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Discussion on “Geochemical implications of uranium-bearing thucholite aggregates in the Upper Permian Kupferschiefer Shale, Lubin district, Poland” by Syczewski et al. (2024) 讨论 Syczewski 等人的论文 "波兰卢宾地区上二叠统库珀弗谢费页岩中含铀褐铁矿聚集体的地球化学影响"(2024)
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-09-06 DOI: 10.1007/s00126-024-01313-z
Krzysztof Foltyn, Adam Piestrzyński, Władysław Zygo, Piotr Ducki
{"title":"Discussion on “Geochemical implications of uranium-bearing thucholite aggregates in the Upper Permian Kupferschiefer Shale, Lubin district, Poland” by Syczewski et al. (2024)","authors":"Krzysztof Foltyn, Adam Piestrzyński, Władysław Zygo, Piotr Ducki","doi":"10.1007/s00126-024-01313-z","DOIUrl":"https://doi.org/10.1007/s00126-024-01313-z","url":null,"abstract":"","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"67 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142142446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stable isotopes (H, C, O) and 3D fluid flow modeling constraints on gold endowment along the Augmitto-Bouzan orogenic gold deposit (Abitibi subprovince, Quebec) 稳定同位素(H、C、O)和三维流体流动模型对奥格米托-布赞(Augmitto-Bouzan)成因金矿床(魁北克阿比提比省)沿线金赋存的制约因素
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-09-06 DOI: 10.1007/s00126-024-01308-w
Guillaume Raymond, Georges Beaudoin, Benoît Quesnel, Christophe Scheffer, Crystal LaFlamme, René Therrien, John W. Molson
{"title":"Stable isotopes (H, C, O) and 3D fluid flow modeling constraints on gold endowment along the Augmitto-Bouzan orogenic gold deposit (Abitibi subprovince, Quebec)","authors":"Guillaume Raymond, Georges Beaudoin, Benoît Quesnel, Christophe Scheffer, Crystal LaFlamme, René Therrien, John W. Molson","doi":"10.1007/s00126-024-01308-w","DOIUrl":"https://doi.org/10.1007/s00126-024-01308-w","url":null,"abstract":"<p>The Augmitto-Bouzan deposit is a 12 km long segment of the Larder Lake-Cadillac Deformation Zone (LLCDz) south of Rouyn-Noranda (Québec, Canada) that is characterized by an uneven gold distribution hosted in quartz-carbonate ± tourmaline veins within Piché Group ultramafic rocks. This study compares the fluid flow conditions between the variable gold-endowed sectors to identify deposit-scale processes responsible for gold endowment. Stable isotopes indicate that quartz and tourmaline have equilibrium temperatures (228–⁠420 °C) that likely define a high vertical thermal gradient (~ 30 °C/100 m) along the LLCDz. Covariation between temperature and computed δ<sup>18</sup>O<sub>H2O</sub> and δD<sub>H2O</sub> is interpreted to result from mixing between a high temperature (&gt; 420 °C), high δ<sup>18</sup>O (&gt; 10.8‰), and low δD (&lt; –29‰) deep-seated metamorphic fluid, and a low temperature (&lt; 230 °C), low δ<sup>18</sup>O (&lt; 4‰) and high δD (~ 0‰) upper crustal pore fluid. Local upwelling of auriferous deep-seated fluid, shown by interpolation of δ<sup>18</sup>O<sub>H2O</sub> in the gold-endowed Augmitto-Cinderella and Astoria segments, was likely focused along higher permeability deformation-related pathways. Sectors of low gold endowment have lower δ<sup>18</sup>O<sub>H2O</sub> and fluid/rock ratios, likely reflecting a larger proportion of upper crustal fluid and differences in fluid-flow behavior. Modeling of fluid flow shows that this is due to 1) weaker metamorphic fluid flux in the thinner band of Piché Group rocks and 2) more porous volcanic rocks north of the LLCDz, drawing more pore fluid into the fault. We suggest that most of the variation of gold endowment is related to variations in advection of auriferous metamorphic fluid along the segment, whereby a weaker metamorphic fluid flux or increased admixture of upper crustal fluids decrease the gold potential along the LLCDz.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"17 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142142447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cassiterite geochronology and geochemistry of the Yunling Sn deposit: implication for late cenozoic mineralization in western Yunnan, China 云岭锡矿床的锡石地质年代和地球化学:对中国云南西部晚新生代成矿作用的影响
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-31 DOI: 10.1007/s00126-024-01309-9
Ke Xiao, Xiang Sun, Rongqing Zhang, Mingjun Zheng, Tong Pei, Pete Hollings, Bin Fu, Jun Deng
