Alexandre Cugerone, Stefano Salvi, Kalin Kouzmanov, Oscar Laurent, Bénédicte Cenki
{"title":"Tracing fluid signature and metal mobility in complex orogens: insights from Pb-Zn mineralization in the Pyrenean Axial Zone","authors":"Alexandre Cugerone, Stefano Salvi, Kalin Kouzmanov, Oscar Laurent, Bénédicte Cenki","doi":"10.1007/s00126-024-01329-5","DOIUrl":"https://doi.org/10.1007/s00126-024-01329-5","url":null,"abstract":"<p>Orogenic processes encompass a complex interplay of deformation and metamorphic events, which can impact the formation of ore deposits to various degrees. However, distinguishing fluid signatures from orogenic versus post-orogenic events presents a significant challenge due to the scarcity of robust geochemical indicators that remain unaffected during multiple post-mineral reworking events. This study carefully examines the properties and chemistry of primary and secondary fluid inclusions (FIs), identifying distinct signatures of two fluid populations linked to different styles of Pb-Zn mineralization in the Pyrenean Axial Zone (PAZ) of Southern-France/Northern-Iberia: These included late-Carboniferous stratabound epigenetic Pb-Zn deposits and Mesozoic crosscutting Pb-Zn(-Ge) vein systems. Population (I) is identified in primary and secondary FIs in a few crosscutting Pb-Zn veins and constitutes a minor component in stratabound epigenetic bodies. It exhibits Na-dominated low to intermediate salinity (< 20 wt% NaCl eq.), intermediate temperatures (200–350 °C), abundant CO<sub>2</sub>-rich FIs and shows low homogeneous Cl/Br molar ratios. These characteristics are consistent with a metamorphic origin of the fluids, associated with Late-Variscan metamorphism. Population (II) is commonly observed in the crosscutting vein systems where it occurs as primary and pseudosecondary FIs, as well as in stratabound epigenetic bodies where it represents the main fluid component of secondary FIs. Population (II) is Ca-dominated with intermediate to high salinity (15–35 wt% NaCl eq.), relatively low temperature (< 200 °C), and shows high Cl/Br molar ratios with significant variations. This last characteristic is typical of mixing of at least two fluids, one with a probable low Cl/Br molar ratio at shallow crustal levels and another with high Cl/Br molar ratio at deeper levels. Characteristics of population (II) are consistent with a fluid of basinal origin that interacted with the basement while circulating in the Pyrenees during the Mesozoic, although a Pyrenean-Alpine age cannot be excluded. Locally, in sphalerite-hosted secondary FIs that form trails in the crosscutting veins, we find evidence of high Ge concentrations (up to few 1000s ppm), which correlate with anomalous Pb and Tl concentrations. Very high metal concentrations (up to 1–2 wt% Pb, Zn), which are inversely proportional to Cl/Br molar ratios, are found in FIs mainly within veins hosted in deep-seated high-grade metamorphic rocks. Based on a compilation of fluid data from the literature, a first-order correlation can be deduced between the metamorphic grade of the rocks hosting the mineralization and the Pb and Zn content in the FIs. Early stratabound orebodies are considered likely sources of metal for the development of the late crosscutting vein mineralization. This study demonstrates the significance and complexity of orogen-scale fluid circulation and supports the importance of pre-","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"87 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142541702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Phillip Gopon, Patrick Sack, Nicolas Pinet, James O. Douglas, Benjamin M. Jenkins, Brooke Johnson, Ella Penny, Michael P. Moody, Laurence Robb
{"title":"Revealing Yukon’s hidden treasure: an atomic-scale investigation of Carlin-type gold mineralization in the Nadaleen Trend, Canada","authors":"Phillip Gopon, Patrick Sack, Nicolas Pinet, James O. Douglas, Benjamin M. Jenkins, Brooke Johnson, Ella Penny, Michael P. Moody, Laurence Robb","doi":"10.1007/s00126-024-01325-9","DOIUrl":"https://doi.org/10.1007/s00126-024-01325-9","url":null,"abstract":"<p>The invisible-gold deposits known as Carlin-type are becoming more important as easier to find deposits are progressively depleted. The combination of the invisible nature of the Au in these deposits, as well as the limited surface indicators of these deposits, makes exploration to find new Carlin-type deposits extremely difficult. Comprehensive mineralization models are essential to find new Carlin-type deposits in similar geologic settings. The