{"title":"Resource utilization strategy of Fe-bearing smelting slag in China: A review","authors":"","doi":"10.1016/j.mineng.2024.109066","DOIUrl":"10.1016/j.mineng.2024.109066","url":null,"abstract":"<div><div>In China’s rapid development, the metallurgy industry plays a pivotal role. However, the processing and utilization of iron ore results in the production of a significant amount of iron-bearing smelting slags. Iron-bearing smelting slags contains iron, zinc, copper, calcium, potassium, and other metal elements. Challenges in processing technology and cost control in smelting enterprises contribute to the slag stockpile issue, leading to significant pollution of the surrounding environment and groundwater resources, and resulting in the underutilization of metal resources in iron-bearing smelting slags. This paper identifies the sources and hazards of iron-bearing smelting slag, delves into resourceful strategies for its comprehensive utilization, such as metal recycling technology and new building materials, summarizes various treatment processes, and employs reaction thermodynamics software to calculate the Gibbs free energy (<em>ΔG<sup>θ</sup></em>) of potential chemical reactions in the slag. This analysis helps elucidate the evolution of iron-bearing phases. Additionally, it examines the role of additives (CaO) in the reduction process of non-ferrous smelting slags and seeks to uncover the factors limiting their industrial application.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Generalized mathematical model applied to a silica sand laboratory-controlled mill: Derivation of simplified ceramic ball entrance flux, ball wear consumption, and mass distribution functions","authors":"","doi":"10.1016/j.mineng.2024.109055","DOIUrl":"10.1016/j.mineng.2024.109055","url":null,"abstract":"<div><div>A laboratory-controlled milling process of silica sand was carried out using aluminum oxide balls of three different sizes. The ball wear kinetic equations were experimentally obtained from the evolution curves of the ball diameter as a function of the operating time. From a generalized model, the ball entrance flux and ball wear consumption were calculated using exact two-parameter solution functions. One-parameter ball entrance flux and ball wear consumption functions were proposed to perform calculations that accurately describe the values provided by the two-parameter functions. In addition, a compact form of the ball mass distribution function is found. This set of simplified equations can be suitable for fast calculations in the milling industry.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study on the influence of high permeability magnetic iron on energy consumption reduction in high gradient magnetic separator","authors":"","doi":"10.1016/j.mineng.2024.109064","DOIUrl":"10.1016/j.mineng.2024.109064","url":null,"abstract":"<div><div>The green processing of weakly magnetic iron ore is inseparable from high-intensity and high-gradient magnetic separator (HGMS), which is one of the most energy-intensive magnetic separation equipment. Iron (Fe) armor serves as the key primary structure for enhancing magnetic field conduction efficiency within the magnetic system. The order of magnetic properties of commonly used magnetic yoke materials is: ordinary carbon structural steel < Q235 steel < DT4 electrical pure iron. But the utilization cost of DT4 electrical pure iron is the highest, especially the magnetic properties of DT4C super electrical pure iron are unstable and the yield is low. On the basis of ordinary pure iron materials, this article has developed a new type of 411 pure iron (411) upon controlling the levels of harmful elements, while increasing the concentration of beneficial elements.intensity Furthermore, through the utilization of magnetic field simulation software, the impact of 411 on the background magnetic field intensity of HGMS was analyzed. The results indicated that the newly developed 411 pure Fe exhibited a coercivity of 24.07 A/m, a saturation magnetization intensity of ∼ 1.69 T, a maximum relative magnetic permeability of 24.38 × 10<sup>-3</sup>H/m, demonstrating superior magnetic properties in comparison with Q235 and DT4C. When using 411 pure iron as the magnetic yoke material, the background magnetic field intensity of the HGMS can be increased by 6.85 % − 14.64 % compared with using DT4C super pure iron under the same excitation current conditions. The magnetic yoke with better magnetic conductivity will enhance the magnetic field utilization efficiency of the magnetic system, a reduce the excitation energy consumption, and improve the sorting performance of HGMS.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"State and parameter estimation of a dynamic froth flotation model using industrial data","authors":"","doi":"10.1016/j.mineng.2024.109059","DOIUrl":"10.1016/j.mineng.2024.109059","url":null,"abstract":"<div><div>This paper investigates an observable dynamic model of froth flotation circuits aimed at online state and parameter estimation and model-based control. The aim is to estimate the model states and parameters online from industrial data. However, in light of limitations in the plant data, additional model analysis is conducted. It is shown that without online compositional measurements, only the states and parameters of a reduced model can be estimated online. The reduced model lumps all recovery mechanisms into a single empirical equation. The reduced model is used to develop a moving horizon estimator (MHE) which is implemented on the industrial data. The state and parameter estimates from the MHE are used to evaluate the model prediction accuracy over a receding control horizon as would be done in model predictive control (MPC). Given the uncertainty of the available data, unmeasured disturbances and missing online measurements, the estimation and prediction results are reasonably accurate, at least in a qualitative sense. If accurate and reliable online measurements are available for estimation, the reduced model shows potential to be used for long-term model-based supervisory control of a flotation circuit.