{"title":"Cassiterite geochronology and geochemistry of the Yunling Sn deposit: implication for late cenozoic mineralization in western Yunnan, China","authors":"Ke Xiao, Xiang Sun, Rongqing Zhang, Mingjun Zheng, Tong Pei, Pete Hollings, Bin Fu, Jun Deng","doi":"10.1007/s00126-024-01309-9","DOIUrl":"https://doi.org/10.1007/s00126-024-01309-9","url":null,"abstract":"<p>Tin deposits within the Baoshan Block in western Yunnan are posited as the northern extension of the Southeast Asian Tin Belt, yet they have been relatively underexplored in terms of geochronology. This study concentrates on the Yunling tin deposit, globally recognized for its production of gemstone-quality cassiterite crystals. We applied U–Pb geochronology on cassiterite, complemented by analyses of its trace element composition and in situ oxygen isotopes in cassiterite and quartz, aiming to delineate the deposit's age and genesis. The Yunling orebodies are hosted by deformed Triassic granite, closely adjacent to the Cenozoic Nantinghe strike-slip shear zone. Three distinct hydrothermal stages have been identified: quartz-cassiterite-muscovite-tourmaline (stage I), arsenopyrite-pyrite-cassiterite-quartz (stage II), and arsenopyrite-calcite-quartz (stage III). Cassiterite grains from a quartz-cassiterite-muscovite-tourmaline vein yield a U–Pb age of 24.4 ± 1.4 Ma (2σ, n = 41, MSWD = 1.6), notably younger than the ore-hosting Triassic granite. Paired cassiterite and quartz oxygen isotopes yield δ<sup>18</sup>O<sub>H2O</sub> values of 5.8 – 7.2 ‰, indicating a magmatic fluid source during stages I and II. The trace element compositions of the Yunling cassiterite resemble those of granite-related tin deposits, suggesting a genetic link between tin mineralization and an unexposed late Cenozoic granite intrusion. Notably, the Triassic granite of Yunling shows a lower degree of magmatic fractionation, thus presenting a limited potential for tin mineralization. The timing of mineralization is correlated with the activity of the Nantinghe fault, alongside geophysical evidence of crust-mantle decoupling and asthenosphere upwelling. Consequently, our findings imply that the Yunling tin mineralization is genetically related to hidden granites, to guide future exploration efforts in western Yunnan.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"380 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Jinchang deposit, Ailaoshan Belt: overprint of Miocene orogenic gold mineralization on Triassic hydrothermal nickel sulfide mineralization 爱老山地带金昌矿床:三叠纪热液硫化镍成矿作用对中新世造山运动金矿成矿作用的叠印
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-29 DOI: 10.1007/s00126-024-01306-y
Huajian Li, Qingfei Wang, David Groves, Chaoyi Dong, Weijun Weng, Wei Ma, Lin Yang, Ziqing Zhu, Jun Deng
{"title":"The Jinchang deposit, Ailaoshan Belt: overprint of Miocene orogenic gold mineralization on Triassic hydrothermal nickel sulfide mineralization","authors":"Huajian Li, Qingfei Wang, David Groves, Chaoyi Dong, Weijun Weng, Wei Ma, Lin Yang, Ziqing Zhu, Jun Deng","doi":"10.1007/s00126-024-01306-y","DOIUrl":"https://doi.org/10.1007/s00126-024-01306-y","url":null,"abstract":"<p>The Jinchang deposit, Ailaoshan Belt, is a hydrothermal gold-nickel deposit in which nickel mineralization formed during Triassic accretionary orogeny and gold mineralization during Miocene collisional orogeny. Although the nickel and gold orebodies largely overlap in an ophiolite melange at the contacts between ultramafic and metasedimentary sequences, nickel and gold concentrations have only a weak correlation in orebodies intersected in drill cores. The hydrothermal nickel sulfide ores are mainly concentrated at ultramafic-metasedimentary rock contacts. Broad alteration zones surround the contacts, with proximal quartz + clinochlore + magnesite in both rocks through quartz + fuchsite to distal muscovite + quartz assemblages in metasedimentary rocks. An apatite U–Pb age of 235.8 ± 1.8 Ma and a pyrite Re-Os age of 254 ± 21 Ma from the nickel mineralization indicate that it formed before the closure of the Ailaoshan Ocean. The As- and S-rich fluids during oceanic subduction leached Ni from the ultramafic rocks in the ophiolite melange forming the hydrothermal nickel sulfide ores. Orogenic gold mineralization comprises auriferous