IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)最新文献

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Nanostructured materials for energy storage and energy conversion devices 用于能量存储和能量转换装置的纳米结构材料
D. Reisner, T. D. Xiao, P. R. Strutt, A. J. Salkind
{"title":"Nanostructured materials for energy storage and energy conversion devices","authors":"D. Reisner, T. D. Xiao, P. R. Strutt, A. J. Salkind","doi":"10.1109/IECEC.1997.661958","DOIUrl":"https://doi.org/10.1109/IECEC.1997.661958","url":null,"abstract":"US Nanocorp, Inc. (USN) has developed an aqueous solution reaction (ASR) technique scalable for high volume production of nanostructured materials (n-materials) for a wide range of applications. By definition, nanophase materials have at least one physical dimension less than 10 nanometers (nm) in length, an attribute which imparts exceptional properties to them because the particle dimensions are close to atomic dimensions and there are a very high fraction of atoms residing at nanocrystalline grain boundaries. The high surface area of these materials has significant implications with respect to energy storage devices with electrochemical active sites (batteries, ultracapacitors) and energy conversion devices depending on catalytic sites or defect structure (e.g., fuel cells and thermoelectric devices). Potential application areas in both energy conversion and energy storage are discussed. Morphological studies of manganese dioxide have revealed the existence of both nanoporosity and mesoporosity within unusual superstructures comprised of nanorod building blocks. Nanophase nickel hydroxide has also been synthesized. Preliminary electrochemical studies are reported.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"52 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126054075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Carbon monoxide poisoning of proton-exchange membrane fuel cells 质子交换膜燃料电池的一氧化碳中毒
A. Rodrigues, J. C. Amphlett, R. Mann, B. Peppley, P. Roberge
{"title":"Carbon monoxide poisoning of proton-exchange membrane fuel cells","authors":"A. Rodrigues, J. C. Amphlett, R. Mann, B. Peppley, P. Roberge","doi":"10.1109/IECEC.1997.660236","DOIUrl":"https://doi.org/10.1109/IECEC.1997.660236","url":null,"abstract":"The platinum-alloy catalyst used in proton-exchange membrane (PEM) fuel cell anodes is highly susceptible to carbon monoxide (CO) poisoning. CO reduces the catalyst activity by blocking active catalyst sites normally available for hydrogen chemisorption and dissociation. The reaction kinetics at the anode catalyst surface can be used to estimate the decrease in cell voltage due to various levels of CO contamination in the inlet fuel stream. Literature data on the effects of CO-contaminated fuel streams on PEM fuel cell performance have been reviewed and analysed in an attempt to further understand the electrochemical properties of the CO adsorption process. A fuel cell performance model of a bipolar, Nafion 117 PEM fuel cell stack has been developed which predicts equilibrium cell output voltage as a function of current density and partial pressure of CO. The model contains both empirical and mechanistic parameters and evolved from a steady-state electrochemical model for a PEM fuel cell fed with a CO-free anode gas. Reaction kinetics and equilibrium surface coverage have been incorporated into the electrochemical model to predict the decrease in fuel cell performance at equilibrium. The effects of CO were studied at various concentrations of CO in hydrogen as the anode feed gas. Literature data were used to develop the model parameters and the resulting model is used to compare the model-predicted voltages, with and without CO, to data found in the literature.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"116 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128040961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 88
Performance of a 10 kW underwater diesel engine system 10千瓦水下柴油机系统的性能
I. Potter, G. Reader, C.E. Bouren
{"title":"Performance of a 10 kW underwater diesel engine system","authors":"I. Potter, G. Reader, C.E. Bouren","doi":"10.1109/IECEC.1997.656680","DOIUrl":"https://doi.org/10.1109/IECEC.1997.656680","url":null,"abstract":"To operate in a nonair environment, a diesel engine must be supplied with a synthetic atmosphere which mimics the role of normally aspirated air. To determine the optimum synthetic atmosphere mixture, an intensive experimental investigation has been carried out by the authors using a specially developed test rig. Provision has been made on the test rig so that a number of different composition synthetic atmospheres can be produced. In this way, it has been possible to measure the effects of carbon dioxide ratios on the performance of the diesel engine. In addition to the shaft performance, power and fuel efficiency, exhaust gas emissions and combustion noise have also been measured. This paper details the operational principle of an underwater diesel engine and reports on the performance of such an engine whilst operating with high intake carbon dioxide levels.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121257454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Accelerated testing for extended service AMTEC cells 延长服务AMTEC电池的加速测试
