endometrial damage. This review explains the progress of intrauterine materials and stem cell combined biopolymers in the study of AS and emphasizes the evidence from animal and clinical trials. Graphical abstract","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":" ","pages":""},"PeriodicalIF":7.4,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44472423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyurea micro-/nano-capsule applications in construction industry: A review 聚脲微/纳米胶囊在建筑工业中的应用综述
IF 7.4 3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0516
Mahdi Madelatparvar, M. Hosseini, Chunwei Zhang
{"title":"Polyurea micro-/nano-capsule applications in construction industry: A review","authors":"Mahdi Madelatparvar, M. Hosseini, Chunwei Zhang","doi":"10.1515/ntrev-2022-0516","DOIUrl":"https://doi.org/10.1515/ntrev-2022-0516","url":null,"abstract":"Abstract The application of micro-/nano-capsules in construction industries has been rising over the past decade. Polyurea with tunable chemical and morphological structure are of interesting polymers to prepare micro-/nano-capsules used in construction. The structure of polyurea micro-/nano-capsule is capable to be tailored via bulk emulsion or microfluidic method. Important factors for production of micro/nano-capsules are the rate of fabrication and having control over mean size, dispersity, and wall thickness. The bulk emulsion method provides higher yield of production with less control over sizes and dispersity in comparison to microfluidic technique. The main applications of polyurea micro-/nano-capsules in construction industries are categorized as thermal energy saving, self-healing concrete, self-healing polymers, and fire retarding. Polyurea showed appropriate thermal conductivity and mechanical properties which is required for encapsulation of phase change materials. Titanium dioxide polyurea microcapsules possess energy storage efficiency of 77.3% and thermal storage capacity of 99.9%. Polyurea microcapsules with sodium silicate cargo provided self-healing abilities for oil well cement in high temperature and showed higher self-healing abilities compared to gelatin microcapsules. Graphene oxide polyurea micro-/nano-capsules demonstrated 62.5% anti-corrosive self-healing efficiency in epoxy coating, and steel coated via dendritic polyurea microcapsules embedded polyurethane remained unchanged after long time immersion in salt water.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":" ","pages":""},"PeriodicalIF":7.4,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44485840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Dispersion of carbon nanotubes in aqueous cementitious materials: A review 碳纳米管在水性胶凝材料中的分散研究进展
IF 7.4 3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0560
Yibo Gao, Jianlin Luo, Zhiqing Li, Fei Teng, Jigang Zhang, Song Gao, M. Ma, Xiaoyang Zhou, Xuejun Tao
{"title":"Dispersion of carbon nanotubes in aqueous cementitious materials: A review","authors":"Yibo Gao, Jianlin Luo, Zhiqing Li, Fei Teng, Jigang Zhang, Song Gao, M. Ma, Xiaoyang Zhou, Xuejun Tao","doi":"10.1515/ntrev-2022-0560","DOIUrl":"https://doi.org/10.1515/ntrev-2022-0560","url":null,"abstract":"Abstract In this review, the research reports on the dispersion processes of carbon nanotubes (CNTs) in aqueous cementitious materials are intensively introduced and summarized. The main processes for the CNTs dispersion in aqueous systems include high shear emulsification, ultrasonic treatment, covalent modification, and non-covalent modification. The influences of various factors on the dispersity of CNTs are evaluated, and the pros and cons of dispersion processes of CNTs are analyzed, along with the dispersion mechanism of CNTs in aqueous materials. Several novel techniques are also introduced, including arc thermal excitation and electromagnetic field-induced method, etc. In addition, the challenges when CNTs dispersion are further involved in cementitious alkali pore solution and the improvement means are also described in detail. And, the direct dispersion process (in situ growth process) of CNTs in cementitious materials has also been discussed in depth.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":" ","pages":""},"PeriodicalIF":7.4,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43782848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the nucleation and growth behavior of Ti2AlC and Ti3AlC nano-precipitates in TiAl alloys TiAl合金中Ti2AlC和Ti3AlC纳米沉淀物成核和生长行为的研究
IF 7.4 3区 材料科学
Nanotechnology Reviews Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0510
Bo-Ren Hou, Aiqin Wang, Pei Liu, J. Xie
{"title":"Investigation of the nucleation and growth behavior of Ti2AlC and Ti3AlC nano-precipitates in TiAl alloys","authors":"Bo-Ren Hou, Aiqin Wang, Pei Liu, J. Xie","doi":"10.1515/ntrev-2022-0510","DOIUrl":"https://doi.org/10.1515/ntrev-2022-0510","url":null,"abstract":"Abstract In this work, the nucleation and growth behavior of Ti2AlC and Ti3AlC nano-precipitates in Ti–44Al–1.2C alloys were systematically studied by observing their distribution, morphology, and interface atomic structure. The experiment results show that the needle-like C atom segregation zones in TiAl alloys are the nucleation site of Ti2AlC, and the long axis direction of segregation zones is parallel to the TiAl(111) plane. The rod-like Ti2AlC nano-precipitates mainly distribute at the TiAl/Ti3Al interface, and the orientation relationship between them is [ 1 ̅ 01 bar{1}01 ]TiAl//[ 11 2 ̅ 0 11bar{2}0 ]Ti2AlC//[ 11 2 ̅ 0 11bar{2}0 ]Ti3Al, (111)TiAl//(0001)Ti2AlC//(0001)Ti3Al. The needle-like Ti3AlC nano-precipitates distribute in TiAl with the orientation relationship of [001]Ti3AlC//[001]TiAl, (100)Ti3AlC//(100)TiAl, (020)Ti3AlC//(020)TiAl, and (110)Ti3AlC//(110)TiAl during the nucleation stage. After growing into the rod-like, the orientation relationship between Ti3AlC precipitates and TiAl is [ 1 1 ̅ 0 1bar{1}0 ]Ti3AlC//[ 1 1 ̅ 0 1bar{1}0 ]TiAl, (001)Ti3AlC//(001)TiAl, (220)Ti3AlC//(220)TiAl, and (111)Ti3AlC//(111)TiAl. Both the needle- and rod-like Ti3AlC precipitates preferentially grow along the [001]TiAl direction. The crystal structure and lattice mismatch between Ti2AlC and Ti3AlC nano-precipitates and the TiAl matrix determine their distribution, morphology, and interface atomic structure.","PeriodicalId":18839,"journal":{"name":"Nanotechnology Reviews","volume":" ","pages":""},"PeriodicalIF":7.4,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44995288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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