Nadaleen Trend of Yukon, Canada, is one such district where an improved understanding of this deposit type has led to new discoveries. Previous studies compared and contrasted the tectonic setting, host rock depositional setting, structural preparation, and mineralization style of the Nadaleen Trend with those in Carlin-type localities, Nevada. However, the comparisons at an atomic scale, between Carlin-type Au deposits in the Nadaleen Trend and those in Nevada, has yet to be investigated. This study fills this knowledge gap by combining high resolution microanalytical techniques with atom probe tomography to examine the distribution of Au and other trace elements in the Nadaleen Trend, compare them to a representative Carlin-type deposit in Nevada (Turquoise Ridge), and determine how widespread the mineralization model is. Our findings show that in the Nadaleen Trend, as in Nevada, Au is generally directly linked with As at the macro to atomic scale, and is incorporated into As/Au rich overgrowths on sedimentary/diagenetic pyrite. Gold-rich pyrite rims in the Nadaleen Trend are generally smaller than those found in Nevada (0.5–2 µm vs > 10 µm), although the ore grades appear comparable. We find that the Au in the pyrite of the Nadaleen Trend is homogenously distributed (i.e. lattice bound) at the atomic scale, but that there is a notable enrichment of As surrounding individual Au atoms. These findings are in agreement with those from previous work on a representative deposit in Nevada, and support the assertation that As is the key ingredient in facilitating the incorporation of Au into the pyrite lattice. Arsenic as an essential component in the trapping mechanisms of Au in CTG deposits, is something that has been as to yet underappreciated in the current models of CTG deposit formation.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"238 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142541704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ming Yang, Yejian Wang, Sven Petersen, Zhongyan Qiu, Honglin Li, Peng Zhou, Yiyang Cai, Xing Yu, Matthias Frische, Jiqiang Liu, Xiqiu Han
{"title":"Gold mineralization in the hydrothermal field at the termination of a detachment fault: A case study of the Tianxiu Vent Field","authors":"Ming Yang, Yejian Wang, Sven Petersen, Zhongyan Qiu, Honglin Li, Peng Zhou, Yiyang Cai, Xing Yu, Matthias Frische, Jiqiang Liu, Xiqiu Han","doi":"10.1007/s00126-024-01323-x","DOIUrl":"https://doi.org/10.1007/s00126-024-01323-x","url":null,"abstract":"<p>Gold mineralization in hydrothermal systems at slow- to ultraslow-spreading ridges commonly occurs either in the hangingwall or the footwall of the detachment fault. However, the Tianxiu Vent Field (TVF) on Carlsberg Ridge is, to our knowledge, the only known example where the mineralization occurs directly at the termination zone of a detachment fault. Located approximately 5 km south of the rift axis near 3°48′N on the slow-spreading Carlsberg Ridge, TVF provides a unique opportunity for studying gold mineralization in this context. Detailed analyses of the mineralogy, mineral chemistry, and bulk geochemistry of massive sulfides from Tianxiu reveal several key findings: (1) both visible gold (native gold and electrum) and invisible gold are predominantly hosted in Cu-rich minerals such as isocubanite and covellite; (2) the content of Au (mean = 5.72 ± 4.38 ppm, <i>n</i> = 43) is positively correlated with Co, Cu, Bi, and Se; and (3) the gold mineralization occurs primarily at high-temperatures under strongly reducing conditions, with additional gold mineralization during late-stage silicification and seafloor weathering. When compared to other detachment-fault-associated deposits along slow- to ultraslow-spreading ridges, the ultramafic source rocks and the strongly reducing conditions at TVF appear to have facilitated Au mineralization. Additionally, the intensity of the fluid/rock interaction is possibly an important factor controlling the distribution of gold. The heterogeneous distribution of gold in Tianxiu is likely due to the spatial variability of fluid pathways within a highly permeable termination zone of the detachment fault. This study underscores a unique mineralization model of gold at the termination of a detachment fault on slow-spreading ridges, which has significant implications for the exploration of massive sulfide resource in off-axis regions.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"79 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marcin D. Syczewski, Paweł Panajew, Leszek Marynowski, Marta Waliczek, Andrzej Borkowski, Jan Rohovec, Šárka Matoušková, Ilona Sekudewicz, Malwina Liszewska, Bartłomiej Jankiewicz, Aliya N. Mukhamed’yarova, Mirosław Słowakiewicz