R.C. Svedberg, D.A. Schaupner, A. Appleby
{"title":"Accelerated testing for extended service AMTEC cells","authors":"R.C. Svedberg, D.A. Schaupner, A. Appleby","doi":"10.1109/IECEC.1997.661944","DOIUrl":"https://doi.org/10.1109/IECEC.1997.661944","url":null,"abstract":"AMTEC cells are built with readily available materials, /spl beta/''-alumina, stainless steel, Mo, Ta, TiCuNi and TiNi brazes, and TiN electrodes. The long term cell performance is dependent on the stability and inertness of these materials in the high temperature Na environment. The task of selecting materials and verifying that they will perform for long times (15 years for a deep space probe) is addressed. Accelerated testing methods and models to utilize the accelerated test data are being developed. A six and twelve month accelerated test plan to evaluate the BASE/Braze/Electrode/Current Collector (BASE Assembly) interfaces in Na vapor at 1200, 1100, and 1000 K is described. An accelerated wick testing program is also discussed. The as-built BASE assembly braze interfaces have been evaluated. TiN electrodes, exposed for about 4000 hours at 1073 K are examined. This information illustrates the direction being taken for evaluating life test results and developing models for life predictions.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"33 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127205248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
A manual of recommended practices for hydrogen energy systems 氢能源系统推荐操作手册
W. Hoagland, S. Leach
{"title":"A manual of recommended practices for hydrogen energy systems","authors":"W. Hoagland, S. Leach","doi":"10.1109/IECEC.1997.656727","DOIUrl":"https://doi.org/10.1109/IECEC.1997.656727","url":null,"abstract":"The author describes how W. Hoagland & Associates is developing, under subcontract to the US Department of Energy, a manual of recommended practices for hydrogen energy systems comprised of a compendium of current knowledge and recent experience as well as guidelines for the design and operation of hydrogen demonstration projects. The manual will be comprehensive in nature, reviewed and approved by credible organizations, and is intended to serve in the interim while a more formal standards process progresses.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"232 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116873487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Regeneration of zinc anodes for the Electric Fuel(R) zinc-air refuelable EV battery system 电动汽车燃料(R)锌-空气可燃料电池系统锌阳极的再生
B. Koretz, J. Goldstein
{"title":"Regeneration of zinc anodes for the Electric Fuel(R) zinc-air refuelable EV battery system","authors":"B. Koretz, J. Goldstein","doi":"10.1109/IECEC.1997.661884","DOIUrl":"https://doi.org/10.1109/IECEC.1997.661884","url":null,"abstract":"The Electric Fuel Limited (EFL) refuelable zinc-air battery system is currently being tested in a number of electric vehicle demonstration projects, the largest of which is a field test of zinc-air postal vans sponsored chiefly by Deutsche Post AG (the German Post Office). The zinc-air battery is not recharged electrically, but rather is 'refueled' through a series of mechanical and electrochemical steps that will require a special infrastructure in commercial application. As part of the German Post Office field test program, Electric Fuel designed and constructed a pilot zinc anode regeneration plant in Bremen, Germany. This plant is capable of servicing up to 100 commercial vans per week, which is adequate for the field test vehicle fleet. This paper describes the design and operation of each of the areas and devices within the plant.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125884959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
High efficiency multifuel combustor with potential for commercial and military applications [AMTEC] 具有商业和军事应用潜力的高效多燃料燃烧器[AMTEC]
R. Mital, R. Sievers
{"title":"High efficiency multifuel combustor with potential for commercial and military applications [AMTEC]","authors":"R. Mital, R. Sievers","doi":"10.1109/IECEC.1997.661897","DOIUrl":"https://doi.org/10.1109/IECEC.1997.661897","url":null,"abstract":"The conceptual design of a novel, outward-flowing, cylindrical laminar flame multifuel combustor, expected to produce ultrahigh temperature uniformity and low pollutant emissions, is presented. A stretched laminar tubular flame was established by injecting a lean gaseous fuel air mixture uniformly in the radial direction from a central porous tube into an annular combustion space formed by an outer tube. Measurements of concentrations of major gaseous species using sampling and chromatography and temperature using thermocouples and an infrared pyrometer revealed that all scalar properties are independent of distance along the tube in this novel burner. Multi-fuel capability including military logistics fuels will make the present burner even more desirable. A modification that will keep the system self sufficient and will not require the use of pressurized or ultrasonic atomizers for liquid fuel combustion is presented. The design of a power system that integrates this novel burner and counterflow recuperator with alkali metal thermoelectric converter (AMTEC) cells to produce 200 W of power with overall efficiencies between 14% and 18% is also conceptually demonstrated.