veins that host gold, Au- and Ag-rich sulfosalt. The veins cut the sulfides associated with nickel mineralization. The auriferous fluids reacted with nickel ore-stage pyrite forming porous or sieve-textures and patchy zoning in BSE images with native gold in pores. Geological and paleomagnetic evidence indicates that Miocene gold mineralization occurred in highly deformed Devonian metasedimentary rocks after the Oligocene–Miocene Ailaoshan sinistral shearing (~ 30 to 20 Ma). The auriferous fluids are most likely sourced from the metasomatized mantle lithosphere if Jinchang has a similar source to other orogenic gold deposits in the Ailaoshan Belt.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"66 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142090151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A newly recognised mafic sill-hosted Ni-sulfide deposit emplaced during the 2.4 Ga Widgiemooltha dike swarm event, Eastern Goldfields, Western Australia 在西澳大利亚东部金矿区 2.4 Ga 的 Widgiemooltha 长堤群事件中新发现的岩浆岩矽卡岩包裹的镍硫化物矿床
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-21 DOI: 10.1007/s00126-024-01305-z
Coralie Siégel, Louise Schoneveld, Catherine Spaggiari, Margaux Le Vaillant, Stephen Barnes, Belinda Godel, David Mahon, Michael Verrall, Laure Martin, Stefano Caruso, Tina Shelton
{"title":"A newly recognised mafic sill-hosted Ni-sulfide deposit emplaced during the 2.4 Ga Widgiemooltha dike swarm event, Eastern Goldfields, Western Australia","authors":"Coralie Siégel, Louise Schoneveld, Catherine Spaggiari, Margaux Le Vaillant, Stephen Barnes, Belinda Godel, David Mahon, Michael Verrall, Laure Martin, Stefano Caruso, Tina Shelton","doi":"10.1007/s00126-024-01305-z","DOIUrl":"https://doi.org/10.1007/s00126-024-01305-z","url":null,"abstract":"<p>The Cathedrals Ni-Cu prospect, located at the western margin of the Eastern Goldfields of the Yilgarn Craton, is hosted within a mafic intrusion interpreted as a sill complex. U-Pb dating of apatite from the sill yielded a crystallisation age of 2336 ± 64 Ma, inferring an association of sill emplacement and Ni mineralisation related to emplacement of the c. 2400 Ma Widgiemooltha dike swarm. The sill is typically differentiated into a lower olivine orthocumulate layer overlain by a dolerite unit containing xenoliths of partially assimilated granitoids in its upper portion. The latter is interpreted to be the result of stoping and melting of the granitic hanging wall, thereby creating a gravitationally stable buoyant melt layer beneath the top contact. Ni-Cu-Fe sulfides are increasingly abundant towards the base of the sill, ranging from globular disseminated sulfides to net-textured and massive sulfides at the basal contact. The presence and orientation of sulfide globule-bubble pairs indicates a primary near-horizontal orientation. Massive sulfides commonly exhibit a loop texture with pyrrhotite grains surrounded by pentlandite and chalcopyrite. Despite the variety of sulfide textures, sulfur isotopes have a homogeneous mantle-like signature without significant mass independent fractionation. Mineral chemistries that indicate sulfide prospectivity in larger intrusions do not work as effectively in this small sill, therefore new indicators may need to be developed to explore for similar deposits. To date, there are no other known magmatic deposits of this age in Australia. Sills of this age may be more prospective than previously recognised.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"17 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142013741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mineralogy, mineral chemistry, and genesis of Cu-Ni-As-rich ores at Lisheen, Ireland 爱尔兰利辛富含铜-镍-砷矿石的矿物学、矿物化学和成因
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-15 DOI: 10.1007/s00126-024-01299-8
Max Frenzel, Markus Röhner, Nigel J. Cook, Sarah Gilbert, Cristiana L. Ciobanu, John F. Güven