{"title":"Reply to Discussion on “Geochemical implication of uranium-bearing thucholite aggregates in the Upper Permian Kupferschiefer shale, Lubin district, Poland” by Syczewski et al. (2024)","authors":"Marcin D. Syczewski, Paweł Panajew, Leszek Marynowski, Marta Waliczek, Andrzej Borkowski, Jan Rohovec, Šárka Matoušková, Ilona Sekudewicz, Malwina Liszewska, Bartłomiej Jankiewicz, Aliya N. Mukhamed’yarova, Mirosław Słowakiewicz","doi":"10.1007/s00126-024-01328-6","DOIUrl":"https://doi.org/10.1007/s00126-024-01328-6","url":null,"abstract":"","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"124 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142448394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jie Yu, Martin Hand, Justin L. Payne, Laura J. Morrissey, Alexander Simpson, Stijn Glorie, Yan-Jing Chen
{"title":"Innovation in apatite Lu-Hf geochronology opens new opportunity for copper systems in southern Australia during the Nuna destruction","authors":"Jie Yu, Martin Hand, Justin L. Payne, Laura J. Morrissey, Alexander Simpson, Stijn Glorie, Yan-Jing Chen","doi":"10.1007/s00126-024-01327-7","DOIUrl":"https://doi.org/10.1007/s00126-024-01327-7","url":null,"abstract":"<p>Precambrian iron oxide copper-gold (IOCG) systems have commonly experienced multiple mineralising and tectonothermal events and identifying their timing and geodynamic framework is challenging. World-class IOCG deposits in the Olympic Cu-Au Province, South Australia, are dominated by hematite and formed in the upper crust, while the magnetite-dominated Cu deposits hosted in granulite facies rocks are considered to represent the deeper expression of giant IOCG system. However, the application of novel in-situ Lu-Hf apatite geochronology reveals the magnetite-hosted Cu mineralisation is significantly younger and unrelated to the well-known ~ 1590 Ma Gawler Craton IOCG systems. Apatite Lu-Hf ages from the granulite that predates Cu mineralisation give ages of 1490 Ma. Infiltration of Cu-bearing fluids resulted in recrystallisation of apatite, LREE mobilisation and formation of secondary monazite. Lu-Hf ages for syn-mineralisation apatite give 1460 Ma, consistent with c. 1460 Ma U-Pb ages from secondary monazite. In contrast to the apatite in situ Lu-Hf ages, all apatite types produce a single U-Pb age of c. 1460 Ma, demonstrating the ability of Lu-Hf to preserve a more complete history of apatite formation than U-Pb in high- to medium-temperature rock systems. The timing of mineralisation coincides with the onset of Nuna fragmentation, representing a previously unrecognised driver for mineral system formation in southern Australia that installed Cu in crust previously dehydrated during a long history of granulite-grade tectonic events. The recognition of this Cu system in rocks generally considered unprospective shows that continental breakup can rejuvenate metallic systems in otherwise unprospective crust.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"24 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142448393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Viktor Bertrandsson Erlandsson, Krzysztof Foltyn, Philippe Muchez, Gerd Rantitsch, Rainer Ellmies, Frank Melcher
{"title":"Chalcopyrite, sphalerite, and pyrite chemistry in stratiform sediment-hosted Cu(-Co) metallogenic districts: trace element characteristics and factors controlling polymetallic mineralization","authors":"Viktor Bertrandsson Erlandsson, Krzysztof Foltyn, Philippe Muchez, Gerd Rantitsch, Rainer Ellmies, Frank Melcher","doi":"10.1007/s00126-024-01320-0","DOIUrl":"https://doi.org/10.1007/s00126-024-01320-0","url":null,"abstract":"<p>Stratiform sediment-hosted Cu deposits are significant global sources of Cu and other important metals. The Polish Kupferschiefer produces Ag, Au, Pb, Ni, Se, and Re as by-products, whereas Co is one the of most important metals in the stratiform sediment-hosted Cu-Co deposits of the Central African Copperbelt and the Namibian Dolostone Ore Formation deposit. This study combines new and published laser ablation inductively coupled plasma mass spectrometry sulfide trace element data from these stratiform sediment-hosted copper districts. All the investigated districts exhibit sulfides occurring as disseminations and within later veins. Chalcopyrite, sphalerite, and pyrite trace element contents vary significantly between the metallogenic districts as well