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Developing a robust indicator to evaluate circular economy through reuse strategy: A case study of using water treatment sludge as a coagulant for dewatering of iron ore tailings slurry","authors":"","doi":"10.1016/j.mineng.2024.109062","DOIUrl":"10.1016/j.mineng.2024.109062","url":null,"abstract":"<div><div>Due to the lack of tools, which are simple enough to assess the reuse strategy in the concept of circular economy (CE), in the present paper, reuse efficiency index (REI) was introduced as a new indicator, inspired by previously developed indexes, namely circular economy index (CEI) and value-based resource efficiency (VRE). The REI, as a measure of economic efficiency of reuse strategy, is the ratio of the net value obtained from the reuse of end of life (EOL) product instead of using a new product over the value of materials and energy inputs required to reproduce the EOL product. To calculate REI for any specific EOL product, information regarding mass, physicochemical properties and operational data on the consumption of energy, which are mainly available in the financial archives of companies, is crucial and the market price of EOL product must also be predicted. In another part of the study, the reuse of ferric chloride-based water treatment sludge (FCS) as a coagulant, instead of using high cost polymeric coagulant, for iron ore tailings slurry dewatering was evaluated through REI. The results showed that depending on the market prices of energy and materials as well as the iron (FeCl<sub>3</sub>) content in the FCS, the REI could vary between 0.51 and 1.04, corresponding to 51–104% added value. Overall, REI is based on accessible information and its simplicity and comprehensibility makes it applicable for managers and policymakers to invest and create technologies for reaching closed-loop cycles in the concept of CE through reuse action.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The mechanism of selective separation of stibnite and arsenopyrite by Cu2+ coordination assembly KBX collector","authors":"","doi":"10.1016/j.mineng.2024.109056","DOIUrl":"10.1016/j.mineng.2024.109056","url":null,"abstract":"<div><div>The similar physicochemical properties of stibnite and arsenopyrite resulted in the difficult separation by traditional collectors in flotation. Hence, this study utilized Cu<sup>2+</sup> and potassium butyl xanthate (KBX) coordinate assembly to form a novel Cu-KBX complex collector, investigating its properties, conformation, and its role in flotation separation of stibnite and arsenopyrite, as well as its diverse adsorption behavior on mineral surfaces. The stable Cu-KBX complex solution was formed when the molar ratio of Cu<sup>2+</sup> to KBX was 1:2, exhibiting a network-like structure at that time. The micro-flotation results showed that at pH 5, the grade of Sb in the concentrate was as high as 61.08 %, with As content at only 4.65 %, enabling effective separation of stibnite and arsenopyrite. Furthermore, the Cu-KBX complex exhibited a reticulated structure at the stibnite surface, while it adhered in a granular fashion on the arsenopyrite surface. FTIR analysis confirmed stronger chemisorption of Cu-KBX onto stibnite compared to arsenopyrite. XPS results indicated that Cu-S was the main collecting component. However, a weak Fe(II)-S substance was found on the arsenopyrite interface, likely due to Fe<sup>3+</sup> oxidizing in the slurry with the Cu-KBX complex. Therefore, this disruption of the Cu-KBX complex structure by Fe<sup>3+</sup> in arsenopyrite sharply reduced its adsorption on arsenopyrite, enhancing the selective separation of stibnite and arsenopyrite.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Optimizing flotation froth image segmentation via parallel branch network and hybrid loss supervision","authors":"","doi":"10.1016/j.mineng.2024.109060","DOIUrl":"10.1016/j.mineng.2024.109060","url":null,"abstract":"<div><div>Flotation is a crucial technology for fine coal separation, and accurately acquiring bubble size information during the flotation process is essential for monitoring flotation conditions and achieving intelligent control. However, existing semantic segmentation models encountered issues with boundary disconnection when segmenting flotation bubbles, resulting in deviations between the extracted bubble sizes and their true values. To address the aforementioned challenges, a semantic segmentation model was proposed to maintain high-resolution feature maps throughout the network by designing a parallel branch network structure. Additionally, a ConvTranspose module was proposed to preserve the detailed feature information of images while gradually enhancing the resolution of feature maps. In the model training phase, a hybrid loss function combining pixel classification loss with shape similarity loss was proposed to alleviate the sample imbalance problem caused by the substantial difference in the number of pixels between bubble boundaries and the interior of bubbles. Moreover, since traditional semantic segmentation evaluation metrics, such as MIoU, lack a mechanism for measuring bubble boundary continuity and cannot effectively penalize the problem of boundary disconnection, this paper proposed a new evaluation method for assessing the segmentation performance of flotation froth images. To comprehensively evaluate the effectiveness of the proposed method, this paper conducted tests using flotation froth images collected from actual production processes. Compared with existing methods, the segmentation model proposed in this paper exhibited clear superiority in mitigating the problem of bubble boundary disconnection. The prediction error for the number of bubbles was 6.38 %, which is significantly better than other methods.