{"title":"Mineralogy, mineral chemistry, and genesis of Cu-Ni-As-rich ores at Lisheen, Ireland","authors":"Max Frenzel, Markus Röhner, Nigel J. Cook, Sarah Gilbert, Cristiana L. Ciobanu, John F. Güven","doi":"10.1007/s00126-024-01299-8","DOIUrl":"https://doi.org/10.1007/s00126-024-01299-8","url":null,"abstract":"<p>The Irish Orefield is characterised by the presence of both Zn-Pb- and Cu-Ni-As-rich deposits, prospects, and orebodies in similar structural and stratigraphic positions. However, the genetic relationships between these mineralisation types are still debated. In this article, we present new mineralogical, paragenetic, and mineral-chemical observations from the Cu-Ni-As-rich ores at the classic Lisheen deposit, County Tipperary. These observations indicate the intimate association and cogenetic nature of these ores with the more abundant Zn-Pb-rich mineralisation. Specifically, both mineralisation types appear to have formed at the same time, under similar physicochemical conditions, and from the same ore fluids. In addition, both types of mineralisation contain elevated Ge contents. The cogenetic nature of the two mineralisation types, the relative absence of Cu-Ni-As-rich ores from most of the larger Irish-type Zn-Pb deposits compared to expectations derived from probable ore fluid compositions, and finally, the known geological characteristics of larger Cu-Ni-As-rich ore bodies, like Gortdrum, indicate that significant Cu-Ni-As-rich mineralisation could be present at lower stratigraphic levels across the Irish Orefield. Areas with extensive known Zn-Pb mineralisation are expected to be particularly prospective for such ores, which may occur at stratigraphic levels as deep as the Old Red Sandstone. This may have additional implications beyond Ireland, and could point to the potential for undiscovered Cu-rich ores in low-temperature carbonate-hosted Zn-Pb districts elsewhere.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"14 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141986599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mineral chemistry of the Geyer SW tin skarn deposit: understanding variable fluid/rock ratios and metal fluxes 盖耶尔西南锡矽卡岩矿床的矿物化学:了解可变的流体/岩石比率和金属通量
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-14 DOI: 10.1007/s00126-024-01297-w
Nicolas Meyer, Mathias Burisch, Jens Gutzmer, Joachim Krause, Henning Scheibert, Gregor Markl
{"title":"Mineral chemistry of the Geyer SW tin skarn deposit: understanding variable fluid/rock ratios and metal fluxes","authors":"Nicolas Meyer, Mathias Burisch, Jens Gutzmer, Joachim Krause, Henning Scheibert, Gregor Markl","doi":"10.1007/s00126-024-01297-w","DOIUrl":"https://doi.org/10.1007/s00126-024-01297-w","url":null,"abstract":"<p>The Geyer tin skarn in the Erzgebirge, Germany, comprises an early skarnoid stage (stage I, ~ 320 Ma) and a younger metasomatic stage (stage II, ~ 305 Ma), but yet, the source and distribution of Sn and the physicochemical conditions of skarn alteration were not constrained. Our results illustrate that contact metamorphic skarnoids of stage I contain only little Sn. REE patterns and elevated concentrations of HFSE indicate that garnet, titanite and vesuvianite of stage I formed under rock-buffered conditions (low fluid/rock ratios). Prograde assemblages of stage II, in contrast, contain two generations of stanniferous garnet, titanite-malayaite and vesuvianite. Oscillation between rock-buffered and fluid-buffered conditions are marked by variable concentrations of HFSE, W, In, and Sn in metasomatic garnet. Trace and REE element signatures of minerals formed under high fluid/rock ratios appear to mimic the signature of the magmatic-hydrothermal fluid which gave rise to metasomatic skarn alteration. Concomitantly with lower fluid-rock ratio, tin was remobilized from Sn-rich silicates and re-precipitated as malayaite. Ingress of meteoric water and decreasing temperatures towards the end of stage II led to the formation of cassiterite, low-Sn amphibole, chlorite, and sulfide minerals. Minor and trace element compositions of cassiterite do not show much variation, even if host rock and gangue minerals vary significantly, suggesting a predominance of a magmatic-hydrothermal fluid and high fluid/rock ratios. The mineral chemistry of major skarn-forming minerals, hence, records the change in the fluid/rock ratio, and the arrival, distribution, and remobilization of tin by magmatic fluids in polyphase tin skarn systems.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"2 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141980906","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Petrogenesis of the 1149 Ma Etoile Suite Mafic Intrusion, Quebec: implications for vanadium mineralisation in Proterozoic anorthosite-bearing terranes 魁北克 1149 Ma Etoile 组岩浆侵入体的成岩作用:对新生代含正长岩钒矿化的影响
