Materials最新文献

{"title":"Effect of Hydride Types on the Fracture Behavior of a Novel Zirconium Alloy Under Different Hydrogen-Charging Current Densities.","authors":"Kun Zhang, Hang Fan, Baifeng Luan, Ping Chen, Bin Jia, Pengwan Chen, Hao Wang","doi":"10.3390/ma18020467","DOIUrl":"10.3390/ma18020467","url":null,"abstract":"<p><p>Hydrogen embrittlement is a critical issue for zirconium alloys, which receives long-term attention in their applications. The formation of brittle hydrides facilitates crack initiation and propagation, thereby significantly reducing the material's ductility. This study investigates the tensile properties and hydride morphology of a novel zirconium alloy under different hydrogen-charging current densities ranging from 0 to 300 mA/cm², aiming to clarify the influence of hydrides on the fracture behavior of the alloy. The mechanical property results reveal that, as the hydrogen-charging current density increases from 0 to 100 mA/cm², the maximal elongation decreases from 24.99% to 21.87%. When the current density is further increased from 100 mA/cm² to 200 mA/cm², the maximal elongation remains basically unchanged. However, a substantial drop in elongation is observed as the hydrogen-charging current density rises from 200 mA/cm² to 300 mA/cm², decreasing from 20.77% to 15.18%, which indicates a marked deterioration in hydrogen embrittlement resistance. Subsequently, phase compositions, fracture morphology, and hydride types in the fracture region of tensile specimens were characterized. The morphology and quantity of hydrides change with increasing hydrogen-charging current density. When the hydrogen-charging current density reaches 100 mA/cm², the δ-phase hydrides form, which significantly reduces the ductility of the zirconium alloy. At a hydrogen-charging current density of 200 mA/cm², metastable ζ-phase hydrides are formed, resulting in negligible variations in the alloy's mechanical properties. However, when it comes to 300 mA/cm², stable δ-phase hydrides with diverse morphologies form, leading to a pronounced degradation in tensile performance. Finally, by integrating mechanical tests with microstructural characterization, the influence of hydrides formed under different hydrogen-charging current densities on the zirconium alloy was analyzed. With increasing hydrogen-charging current density, the maximal elongation of the specimens gradually decreases, while the tensile strength steadily increases. At a hydrogen-charging current density of 300 mA/cm², a larger amount of hydrides is formed, and the hydride type transitions completely from a mixture of δ-phase and ζ-phase hydrides to entirely δ-phase hydrides. The formation of lath-like δ-phase hydrides induces twinning structures, resulting in further lattice mismatch, which significantly reduces the maximal elongation of the zirconium alloy. Additionally, the morphology of the δ-phase hydrides changes from slender needle-like structures to lath-like structures, leading to a notable increase in internal stress, which in turn further enhances the tensile strength of the specimens.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766749/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental Investigation on Macroscopic and Microscopic Mechanical Properties of Geopolymer-Stabilized Macadam.","authors":"Hancheng Dan, Shenglong Ma, Mengjin Li, Jiawei Tan, Haoran Zhang","doi":"10.3390/ma18020454","DOIUrl":"10.3390/ma18020454","url":null,"abstract":"<p><p>Geopolymer, as a promising inorganic binding material, holds potential for use in constructing base layers for highway pavements. This study aims to evaluate the mechanical properties of geopolymer-stabilized macadam (GSM) at both the micro- and macro-scale by a series of tests, demonstrating that high-Ca GSM is a high-quality material for pavement base layers. The results demonstrated that GSM exhibits outstanding mechanical and fatigue properties, significantly surpassing those of cement-stabilized macadam (CSM). Performance improvements were particularly notable with higher binder-to-aggregate ratios. GSM derived from a high-Ca precursor achieved a relatively higher fatigue life and resistance to permanent deformation under cyclic loading, outperforming CSM. Furthermore, relationship models developed from the indirect tensile fatigue test results provide a valuable framework for evaluating GSM's long-term road performance. Microstructural analyses revealed that geopolymer features a reticulated gel structure and a denser, more continuous internal matrix, which contribute to its superior properties. The interface products of GSM, including C-A-S-H gel and C(N)-A-S-H gel, enhance mechanical interlocking and promote early strength development, accounting for its exceptional mechanical strength and fatigue resistance. These findings offer valuable insights and technical guidance for employing geopolymer as a sustainable and effective alternative to cement-stabilized macadam in base layer construction.