as between different ore stages. Random Forest discriminates the stratiform sediment-hosted Cu(-Co) districts based on trace element geochemistry. High Ag and Tl in chalcopyrite is attributed to the Polish Kupferschiefer, Ga and Ge to the Katanga Copperbelt, and Zn and In to the Dolostone Ore Formation deposit. Sphalerite from the Polish Kupferschiefer and the Dolostone Ore Formation deposit can be distinguished on the basis of the Fe and Cd contents. Cobalt and As are significantly elevated in pyrite from the Katanga Copperbelt and Mn in pyrite from the Dolostone Ore Formation deposit. The trace element contents also show that the stratiform sediment-hosted Cu(-Co) deposit sulfide data cluster separately from other deposit types. The variation in sulfide trace element contents between the three investigated stratiform sediment-hosted Cu(-Co) districts suggests that sulfide chemistry is related to the geology of the host basin and the nature of the underlying basement, which includes preexisting ore occurrences.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"2 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142415790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Stefano Caruso, Margaux Le Vaillant, Stephen J. Barnes, Ville J. Virtanen, Giada Iacono-Marziano
{"title":"Sulfide and Fe-Ti-P liquid immiscibility in the Ni-Cu-Co ovoid deposit of the Voisey’s Bay complex, Labrador, Canada","authors":"Stefano Caruso, Margaux Le Vaillant, Stephen J. Barnes, Ville J. Virtanen, Giada Iacono-Marziano","doi":"10.1007/s00126-024-01319-7","DOIUrl":"https://doi.org/10.1007/s00126-024-01319-7","url":null,"abstract":"<p>In the Voisey’s Bay complex, sulfide-matrix breccias developed through the percolation of dense sulfide melt, leading to the displacement of the silicate melt within partially molten silicate-matrix breccias. In these sulfide matrix-breccias, hydrous silicate rims are commonly present at the interface between the sulfide matrix and the silicate framework. Multiple lines of evidence support a magmatic origin of these hornblende-biotite rims, which was largely coeval with the emplacement of the sulfide melt in the magmatic breccias. The formation of the hornblende-biotite rims required the addition of alkalis and water that could not have entirely been sourced from either the sulfide melt or the silicate framework. Through the integration of compositional maps with major and trace element analyses of the main accessory minerals, we propose that the critical components required for the development of the hydrous silicate rims in sulfide-matrix breccias originated from an immiscible Fe-Ti-P melt. Distinct textural and compositional features of apatite, hercynite, ilmenite and magnetite support the presence of small amounts of Fe-Ti-P melt in the sulfide melt. This Fe-Ti-P melt likely formed through melt immiscibility in the early stages of the development of the Voisey’s Bay complex, and was transported in the magma conduits together with the sulfide melt.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"32 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142385545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jia-Feng He, Guo-Guang Wang, Matthew J. Brzozowski, Pei Ni, Xiang-Long Luo, Jun Mu, Weiqiang Li
{"title":"Hypogene sulfide precipitation during phyllic alteration: insights from copper isotopic evolution of the Dexing porphyry Cu–Mo–Au deposit, South China","authors":"Jia-Feng He, Guo-Guang Wang, Matthew J. Brzozowski, Pei Ni, Xiang-Long Luo, Jun Mu, Weiqiang Li","doi":"10.1007/s00126-024-01321-z","DOIUrl":"https://doi.org/10.1007/s00126-024-01321-z","url":null,"abstract":"<p>The contributions of early potassic and later phyllic alteration stages to Cu endowment of the giant Dexing porphyry Cu–Mo–Au system in South China are determined using changes in the Cu isotope composition of hypogene chalcopyrite from three vein stages. The δ<sup>65</sup>Cu values of chalcopyrite (δ<sup>65</sup>Cu<sub>cpy</sub> values) from the potassic (stage 1: -0.05‰ to 0.21‰) to the phyllic alteration stages (stage 2: -0.03‰ to 0.24‰) are relatively invariable, but chalcopyrite in the propylitic alteration stage (stage 3) has notably lower isotopic values (-0.35‰ to 0.02‰). The sharp decrease in δ<sup>65</sup>Cu<sub>cpy</sub> values in the latest vein stage is likely a result of precipitation of significant amounts of isotopically heavy chalcopyrite in the phyllic alteration environment. The overall isotopic evolution can be simulated, using a Rayleigh fractionation model, with the majority of Cu having precipitated during the phyllic alteration stage. By comparing our data with published Cu isotope results from other porphyry deposits, we demonstrate that the systematics of δ<sup>65</sup>Cu<sub>cpy</sub> values during different hydrothermal alteration stages could convincingly trace the relative timing and mechanism(s) of Cu precipitation in porphyry Cu systems. Spatial mapping of Cu isotopes at Dexing suggest that sharp decreases of δ<sup>65</sup>Cu<sub>cpy</sub> values in hypogene zones may be used to delineate the boundary of high-grade ore zones.