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-10 DOI: 10.1007/s00126-024-01298-9
Randolph P. Maier, Sarah A. S. Dare, William D. Smith
{"title":"Petrogenesis of the 1149 Ma Etoile Suite Mafic Intrusion, Quebec: implications for vanadium mineralisation in Proterozoic anorthosite-bearing terranes","authors":"Randolph P. Maier, Sarah A. S. Dare, William D. Smith","doi":"10.1007/s00126-024-01298-9","DOIUrl":"https://doi.org/10.1007/s00126-024-01298-9","url":null,"abstract":"<p>Iron-titanium-vanadium (Fe-Ti-V) oxide mineralisation is commonly associated with Proterozoic massif-type anorthosites, but the conditions required for their formation remain poorly understood. The Etoile Suite Mafic Intrusion (1149 ± 11 Ma), in the Grenville Province, Quebec (Canada), comprises a layered mafic intrusion that is coeval with nearby massif-type anorthosites. The mafic intrusion consists of troctolite and olivine gabbro cumulates, where magnetite and ilmenite are intercumulus at the base (Zone A) and top (Zone C) but cumulus (&lt;30 modal %) in the centre (Zone B). Towards the base of Zone B, vanadium mineralisation occurs in a 1-km-thick oxide-rich wehrlite horizon, where V-rich titanomagnetite (&lt;1.85 wt% V<sub>2</sub>O<sub>5</sub>) and ilmenite form semi-massive oxide layers. From the base to the top of Zone B there is an overall progressive decrease in An<sub>pl</sub>, Fo<sub>ol</sub>, and Mg#<sub>cpx</sub>, and in Cr and Ni concentrations of magnetite, albeit with several reversals to more primitive compositions, including one near the base of Zone C. This indicates fractional crystallisation in an open magma chamber. The intrusion crystallised at moderate <i>f</i>O<sub>2</sub> (~FMQ 1.1 ± 0.3), resulting in the late crystallisation of V-rich magnetite from a relatively evolved magma. The parental magma was likely a high-Al basalt derived from a depleted mantle source, recording minimal crustal contamination, in contrast to coeval massif-type anorthosites that commonly contain orthopyroxene reflecting higher degrees of crustal contamination. As a result, V mineralisation in noritic anorthosites formed at higher <i>f</i>O<sub>2</sub>, with early crystallisation of relatively V-poor magnetite, whereas magnetite in troctolitic-olivine gabbroic intrusions crystallised later with higher V contents, due to lower <i>f</i>O<sub>2</sub>.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"13 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141910294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Relationship between U and Ni-Co-As mineralization in the Midwest polymetallic U deposit, Athabasca Basin (Canada) – constraints from mineralogical, geochemical, and fluid inclusion studies 加拿大阿萨巴斯卡盆地中西部多金属铀矿床中铀矿化与镍钴砷矿化之间的关系--矿物学、地球化学和流体包裹体研究的制约因素
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-09 DOI: 10.1007/s00126-024-01304-0
Daniel Ferguson, Guoxiang Chi, Charles Normand, Julien Mercadier, Yumeng Wang, Kelsey McKee, Magdalena Anderson, John Robbins
{"title":"Relationship between U and Ni-Co-As mineralization in the Midwest polymetallic U deposit, Athabasca Basin (Canada) – constraints from mineralogical, geochemical, and fluid inclusion studies","authors":"Daniel Ferguson, Guoxiang Chi, Charles Normand, Julien Mercadier, Yumeng Wang, Kelsey McKee, Magdalena Anderson, John Robbins","doi":"10.1007/s00126-024-01304-0","DOIUrl":"https://doi.org/10.1007/s00126-024-01304-0","url":null,"abstract":"<p>The unconformity-related uranium (URU) deposits in the Proterozoic Athabasca Basin are one of the most important U resources in the world. This type of U deposit can be divided into monometallic (U) and polymetallic (U-Ni-Co-As) subtypes. While it is generally agreed that the URU deposits formed from reaction between oxidizing, basinal brines carrying U and/or Ni-Co-As with reducing basement fluids or lithologies, it is debatable whether the polymetallic deposits formed from co-enrichment of U-Ni-Co-As or enrichment of U superimposed by a separate Ni-Co-As mineralization event. This study addresses this problem through mineralogical, geochemical and fluid inclusion investigation of the Midwest