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766898/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigating the Detachment of Glazed Ceramic Tiles Used in Buildings: A Brazilian Case Study.","authors":"Renato Freua Sahade, Priscila R M Leal, Sérgio S Lima, Paulo Sérgio da Silva, Carlos R C Lima","doi":"10.3390/ma18020465","DOIUrl":"10.3390/ma18020465","url":null,"abstract":"<p><p>Ceramic detachments in cladding systems are indicative of adhesion loss between the ceramic tiles and the substrate or its adhesive mortar due to inadequate quality workmanship, the quality of the adhesive mortar or that of the ceramic material, whether acting simultaneously or not. The shear stresses resulting from the ceramic tiles' expansion due to humidity accelerate this process. There is a shortage of studies on the quality of ceramic tiles and adhesive mortars. This study conducted elemental, physical and microstructural characterization tests on ceramic tiles and adhesive mortars that showed detachment up to two years after being laid. At first glance, the adhesive mortar samples had adequate traits and degree of hydration. The ceramic tiles, on the other hand, showed high porosity and high levels of amorphous and poorly sintered materials, with no crystalline phase. In a second analysis, scanning electron microscopy (SEM) tests associated with boiling plus autoclave moisture expansion tests executed on unused ceramic pieces of the same conformation proved to be more suitable for predicting expansion potential than standard tests. Due to the costs and difficulties in accessing and analyzing the SEM tests, chemical analysis of the ceramic tiles was executed using X-ray fluorescence (XRF) to assess the presence of the amorphous silica (free quartz) and alkaline oxides. Together with pressure and temperature determination tests (autoclave), they may represent another alternative that is easier to access and more cost-effective for predicting future expansion.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766741/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Complex Inhibitor Protection of Some Steels in Hydrochloric Acid Solutions by 1,2,4-Triazole Derivatives.","authors":"Yaroslav G Avdeev, Tatyana A Nenasheva, Andrey Y Luchkin, Andrey I Marshakov, Yurii I Kuznetsov","doi":"10.3390/ma18020464","DOIUrl":"10.3390/ma18020464","url":null,"abstract":"<p><p>The behavior of low-carbon steels (LCSs), a high-strength steel and a nickel-chromium alloy in HCl solutions in the presence of N-containing organic substances has been studied. N-containing organic substances that comprise 1,2,4-triazole in their structure (substance I and substance II) provide comprehensive protection of various steel grades from corrosion and hydrogen absorption by the metal bulk in HCl solutions under both isobaric and isochoric conditions. All the compounds studied reduce, to varying degrees, the concentration of hydrogen adsorbed and absorbed by steel in HCl solutions. The most promising way to expand the scope of application is to use substance I in HCl solutions for protecting steels from high-temperature corrosion as a mixture with hexamethylenetetramine (HMT). In 2 M HCl (100 °C) under isochoric conditions, a mixture of compound I and HMT exhibited an excellent result: the degree of protection of LCS against corrosion was 99.5%. Substance I and its mixture with HMT protect steels not only in pure HCl solutions, but also in environments contaminated with hydrogen sulfide, which is especially important for the acid stimulation of wells in oil production.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766597/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"From Powders to Performance-A Comprehensive Study of Two Advanced Cutting Tool Materials Sintered with Pressure Assisted Methods.","authors":"Kinga Momot, Piotr Klimczyk, Beata Leszczyńska-Madej, Marcin Podsiadło, Yuliia Rumiantseva, Agnieszka Gubernat","doi":"10.3390/ma18020461","DOIUrl":"10.3390/ma18020461","url":null,"abstract":"<p><p>This paper presents a comprehensive study of two tool materials designed for the machining of Inconel 718 superalloy, produced through two distinct sintering techniques: High Pressure-High Temperature (HPHT) sintering and Spark Plasma Sintering (SPS). The first composite (marked as BNT), composed of 65 vol% cubic boron nitride (cBN), was sintered from the cBN-TiN-Ti₃SiC₂ system using the HPHT technique at a pressure of 7.7 GPa. The second composite (marked as AZW) was fabricated from the Al₂O₃-ZrO₂-WC system using SPS at a pressure of 63 MPa. The final phase composition of BNT material differed significantly from the initial composition due to reactions occurred during sintering. In contrast, the phase composition of the AZW ceramic composite before and after sintering was similar. The materials exhibited high quality, as evidenced by a Young's modulus of 580 GPa for BNT and 470 GPa for AZW, along with hardness of 26 GPa for BNT and 21 GPa for AZW. Both composites were used to prepare cutting inserts that were evaluated for their performance in machining Inconel 718 alloy. While both inserts showed durability comparable to their respective reference commercial inserts, they differed in performance and price relative to one another.