从农业废料中提取的生物基润滑脂:从玉米秸秆中提取的用于可持续润滑的改性纤维素。

IF 3.2 3区 材料科学 Q3 CHEMISTRY, PHYSICAL
Materials Pub Date : 2025-09-22 DOI:10.3390/ma18184413
Yuhao Fang, Gaobo Lou, Qiang Wu, Xingguo Cheng, Yifan Chen
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引用次数: 0

摘要

以纤维素和环氧大豆油(ESO)为原料,制备了绿色润滑脂。利用二苯基甲烷二异氰酸酯(diphenylmethane diisocyanate, MDI)对玉米秸秆中提取的纤维素进行功能化处理,提高了纤维素在非极性油中的相容性和增稠能力,随后分散在ESO中形成稳定的凝胶状生物基油脂。利用红外光谱(FTIR)、扫描电镜(SEM)和x射线衍射(XRD)对纤维素的功能化表面进行了表征。讨论了制备的生物基润滑脂的流变学和摩擦学特性。我们的生物基润滑脂具有优异的润滑性和抗磨性能,与商用锂基配方相比,它的摩擦更低,磨损更少。这项工作为设计可持续润滑的环保型润滑脂提供了实用指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Bio-Based Grease from Agricultural Waste: Modified Cellulose from Corn Stover for Sustainable Lubrication.

Bio-Based Grease from Agricultural Waste: Modified Cellulose from Corn Stover for Sustainable Lubrication.

Bio-Based Grease from Agricultural Waste: Modified Cellulose from Corn Stover for Sustainable Lubrication.

Bio-Based Grease from Agricultural Waste: Modified Cellulose from Corn Stover for Sustainable Lubrication.

In this study, a green lubricating grease was prepared based on cellulose and epoxidized soybean oil (ESO). The cellulose extracted from the corn stover was functionalized using diphenylmethane diisocyanate (MDI), which enhances its compatibility and thickening ability in non-polar oil, and subsequently dispersed in ESO to form a stable gel-like bio-based grease. The functionalized surface of cellulose was characterized by FTIR, SEM, and XRD. And the rheological and tribological characteristics of the prepared bio-based grease were discussed. The superior lubricity and anti-wear properties of our bio-based grease are demonstrated by its lower friction and diminished wear relative to commercial lithium-based formulations. This work provides practical guidance for designing environmentally friendly grease for sustainable lubrication.

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来源期刊
Materials
Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
5.80
自引率
14.70%
发文量
7753
审稿时长
1.2 months
期刊介绍: Materials (ISSN 1996-1944) is an open access journal of related scientific research and technology development. It publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Materials provides a forum for publishing papers which advance the in-depth understanding of the relationship between the structure, the properties or the functions of all kinds of materials. Chemical syntheses, chemical structures and mechanical, chemical, electronic, magnetic and optical properties and various applications will be considered.
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