U-Ni-Co-As deposit. Petrographic studies indicate that the sequence of ore precipitation started with uraninite, followed by Ni-Co arsenides and sulfoarsenides and then Cu-Pb-Fe sulfides, and this sequence was repeated episodically. This observation suggests that the deposit did not form from two separate U and Ni-Co-As mineralization events, but rather multiple episodes of U-Ni-Co-As mineralization. Linear correlations between chemical ages and Si-Ca-Fe contents of the most pristine uraninite U1 suggest a maximum primary mineralization of ca. 1600 Ma, which is consistent with the inferred primary U mineralization age in the Athabasca Basin. Microthermometric and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of fluid inclusions in syn-mineralization drusy quartz indicate that the composition of the ore-forming fluids is characterized by the H<sub>2</sub>O-NaCl-CaCl<sub>2</sub>-KCl-MgCl<sub>2</sub> system and comparable to those from both monometallic and polymetallic URU deposits. The relationship between U and Ni + Co in the fluid inclusions and its comparison with other URU deposits support a model in which U and Ni-Co were co-enriched in a unified mineralization process. The development of breccia structures in the ores and the dramatic fluid pressure fluctuation revealed by fluid inclusions suggest that the deposit formed from multiple episodes of fluid flow related to repeated reactivation of basement-rooted faults.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"66 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141909081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Davenda-Klyuchevskoe Au-Mo-(Cu) cluster in the Mogocha gold district (Russia): an intrusion-related or porphyry system overprinted by epithermal gold? 俄罗斯莫戈查金矿区的 Davenda-Klyuchevskoe Au-Mo(Cu)矿集群:是与侵入有关的系统,还是由表生金叠加的斑岩系统?
IF 4.8 2区 地球科学
Mineralium Deposita Pub Date : 2024-08-07 DOI: 10.1007/s00126-024-01302-2
Alexander Yakubchuk, Konstantin Lobanov, Sergei Shmatov
{"title":"The Davenda-Klyuchevskoe Au-Mo-(Cu) cluster in the Mogocha gold district (Russia): an intrusion-related or porphyry system overprinted by epithermal gold?","authors":"Alexander Yakubchuk, Konstantin Lobanov, Sergei Shmatov","doi":"10.1007/s00126-024-01302-2","DOIUrl":"https://doi.org/10.1007/s00126-024-01302-2","url":null,"abstract":"<p>The 18 × 4 km Davenda-Klyuchevskoe cluster in the Mogocha mineral district of the Siberian craton hosts gold, silver, molybdenum and copper in six types of mineralization. The general sulphide zoning at the Sergeevskoe and Klyuchevskoe deposits, the largest in the cluster, is similar to porphyry systems, but the orebodies form 4.5 × 1 km multiple linear sulphide-rich quartz-veinlet swarms, rather than a bulk mineralized envelope. Five types of mineralization formed at 162 − 150 Ma. They are clearly overprinted by northeast-striking epithermal Au-Ag carbonate-quartz veins. All mineralization is genetically linked to the Peak Klyuchi subvolcanic centre of Late Jurassic to Early Cretaceous age (159 − 132 Ma) which is part of the Amudzhikan intrusive complex, consisting of early complexly shaped ENE-striking granodiorite porphyry stock and dykes, intruded by magmatic to hydrothermal breccia and five generations of WNW-trending dykes of dioritic porphyry, hybrid porphyry, rhyolite, and ultimate lamprophyre. The dykes control or parallel five types of megastockwork orebodies within a dextral extensional strike-slip duplex. However, Au-Ag epithermal veins follow late-mineral northeast faults, dividing the megastockwork into several domains. The Davenda-Klyuchevskoe cluster is part of the Shilka Mo-(Au-Ag-Cu) metallogenic belt, striking within the Siberian craton just 25 km north in parallel to the Mongol-Okhotsk suture. Geochronological and petrological data suggest that the intrusive complex and its mineralization formed in relation to northward-dipping subduction prior to scissor-like suturing in this segment of the Mongol-Okhotsk Ocean in response to the northward push by the North China and Yangtze cratons towards Siberia.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"190 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141899853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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