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121760987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quantifying and minimizing entropy generation in AMTEC cells 定量和最小化熵产生在AMTEC细胞
T.J. Hendricks, Chendong Huang
{"title":"Quantifying and minimizing entropy generation in AMTEC cells","authors":"T.J. Hendricks, Chendong Huang","doi":"10.1109/IECEC.1997.661933","DOIUrl":"https://doi.org/10.1109/IECEC.1997.661933","url":null,"abstract":"Entropy generation in an AMTEC cell represents inherent power loss to the AMTEC cell. Minimizing cell entropy generation directly maximizes cell power generation and efficiency. An internal project is on-going at AMPS to identify, quantify and minimize entropy generation mechanisms within an AMTEC cell, with the goal of determining cost-effective design approaches for maximizing AMTEC cell power generation. Various entropy generation mechanisms have been identified and quantified. The project has investigated several cell design techniques in a solar-driven AMTEC system to minimize cell entropy generation and produce maximum power cell designs. In many cases, various sources of entropy generation are interrelated such that minimizing entropy generation requires cell and system design optimization. Some of the tradeoffs between various entropy generation mechanisms are quantified and explained and their implications on cell design are discussed. The relationship between AMTEC cell power and efficiency and entropy generation is presented and discussed.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"109 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123110167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Numerical simulation of coupled electrochemical and transport processes in battery systems 电池系统中电化学与输运耦合过程的数值模拟
B. Liaw, W. Gu, Chaoyang Wang
{"title":"Numerical simulation of coupled electrochemical and transport processes in battery systems","authors":"B. Liaw, W. Gu, Chaoyang Wang","doi":"10.1109/IECEC.1997.661888","DOIUrl":"https://doi.org/10.1109/IECEC.1997.661888","url":null,"abstract":"Advanced numerical modeling to simulate dynamic battery performance characteristics for several types of advanced batteries is being conducted using computational fluid dynamics (CFD) techniques. The CFD techniques provide efficient algorithms to solve a large set of highly nonlinear partial differential equations that represent the complex battery behavior governed by coupled electrochemical reactions and transport processes. We have successfully applied such techniques to model advanced lead-acid, Ni-Cd and Ni-MH cells. In this paper, we briefly discuss how the governing equations were numerically implemented, show some preliminary modeling results, and compare them with other modeling or experimental data reported in the literature. More importantly, we describe the advantages and implications using the CFD techniques and their capabilities in future battery applications.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"25 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129983306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Fuzzy-neural network based short term peak and average load forecasting (STPALF) system with network security 基于模糊神经网络的短期峰值和平均负荷预测(STPALF)系统
S. Mandal, A. Agrawal
{"title":"Fuzzy-neural network based short term peak and average load forecasting (STPALF) system with network security","authors":"S. Mandal, A. Agrawal","doi":"10.1109/IECEC.1997.656766","DOIUrl":"https://doi.org/10.1109/IECEC.1997.656766","url":null,"abstract":"In this paper, an attempt is made to forecast load using fuzzy neural network (FNN) for an integrated power system. Here, the proposed system uses a two stage FNN for short-term peak and average load forecasting (STPALF). The first stage FNN deals with the load forecasting and the second stage algorithm can be worked independently for power network security. This technique is used to forecast load accurately on weekdays as well as holidays, weekends and some special occasions considering historical data of load and weather information and also take necessary control action for power network security.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"50 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132163145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
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