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"122 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142385652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Laura Maydagán, María Agustina Cócola, David Selby, Andrea Montoya, Federico Mateos, Martín Gonzalo Vallejos, Sergio Palma, Guillermo Delle Vedove, Raúl Alvarez Cifuentes
{"title":"U-Pb, Re-Os, and 40Ar/39Ar geochronological constraints on the Cerros Taguas deposit, northern El Indio belt (29°S): implications for the timing of high-sulfidation and porphyry-style mineralization","authors":"Laura Maydagán, María Agustina Cócola, David Selby, Andrea Montoya, Federico Mateos, Martín Gonzalo Vallejos, Sergio Palma, Guillermo Delle Vedove, Raúl Alvarez Cifuentes","doi":"10.1007/s00126-024-01322-y","DOIUrl":"https://doi.org/10.1007/s00126-024-01322-y","url":null,"abstract":"<p>Cerros Taguas is one of the high-sulfidation epithermal Au-Ag deposits (131.35 Mt @ 0.29 g/t Au, 8.8 g/t Ag, 0.11% Cu) of the Taguas project, located in the northern sector of the El Indio belt (~ 29°S), Central Andes, Argentina. Zircon LA-ICP-MS U-Pb dating of a rhyolitic tuff that hosts Au-Ag mineralization constrain the timing of volcanism to the middle Miocene (12.14 ± 0.14 to 11.85 ± 0.26 Ma). Above 3800 m.a.s.l., the rocks display advanced argillic alteration, characterized by alunite + pyrophyllite + dickite ± diaspore ± topaz. Hypogene alunite associated with epithermal Au-Ag mineralization yielded a <sup>40</sup>Ar/<sup>39</sup>Ar plateau date of 9.5 ± 0.4 Ma. Below 3800 m.a.s.l., the presence of sericitic alteration (muscovite + illite + quartz) and a molybdenum halo associated with molybdenite-bearing B-type and pyrite ± quartz D-type veins suggests a transition from epithermal to porphyry-style mineralization. Molybdenite in quartz-dominated B-type veins and molybdenite ± quartz veins cross-cutting the rhyolitic tuff yielded ID-NTIMS Re-Os dates of 10.60 ± 0.06 and 10.48 ± 0.05 Ma. A nominally older molybdenite ID-NTIMS Re-Os date (11.10 ± 0.11 Ma) was obtained for the hydrothermal cement of a breccia. The timing of molybdenum mineralization at Cerros Taguas was broadly coeval with the emplacement of inter-mineralization porphyritic stocks and slightly older than molybdenite mineralization in the nearby Valeriano and El Encierro porphyry deposits. The occurrence of a porphyry-style mineralization at Cerros Taguas reflects the prospectivity for porphyry deposits beneath Miocene-age volcanic rocks and advanced argillic alteration zones in the northern sector of the El Indio belt.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"54 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142384402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tobias Kluge, Elisabeth Eiche, Benjamin Walter, Utz Kramar, Jörg Göttlicher, Dominik Gudelius, Johannes Giebel, Jochen Kolb
{"title":"The influence of fluid pressure, redox potential and crystal growth characteristics in Mississippi-Valley-Type (MVT) ore formation - lessons from a modern geothermal scale","authors":"Tobias Kluge, Elisabeth Eiche, Benjamin Walter, Utz Kramar, Jörg Göttlicher, Dominik Gudelius, Johannes Giebel, Jochen Kolb","doi":"10.1007/s00126-024-01314-y","DOIUrl":"https://doi.org/10.1007/s00126-024-01314-y","url":null,"abstract":"<p>MVT-related elements show a specific enrichment pattern in a geothermal scale.</p>\u0000<p>Comparison with fluid parameters suggests pressure reduction and CO<sub>2</sub> degassing as basis for mineral formation and element enrichment.</p>\u0000<p>Exchange processes at the contact surface mineral-fluid and changes in the redox potential allow for element-specific concentration changes.</p>\u0000<p>Methane oxidation and sulfate reduction cause major chemical changes.</p>\u0000<p>Isotope data track the observed chemical variations.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":"36 1","pages":""},"PeriodicalIF":4.8,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142317566","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}