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766539/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanical Strength and Mechanism Analysis of Silt Soil Cured by Straw Ash-Calcium Carbide Slag.","authors":"Yue Huang, Wenyuan Xu, Yongcheng Ji, Liang Yang","doi":"10.3390/ma18020455","DOIUrl":"10.3390/ma18020455","url":null,"abstract":"<p><p>Large-scale engineering projects frequently involve pit excavation and wetland landfill operations, resulting in significant silt accumulation that occupies land and adversely affects the environment. Curing technology offers a solution for reusing this waste silt. In this study, straw ash and calcium carbide slag are proposed as effective curing agents for silt soil. Various indoor tests were conducted to evaluate the mechanical properties of the cured silt soil, while X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to analyze its mineral composition and micro-morphology. The results showed that increasing the curing agent dosage significantly improved soil strength. Specifically, at a 10% dosage, the California bearing ratio (CBR) value increased to 18.7%, which is 13.4 times higher than untreated silt soil and exceeds road specifications by 8%. At a 20% dosage, the unconfined compressive strength (UCS) value reached 1.38 MPa, meeting the ≥0.8 MPa requirement for roadbeds. Based on economic considerations, a 20% dosage of straw ash-calcium carbide slag was selected as optimal. Microscopic analysis revealed that the addition of these agents promoted the formation of hydrated calcium silicate, filling pores and enhancing the mechanical properties of the cured soil, resulting in a more dense and stable structure.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11767109/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanical Properties and Durability Performance of Low Liquid Limit Soil Stabilized by Industrial Solid Waste.","authors":"Xiaoli Wang, Xiancong Wang, Pingfeng Fu, Jinjin Shi","doi":"10.3390/ma18020469","DOIUrl":"10.3390/ma18020469","url":null,"abstract":"<p><p>To improve the mechanical and durability properties of low liquid limit soil, an eco-friendly, all-solid, waste-based stabilizer (GSCFC) was proposed using five different industrial solid wastes: ground granulated blast-furnace slag (GGBS), steel slag (SS), coal fly ash (CFA), flue-gas desulfurization (FGD) gypsum, and carbide slag (CS). The mechanical and durability performance of GSCFC-stabilized soil were evaluated using unconfined compressive strength (UCS), California bearing ratio (CBR), and freeze-thaw and wet-dry cycles. The Rietveld method was employed to analyze the mineral phases in the GSCFC-stabilized soil. The optimal composition of the GSCFC stabilizer was determined as 15% SS, 12% GGBS, 16% FGD gypsum, 36% CS, and 12% CFA. The GSCFC-stabilized soil exhibited higher CBR values, with results of 31.38%, 77.13%, and 94.58% for 30, 50, and 98 blows, respectively, compared to 27.23%, 68.34%, and 85.03% for OPC. Additionally, GSCFC-stabilized soil demonstrated superior durability under dry-wet and freeze-thaw cycles, maintaining a 50% higher UCS (1.5 MPa) and a 58.6% lower expansion rate (3.16%) after 15 dry-wet cycles and achieving a BDR of 86.86% after 5 freeze-thaw cycles, compared to 65% for OPC. Rietveld analysis showed increased hydration products (ettringite by 2.63 times, C-S-H by 2.51 times), significantly enhancing soil strength. These findings highlight the potential of GSCFC-stabilized soil for durable road sub-base applications. This research provides theoretical and technical support for the development of sustainable, cost-effective, and eco-friendly soil stabilizers as alternatives to traditional cement-based stabilizers while also promoting the synergistic utilization of multiple solid wastes.