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Prospect for recycling critical elements in combustion residues of coal, lignite, and biomass feedstocks","authors":"","doi":"10.1016/j.mineng.2024.109063","DOIUrl":"10.1016/j.mineng.2024.109063","url":null,"abstract":"<div><div>The combustion residues derived from coal, lignite, biomass, and spent wash could be recycled to extract critical elements required for energy transition. To recycle these elements from the combustion residues, it is necessary to understand their chemical mode of occurrence in the ash. This study presents the content of critical elements and their chemical mode of occurrence in coal, lignite, biomass, and incinerator ash. Lignite ash, rich in Ca and Si, offers Sc (31 mg/kg) and Nd (212 mg/kg), while coal ash, dominated by Si and Al, contains Ga (44.8 mg/kg). Biomass and spent wash ash, characterized by K, Ca, and S, present substantial potential for potash and Sc. Lignite ash primarily contains rare earth elements (REEs) in metal oxide-bound fractions, whereas in coal ash, the REEs are associated with the hard mullite or quartz phase. Biomass and incinerator ashes have significant water-soluble potash, and the Sc is associated with metal oxides. Green acids can extract critical elements from lignite, biomass, and incinerator ashes, but extracting from coal ash requires harsh conditions. Future research should concentrate on green extraction processes considering the chemical patterns of occurrence of critical elements.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142533337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Processing of low-grade ultramafic nickel ores: A critical review","authors":"","doi":"10.1016/j.mineng.2024.108976","DOIUrl":"10.1016/j.mineng.2024.108976","url":null,"abstract":"<div><div>Nickel (Ni) is used to fabricate a variety of products, including various alloys- stainless steel being a prominent one, batteries, and catalysts. Global Ni demand is projected to increase by up to 350% by the year 2050 relative to 2017, while the high-grade Ni sulfide ore deposits have largely been depleted. The increasing demand for Ni from emerging markets such as electric vehicles and energy storage requires newer sources of nickel. In addition, the systemic exploration of nickel sulfide ores has led to resources that are more challenging to process due to the higher impurities. The processing complexity necessitates the development of new technologies and pathways to sustainably process globally abundant low-grade Ni sulphide ores. This work systematically reviews and compares various Ni resources in terms of their composition, occurrence, challenges, and opportunities. The conventional processing methods of low-grade ultramafic Ni ore are discussed along with emerging technologies. Key challenges remaining and future perspectives that tie together fundamental and applied research are also provided.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of solids concentration and operational variables on the performance of a geometrically optimized concentrator hydrocyclone employing a pseudoplastic fluid","authors":"","doi":"10.1016/j.mineng.2024.109046","DOIUrl":"10.1016/j.mineng.2024.109046","url":null,"abstract":"<div><div>The employment of hydrocyclones in thickening operations is an attractive option when compared to centrifuges and filters due to their low operating, maintenance, and acquisition costs. However, the performance of hydrocyclone separation is impaired as the concentration of solids and the viscosity of the suspension increases. Using geometric optimization techniques, the Federal University of Uberlândia developed one concentrator hydrocyclone named HC. When working with diluted and Newtonian slurries, the HC could generate a stream 45 times more concentrated than the one fed into it. In this study, the HC performance was evaluated when operating pseudoplastic fluids containing up to 10% solids by volume. The combination of the underflow diameter and vortex finder length with an adequate supply of pressure energy maintained the thickening potential of the HC even when the rheology of the fluid was changed. For different working suspensions, the HC hydrocyclone achieved a minimum water split to underflow of 5%, a maximum concentration ratio of 7.0, and a maximum efficiency of 49%. The encouraging results obtained by the HC validated the benefits of the geometric optimization, as they point to a significant advance in the thickening operation of non–Newtonian sludges with a flow behavior index greater than 0.5.</div></div>","PeriodicalId":18594,"journal":{"name":"Minerals Engineering","volume":null,"pages":null},"PeriodicalIF":4.9,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}