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766852/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143038664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Clamped Member Material and Thickness on Bolt Self-Loosening Under Transverse Loads.","authors":"Rashique Iftekhar Rousseau, Abdel-Hakim Bouzid","doi":"10.3390/ma18020462","DOIUrl":"10.3390/ma18020462","url":null,"abstract":"<p><p>Bolted joints, prevalent in industrial applications for component fastening, are susceptible to self-loosening-a critical issue resulting in a gradual reduction in clamping force. Gaining insight into the underlying mechanisms of self-loosening is crucial. While prior research has largely focused on evaluating component stiffness, limited attention has been given to its impact on the self-loosening behavior of bolted joints under transverse cyclic loading. This study investigates how component stiffness influences self-loosening in bolted joints by varying the material and thickness of clamped members. An experimental setup replicating real-world conditions is devised to simulate loosening caused by cyclic lateral displacement. Tests are conducted using steel and high-density polyethylene (HDPE) clamped members of different grip lengths to explore the relationship between stiffness and self-loosening. Key parameters measured include bolt axial load, transverse force on clamped members, relative displacement, and rotation between the bolt and nut. The findings provide valuable insights into the effects of stiffness across various clamped member materials and grip length combinations, which can enhance the understanding of conditions that promote loosening resistance. Moreover, by highlighting stage-II or rotational loosening, with each test resulting in complete preload loss, the study provides a comparative analysis of the influencing factors. This enables the identification of distinct loosening patterns and supports the development of improved bolted joint designs to reduce loosening.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766740/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Influence of Rice Husk Ash Incorporation on the Properties of Cement-Based Materials.","authors":"Zhiyun Guo, Zhao Chen, Xurong Yang, Lanyue Zhang, Canhua Li, Chuan He, Weihong Xu","doi":"10.3390/ma18020460","DOIUrl":"10.3390/ma18020460","url":null,"abstract":"<p><p>Rice husk ash is a kind of biomass material. Its main component is silicon dioxide, with a content of up to 80%. It has high pozzolanic activity and can react with hydroxide in cement. When treating rice husks, rice husk ash with high volcanic ash activity and a good microaggregate filling effect can be obtained by selecting a suitable incineration environment. These advantages make rice husk ash an ideal concrete admixture, replacing the traditional admixture such as fly ash and slag in concrete. This paper summarizes the preparation methods and physical and chemical properties of rice husk ash, as well as the physical and chemical properties of rice husk ash concrete, such as mechanical properties, temperature resistance, freezing resistance, permeability resistance and chemical erosion resistance. The results show that using 20% rice husk ash as a substitute material for cement improves the resistance strength, compressive strength, flexural strength, and permeability of concrete. In short, the incorporation of rice husk ash can effectively improve the performance of cement-based materials, which will be conducive to the green development of the building material industry and the implementation of the two-carbon strategy.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11766660/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Size Distribution of Zinc Oxide Nanoparticles Depending on the Temperature of Electrochemical Synthesis.","authors":"Michał Hajos, Maria Starowicz, Beata Brzychczyk, Grzegorz Basista, Sławomir Francik","doi":"10.3390/ma18020458","DOIUrl":"10.3390/ma18020458","url":null,"abstract":"<p><p>One of the methods for obtaining zinc oxide nanoparticles (ZnO NPs) is electrochemical synthesis. In this study, the anodic dissolution process of metallic zinc in alcohol solutions of LiCl was used to synthesize ZnO NPs. The products were obtained as colloidal suspensions in an electrolyte solution. Due to the small size and ionic nature of the zinc oxide molecule, colloidal nanoparticles tend to cluster into larger groupings, so the size of nanoparticles in solutions will differ from the size of nanoparticles observed in ZnO powders after solvent evaporation. The main goal of this research is to investigate the influence of the temperature of synthesis and the kind of alcohol on the size of ZnO NP micelles. Nanocrystals of zinc oxide were obtained in all tested alcohols: methanol, ethanol, and 1-propanol. The particle size was determined using the Dynamic Light Scattering (DLS) method. It was observed that the particles synthesized in methanol were the largest, followed by smaller particles in ethanol, while the smallest particles were obtained in 1-propanol. Additionally, the particles obtained in ethanol were the most uniform in size, showing the highest level of size homogeneity.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 2","pages":""},"PeriodicalIF":3.1,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11767220/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143039140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}